JP2020502327A5 - - Google Patents
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- Publication number
- JP2020502327A5 JP2020502327A5 JP2019531971A JP2019531971A JP2020502327A5 JP 2020502327 A5 JP2020502327 A5 JP 2020502327A5 JP 2019531971 A JP2019531971 A JP 2019531971A JP 2019531971 A JP2019531971 A JP 2019531971A JP 2020502327 A5 JP2020502327 A5 JP 2020502327A5
- Authority
- JP
- Japan
- Prior art keywords
- butylfluorene
- cyclopentadienyl
- methylene
- tert
- isopropylphenyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000003054 catalyst Substances 0.000 claims 14
- 238000000034 method Methods 0.000 claims 8
- 125000003118 aryl group Chemical group 0.000 claims 6
- 229920006395 saturated elastomer Polymers 0.000 claims 6
- 125000005842 heteroatom Chemical group 0.000 claims 5
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 5
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 5
- LWNGJAHMBMVCJR-UHFFFAOYSA-N (2,3,4,5,6-pentafluorophenoxy)boronic acid Chemical compound OB(O)OC1=C(F)C(F)=C(F)C(F)=C1F LWNGJAHMBMVCJR-UHFFFAOYSA-N 0.000 claims 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 4
- 125000002877 alkyl aryl group Chemical group 0.000 claims 4
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 claims 4
- 238000006116 polymerization reaction Methods 0.000 claims 4
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims 3
- 229910052796 boron Inorganic materials 0.000 claims 3
- 229920001038 ethylene copolymer Polymers 0.000 claims 3
- 125000005843 halogen group Chemical group 0.000 claims 3
- 125000001072 heteroaryl group Chemical group 0.000 claims 3
- 229930195733 hydrocarbon Natural products 0.000 claims 3
- 150000002430 hydrocarbons Chemical class 0.000 claims 3
- 125000006546 (C4-C10) cycloalkyl group Chemical group 0.000 claims 2
- 239000004215 Carbon black (E152) Substances 0.000 claims 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 2
- 239000005977 Ethylene Substances 0.000 claims 2
- 125000000217 alkyl group Chemical group 0.000 claims 2
- 125000003710 aryl alkyl group Chemical group 0.000 claims 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims 2
- 239000003426 co-catalyst Substances 0.000 claims 2
- 125000000753 cycloalkyl group Chemical group 0.000 claims 2
- 239000004711 α-olefin Substances 0.000 claims 2
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 claims 1
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims 1
- QWUWMCYKGHVNAV-UHFFFAOYSA-N 1,2-dihydrostilbene Chemical group C=1C=CC=CC=1CCC1=CC=CC=C1 QWUWMCYKGHVNAV-UHFFFAOYSA-N 0.000 claims 1
- XTFIVUDBNACUBN-UHFFFAOYSA-N 1,3,5-trinitro-1,3,5-triazinane Chemical compound [O-][N+](=O)N1CN([N+]([O-])=O)CN([N+]([O-])=O)C1 XTFIVUDBNACUBN-UHFFFAOYSA-N 0.000 claims 1
- SVYKKECYCPFKGB-UHFFFAOYSA-N N,N-dimethylcyclohexylamine Chemical compound CN(C)C1CCCCC1 SVYKKECYCPFKGB-UHFFFAOYSA-N 0.000 claims 1
- ONMVTOSZWOATRS-UHFFFAOYSA-L [Cl-].[Cl-].C(C)(C)C1=CC=C(C=C1)C(=[Hf+2](C1C2=CC(=CC=C2C=2C=CC(=CC1=2)C(C)(C)C)C(C)(C)C)C1C=CC=C1)C1CCC1 Chemical compound [Cl-].[Cl-].C(C)(C)C1=CC=C(C=C1)C(=[Hf+2](C1C2=CC(=CC=C2C=2C=CC(=CC1=2)C(C)(C)C)C(C)(C)C)C1C=CC=C1)C1CCC1 ONMVTOSZWOATRS-UHFFFAOYSA-L 0.000 claims 1
- YRCJJVYPPMVDNA-UHFFFAOYSA-L [Cl-].[Cl-].C(C)(C)C1=CC=C(C=C1)C(=[Hf+2](C1C2=CC(=CC=C2C=2C=CC(=CC1=2)C(C)(C)C)C(C)(C)C)C1C=CC=C1)C1CCCC1 Chemical compound [Cl-].[Cl-].C(C)(C)C1=CC=C(C=C1)C(=[Hf+2](C1C2=CC(=CC=C2C=2C=CC(=CC1=2)C(C)(C)C)C(C)(C)C)C1C=CC=C1)C1CCCC1 YRCJJVYPPMVDNA-UHFFFAOYSA-L 0.000 claims 1
- LSVZCIRHRWZPTE-UHFFFAOYSA-L [Cl-].[Cl-].C(C)(C)C1=CC=C(C=C1)C(=[Hf+2](C1C2=CC(=CC=C2C=2C=CC(=CC1=2)C(C)(C)C)C(C)(C)C)C1C=CC=C1)C1CCCCC1 Chemical compound [Cl-].[Cl-].C(C)(C)C1=CC=C(C=C1)C(=[Hf+2](C1C2=CC(=CC=C2C=2C=CC(=CC1=2)C(C)(C)C)C(C)(C)C)C1C=CC=C1)C1CCCCC1 LSVZCIRHRWZPTE-UHFFFAOYSA-L 0.000 claims 1
- OEHSYQRZNOODOH-UHFFFAOYSA-L [Cl-].[Cl-].C(C)(C)C=1C=C(C=C(C=1)C(C)C)C(=[Hf+2](C1C2=CC(=CC=C2C=2C=CC(=CC1=2)C(C)(C)C)C(C)(C)C)C1C=CC=C1)C1CCC1 Chemical compound [Cl-].[Cl-].C(C)(C)C=1C=C(C=C(C=1)C(C)C)C(=[Hf+2](C1C2=CC(=CC=C2C=2C=CC(=CC1=2)C(C)(C)C)C(C)(C)C)C1C=CC=C1)C1CCC1 OEHSYQRZNOODOH-UHFFFAOYSA-L 0.000 claims 1
- WADHYVLTBPIBEK-UHFFFAOYSA-L [Cl-].[Cl-].C(C)(C)C=1C=C(C=C(C=1)C(C)C)C(=[Hf+2](C1C2=CC(=CC=C2C=2C=CC(=CC1=2)C(C)(C)C)C(C)(C)C)C1C=CC=C1)C1CCCC1 Chemical compound [Cl-].[Cl-].C(C)(C)C=1C=C(C=C(C=1)C(C)C)C(=[Hf+2](C1C2=CC(=CC=C2C=2C=CC(=CC1=2)C(C)(C)C)C(C)(C)C)C1C=CC=C1)C1CCCC1 WADHYVLTBPIBEK-UHFFFAOYSA-L 0.000 claims 1
- PURJWWPDSBUQGG-UHFFFAOYSA-L [Cl-].[Cl-].C(C)(C)C=1C=C(C=C(C=1)C(C)C)C(=[Hf+2](C1C2=CC(=CC=C2C=2C=CC(=CC1=2)C(C)(C)C)C(C)(C)C)C1C=CC=C1)C1CCCCC1 Chemical compound [Cl-].[Cl-].C(C)(C)C=1C=C(C=C(C=1)C(C)C)C(=[Hf+2](C1C2=CC(=CC=C2C=2C=CC(=CC1=2)C(C)(C)C)C(C)(C)C)C1C=CC=C1)C1CCCCC1 PURJWWPDSBUQGG-UHFFFAOYSA-L 0.000 claims 1
- MOTSWIZLEAPLMJ-UHFFFAOYSA-L [Cl-].[Cl-].C1(=CC=CC=C1)C(=[Hf+2](C1C2=CC(=CC=C2C=2C=CC(=CC1=2)C(C)(C)C)C(C)(C)C)C1C=CC=C1)C1CCC1 Chemical compound [Cl-].[Cl-].C1(=CC=CC=C1)C(=[Hf+2](C1C2=CC(=CC=C2C=2C=CC(=CC1=2)C(C)(C)C)C(C)(C)C)C1C=CC=C1)C1CCC1 MOTSWIZLEAPLMJ-UHFFFAOYSA-L 0.000 claims 1
- DHQQPROSBWJUIU-UHFFFAOYSA-L [Cl-].[Cl-].C1(=CC=CC=C1)C(=[Hf+2](C1C2=CC(=CC=C2C=2C=CC(=CC1=2)C(C)(C)C)C(C)(C)C)C1C=CC=C1)C1CCCC1 Chemical compound [Cl-].[Cl-].C1(=CC=CC=C1)C(=[Hf+2](C1C2=CC(=CC=C2C=2C=CC(=CC1=2)C(C)(C)C)C(C)(C)C)C1C=CC=C1)C1CCCC1 DHQQPROSBWJUIU-UHFFFAOYSA-L 0.000 claims 1
- NCJFTUWQPXPFID-UHFFFAOYSA-L [Cl-].[Cl-].C1(=CC=CC=C1)C(=[Hf+2](C1C2=CC(=CC=C2C=2C=CC(=CC1=2)C(C)(C)C)C(C)(C)C)C1C=CC=C1)C1CCCCC1 Chemical compound [Cl-].[Cl-].C1(=CC=CC=C1)C(=[Hf+2](C1C2=CC(=CC=C2C=2C=CC(=CC1=2)C(C)(C)C)C(C)(C)C)C1C=CC=C1)C1CCCCC1 NCJFTUWQPXPFID-UHFFFAOYSA-L 0.000 claims 1
- 125000002015 acyclic group Chemical group 0.000 claims 1
- 150000001450 anions Chemical class 0.000 claims 1
- 239000003849 aromatic solvent Substances 0.000 claims 1
- 230000003197 catalytic effect Effects 0.000 claims 1
- 125000001309 chloro group Chemical group Cl* 0.000 claims 1
- 238000007334 copolymerization reaction Methods 0.000 claims 1
- 125000004122 cyclic group Chemical group 0.000 claims 1
- 239000003085 diluting agent Substances 0.000 claims 1
- JLTDJTHDQAWBAV-UHFFFAOYSA-O dimethyl(phenyl)azanium Chemical compound C[NH+](C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-O 0.000 claims 1
- XXBDWLFCJWSEKW-UHFFFAOYSA-N dimethylbenzylamine Chemical compound CN(C)CC1=CC=CC=C1 XXBDWLFCJWSEKW-UHFFFAOYSA-N 0.000 claims 1
- 229910052735 hafnium Inorganic materials 0.000 claims 1
- 239000003446 ligand Substances 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 125000001037 p-tolyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C([H])([H])[H] 0.000 claims 1
- 230000000379 polymerizing effect Effects 0.000 claims 1
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 239000007787 solid Substances 0.000 claims 1
- 239000002904 solvent Substances 0.000 claims 1
- 125000001424 substituent group Chemical group 0.000 claims 1
- OLFPYUPGPBITMH-UHFFFAOYSA-N tritylium Chemical compound C1=CC=CC=C1[C+](C=1C=CC=CC=1)C1=CC=CC=C1 OLFPYUPGPBITMH-UHFFFAOYSA-N 0.000 claims 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP16204328.5 | 2016-12-15 | ||
| EP16204328 | 2016-12-15 | ||
| PCT/EP2017/082434 WO2018108918A1 (en) | 2016-12-15 | 2017-12-12 | Catalyst system for producing polyethylene copolymers in a high temperature solution polymerization process |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2020502327A JP2020502327A (ja) | 2020-01-23 |
| JP2020502327A5 true JP2020502327A5 (enExample) | 2021-01-28 |
| JP7130644B2 JP7130644B2 (ja) | 2022-09-05 |
Family
ID=57614134
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2019531971A Active JP7130644B2 (ja) | 2016-12-15 | 2017-12-12 | 高温溶液重合プロセスでポリエチレンコポリマーを製造する為の新規な触媒系 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US11279781B2 (enExample) |
| EP (1) | EP3555148B1 (enExample) |
| JP (1) | JP7130644B2 (enExample) |
| KR (1) | KR102534541B1 (enExample) |
| CN (1) | CN110234665B (enExample) |
| ES (1) | ES2943392T3 (enExample) |
| WO (1) | WO2018108918A1 (enExample) |
Families Citing this family (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11352376B2 (en) | 2016-11-18 | 2022-06-07 | Borealis Ag | Catalysts |
| KR102618904B1 (ko) | 2016-12-29 | 2023-12-27 | 보레알리스 아게 | 촉매 |
| JP7297782B2 (ja) | 2018-03-19 | 2023-06-26 | ボレアリス エージー | オレフィン重合用触媒 |
| JP7440431B2 (ja) | 2018-06-28 | 2024-02-28 | ボレアリス エージー | 触媒 |
| US12202964B2 (en) | 2019-01-28 | 2025-01-21 | Borealis Ag | Polymer composition |
| EP3917750B1 (en) | 2019-01-28 | 2025-12-17 | Borealis GmbH | Polymer composition |
| WO2020178010A1 (en) | 2019-03-04 | 2020-09-10 | Borealis Ag | Polymerization process |
| EP3763745A1 (en) | 2019-07-10 | 2021-01-13 | Borealis AG | High temperature solution process for the copolymerization of alpha-olefins |
| CN114423769B (zh) * | 2019-09-20 | 2024-04-26 | Sabic环球技术有限责任公司 | 用于生产聚烯烃的催化剂组合物中的化合物 |
| EP3838933A1 (en) | 2019-12-20 | 2021-06-23 | Borealis AG | Polymerization process and reactor for controlling molecular weight distribution and comonomer composition distribution |
| EP3845572A1 (en) | 2020-01-02 | 2021-07-07 | Borealis AG | Process for the polymerization of olefins in solution with controlled activity of catalyst in reactor outlet stream |
| EP3845569A1 (en) | 2020-01-02 | 2021-07-07 | Borealis AG | Process for the polymerization of olefins in solution comprising deactivating the polymerization catalyst by heat |
| EP4179035B1 (en) | 2020-07-13 | 2026-03-04 | Borealis GmbH | Adhesive polyethylene composition |
| US20230250319A1 (en) | 2020-07-13 | 2023-08-10 | Borealis Ag | Adhesive polyethylene composition |
| WO2022018293A1 (en) * | 2020-07-23 | 2022-01-27 | Borealis Ag | Metallocene complexes and catalysts made therefrom |
| KR102897897B1 (ko) | 2020-09-30 | 2025-12-08 | 보레알리스 게엠베하 | 개선된 용융 및 유리 전이 온도를 갖는 에틸렌 코폴리머 |
| BR112023006045A2 (pt) | 2020-09-30 | 2023-05-09 | Borealis Ag | Copolímero de etileno e uma alfa-olefina |
| EP4222181A1 (en) * | 2020-09-30 | 2023-08-09 | Borealis AG | Ethylene-octene copolymers with improved property profile |
| CN116234871A (zh) | 2020-09-30 | 2023-06-06 | 博里利斯股份公司 | 用于生产在线混合的聚合物的设备和方法 |
| WO2022073805A1 (en) | 2020-10-05 | 2022-04-14 | Borealis Ag | High temperature solution process for the copolymerization of ethylene with one ore more α-Olefin comonomer(s) |
| CN114437261B (zh) * | 2020-11-02 | 2024-03-26 | 中国石油化工股份有限公司 | 一种烯烃聚合茂金属催化剂及其制备方法和应用 |
| KR20230117424A (ko) | 2020-12-08 | 2023-08-08 | 보레알리스 아게 | 중합 방법 및 장치 |
| US20230416429A1 (en) * | 2020-12-11 | 2023-12-28 | Nova Chemicals (International) S.A. | High crystallinity ethylene-vinylcyclohexane copolymers |
| US20240002561A1 (en) * | 2020-12-11 | 2024-01-04 | Nova Chemicals (International) S.A. | Low crystallinity ethylene-vinylcyclohexane copolymers |
| BR112023021116A2 (pt) | 2021-04-16 | 2023-12-12 | Borealis Ag | Copolímeros de etileno com estruturas moleculares homogêneas melhoradas |
| EP4137521A1 (en) | 2021-08-16 | 2023-02-22 | Borealis AG | Process for producing a polyolefin with low volatile content |
| EP4219599A1 (en) | 2022-01-28 | 2023-08-02 | Borealis AG | Polyethylene blend for a film layer |
| EP4424414A1 (en) | 2023-02-28 | 2024-09-04 | Borealis AG | Rapid mixing polymerization reactor and process |
| EP4424413A1 (en) | 2023-02-28 | 2024-09-04 | Borealis AG | Rapid mixing polymerization process |
| KR102869729B1 (ko) * | 2023-12-26 | 2025-10-14 | 디엘케미칼 주식회사 | 에틸렌/알파올레핀 공중합체 및 이의 제조방법 |
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2017
- 2017-12-12 JP JP2019531971A patent/JP7130644B2/ja active Active
- 2017-12-12 US US16/469,617 patent/US11279781B2/en active Active
- 2017-12-12 EP EP17811610.9A patent/EP3555148B1/en active Active
- 2017-12-12 WO PCT/EP2017/082434 patent/WO2018108918A1/en not_active Ceased
- 2017-12-12 ES ES17811610T patent/ES2943392T3/es active Active
- 2017-12-12 KR KR1020197020143A patent/KR102534541B1/ko active Active
- 2017-12-12 CN CN201780085191.8A patent/CN110234665B/zh active Active
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