CN1075076C - 金属茂化合物及其制法和在烯烃聚合催化剂中的应用 - Google Patents

金属茂化合物及其制法和在烯烃聚合催化剂中的应用

Info

Publication number
CN1075076C
CN1075076C CN96190226A CN96190226A CN1075076C CN 1075076 C CN1075076 C CN 1075076C CN 96190226 A CN96190226 A CN 96190226A CN 96190226 A CN96190226 A CN 96190226A CN 1075076 C CN1075076 C CN 1075076C
Authority
CN
China
Prior art keywords
substituting group
hydrogen atom
formula
compound
metallocenic compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN96190226A
Other languages
English (en)
Chinese (zh)
Other versions
CN1150430A (zh
Inventor
L·雷斯康尼
F·皮蒙特西
I·E·尼芬特夫
P·V·伊夫陈科
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Technology Co BV
Original Assignee
Montell Technology Co BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=11370281&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CN1075076(C) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Montell Technology Co BV filed Critical Montell Technology Co BV
Publication of CN1150430A publication Critical patent/CN1150430A/zh
Application granted granted Critical
Publication of CN1075076C publication Critical patent/CN1075076C/zh
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CN96190226A 1995-01-23 1996-01-17 金属茂化合物及其制法和在烯烃聚合催化剂中的应用 Expired - Fee Related CN1075076C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ITMI95A000099 1995-01-23
ITMI950099A IT1272923B (it) 1995-01-23 1995-01-23 Composti metallocenici,procedimento per la loro preparazione,e loro utilizzo in catalizzatori per la polimerizzazione delle olefine

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CNB011208953A Division CN1196721C (zh) 1995-01-23 2001-06-07 金属茂化合物及其制法和在烯烃聚合催化剂中的应用

Publications (2)

Publication Number Publication Date
CN1150430A CN1150430A (zh) 1997-05-21
CN1075076C true CN1075076C (zh) 2001-11-21

Family

ID=11370281

Family Applications (2)

Application Number Title Priority Date Filing Date
CN96190226A Expired - Fee Related CN1075076C (zh) 1995-01-23 1996-01-17 金属茂化合物及其制法和在烯烃聚合催化剂中的应用
CNB011208953A Expired - Fee Related CN1196721C (zh) 1995-01-23 2001-06-07 金属茂化合物及其制法和在烯烃聚合催化剂中的应用

Family Applications After (1)

Application Number Title Priority Date Filing Date
CNB011208953A Expired - Fee Related CN1196721C (zh) 1995-01-23 2001-06-07 金属茂化合物及其制法和在烯烃聚合催化剂中的应用

Country Status (24)

Country Link
US (3) US6051728A (https=)
EP (1) EP0751946B2 (https=)
JP (1) JP3838662B2 (https=)
KR (2) KR100418106B1 (https=)
CN (2) CN1075076C (https=)
AR (1) AR000776A1 (https=)
AU (1) AU700256B2 (https=)
BG (1) BG100904A (https=)
BR (1) BR9606373A (https=)
CA (1) CA2186232A1 (https=)
CZ (1) CZ309596A3 (https=)
DE (1) DE69617543T3 (https=)
ES (1) ES2167539T5 (https=)
FI (1) FI963759A0 (https=)
HU (1) HUP9602907A3 (https=)
IL (1) IL116853A (https=)
IT (1) IT1272923B (https=)
MX (1) MX9604229A (https=)
PL (1) PL185055B1 (https=)
RU (1) RU2177948C2 (https=)
TR (1) TR199600720T1 (https=)
TW (1) TW319777B (https=)
WO (1) WO1996022995A1 (https=)
ZA (1) ZA96485B (https=)

Families Citing this family (61)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19533336A1 (de) * 1995-09-11 1997-03-13 Basf Ag Verfahren zur Herstellung von Propen/But-1-en-Copolymeren
DE19533337A1 (de) * 1995-09-11 1997-03-13 Basf Ag Propen/But-1-en-Copolymere
JP3566819B2 (ja) * 1996-10-04 2004-09-15 関東化学株式会社 新規な有機遷移金属化合物
DE19644039A1 (de) * 1996-10-31 1998-05-07 Hoechst Ag Metallocene
TR199901635T2 (xx) * 1996-11-15 2000-02-21 Montell Technology Company Bv Heterosiklik metalosenler ve polimerizasyon kataliz�rleri.
US5900497A (en) * 1996-12-20 1999-05-04 Union Carbide Chemicals & Plsatics Technology Corporation Process for preparing metallocene procatalysts
BR9804807A (pt) * 1997-03-29 1999-08-17 Montell Technology Company Bv Compostos metalocenos e catalisadores para a polimeraza-Æo de olefinas
AT405834B (de) 1997-10-09 1999-11-25 Borealis Ag Metallocene mit ferrocenyl-substituierten brücken und deren einsatz für die olefinpolymerisation
DE19748388A1 (de) * 1997-11-03 1999-05-06 Borealis Polymere Holding Gmbh Metallocene mit ferrocenyl-substituierten Brücken und deren Einsatz für die Olefinpolymerisation
CA2294239A1 (en) 1998-04-21 1999-10-28 Montell Technology Company B.V. Process for the preparation of copolymers of ethylene with alpha-olefins
EP1017729B1 (en) * 1998-07-02 2005-09-14 Basell Polyolefine GmbH Process for the preparation of substantially amorphous alpha-olefin polymers, compositions containing them and process for the preparation of bridged ligand
DE19922020A1 (de) * 1999-05-12 2000-11-16 Targor Gmbh Übergangsmetallverbindung, Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen
WO2001062764A1 (en) 2000-02-24 2001-08-30 Basell Technology Company B.V. Organometallic compound useful as cocatalyst for polymerizing olefins
KR20020007419A (ko) 2000-03-22 2002-01-26 간디 지오프레이 에이치. 이소택틱 프로필렌 중합체 및 감소된 이소택틱성을 갖는유연성 프로필렌 중합체의 열가소성 조성물 및 그 제조방법
WO2001090205A1 (en) 2000-05-24 2001-11-29 Basell Technology Company B.V. Propylene polymers and process for the preparation thereof
US6673869B2 (en) 2000-07-27 2004-01-06 Basell Poliolefine Italia S.P.A. Transparent elastomeric thermoplastic polyolefin compositions
EP1265933B1 (en) 2000-12-22 2008-08-13 Basell Polyolefine GmbH Catalyst components for the polymerization of olefins
EP1355958A2 (en) 2000-12-22 2003-10-29 Basell Poliolefine Italia S.p.A. Process for the preparation of porous polymers and polymers obtainable thereof
DE60202524T2 (de) 2001-05-21 2005-06-30 Basell Polyolefine Gmbh Katalysatorsystem für die polymerisierung von olefinen
US6936675B2 (en) * 2001-07-19 2005-08-30 Univation Technologies, Llc High tear films from hafnocene catalyzed polyethylenes
JP4020862B2 (ja) * 2001-07-19 2007-12-12 ユニベーション・テクノロジーズ・エルエルシー コモノマー少量組込み触媒とコモノマー多量組込み触媒を含有する混合メタロセン触媒系
CA2454060A1 (en) 2001-07-19 2003-01-30 Univation Technologies, Llc Low comonomer incorporating metallocene catalyst compounds
AU2002320633B2 (en) * 2001-07-19 2005-08-25 Univation Technologies, Llc Polyethylene films with improved physical properties
WO2003046022A1 (en) 2001-11-27 2003-06-05 Basell Polyolefine Gmbh Process for the treatment of polymer compositions
RU2214415C1 (ru) * 2002-05-13 2003-10-20 Общество с ограниченной ответственностью "Научно-исследовательская лаборатория "Синор" Способ получения галогенидов металлоценов (варианты)
MXPA04012699A (es) * 2002-06-26 2005-03-23 Basell Poliolefine Spa Composiciones de poliolefina resistentes a impactos.
EP1517954B1 (en) 2002-06-26 2014-05-28 Basell Poliolefine Italia S.r.l. Impact-resistant polyolefin compositions
US7449246B2 (en) * 2004-06-30 2008-11-11 General Electric Company Barrier coatings
JP2006502260A (ja) * 2002-10-10 2006-01-19 バセル ポリオレフィン ジーエムビーエイチ エチレンの共重合方法
WO2004046214A2 (en) * 2002-10-15 2004-06-03 Exxonmobil Chemical Patents Inc. Multiple catalyst system for olefin polymerization and polymers produced therefrom
US7550528B2 (en) 2002-10-15 2009-06-23 Exxonmobil Chemical Patents Inc. Functionalized olefin polymers
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
US7541402B2 (en) 2002-10-15 2009-06-02 Exxonmobil Chemical Patents Inc. Blend functionalized polyolefin adhesive
BRPI0409738B1 (pt) 2003-04-17 2014-01-21 Processo contínuo para a polimerização de olefinas em um reator de leito fluidizado
JP4709748B2 (ja) 2003-07-04 2011-06-22 バーゼル・ポリオレフィン・ゲーエムベーハー オレフィン重合方法
EP1564226A1 (en) 2004-02-16 2005-08-17 Stichting Dutch Polymer Institute Titanocene-based catalyst system
US7943716B2 (en) 2004-03-12 2011-05-17 Basell Polyolefine Gmbh Process for polymerizing 1-hexene or higher alpha-olefins
BRPI0508155A (pt) 2004-03-12 2007-08-07 Basell Polyolefine Gmbh sistema catalìtico para a polimerização de olefinas
JP2007528925A (ja) 2004-03-12 2007-10-18 バセル ポリオレフィン ジーエムビーエイチ １−ヘキセンまたは高級α−オレフィンの重合方法
EP1655314A1 (en) 2004-11-09 2006-05-10 Basell Polyolefine GmbH Process for the preparation of 1-butene/propylene copolymers
WO2006053911A1 (en) 2004-11-22 2006-05-26 Basell Polyolefine Gmbh Propylene based terpolymers
US7300994B2 (en) * 2004-11-22 2007-11-27 Cornell Research Foundation, Inc. Isotactic polypropylene containing polymers
EP1825036A1 (en) * 2004-12-13 2007-08-29 Basell Poliolefine Italia S.r.l. Polyolefin composition, fibres and nonwoven fabrics
JP2008525651A (ja) * 2004-12-23 2008-07-17 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ 弾性を有する繊維
US7026494B1 (en) 2005-01-10 2006-04-11 Chevron Phillips Chemical Company, Lp Polymerization catalysts for producing high melt index polymers without the use of hydrogen
ATE519788T1 (de) 2007-12-18 2011-08-15 Basell Polyolefine Gmbh Gasphasenverfahren zur polymerisation von alpha- olefinen
WO2009088033A1 (ja) * 2008-01-11 2009-07-16 Mitsui Chemicals, Inc. 変性プロピレン樹脂
US8378028B2 (en) * 2008-02-29 2013-02-19 Basell Poliolefine Italia, s.r.l. Polyolefin compositions
CN102216349A (zh) * 2008-11-18 2011-10-12 北欧化工公司 在茂金属催化剂存在下所生产的丙烯-丁烯无规共聚物
EP2341086A1 (en) † 2009-12-30 2011-07-06 Borealis AG Bopp-film
EP3022235B1 (en) 2013-07-17 2020-04-08 ExxonMobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
US9458260B2 (en) 2013-07-17 2016-10-04 Exxonmobil Chemical Patents Inc. Process using substituted metallocene catalysts and products therefrom
US9938364B2 (en) 2013-07-17 2018-04-10 Exxonmobil Chemical Patents Inc. Substituted metallocene catalysts
EP3539993A1 (en) 2013-07-17 2019-09-18 ExxonMobil Chemical Patents Inc. Cyclopropyl substituted metallocene catalysts
US9458254B2 (en) 2013-07-17 2016-10-04 Exxonmobil Chemical Patents Inc. Substituted metallocene catalysts
WO2015009472A1 (en) 2013-07-17 2015-01-22 Exxonmobil Chemcal Patents Inc. Metallocenes and catalyst compositions derived therefrom
WO2015047030A1 (ko) * 2013-09-30 2015-04-02 주식회사 엘지화학 프로필렌-1-부텐 공중합체의 제조방법 및 이로부터 수득되는 프로필렌-1-부텐 공중합체
KR101768193B1 (ko) * 2014-12-15 2017-08-16 주식회사 엘지화학 메탈로센 담지 촉매 및 이를 이용하는 폴리올레핀의 제조 방법
KR101826253B1 (ko) 2015-07-15 2018-02-06 한화케미칼 주식회사 메탈로센 화합물 및 이의 제조방법
MY191910A (en) * 2016-12-05 2022-07-18 Exxonmobil Chemical Patents Inc Broad orthogonal distribution metallocene polyethylenes for films
US11518824B2 (en) 2017-10-11 2022-12-06 Basell Polyolefine Gmbh Supported catalyst system

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0416566A2 (de) * 1989-09-07 1991-03-13 Hoechst Aktiengesellschaft Verfahren zur Herstellung eines Polyolefinwachses
EP0485821A1 (de) * 1990-11-12 1992-05-20 Hoechst Aktiengesellschaft Metallocene mit Liganden aus 2-substituierten Indenylderivaten, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren
EP0485823A1 (de) * 1990-11-12 1992-05-20 Hoechst Aktiengesellschaft 2-Substituierte Bisindenylmetallocene, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren bei der Olefinpolymerisation
EP0516108A2 (en) * 1991-05-29 1992-12-02 Dow Corning Toray Silicone Company, Limited Hexenyl-containing silicone resin and method for its preparation
EP0588208A2 (de) * 1992-09-12 1994-03-23 Hoechst Aktiengesellschaft Polyolefin-Formmasse mit breitem Schmelzbereich, Verfahren zu ihrer Herstellung und ihre Verwendung

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ZA844157B (en) * 1983-06-06 1986-01-29 Exxon Research Engineering Co Process and catalyst for polyolefin density and molecular weight control
DE3443087A1 (de) * 1984-11-27 1986-05-28 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von polyolefinen
US4668773A (en) * 1985-03-25 1987-05-26 Northwestern University Organolanthanide catalysts
EP0284708B1 (en) * 1987-04-03 1996-01-31 Fina Technology, Inc. Metallocene catalyst systems for olefin polymerization having a silicon hydrocarbyl bridge.
US4892851A (en) * 1988-07-15 1990-01-09 Fina Technology, Inc. Process and catalyst for producing syndiotactic polyolefins
DE68928696T2 (de) * 1988-12-26 1998-12-03 Mitsui Chemicals, Inc., Tokio/Tokyo Olefin-kopolymer und verfahren zur herstellung
US5026798A (en) * 1989-09-13 1991-06-25 Exxon Chemical Patents Inc. Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system
IT1249008B (it) * 1990-06-27 1995-02-11 Himont Inc Copolimeri cristallini sindiotattici del propilene
AU9159191A (en) * 1990-12-28 1992-08-17 Exxon Chemical Patents Inc. Syndiotactic polypropylene
EP0702030B1 (de) * 1991-05-27 2001-03-21 TARGOR GmbH Verfahren zur Herstellung von Polyolefinen mit breiter Molmassenverteilung
TW300901B (https=) * 1991-08-26 1997-03-21 Hoechst Ag
US5330948A (en) * 1992-03-31 1994-07-19 Northwestern University Homogeneous catalysts for stereoregular olefin polymerization
FI112233B (fi) * 1992-04-01 2003-11-14 Basell Polyolefine Gmbh Katalyytti olefiinipolymerointia varten, menetelmä sen valmistamiseksi ja sen käyttö
ES2128371T3 (es) * 1992-08-15 1999-05-16 Targor Gmbh Procedimiento para la obtencion de poliolefinas.
TW272985B (https=) * 1992-09-11 1996-03-21 Hoechst Ag
JP3307704B2 (ja) * 1993-02-19 2002-07-24 三菱化学株式会社 α‐オレフィン重合体の製造法
EP0629631B1 (en) * 1993-06-07 2002-08-28 Mitsui Chemicals, Inc. Novel transition metal compound, and polymerization catalyst containing it
EP0812854B2 (en) * 1993-06-07 2011-04-20 Mitsui Chemicals, Inc. Novel transition metal compound, olefin polymerization catalyst comprising said compound, process for olefin polymerization using said catalyst and propylene homo- and copolymer
US5459117A (en) * 1993-08-27 1995-10-17 Ewen; John A. Doubly-conformationally locked, stereorigid catalysts for the preparation of tactiospecific polymers
DE4333128A1 (de) * 1993-09-29 1995-03-30 Hoechst Ag Verfahren zur Herstellung von Polyolefinen
DE4344689A1 (de) * 1993-12-27 1995-06-29 Hoechst Ag Metallocenverbindung
US5504223A (en) * 1994-01-25 1996-04-02 The Dow Chemical Company Synthesis of cyclopentadienyl metal coordination complexes from metal hydrocarbyloxides

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0416566A2 (de) * 1989-09-07 1991-03-13 Hoechst Aktiengesellschaft Verfahren zur Herstellung eines Polyolefinwachses
EP0485821A1 (de) * 1990-11-12 1992-05-20 Hoechst Aktiengesellschaft Metallocene mit Liganden aus 2-substituierten Indenylderivaten, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren
EP0485823A1 (de) * 1990-11-12 1992-05-20 Hoechst Aktiengesellschaft 2-Substituierte Bisindenylmetallocene, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren bei der Olefinpolymerisation
EP0516108A2 (en) * 1991-05-29 1992-12-02 Dow Corning Toray Silicone Company, Limited Hexenyl-containing silicone resin and method for its preparation
EP0588208A2 (de) * 1992-09-12 1994-03-23 Hoechst Aktiengesellschaft Polyolefin-Formmasse mit breitem Schmelzbereich, Verfahren zu ihrer Herstellung und ihre Verwendung

Also Published As

Publication number Publication date
FI963759L (fi) 1996-09-20
AR000776A1 (es) 1997-08-06
IT1272923B (it) 1997-07-01
PL316387A1 (en) 1997-01-06
IL116853A0 (en) 1996-07-23
CA2186232A1 (en) 1996-08-01
FI963759A7 (fi) 1996-09-20
DE69617543D1 (de) 2002-01-17
US6051728A (en) 2000-04-18
ES2167539T5 (es) 2007-04-01
BG100904A (bg) 1997-07-31
WO1996022995A1 (en) 1996-08-01
EP0751946B2 (en) 2006-08-09
US20030120015A1 (en) 2003-06-26
EP0751946A1 (en) 1997-01-08
TW319777B (https=) 1997-11-11
CN1150430A (zh) 1997-05-21
KR100418106B1 (ko) 2004-04-30
ES2167539T3 (es) 2002-05-16
AU4536696A (en) 1996-08-14
FI963759A0 (fi) 1996-09-20
IL116853A (en) 2000-09-28
KR970701723A (ko) 1997-04-12
HUP9602907A3 (en) 1997-12-29
JP3838662B2 (ja) 2006-10-25
ITMI950099A0 (it) 1995-01-23
CN1355256A (zh) 2002-06-26
AU700256B2 (en) 1998-12-24
DE69617543T2 (de) 2002-08-01
BR9606373A (pt) 2004-06-29
JPH09510994A (ja) 1997-11-04
RU2177948C2 (ru) 2002-01-10
CZ309596A3 (en) 1997-04-16
ZA96485B (en) 1996-08-13
EP0751946B1 (en) 2001-12-05
KR100414759B1 (ko) 2004-01-13
DE69617543T3 (de) 2007-01-18
ITMI950099A1 (it) 1996-07-23
TR199600720T1 (tr) 1997-03-21
US6518386B1 (en) 2003-02-11
PL185055B1 (pl) 2003-02-28
CN1196721C (zh) 2005-04-13
HUP9602907A2 (en) 1997-05-28
MX9604229A (es) 1997-12-31

Similar Documents

Publication Publication Date Title
CN1075076C (zh) 金属茂化合物及其制法和在烯烃聚合催化剂中的应用
CN1092672C (zh) 乙烯共聚物,乙烯基聚合物制备方法及所用的催化剂体系
CN1113899C (zh) 用于烯烃聚合的催化剂及方法
CN1124296C (zh) 乙烯共聚方法
CN1116314C (zh) 烯烃聚合的催化剂及方法
CN1049899C (zh) 烯烃的聚合方法
CN1052736C (zh) 无定形丙烯聚合物的制备方法
CN1147822A (zh) 反应器掺混聚丙烯，其制备方法和金属茂配位体的制备方法
CN1226894A (zh) 金属茂和烯烃聚合催化剂
JP3946282B2 (ja) プロピレンのエチレンとのアモルファスコポリマー
CN1019579B (zh) 制备烯烃聚合催化剂的方法
CN1270596A (zh) 双金属配合物和从其获得的聚合催化剂
CN1269855C (zh) 含有在4－、5－、6－或7－位被甲硅烷氧基或甲锗烷氧基取代的茚基部分的金属茂催化剂
CN1308090A (zh) 乙烯弹性共聚物
JPH09157322A (ja) オレフインの重合法
CN1093092A (zh) 用于制备控制立构规正度的聚合α-烯烃的离子催化剂
CN1123287A (zh) 生产宽分子量分布的聚烯烃用的催化剂体系和生产这种聚烯烃的方法
CN1099426C (zh) 用于α－烯烃聚合的催化剂
CN1152056C (zh) 聚烯烃的生产
CN1150809A (zh) 由乙烯、α-烯烃和任选的二烯烃制备弹性体聚合物的方法
CN1271366A (zh) 均质填充聚合物复合材料
CN1192442A (zh) 金属茂,其制备方法及在α-烯烃聚合上的应用
CN1575295A (zh) 连接金属茂配合物,催化剂体系和使用该催化剂体系的烯烃聚合方法
CN1380892A (zh) 全同立构丙烯聚合物和全同立构规整度降低的软丙烯聚合物的热塑性组合物及其制备方法
CN1096305A (zh) 乙烯与α-烯烃的弹性共聚物及其制备方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
C19 Lapse of patent right due to non-payment of the annual fee
CF01 Termination of patent right due to non-payment of annual fee