JP2017160196A5 - - Google Patents
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- JP2017160196A5 JP2017160196A5 JP2017041011A JP2017041011A JP2017160196A5 JP 2017160196 A5 JP2017160196 A5 JP 2017160196A5 JP 2017041011 A JP2017041011 A JP 2017041011A JP 2017041011 A JP2017041011 A JP 2017041011A JP 2017160196 A5 JP2017160196 A5 JP 2017160196A5
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- JP
- Japan
- Prior art keywords
- carbon atoms
- hydrocarbon group
- group
- atom
- halogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000005977 Ethylene Substances 0.000 claims description 45
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 44
- 238000006116 polymerization reaction Methods 0.000 claims description 25
- 150000001875 compounds Chemical class 0.000 claims description 22
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 21
- 238000004519 manufacturing process Methods 0.000 claims description 11
- 229910052757 nitrogen Inorganic materials 0.000 claims description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- 229920000573 polyethylene Polymers 0.000 claims description 6
- 239000003054 catalyst Substances 0.000 claims description 5
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- 125000001424 substituent group Chemical group 0.000 claims description 3
- 150000002430 hydrocarbons Chemical group 0.000 claims 41
- 125000004432 carbon atom Chemical group C* 0.000 claims 36
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 15
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 14
- 229910052736 halogen Inorganic materials 0.000 claims 13
- 239000004215 Carbon black (E152) Substances 0.000 claims 12
- 229930195733 hydrocarbon Natural products 0.000 claims 12
- 229910052799 carbon Inorganic materials 0.000 claims 11
- 150000002367 halogens Chemical class 0.000 claims 11
- 229910052710 silicon Inorganic materials 0.000 claims 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 9
- 229910052760 oxygen Inorganic materials 0.000 claims 9
- 239000001301 oxygen Substances 0.000 claims 9
- 150000001336 alkenes Chemical class 0.000 claims 8
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 8
- 150000001721 carbon Chemical group 0.000 claims 7
- 239000010703 silicon Substances 0.000 claims 6
- 125000003808 silyl group Chemical class [H][Si]([H])([H])[*] 0.000 claims 6
- 125000003277 amino group Chemical class 0.000 claims 5
- 229920000098 polyolefin Polymers 0.000 claims 5
- 229910052726 zirconium Inorganic materials 0.000 claims 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 4
- 229910052735 hafnium Inorganic materials 0.000 claims 4
- 239000002685 polymerization catalyst Substances 0.000 claims 4
- 125000003545 alkoxy group Chemical class 0.000 claims 3
- 125000004429 atom Chemical group 0.000 claims 3
- 229910052732 germanium Inorganic materials 0.000 claims 3
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical group [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims 3
- 229910052719 titanium Inorganic materials 0.000 claims 3
- 229910052723 transition metal Inorganic materials 0.000 claims 3
- 150000003624 transition metals Chemical class 0.000 claims 3
- 125000003860 C1-C20 alkoxy group Chemical class 0.000 claims 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims 2
- 125000005843 halogen group Chemical group 0.000 claims 2
- 125000003118 aryl group Chemical group 0.000 claims 1
- 125000002091 cationic group Chemical group 0.000 claims 1
- 239000010419 fine particle Substances 0.000 claims 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims 1
- 125000004430 oxygen atom Chemical group O* 0.000 claims 1
- 230000000737 periodic effect Effects 0.000 claims 1
- 229910052717 sulfur Inorganic materials 0.000 claims 1
- 125000004434 sulfur atom Chemical group 0.000 claims 1
- 239000011949 solid catalyst Substances 0.000 description 57
- VXNZUUAINFGPBY-UHFFFAOYSA-N ethyl ethylene Natural products CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 54
- 229920001577 copolymer Polymers 0.000 description 45
- 238000002360 preparation method Methods 0.000 description 30
- 230000000052 comparative effect Effects 0.000 description 12
- 229940126062 Compound A Drugs 0.000 description 10
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 description 10
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 10
- 239000001257 hydrogen Substances 0.000 description 10
- 229910052739 hydrogen Inorganic materials 0.000 description 10
- 238000003756 stirring Methods 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
- 150000002431 hydrogen Chemical class 0.000 description 5
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Chemical compound C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical compound C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 description 2
- 239000012299 nitrogen atmosphere Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 2
- VDVAMDZTDPBPFB-UHFFFAOYSA-N 2-cyclopenta-2,4-dien-1-ylthiophene Chemical group C1=CC=CC1C1=CC=CS1 VDVAMDZTDPBPFB-UHFFFAOYSA-N 0.000 description 1
- KVPBSBOTFRNKOM-UHFFFAOYSA-N 2h-cyclopenta[b]thiophene Chemical compound C1=CC2=CCSC2=C1 KVPBSBOTFRNKOM-UHFFFAOYSA-N 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- JNGZXGGOCLZBFB-IVCQMTBJSA-N compound E Chemical compound N([C@@H](C)C(=O)N[C@@H]1C(N(C)C2=CC=CC=C2C(C=2C=CC=CC=2)=N1)=O)C(=O)CC1=CC(F)=CC(F)=C1 JNGZXGGOCLZBFB-IVCQMTBJSA-N 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000001282 iso-butane Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000037048 polymerization activity Effects 0.000 description 1
- LVTJOONKWUXEFR-FZRMHRINSA-N protoneodioscin Natural products O(C[C@@H](CC[C@]1(O)[C@H](C)[C@@H]2[C@]3(C)[C@H]([C@H]4[C@@H]([C@]5(C)C(=CC4)C[C@@H](O[C@@H]4[C@H](O[C@H]6[C@@H](O)[C@@H](O)[C@@H](O)[C@H](C)O6)[C@@H](O)[C@H](O[C@H]6[C@@H](O)[C@@H](O)[C@@H](O)[C@H](C)O6)[C@H](CO)O4)CC5)CC3)C[C@@H]2O1)C)[C@H]1[C@H](O)[C@H](O)[C@H](O)[C@@H](CO)O1 LVTJOONKWUXEFR-FZRMHRINSA-N 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 150000003613 toluenes Chemical class 0.000 description 1
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110776553.6A CN113637036A (zh) | 2016-03-04 | 2017-03-21 | 茂金属化合物、烯烃聚合用催化剂组分和烯烃聚合用催化剂、和生产烯烃聚合物的方法 |
| CN201780015273.5A CN108811500A (zh) | 2016-03-04 | 2017-03-21 | 茂金属化合物、包含其的烯烃聚合用催化剂组分和烯烃聚合用催化剂、和使用烯烃聚合用催化剂生产烯烃聚合物的方法 |
| PCT/JP2017/011281 WO2018158966A1 (ja) | 2016-03-04 | 2017-03-21 | メタロセン化合物、それを含むオレフィン重合用触媒成分およびオレフィン重合用触媒、並びにそのオレフィン重合用触媒を用いたオレフィン重合体の製造方法 |
| CN202410276949.8A CN118290622A (zh) | 2016-03-04 | 2017-03-21 | 茂金属化合物、包含其的烯烃聚合用催化剂组分和烯烃聚合用催化剂、和使用烯烃聚合用催化剂生产烯烃聚合物的方法 |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2016042853 | 2016-03-04 | ||
| JP2016042853 | 2016-03-04 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2017160196A JP2017160196A (ja) | 2017-09-14 |
| JP2017160196A5 true JP2017160196A5 (enExample) | 2019-11-28 |
| JP6787188B2 JP6787188B2 (ja) | 2020-11-18 |
Family
ID=59743009
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2017041011A Active JP6787188B2 (ja) | 2016-03-04 | 2017-03-03 | メタロセン化合物、それを含むオレフィン重合用触媒成分およびオレフィン重合用触媒、並びにそのオレフィン重合用触媒を用いたオレフィン重合体の製造方法 |
Country Status (5)
| Country | Link |
|---|---|
| US (2) | US10919994B2 (enExample) |
| EP (1) | EP3424937B1 (enExample) |
| JP (1) | JP6787188B2 (enExample) |
| CN (3) | CN108811500A (enExample) |
| WO (2) | WO2017150731A1 (enExample) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP7106971B2 (ja) * | 2017-05-10 | 2022-07-27 | 日本ポリエチレン株式会社 | オレフィン重合体の製造方法 |
| JP7676863B2 (ja) * | 2020-03-24 | 2025-05-15 | 日本ポリプロ株式会社 | オレフィン重合用担持系触媒、及び、当該オレフィン重合用担持系触媒を用いたプロピレン系重合体の製造方法 |
| CN114890987B (zh) * | 2022-04-13 | 2023-12-19 | 万华化学集团股份有限公司 | 一种硫酚-噻吩配体及其制备方法、烯烃聚合催化剂及其制备方法、应用 |
| CN117164616A (zh) * | 2022-05-27 | 2023-12-05 | 中国石油化工股份有限公司 | 茂金属配合物及制备方法和催化剂组合物及其用途 |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0543619A (ja) | 1991-08-16 | 1993-02-23 | Showa Denko Kk | 分岐を持つポリエチレンの製造方法及び触媒成分 |
| US5278272A (en) | 1991-10-15 | 1994-01-11 | The Dow Chemical Company | Elastic substantialy linear olefin polymers |
| ATE304025T1 (de) | 1994-04-07 | 2005-09-15 | Innovene Europ Ltd | Copolymere |
| US6444833B1 (en) | 1999-12-15 | 2002-09-03 | Basell Technology Company Bv | Metallocene compounds, process for their preparation and their use in catalytic systems for the polymerization of olefins |
| DE60045930D1 (de) | 1999-12-28 | 2011-06-16 | Basell Polyolefine Gmbh | Heterocyclische Metallocene und ihre Verwendung in Katalysatorsystemen zur Herstellung von Olefin Polymeren |
| JP4571798B2 (ja) * | 2001-06-12 | 2010-10-27 | バーゼル・ポリオレフィン・ゲーエムベーハー | １−ブテンの重合方法 |
| DE10145453A1 (de) * | 2001-09-14 | 2003-06-05 | Basell Polyolefine Gmbh | Monocyclopentadienylkomplexe mit einem kondensierten Heterocyclus |
| ES2268126T3 (es) * | 2001-11-30 | 2007-03-16 | Basell Polyolefine Gmbh | Compuestos de metaloceno y procedimiento para la preparacion de polimeros de propileno. |
| JP2005538198A (ja) * | 2002-09-06 | 2005-12-15 | バセル ポリオレフィン ジーエムビーエイチ | エチレンの共重合方法 |
| JP5006783B2 (ja) * | 2004-07-13 | 2012-08-22 | バーゼル・ポリオレフィン・ゲーエムベーハー | メタロセン化合物、それらの調製で使用される配位子、１−ブテンポリマーの調製法、およびその方法から得られる１−ブテンポリマー |
| DE102004056104A1 (de) * | 2004-11-19 | 2006-05-24 | Basell Polyolefine Gmbh | Verfahren zur Herstellung von niedermolekularen Olefinpolymeren, Organoübergangsmetallverbindungen, Biscyclopentadienylligandsysteme und Katalysatorsysteme |
| WO2006065843A2 (en) | 2004-12-16 | 2006-06-22 | Exxonmobil Chemical Patents Inc. | Halogen substituted metallocene compounds for olefin polymerization |
| US20090234084A1 (en) * | 2005-06-30 | 2009-09-17 | Basell Polyolefine Gmbh | Metallocene Compounds |
| JP5205726B2 (ja) | 2006-08-22 | 2013-06-05 | 東ソー株式会社 | 遷移金属化合物、オレフィン重合用触媒、およびポリオレフィンの製造方法 |
| US20100286124A1 (en) * | 2009-04-10 | 2010-11-11 | Auspex Pharmaceuticals, Inc. | Prop-2-yn-1-amine inhibitors of monoamine oxidase type b |
| JP5487089B2 (ja) * | 2009-12-02 | 2014-05-07 | 日本ポリエチレン株式会社 | エチレン系重合体の製造方法 |
| CN104558058B (zh) * | 2013-10-12 | 2017-08-08 | 中国科学院长春应用化学研究所 | 茂金属配合物及其制备方法、催化剂组合物 |
-
2017
- 2017-03-03 WO PCT/JP2017/008621 patent/WO2017150731A1/ja not_active Ceased
- 2017-03-03 US US16/081,311 patent/US10919994B2/en active Active
- 2017-03-03 JP JP2017041011A patent/JP6787188B2/ja active Active
- 2017-03-03 EP EP17760193.7A patent/EP3424937B1/en active Active
- 2017-03-21 CN CN201780015273.5A patent/CN108811500A/zh active Pending
- 2017-03-21 WO PCT/JP2017/011281 patent/WO2018158966A1/ja not_active Ceased
- 2017-03-21 CN CN202410276949.8A patent/CN118290622A/zh active Pending
- 2017-03-21 CN CN202110776553.6A patent/CN113637036A/zh active Pending
-
2020
- 2020-12-22 US US17/130,803 patent/US11485808B2/en active Active
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