KR101075404B1 - 지지된 비메탈로센 올레핀 중합 촉매, 제조 방법 및 그용도 - Google Patents

지지된 비메탈로센 올레핀 중합 촉매, 제조 방법 및 그용도 Download PDF

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Publication number
KR101075404B1
KR101075404B1 KR1020077016440A KR20077016440A KR101075404B1 KR 101075404 B1 KR101075404 B1 KR 101075404B1 KR 1020077016440 A KR1020077016440 A KR 1020077016440A KR 20077016440 A KR20077016440 A KR 20077016440A KR 101075404 B1 KR101075404 B1 KR 101075404B1
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catalyst
polymerization
olefin polymerization
solvent
carrier
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Expired - Lifetime
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KR1020077016440A
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Korean (ko)
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KR20070093114A (ko
Inventor
호울리앙 다이
호우핑 유
추안펭 리
지아올리 야오
리진 조우
지아오키앙 리
야밍 왕
종린 마
지예 바이
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양지 페트로케미컬 컴퍼니 코., 리미티드.
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Priority claimed from CN 200410066070 external-priority patent/CN1789291A/zh
Priority claimed from CNB2004100660686A external-priority patent/CN100362024C/zh
Priority claimed from CN 200410066069 external-priority patent/CN1789292A/zh
Application filed by 양지 페트로케미컬 컴퍼니 코., 리미티드. filed Critical 양지 페트로케미컬 컴퍼니 코., 리미티드.
Publication of KR20070093114A publication Critical patent/KR20070093114A/ko
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/02—Carriers therefor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerization Catalysts (AREA)
KR1020077016440A 2004-12-17 2005-10-21 지지된 비메탈로센 올레핀 중합 촉매, 제조 방법 및 그용도 Expired - Lifetime KR101075404B1 (ko)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
CN200410066070.3 2004-12-17
CN 200410066070 CN1789291A (zh) 2004-12-17 2004-12-17 负载型非茂金属催化剂的烯烃聚合和共聚合方法
CNB2004100660686A CN100362024C (zh) 2004-12-17 2004-12-17 非茂金属催化剂的高活性负载化方法
CN200410066069.0 2004-12-17
CN200410066068.6 2004-12-17
CN 200410066069 CN1789292A (zh) 2004-12-17 2004-12-17 负载型非茂金属催化剂在淤浆法乙烯聚合工艺中的应用方法

Publications (2)

Publication Number Publication Date
KR20070093114A KR20070093114A (ko) 2007-09-17
KR101075404B1 true KR101075404B1 (ko) 2011-10-24

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KR1020077016440A Expired - Lifetime KR101075404B1 (ko) 2004-12-17 2005-10-21 지지된 비메탈로센 올레핀 중합 촉매, 제조 방법 및 그용도

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Country Link
US (1) US7875568B2 (https=)
EP (1) EP1829897B1 (https=)
JP (1) JP5346469B2 (https=)
KR (1) KR101075404B1 (https=)
WO (1) WO2006063501A1 (https=)

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US8138285B2 (en) * 2007-10-26 2012-03-20 Fina Technology, Inc. Fluorinated impregnated catalyst systems and methods of forming the same
KR100996336B1 (ko) 2008-08-26 2010-11-24 삼성토탈 주식회사 폴리올레핀 중합용 촉매의 제조방법
JP5748415B2 (ja) * 2009-06-08 2015-07-15 三井化学株式会社 遷移金属化合物、オレフィン重合用触媒およびポリオレフィンの製造方法
WO2011050565A1 (zh) 2009-10-26 2011-05-05 中国石油化工股份有限公司 负载型非茂金属催化剂、其制备方法及其应用
WO2011050566A1 (zh) 2009-10-26 2011-05-05 中国石油化工股份有限公司 负载型非茂金属催化剂、其制备方法及其应用
US8952113B2 (en) * 2009-11-13 2015-02-10 China Petroleum & Chemical Corp. Supported nonmetallocene catalyst, preparation and use thereof
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CN102399313B (zh) * 2010-09-16 2013-09-11 中国石油化工股份有限公司 负载型非茂金属催化剂、其制备方法及其应用
CN102399318B (zh) * 2010-09-16 2013-11-06 中国石油化工股份有限公司 负载型非茂金属催化剂、其制备方法及其应用
JP6016426B2 (ja) * 2012-04-16 2016-10-26 三井化学株式会社 オレフィン重合用触媒
PT2841471T (pt) * 2012-04-27 2020-05-29 Grace W R & Co Composições de ativador, a sua preparação e a sua utilização em catalisadores
KR101799718B1 (ko) * 2014-01-22 2017-11-20 라이온델 케미칼 테크놀로지, 엘.피. 에폭시화 촉매의 제조 방법
CN105732852B (zh) * 2014-12-10 2018-08-10 中国石油天然气股份有限公司 Z-n催化剂
CN113754798A (zh) 2020-06-05 2021-12-07 中国石油化工股份有限公司 类球形超大孔介孔材料和聚烯烃催化剂及其制备方法以及烯烃聚合方法
CN112390902A (zh) * 2020-07-22 2021-02-23 北京锦吾新材科技有限公司 烯烃聚合工艺与应用
US20240117085A1 (en) * 2021-02-01 2024-04-11 China Petroleum & Chemical Corporation Ethylene polymer and preparation method therefor
JP7775318B2 (ja) * 2021-02-01 2025-11-25 中国石油化工股▲ふん▼有限公司 超高分子量ポリエチレンおよびその製造方法
CN115819644B (zh) * 2021-09-18 2024-01-09 中国科学技术大学 负载型催化剂及其制备方法和应用
CN115838448B (zh) * 2021-09-18 2024-01-09 中国科学技术大学 负载型催化剂及其制备方法和应用
CN113999334B (zh) * 2021-11-09 2023-08-29 上海化工研究院有限公司 一种用于烯烃聚合的催化剂及其制备方法与应用
CN116178595B (zh) * 2021-11-26 2024-07-12 中国石油天然气股份有限公司 烯烃聚合用负载茂金属催化剂及其制备方法和应用
CN116178594B (zh) * 2021-11-26 2024-07-16 中国石油天然气股份有限公司 烯烃聚合用原位负载茂金属催化剂及其制备方法和应用
CN116655676B (zh) * 2022-02-18 2025-08-29 中国石油天然气股份有限公司 一种非茂金属催化剂、聚丁烯-1弹性体及其制备方法
CN114605581B (zh) * 2022-03-11 2023-07-14 中国科学院青岛生物能源与过程研究所 一种功能化极性聚烯烃聚合物及其制备方法和应用
CN117659236A (zh) * 2023-10-19 2024-03-08 中国石油化工股份有限公司 一种宽分子量分布的茂金属聚乙烯的制备方法
CN121226589A (zh) * 2024-06-27 2025-12-30 中国石油天然气股份有限公司 双中心非茂金属催化剂及其制备方法和丁烯-1基弹性体及其制备方法
CN120349441B (zh) * 2025-06-25 2025-08-29 淄博新塑化工有限公司 一种复合型烯烃聚合催化剂及其制备方法

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Also Published As

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US20080227936A1 (en) 2008-09-18
JP2008524344A (ja) 2008-07-10
KR20070093114A (ko) 2007-09-17
EP1829897A1 (en) 2007-09-05
EP1829897A4 (en) 2012-04-25
JP5346469B2 (ja) 2013-11-20
WO2006063501A1 (fr) 2006-06-22
EP1829897B1 (en) 2014-12-10
US7875568B2 (en) 2011-01-25

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