JP6228009B2 - イオン性ゲル電解質、エネルギー貯蔵デバイス、およびそれらの製造方法 - Google Patents
イオン性ゲル電解質、エネルギー貯蔵デバイス、およびそれらの製造方法 Download PDFInfo
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Description
Zn←→Zn2++2e− 式1
2e−+(2MnO2 −)Zn2+←→Zn2++2MnO2 式2
Claims (10)
- アノード層、
カソード層、および
前記アノード層および前記カソード層に直接連結された、印刷された非水性ゲル電解質層を含む電気化学セルであって、
前記アノード層は、亜鉛を含み、
前記カソード層は、五酸化バナジウム(V2O5)、二酸化マンガン(MnO2)粒子、酸化コバルト(CoOx)粒子、酸化鉛(PbOx)粒子を含み、
前記ゲル電解質層は、前記アノード層と前記カソード層との間を物理的に分離し、
前記ゲル電解質層は、少なくとも1つのイオン液体および電解質塩が吸収されているポリマーを含み、かつ、75重量%を超えない少なくとも1つの前記イオン液体の濃度を有し、さらに、前記電解質塩は0.3Mから0.75Mの濃度を有し、
前記ゲル電解質層は、前記アノード層とカソード層との間に多価イオンの伝送を促進することによって、前記アノード層とカソード層との間のイオン性連通を提供するように構成される組成物を含み、
前記イオン液体に溶解した前記電解質塩が、亜鉛を含む多価カチオンを放出し、
前記ポリマーが、ポリ(フッ化ビニリデン)(PVDF)、ポリ(ビニリデンフルオライドヘキサフルオロプロピレン)(PVDF−HFP)、ポリビニルアルコール(PVA)、ポリ(エチレンオキシド)(PEO)、ポリ(アクリロニトリル)(PAN)、およびポリ(メチルメタクリレート)(PMMA)、エポキシ誘導体、およびシリコーン誘導体からなる群から選択される1つ以上のポリマーを含み、
前記イオン液体が、イミダゾリウム変異体、ピロリジニウム変異体、アンモニウム変異体、ピリジニウム変異体、ピペリジニウム変異体、ホスホニウム変異体、およびスルホニウム変異体からなる群から選択される、室温でカチオンを有する塩であり、
前記電解質塩は、亜鉛トリフレートまたは亜鉛ビス(トリフルオロメタンスルホネート)を含む亜鉛塩である、
電気化学セル。 - イオン液体が、クロリド、テトラフルオロボレート(BF4−)、トリフルオロアセテート(CF3CO2−)、トリフルオロメタンスルホネート(CF3SO3−)、ヘキサフルオロホスフェート(PF6−)、ビス(トリフルオロメチルスルホニル)アミド(NTf2−)、およびビス(フルオロスルホニル)イミド(N(SO2F)2−)からなる群から選択される、室温でアニオンを有する塩である、請求項1に記載の電気化学セル。
- 前記ゲル電解質層が1μm〜30μmの厚さを有する、請求項1に記載の電気化学セル。
- 電気化学セルにおけるアノードとカソードとの間を物理的に分離するように構成される電解質であって、
前記アノード層は、亜鉛を含み、
前記カソード層は、五酸化バナジウム(V2O5)、二酸化マンガン(MnO2)粒子、酸化コバルト(CoOx)粒子、酸化鉛(PbOx)粒子を含み、
イオン液体及び溶解塩を含む室温イオン液体電解質であって、印刷できる非水性ゲル電解質を形成するためにポリマー中に吸収され、0.3Mから0.75Mまでの前記溶解塩の濃度を含み、前記イオン液体の濃度は75重量%を超えない、前記イオン液体電解質と、
前記電解質を横断する多価イオンの伝送を促進することによって前記アノードと前記カソードとの間にイオン性連通を提供するように構成される組成物と、
を備え、
前記ゲル電解質は直接アノードとカソードに結合するように構成されており、
前記ゲル電解質が、亜鉛を含む多価カチオンを放出し、且つ、前記電解質が可撓性の層を形成し、
前記ポリマーが、ポリ(フッ化ビニリデン)(PVDF)、ポリ(ビニリデンフルオライドヘキサフルオロプロピレン)(PVDF−HFP)、ポリビニルアルコール(PVA)、ポリ(エチレンオキシド)(PEO)、ポリ(アクリロニトリル)(PAN)、およびポリ(メチルメタクリレート)(PMMA)、エポキシ誘導体、およびシリコーン誘導体からなる群から選択される1つ以上のポリマーを含み、
前記イオン液体が、イミダゾリウム変異体、ピロリジニウム変異体、アンモニウム変異体、ピリジニウム変異体、ピペリジニウム変異体、ホスホニウム変異体、およびスルホニウム変異体からなる群から選択される、室温でカチオンを有する塩であり、
前記溶解塩は、亜鉛トリフレートまたは亜鉛ビス(トリフルオロメタンスルホネート)を含む亜鉛塩である、
電解質。 - 前記イオン液体が、クロリド、テトラフルオロボレート(BF4−)、トリフルオロアセテート(CF3CO2−)、トリフルオロメタンスルホネート(CF3SO3−)、ヘキサフルオロホスフェート(PF6−)、ビス(トリフルオロメチルスルホニル)アミド(NTf2−)、およびビス(フルオロスルホニル)イミド(N(SO2F)2−)からなる群から選択される、室温でアニオンを有する塩である、請求項4に記載の電解質。
- 前記イオン液体電解質が1mS/cmを超えるイオン伝導度を有する、請求項4に記載の電解質。
- 第1の電極インクおよび第2の電極インクを提供する工程と、
液体電解質インクを提供する工程と、
第1の電極インクの第1の電極層を印刷して、印刷された第1の電極を供給する工程と、
前記液体電解質インクの電解質層を印刷して、印刷されたゲル電解質を供給する工程であって、この工程は前記印刷された第1の電極上に直接的に前記電解質層を印刷する工程を備え、前記電解質層が、少なくとも1つのイオン液体および少なくとも1つの電解質塩が吸収されているポリマーを含み、前記イオン液体の濃度は75重量%を超えず、前記電解質塩は0.3Mから0.75Mの濃度を有する、工程と、
第2の電極インクの第2の電極層を印刷して、印刷された第2の電極を供給する工程であって、この工程は前記印刷されたゲル電解質上に直接的に前記第2の電極層を印刷する工程を備える、工程と、
を備え、
前記印刷されたゲル電解質は、直接的に、前記印刷された第1の電極と前記印刷された第2の電極とへ結合さており、
前記電解質層は、第1の電極層と第2の電極層との間を物理的に分離して、電気化学セルを形成し、
前記電解質の層は、第1の電極層と第2の電極層との間で多価イオンの伝送を促進することにより、前記第1の電極層と前記第2の電極層との間にイオン性連通を提供するように構成され、
前記イオン液体に溶解した前記電解質塩が、亜鉛を含む多価カチオンを放出し、
前記第1の電極は、亜鉛を含み、
前記第2の電極は、五酸化バナジウム(V2O5)、二酸化マンガン(MnO2)粒子、酸化コバルト(CoOx)粒子、酸化鉛(PbOx)粒子群から選択される構成成分を含み、
前記ポリマーが、ポリ(フッ化ビニリデン)(PVDF)、ポリ(ビニリデンフルオライドヘキサフルオロプロピレン)(PVDF−HFP)、ポリビニルアルコール(PVA)、ポリ(エチレンオキシド)(PEO)、ポリ(アクリロニトリル)(PAN)、およびポリ(メチルメタクリレート)(PMMA)、エポキシ誘導体、およびシリコーン誘導体からなる群から選択される1つ以上のポリマーを含み、
前記イオン液体が、イミダゾリウム変異体、ピロリジニウム変異体、アンモニウム変異体、ピリジニウム変異体、ピペリジニウム変異体、ホスホニウム変異体、およびスルホニウム変異体からなる群から選択される、室温でカチオンを有する塩であり、
前記電解質塩は、亜鉛トリフレートまたは亜鉛ビス(トリフルオロメタンスルホネート)を含む亜鉛塩である、
電気化学セルを製造する方法。 - 集電体インクを提供する工程と、
前記第1の電極層および第2の電極層の1つ以上に隣接する集電体インクの層を印刷する工程と、をさらに備えた、請求項7に記載の方法。 - 前記イオン液体が、クロリド、テトラフルオロボレート(BF4−)、トリフルオロアセテート(CF3CO2−)、トリフルオロメタンスルホネート(CF3SO3−)、ヘキサフルオロホスフェート(PF6−)、ビス(トリフルオロメチルスルホニル)アミド(NTf2−)、およびビス(フルオロスルホニル)イミド(N(SO2F)2−)からなる群から選択される、室温でアニオンを有する塩である、請求項7に記載の方法。
- 前記印刷工程の少なくとも1つが、直接描画ディスペンサ方法を用いて行われる、請求項7に記載の方法。
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US20190288334A1 (en) | 2019-09-19 |
US20160344062A1 (en) | 2016-11-24 |
US9368283B2 (en) | 2016-06-14 |
CN103181016B (zh) | 2016-06-22 |
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