JP5346469B2 - 担持非メタロセンオレフィン重合触媒、その調製方法及び使用方法 - Google Patents
担持非メタロセンオレフィン重合触媒、その調製方法及び使用方法 Download PDFInfo
- Publication number
- JP5346469B2 JP5346469B2 JP2007545817A JP2007545817A JP5346469B2 JP 5346469 B2 JP5346469 B2 JP 5346469B2 JP 2007545817 A JP2007545817 A JP 2007545817A JP 2007545817 A JP2007545817 A JP 2007545817A JP 5346469 B2 JP5346469 B2 JP 5346469B2
- Authority
- JP
- Japan
- Prior art keywords
- polymerization
- catalyst
- solvent
- nonmetallocene
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/02—Carriers therefor
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymerization Catalysts (AREA)
Applications Claiming Priority (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200410066070.3 | 2004-12-17 | ||
| CN 200410066070 CN1789291A (zh) | 2004-12-17 | 2004-12-17 | 负载型非茂金属催化剂的烯烃聚合和共聚合方法 |
| CNB2004100660686A CN100362024C (zh) | 2004-12-17 | 2004-12-17 | 非茂金属催化剂的高活性负载化方法 |
| CN200410066069.0 | 2004-12-17 | ||
| CN200410066068.6 | 2004-12-17 | ||
| CN 200410066069 CN1789292A (zh) | 2004-12-17 | 2004-12-17 | 负载型非茂金属催化剂在淤浆法乙烯聚合工艺中的应用方法 |
| PCT/CN2005/001737 WO2006063501A1 (fr) | 2004-12-17 | 2005-10-21 | Catalyseur de polimerisation olefinique non metallocene supporte, sa preparation et son utilisation |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2008524344A JP2008524344A (ja) | 2008-07-10 |
| JP2008524344A5 JP2008524344A5 (https=) | 2008-12-04 |
| JP5346469B2 true JP5346469B2 (ja) | 2013-11-20 |
Family
ID=36587519
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2007545817A Expired - Lifetime JP5346469B2 (ja) | 2004-12-17 | 2005-10-21 | 担持非メタロセンオレフィン重合触媒、その調製方法及び使用方法 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US7875568B2 (https=) |
| EP (1) | EP1829897B1 (https=) |
| JP (1) | JP5346469B2 (https=) |
| KR (1) | KR101075404B1 (https=) |
| WO (1) | WO2006063501A1 (https=) |
Families Citing this family (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20090036621A1 (en) * | 2006-01-11 | 2009-02-05 | Grant Berent Jacobsen | Catalyst System |
| US8110518B2 (en) * | 2006-04-28 | 2012-02-07 | Fina Technology, Inc. | Fluorinated transition metal catalysts and formation thereof |
| JP2009072665A (ja) * | 2007-09-19 | 2009-04-09 | Mitsui Chemicals Inc | オレフィン多量化用触媒およびエチレン多量体の製造方法 |
| WO2009052701A1 (en) | 2007-10-16 | 2009-04-30 | Sinopec Yangzi Petrochemical Company Ltd. | Non-metallocene catalyst supported on magnesium compound and its preparation method |
| KR101207294B1 (ko) * | 2007-10-16 | 2012-12-03 | 시노펙 양지 페트로케미컬 컴퍼니 엘티디. | 담지된 비-메탈로센 촉매 및 이의 제조방법 |
| US8138285B2 (en) * | 2007-10-26 | 2012-03-20 | Fina Technology, Inc. | Fluorinated impregnated catalyst systems and methods of forming the same |
| KR100996336B1 (ko) | 2008-08-26 | 2010-11-24 | 삼성토탈 주식회사 | 폴리올레핀 중합용 촉매의 제조방법 |
| JP5748415B2 (ja) * | 2009-06-08 | 2015-07-15 | 三井化学株式会社 | 遷移金属化合物、オレフィン重合用触媒およびポリオレフィンの製造方法 |
| WO2011050565A1 (zh) | 2009-10-26 | 2011-05-05 | 中国石油化工股份有限公司 | 负载型非茂金属催化剂、其制备方法及其应用 |
| WO2011050566A1 (zh) | 2009-10-26 | 2011-05-05 | 中国石油化工股份有限公司 | 负载型非茂金属催化剂、其制备方法及其应用 |
| US8952113B2 (en) * | 2009-11-13 | 2015-02-10 | China Petroleum & Chemical Corp. | Supported nonmetallocene catalyst, preparation and use thereof |
| EP2500364B1 (en) * | 2009-11-13 | 2020-03-04 | China Petroleum & Chemical Corporation | Supported non-metallocene catalyst preparation method and application thereof |
| CN102399315B (zh) * | 2010-09-16 | 2013-09-11 | 中国石油化工股份有限公司 | 负载型非茂金属催化剂、其制备方法及其应用 |
| CN102399313B (zh) * | 2010-09-16 | 2013-09-11 | 中国石油化工股份有限公司 | 负载型非茂金属催化剂、其制备方法及其应用 |
| CN102399318B (zh) * | 2010-09-16 | 2013-11-06 | 中国石油化工股份有限公司 | 负载型非茂金属催化剂、其制备方法及其应用 |
| JP6016426B2 (ja) * | 2012-04-16 | 2016-10-26 | 三井化学株式会社 | オレフィン重合用触媒 |
| PT2841471T (pt) * | 2012-04-27 | 2020-05-29 | Grace W R & Co | Composições de ativador, a sua preparação e a sua utilização em catalisadores |
| KR101799718B1 (ko) * | 2014-01-22 | 2017-11-20 | 라이온델 케미칼 테크놀로지, 엘.피. | 에폭시화 촉매의 제조 방법 |
| CN105732852B (zh) * | 2014-12-10 | 2018-08-10 | 中国石油天然气股份有限公司 | Z-n催化剂 |
| CN113754798A (zh) | 2020-06-05 | 2021-12-07 | 中国石油化工股份有限公司 | 类球形超大孔介孔材料和聚烯烃催化剂及其制备方法以及烯烃聚合方法 |
| CN112390902A (zh) * | 2020-07-22 | 2021-02-23 | 北京锦吾新材科技有限公司 | 烯烃聚合工艺与应用 |
| US20240117085A1 (en) * | 2021-02-01 | 2024-04-11 | China Petroleum & Chemical Corporation | Ethylene polymer and preparation method therefor |
| JP7775318B2 (ja) * | 2021-02-01 | 2025-11-25 | 中国石油化工股▲ふん▼有限公司 | 超高分子量ポリエチレンおよびその製造方法 |
| CN115819644B (zh) * | 2021-09-18 | 2024-01-09 | 中国科学技术大学 | 负载型催化剂及其制备方法和应用 |
| CN115838448B (zh) * | 2021-09-18 | 2024-01-09 | 中国科学技术大学 | 负载型催化剂及其制备方法和应用 |
| CN113999334B (zh) * | 2021-11-09 | 2023-08-29 | 上海化工研究院有限公司 | 一种用于烯烃聚合的催化剂及其制备方法与应用 |
| CN116178595B (zh) * | 2021-11-26 | 2024-07-12 | 中国石油天然气股份有限公司 | 烯烃聚合用负载茂金属催化剂及其制备方法和应用 |
| CN116178594B (zh) * | 2021-11-26 | 2024-07-16 | 中国石油天然气股份有限公司 | 烯烃聚合用原位负载茂金属催化剂及其制备方法和应用 |
| CN116655676B (zh) * | 2022-02-18 | 2025-08-29 | 中国石油天然气股份有限公司 | 一种非茂金属催化剂、聚丁烯-1弹性体及其制备方法 |
| CN114605581B (zh) * | 2022-03-11 | 2023-07-14 | 中国科学院青岛生物能源与过程研究所 | 一种功能化极性聚烯烃聚合物及其制备方法和应用 |
| CN117659236A (zh) * | 2023-10-19 | 2024-03-08 | 中国石油化工股份有限公司 | 一种宽分子量分布的茂金属聚乙烯的制备方法 |
| CN121226589A (zh) * | 2024-06-27 | 2025-12-30 | 中国石油天然气股份有限公司 | 双中心非茂金属催化剂及其制备方法和丁烯-1基弹性体及其制备方法 |
| CN120349441B (zh) * | 2025-06-25 | 2025-08-29 | 淄博新塑化工有限公司 | 一种复合型烯烃聚合催化剂及其制备方法 |
Family Cites Families (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2082153A5 (fr) * | 1970-03-05 | 1971-12-10 | Solvay | Catalyseurs et procede perfectionnes pour la polymerisation et la copolymerisation des olefines |
| US4374753A (en) * | 1981-07-29 | 1983-02-22 | Chemplex Company | Polymerization catalyst and method |
| US4397762A (en) * | 1982-01-27 | 1983-08-09 | Bp Chemicals Limited | Polymerization catalyst |
| US5064795A (en) * | 1982-08-27 | 1991-11-12 | Phillips Petroleum Company | Polymerization of olefins |
| US4665138A (en) * | 1982-11-24 | 1987-05-12 | Cities Service Oil & Gas Corp | Process for polymerizing a monomer charge |
| JPH0629287B2 (ja) * | 1984-03-14 | 1994-04-20 | 三菱油化株式会社 | オレフィン重合用触媒成分 |
| CA1268754A (en) | 1985-06-21 | 1990-05-08 | Howard Curtis Welborn, Jr. | Supported polymerization catalyst |
| US5077255A (en) | 1986-09-09 | 1991-12-31 | Exxon Chemical Patents Inc. | New supported polymerization catalyst |
| US4727051A (en) * | 1986-12-15 | 1988-02-23 | Stauffer Chemical Company | Production of halide-and alkoxy-containing magnesium compositions |
| US4921825A (en) | 1986-12-30 | 1990-05-01 | Mitsui Petrochemical Industries, Ltd. | Solid catalyst for olefin polymerization and processes for its production |
| US5352749A (en) | 1992-03-19 | 1994-10-04 | Exxon Chemical Patents, Inc. | Process for polymerizing monomers in fluidized beds |
| US5288933A (en) * | 1992-04-16 | 1994-02-22 | Union Carbide Chemicals & Plastics Technology Corporation | Process for the production of polyethylene |
| DK0685494T3 (da) | 1994-06-03 | 1999-02-15 | Pcd Polymere Ag | Katalysatorbærere, understøttede metallocenkatalysatorer og deres anvendelse til fremstilling af polyolefiner |
| ES2143636T3 (es) | 1994-06-24 | 2000-05-16 | Exxon Chemical Patents Inc | Sistemas de catalizadores de polimerizacion, su produccion y uso. |
| ES2133881T3 (es) * | 1995-12-01 | 1999-09-16 | Borealis Ag | Catalizador soportado para la polimerizacion de olefinas. |
| US5856255A (en) | 1996-01-22 | 1999-01-05 | Albemarle Corporation | Preparation of supported auxiliary catalysts at elevated temperature and pressure in a closed vessel |
| US6114477A (en) | 1996-02-09 | 2000-09-05 | Exxon Chemical Patents Inc. | Polymerization process |
| US6417130B1 (en) * | 1996-03-25 | 2002-07-09 | Exxonmobil Oil Corporation | One pot preparation of bimetallic catalysts for ethylene 1-olefin copolymerization |
| JP3913814B2 (ja) * | 1996-08-21 | 2007-05-09 | 日本ポリオレフィン株式会社 | エチレンの重合方法 |
| EP0878484B1 (en) | 1997-03-27 | 2004-12-15 | Council of Scientific and Industrial Research | A process for the preparation of a megnesium halide supported metallocene catalyst |
| US6368999B1 (en) * | 1998-08-26 | 2002-04-09 | Exxon Mobil Chemical Patents Inc. | Highly active supported catalyst compositions |
| US6211311B1 (en) | 1999-05-25 | 2001-04-03 | Equistar Chemicals, L.P. | Supported olefin polymerization catalysts |
| US6531424B2 (en) * | 1999-12-17 | 2003-03-11 | E. I. Du Pont De Nemours And Company | Polymerization of olefins |
| CN1136239C (zh) | 2001-01-18 | 2004-01-28 | 中国石油化工股份有限公司 | 卤化镁/二氧化硅负载的半茂金属催化剂及其制备与应用 |
| US6534609B2 (en) * | 2001-03-13 | 2003-03-18 | Chevron Phillips Chemical Company Lp | Method for making and using a metallocene catalyst system |
| EP1426385B1 (en) | 2001-07-23 | 2012-08-22 | Shanghai Institute Of Organic Chemistry, Chinese Academy Of Sciences | Catalyst for polymerization or copolymerization of olefins, preparation and use of the same |
| BR0214554A (pt) | 2001-11-30 | 2004-11-09 | Exxonmobil Chemical Patentes I | Método de produção de catalisadores ziegler-natta/metalocenos mistos |
| CN1691979A (zh) | 2001-11-30 | 2005-11-02 | 埃克森美孚化学专利公司 | 具有高活性的双金属催化剂 |
| US6855655B2 (en) * | 2002-07-15 | 2005-02-15 | Univation Technologies, Llc | Supported polymerization catalyst |
| JP2004285231A (ja) * | 2003-03-24 | 2004-10-14 | Sumitomo Chem Co Ltd | 接触処理物、付加重合用触媒成分、付加重合用触媒および付加重合体の製造方法 |
| CN1269852C (zh) * | 2003-10-29 | 2006-08-16 | 扬子石油化工股份有限公司 | 负载型非茂金属催化剂的负载化方法和聚合应用 |
| CN1281634C (zh) * | 2003-10-29 | 2006-10-25 | 扬子石油化工股份有限公司 | 复合载体负载的非茂金属催化剂的负载化方法和聚合应用 |
| WO2006049699A1 (en) * | 2004-10-29 | 2006-05-11 | Exxonmobil Chemical Patents Inc | Catalyst compound containing divalent tridentate ligand |
-
2005
- 2005-10-21 JP JP2007545817A patent/JP5346469B2/ja not_active Expired - Lifetime
- 2005-10-21 WO PCT/CN2005/001737 patent/WO2006063501A1/zh not_active Ceased
- 2005-10-21 US US11/793,046 patent/US7875568B2/en active Active
- 2005-10-21 KR KR1020077016440A patent/KR101075404B1/ko not_active Expired - Lifetime
- 2005-10-21 EP EP05801846.6A patent/EP1829897B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| US20080227936A1 (en) | 2008-09-18 |
| JP2008524344A (ja) | 2008-07-10 |
| KR20070093114A (ko) | 2007-09-17 |
| EP1829897A1 (en) | 2007-09-05 |
| EP1829897A4 (en) | 2012-04-25 |
| WO2006063501A1 (fr) | 2006-06-22 |
| KR101075404B1 (ko) | 2011-10-24 |
| EP1829897B1 (en) | 2014-12-10 |
| US7875568B2 (en) | 2011-01-25 |
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