JP4824561B2 - 微孔性pvdfフィルムおよび製造方法 - Google Patents

微孔性pvdfフィルムおよび製造方法 Download PDF

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JP4824561B2
JP4824561B2 JP2006526064A JP2006526064A JP4824561B2 JP 4824561 B2 JP4824561 B2 JP 4824561B2 JP 2006526064 A JP2006526064 A JP 2006526064A JP 2006526064 A JP2006526064 A JP 2006526064A JP 4824561 B2 JP4824561 B2 JP 4824561B2
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membrane
pvdf
polyvinylidene fluoride
copolymer
microporous
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Expired - Fee Related
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JP2006526064A
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Japanese (ja)
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JP2007505185A5 (https=
JP2007505185A (ja
Inventor
ディー. スミス,サマンサ
エイチ. シップマン,ジーン
エム. フロイド,ロバート
フリーマイヤー,エイチ.トッド
ジェイ. ハムロック,スティーブン
エー. ヤンドラシッツ,マイケル
ジー.エス. ワルトン,デイビッド
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3M Innovative Properties Co
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3M Innovative Properties Co
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/10Fuel cells with solid electrolytes
    • H01M8/1016Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018Polymeric electrolyte materials
    • H01M8/1041Polymer electrolyte composites, mixtures or blends
    • H01M8/1044Mixtures of polymers, of which at least one is ionically conductive
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D67/00Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0002Organic membrane manufacture
    • B01D67/0023Organic membrane manufacture by inducing porosity into non porous precursor membranes
    • B01D67/0025Organic membrane manufacture by inducing porosity into non porous precursor membranes by mechanical treatment, e.g. pore-stretching
    • B01D67/0027Organic membrane manufacture by inducing porosity into non porous precursor membranes by mechanical treatment, e.g. pore-stretching by stretching
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D67/00Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0002Organic membrane manufacture
    • B01D67/0009Organic membrane manufacture by phase separation, sol-gel transition, evaporation or solvent quenching
    • B01D67/00091Organic membrane manufacture by phase separation, sol-gel transition, evaporation or solvent quenching by evaporation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D67/00Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0002Organic membrane manufacture
    • B01D67/0009Organic membrane manufacture by phase separation, sol-gel transition, evaporation or solvent quenching
    • B01D67/0011Casting solutions therefor
    • B01D67/00111Polymer pretreatment in the casting solutions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D71/00Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06Organic material
    • B01D71/30Polyalkenyl halides
    • B01D71/32Polyalkenyl halides containing fluorine atoms
    • B01D71/34Polyvinylidene fluoride
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C55/00Shaping by stretching, e.g. drawing through a die; Apparatus therefor
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    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20Manufacture of shaped structures of ion-exchange resins
    • C08J5/22Films, membranes or diaphragms
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    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20Manufacture of shaped structures of ion-exchange resins
    • C08J5/22Films, membranes or diaphragms
    • C08J5/2206Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2275Heterogeneous membranes
    • C08J5/2281Heterogeneous membranes fluorine containing heterogeneous membranes
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    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/28Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum
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    • H01M8/102Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1023Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon, e.g. polyarylenes, polystyrenes or polybutadiene-styrenes
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    • H01M8/1039Polymeric electrolyte materials halogenated, e.g. sulfonated polyvinylidene fluorides
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    • H01M8/1041Polymer electrolyte composites, mixtures or blends
    • H01M8/1046Mixtures of at least one polymer and at least one additive
    • H01M8/1048Ion-conducting additives, e.g. ion-conducting particles, heteropolyacids, metal phosphate or polybenzimidazole with phosphoric acid
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    • H01M8/1018Polymeric electrolyte materials
    • H01M8/1058Polymeric electrolyte materials characterised by a porous support having no ion-conducting properties
    • H01M8/106Polymeric electrolyte materials characterised by a porous support having no ion-conducting properties characterised by the chemical composition of the porous support
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    • H01M8/1016Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018Polymeric electrolyte materials
    • H01M8/1069Polymeric electrolyte materials characterised by the manufacturing processes
    • H01M8/1079Inducing porosity into non porous precursors membranes, e.g. leaching, pore stretching
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
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    • H01M8/00Fuel cells; Manufacture thereof
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    • H01M8/1016Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018Polymeric electrolyte materials
    • H01M8/1069Polymeric electrolyte materials characterised by the manufacturing processes
    • H01M8/1083Starting from polymer melts other than monomer melts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2323/00Details relating to membrane preparation
    • B01D2323/46Impregnation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2325/00Details relating to properties of membranes
    • B01D2325/02Details relating to pores or porosity of the membranes
    • B01D2325/022Asymmetric membranes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2325/00Details relating to properties of membranes
    • B01D2325/20Specific permeability or cut-off range
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2325/00Details relating to properties of membranes
    • B01D2325/24Mechanical properties, e.g. strength
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/12Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08J2327/16Homopolymers or copolymers of vinylidene fluoride
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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  • Chemical & Material Sciences (AREA)
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  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Electrochemistry (AREA)
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  • Composite Materials (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Laminated Bodies (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Cell Separators (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
JP2006526064A 2003-09-12 2004-07-06 微孔性pvdfフィルムおよび製造方法 Expired - Fee Related JP4824561B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US10/661,908 US7338692B2 (en) 2003-09-12 2003-09-12 Microporous PVDF films
US10/661,908 2003-09-12
PCT/US2004/021609 WO2005035641A1 (en) 2003-09-12 2004-07-06 Microporous pvdf films and method of manufacturing

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Publication Number Publication Date
JP2007505185A JP2007505185A (ja) 2007-03-08
JP2007505185A5 JP2007505185A5 (https=) 2007-08-23
JP4824561B2 true JP4824561B2 (ja) 2011-11-30

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US (3) US7338692B2 (https=)
EP (1) EP1678245B1 (https=)
JP (1) JP4824561B2 (https=)
KR (1) KR20060122829A (https=)
CN (1) CN1867622B (https=)
AT (1) ATE462748T1 (https=)
BR (1) BRPI0414260A (https=)
DE (1) DE602004026337D1 (https=)
MX (1) MXPA06002795A (https=)
WO (1) WO2005035641A1 (https=)

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JP4427291B2 (ja) * 2003-09-03 2010-03-03 東亞合成株式会社 機能性膜の連続製造方法
US7338692B2 (en) * 2003-09-12 2008-03-04 3M Innovative Properties Company Microporous PVDF films
GB0509422D0 (en) * 2005-05-09 2005-06-15 Mabtech Ab Membranes
JP5044132B2 (ja) * 2005-07-07 2012-10-10 富士フイルム株式会社 固体電解質フィルムの製造方法及び製造設備
JP4969126B2 (ja) * 2005-07-07 2012-07-04 富士フイルム株式会社 固体電解質フィルム及びその製造方法、製造設備並びに電極膜複合体及び燃料電池
PT103318B (pt) * 2005-07-19 2009-01-22 Univ Do Minho Filmes não porosos na fase beta de poli(fluoreto de vinilideno) (pvdf) e método para o seu processamento
CN100404114C (zh) * 2005-09-02 2008-07-23 清华大学 热致相分离工艺制备聚偏氟乙烯平板微孔膜的方法
US20070128425A1 (en) * 2005-12-07 2007-06-07 3M Innovative Properties Company Reinforced ion-conductive membranes
EP1968792B1 (en) * 2005-12-30 2013-12-11 3M Innovative Properties Company Functionalized substrates
US20090110998A1 (en) * 2006-03-30 2009-04-30 Fujifilm Corporation Solid electrolyte membrane, method and apparatus for producing the same, membrane electrode assembly and fuel cell
DE602007002769D1 (de) * 2006-05-09 2009-11-26 Porex Corp Poröse materialzusammensatzungen für membranen und zugehöroge anwendungen
WO2007147167A2 (en) * 2006-06-16 2007-12-21 Porous Power Technologies, Llc Optimized microporous structure of electrochemical cells
US20080107564A1 (en) * 2006-07-20 2008-05-08 Shmuel Sternberg Medical fluid access site with antiseptic indicator
JP5118389B2 (ja) * 2007-05-26 2013-01-16 中村製作所株式会社 ワークへの凹所形成方法
US8513322B2 (en) * 2007-05-31 2013-08-20 3M Innovative Properties Company Polymeric beads and methods of making polymeric beads
USRE47452E1 (en) 2007-07-20 2019-06-25 Baxter International Inc. Antimicrobial housing and cover for a medical device
US9125973B2 (en) 2007-07-20 2015-09-08 Baxter International Inc. Antimicrobial housing and cover for a medical device
US20090045544A1 (en) * 2007-08-14 2009-02-19 General Electric Company Method for manufacturing ultra-thin polymeric films
US20090098359A1 (en) * 2007-10-11 2009-04-16 Waller Jr Clinton P Hydrophilic porous substrates
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