JP5764046B2 - 炭化珪素半導体装置の製造方法 - Google Patents
炭化珪素半導体装置の製造方法 Download PDFInfo
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- JP5764046B2 JP5764046B2 JP2011253614A JP2011253614A JP5764046B2 JP 5764046 B2 JP5764046 B2 JP 5764046B2 JP 2011253614 A JP2011253614 A JP 2011253614A JP 2011253614 A JP2011253614 A JP 2011253614A JP 5764046 B2 JP5764046 B2 JP 5764046B2
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- silicon carbide
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- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 title claims description 138
- 229910010271 silicon carbide Inorganic materials 0.000 title claims description 137
- 239000004065 semiconductor Substances 0.000 title claims description 59
- 238000000034 method Methods 0.000 title claims description 53
- 238000004519 manufacturing process Methods 0.000 title claims description 47
- 238000005530 etching Methods 0.000 claims description 105
- 239000000758 substrate Substances 0.000 claims description 35
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 21
- 239000000460 chlorine Substances 0.000 claims description 21
- 229910052801 chlorine Inorganic materials 0.000 claims description 21
- 239000010410 layer Substances 0.000 description 134
- 239000013078 crystal Substances 0.000 description 45
- 239000007789 gas Substances 0.000 description 35
- 239000000126 substance Substances 0.000 description 28
- 230000015556 catabolic process Effects 0.000 description 12
- 239000011229 interlayer Substances 0.000 description 11
- 238000000137 annealing Methods 0.000 description 10
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 9
- 230000004913 activation Effects 0.000 description 9
- 239000004020 conductor Substances 0.000 description 9
- 239000012535 impurity Substances 0.000 description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 229910052814 silicon oxide Inorganic materials 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 6
- 150000002500 ions Chemical class 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 238000001020 plasma etching Methods 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 238000005468 ion implantation Methods 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 3
- 229910004298 SiO 2 Inorganic materials 0.000 description 3
- 239000012159 carrier gas Substances 0.000 description 3
- 238000005229 chemical vapour deposition Methods 0.000 description 3
- 229910001882 dioxygen Inorganic materials 0.000 description 3
- 230000005684 electric field Effects 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 238000000206 photolithography Methods 0.000 description 3
- 230000001681 protective effect Effects 0.000 description 3
- 239000012495 reaction gas Substances 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 238000004544 sputter deposition Methods 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 238000002050 diffraction method Methods 0.000 description 1
- 230000005669 field effect Effects 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 238000009616 inductively coupled plasma Methods 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000001000 micrograph Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 238000000992 sputter etching Methods 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
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Description
図1および図2に示すように、本実施の形態の炭化珪素半導体装置は、トレンチゲートを有する縦型のMOSFET101である。MOSFET101は、n型の導電型を有する基板1と、基板1の主表面MS上にエピタキシャルに形成された炭化珪素層19とを有する。炭化珪素層19は、n型の導電型を有する耐圧保持層2と、p型ボディ層3と、n型ソースコンタクト層4と、p型の導電型を有するコンタクト領域5とを含む。
まず炭化珪素から作られた基板1(図3)が準備される。基板1の主表面MSは、六方晶系の場合はほぼ{000−1}面であり、立方晶系の場合はほぼ{111}面である。
プロセスガスとしては、酸素ガスと塩素ガスとの混合ガスを反応ガスとして用い、熱処理温度をたとえば700℃以上1200℃以下としたエッチングを行なう。熱処理温度は、好ましくは700℃以上1200℃以下である。1200℃以下の場合、熱処理のための装置に石英部材を用いることができる。温度の上限は、より好ましくは1100℃、さらに好ましくは1000℃である。温度の下限は、より好ましくは800℃、さらに好ましくは900℃である。この場合、上記{0−33−8}面、{01−1−4}面または{100}面を含む面を形成する熱エッチング工程でのエッチング速度を十分実用的な値とすることができるので、当該工程の処理時間を十分短くすることができる。
図10および図11に示すように、コンタクト領域5および電界緩和領域7が形成される。具体的には、まず、トレンチ6の内部からn型ソースコンタクト層4の上部表面上にまで延在するように、所定のパターンを有するレジスト膜(図示せず)が、フォトリソグラフィ法を用いて形成される。レジスト膜としては、トレンチ6の底部およびn型ソースコンタクト層4の上部表面の一部に開口パターンが形成されているものを用いる。そして、このレジスト膜をマスクとして用いて、p型を付与するための不純物イオンを注入することにより、トレンチ6の底部に電界緩和領域7が形成され、またn型ソースコンタクト層4の一部領域にp型のコンタクト領域5が形成される。その後レジスト膜が除去される。
図21に示すように、本実施の形態の炭化珪素半導体装置としての、PiNダイオード102は、基板1と、n-エピタキシャル層42およびp+半導体層43を有する炭化珪素層とを有する。基板1はn型の導電型を有する。n-エピタキシャル層42は、n型の導電型を有し、基板1の導電型不純物の濃度よりも低い不純物濃度を有する。p+半導体層43は、n-エピタキシャル層42上に設けられている。上記炭化珪素層には、頂面としての主表面TSと、側面SSとを有するメサ構造44が形成されている。炭化珪素層は、このメサ構造44を取り囲むように、n-エピタキシャル層42からなる表面を有し、この表面上には、ガードリング45が設けられている。ガードリング45は、p型の導電型を有する。
なお図22に示すように、JTE(Junction Termination Extension)領域46が設けられたPiNダイオード102vが用いられてもよい。JTE領域46はp型の導電型を有し、p+半導体層43につながるようにn-エピタキシャル層42上に配置されている。
Claims (12)
- 炭化珪素半導体装置の製造方法であって、
基板上に、主表面が設けられた炭化珪素層を形成する工程と、
前記炭化珪素層の前記主表面の一部を覆うマスクを形成する工程と、
前記主表面に対して傾斜した側面が前記炭化珪素層に設けられるように、前記マスクが形成された前記炭化珪素層の前記主表面に対して、塩素系ガスを用いた熱エッチングを行う工程とを備え、
前記熱エッチングを行う工程は、前記側面が{0−33−8}面、{01−1−4}面または{100}面のいずれかを含む面となるように、前記塩素系ガスの分圧が50%以下である雰囲気下で行われる、炭化珪素半導体装置の製造方法。 - 前記熱エッチングを行う工程は、減圧雰囲気下で行われる、請求項1に記載の炭化珪素半導体装置の製造方法。
- 前記熱エッチングを行う工程は1000℃以上で行われる、請求項1または請求項2に記載の炭化珪素半導体装置の製造方法。
- 炭化珪素半導体装置の製造方法であって、
基板上に、主表面が設けられた炭化珪素層を形成する工程と、
前記炭化珪素層の前記主表面の一部を覆うマスクを形成する工程と、
前記主表面に対して傾斜した側面が前記炭化珪素層に設けられるように、前記マスクが形成された前記炭化珪素層の前記主表面に対して、塩素系ガスを用いた熱エッチングを行う工程とを備え、
前記熱エッチングを行う工程は、前記側面が{0−33−8}面、{01−1−4}面または{100}面のいずれかを含む面となるように、減圧雰囲気下で行われる、炭化珪素半導体装置の製造方法。 - 前記減圧雰囲気は大気圧の1/10以下の圧力を有する、請求項4に記載の炭化珪素半導体装置の製造方法。
- 前記熱エッチングを行う工程は、前記塩素系ガスの分圧が50%以下である雰囲気下で行われる、請求項4または請求項5に記載の炭化珪素半導体装置の製造方法。
- 前記熱エッチングを行う工程は1000℃以上で行われる、請求項4〜請求項6のいずれか1項に記載の炭化珪素半導体装置の製造方法。
- 炭化珪素半導体装置の製造方法であって、
基板上に、主表面が設けられた炭化珪素層を形成する工程と、
前記炭化珪素層の前記主表面の一部を覆うマスクを形成する工程と、
前記主表面に対して傾斜した側面が前記炭化珪素層に設けられるように、前記マスクが形成された前記炭化珪素層の前記主表面に対して、塩素系ガスを用いた熱エッチングを行う工程とを備え、
前記熱エッチングを行う工程は、前記側面が{0−33−8}面、{01−1−4}面または{100}面のいずれかを含む面となるように、1000℃以上で行われる、炭化珪素半導体装置の製造方法。 - 前記熱エッチングを行う工程は、前記塩素系ガスの分圧が50%以下である雰囲気下で行われる、請求項8に記載の炭化珪素半導体装置の製造方法。
- 前記熱エッチングを行う工程は、減圧雰囲気下で行われる、請求項8または請求項9に記載の炭化珪素半導体装置の製造方法。
- 前記炭化珪素層の前記側面上にゲート絶縁膜を形成する工程と、
前記ゲート絶縁膜を介して前記炭化珪素層の前記側面に対向するゲート電極を形成する工程とをさらに備える、請求項1〜請求項10のいずれか1項に記載の炭化珪素半導体装置の製造方法。 - 前記炭化珪素半導体装置は、前記炭化珪素層の前記主表面と前記基板との間において前記炭化珪素層の厚さ方向に沿った電流経路を有するダイオードである、請求項1〜請求項10のいずれか1項に記載の炭化珪素半導体装置の製造方法。
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