JP2017523066A - 熱成形用途のための導電性多層シート - Google Patents
熱成形用途のための導電性多層シート Download PDFInfo
- Publication number
- JP2017523066A JP2017523066A JP2017506697A JP2017506697A JP2017523066A JP 2017523066 A JP2017523066 A JP 2017523066A JP 2017506697 A JP2017506697 A JP 2017506697A JP 2017506697 A JP2017506697 A JP 2017506697A JP 2017523066 A JP2017523066 A JP 2017523066A
- Authority
- JP
- Japan
- Prior art keywords
- substrate
- multilayer sheet
- curable coating
- coating layer
- conductive layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/12—Chemical modification
- C08J7/16—Chemical modification with polymerisable compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/044—Forming conductive coatings; Forming coatings having anti-static properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B11/00—Making preforms
- B29B11/06—Making preforms by moulding the material
- B29B11/12—Compression moulding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B13/00—Conditioning or physical treatment of the material to be shaped
- B29B13/08—Conditioning or physical treatment of the material to be shaped by using wave energy or particle radiation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C51/00—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
- B29C51/002—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor characterised by the choice of material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C51/00—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
- B29C51/02—Combined thermoforming and manufacture of the preform
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C51/00—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
- B29C51/10—Forming by pressure difference, e.g. vacuum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C51/00—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
- B29C51/14—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor using multilayered preforms or sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
- B32B27/365—Layered products comprising a layer of synthetic resin comprising polyesters comprising polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/042—Coating with two or more layers, where at least one layer of a composition contains a polymer binder
- C08J7/0423—Coating with two or more layers, where at least one layer of a composition contains a polymer binder with at least one layer of inorganic material and at least one layer of a composition containing a polymer binder
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/043—Improving the adhesiveness of the coatings per se, e.g. forming primers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/046—Forming abrasion-resistant coatings; Forming surface-hardening coatings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/12—Chemical modification
- C08J7/16—Chemical modification with polymerisable compounds
- C08J7/18—Chemical modification with polymerisable compounds using wave energy or particle radiation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/07—Aldehydes; Ketones
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/24—Electrically-conducting paints
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2069/00—Use of PC, i.e. polycarbonates or derivatives thereof, as moulding material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/25—Solid
- B29K2105/253—Preform
- B29K2105/256—Sheets, plates, blanks or films
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/10—Coating on the layer surface on synthetic resin layer or on natural or synthetic rubber layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/26—Polymeric coating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2369/00—Characterised by the use of polycarbonates; Derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2433/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2433/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2433/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
- C08J2433/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C08J2433/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2435/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least one other carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Derivatives of such polymers
- C08J2435/02—Characterised by the use of homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2475/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2475/04—Polyurethanes
- C08J2475/14—Polyurethanes having carbon-to-carbon unsaturated bonds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Toxicology (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Manufacturing & Machinery (AREA)
- Laminated Bodies (AREA)
- Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
Abstract
Description
Claims (20)
- 基材第1表面と基材第2表面とを含む基材、
前記基材第1表面上に配置された導電層第1表面を有する導電層、および
多官能アクリレートオリゴマーとアクリレートモノマーとを含む紫外線硬化性コーティング層であって、前記紫外線硬化性コーティング層の総重量の30%〜80%が前記多官能アクリレートオリゴマーで構成され、前記総重量の15%〜65%が前記アクリレートモノマーで構成される紫外線硬化性コーティング層
を含み、前記紫外線硬化性コーティング層が導電層第2表面上に配置されることを特徴とする、多層シート。 - 請求項1に記載の多層シートであって、前記多官能アクリレートオリゴマーが、脂肪族ウレタンアクリレートオリゴマー、ペンタエリスリトールテトラアクリレート、脂肪族ウレタンアクリレート、アクリル酸エステル、ジペンタエリスリトールヘキサアクリレート、アクリレート化樹脂、トリメチロールプロパントリアクリレート(TMPTA)、ジペンタエリスリトールペンタアクリレートエステル、または前述の少なくとも1種を含む組み合わせを含むことを特徴とする、多層シート。
- 請求項1から2のいずれか1項に記載の多層シートであって、前記多官能アクリレートオリゴマーが、脂肪族ウレタンアクリレートオリゴマーおよびペンタエリスリトールテトラアクリレートを含み、前記多官能アクリレートオリゴマーの重量の30%〜50%が前記脂肪族ウレタンアクリレートオリゴマーで構成され、前記多官能アクリレートオリゴマーの重量の50%〜70%が前記ペンタエリスリトールテトラアクリレートで構成されることを特徴とする、多層シート。
- 請求項1から3のいずれか1項に記載の多層シートであって、前記多官能アクリレートオリゴマーがアクリレート化樹脂を含むことを特徴とする、多層シート。
- 請求項1から4のいずれか1項に記載の多層シートであって、前記紫外線硬化性コーティング層が光開始剤をさらに含み、前記総重量の3%〜7%が前記光開始剤で構成されることを特徴とする、多層シート。
- 請求項5に記載の多層シートであって、前記光開始剤がα−ヒドロキシケトン光開始剤を含むことを特徴とする、多層シート。
- 請求項6に記載の多層シートであって、前記α−ヒドロキシケトン光開始剤が1−ヒドロキシ−シクロヘキシルフェニルケトンであることを特徴とする、多層シート。
- 請求項1から7のいずれか1項に記載の多層シートであって、前記アクリレートモノマーが1,6−ヘキサンジオールジアクリレートを含むことを特徴とする、多層シート。
- 請求項1から8のいずれか1項に記載の多層シートであって、前記基材が、ポリカーボネート、ポリ(メタクリル酸メチル)(PMMA)、ポリエチレンテレフタレート(PET)、ポリエチレンナフタレート(PEN)、環式オレフィンコポリマー(COC)、ポリエーテルイミド(PEI)、ポリスチレン、ポリイミド、ポリプロピレン(PP)、ポリエチレン(PE)、ポリフッ化ビニル(PVF)、ポリフッ化ビニリデン(PVDF)、ガラス、または前述の少なくとも1種を含む組み合わせを含むことを特徴とする、多層シート。
- 請求項1から9のいずれか1項に記載の多層シートであって、前記紫外線硬化性コーティング層が、ASTM D3359に従って測定された5Bの接着強度でポリカーボネート基材に接着することができることを特徴とする、多層シート。
- 請求項1から10のいずれか1項に記載の多層シートであって、CIE標準光源Cを使用してASTM D1003手順Aに従って測定された、80%以上の透過率を有することを特徴とする、多層シート。
- 多層シートを作製する方法であって、
基材第1表面と基材第2表面とを含む基材を形成する工程、
基体と導電性コーティングとを含む導電層を前記基材第1表面に塗布する工程、ならびに
前記導電層の、前記基材第2表面との接触面と反対側の表面に紫外線硬化コーティング層を塗布する工程であって、前記紫外線硬化コーティング層が、多官能アクリレートオリゴマーとアクリレートモノマーとを含み、前記紫外線硬化コーティング層の総重量の30%〜80%が前記多官能アクリレートオリゴマーで構成され、前記総重量の15%〜65%が前記アクリレートモノマーで構成される工程、
前記基材、導電層、および紫外線硬化コーティング層を一緒にプレス成形して積層体を形成する工程、
前記積層体を加熱する工程、
前記紫外線硬化コーティング層を紫外線放射線源で活性化する工程、ならびに
前記積層体から前記基体を除去して導電性多層シートを残す工程であって、前記紫外線硬化コーティング層が前記導電層に接着したままである工程
を含むことを特徴とする、多層シートを作製する方法。 - 請求項12に記載の方法であって、前記基材が、ポリカーボネート、ポリ(メタクリル酸メチル)(PMMA)、ポリエチレンテレフタレート(PET)、ポリエチレンナフタレート(PEN)、環式オレフィンコポリマー(COC)、ポリエーテルイミド(PEI)、ポリスチレン、ポリイミド、ポリプロピレン(PP)およびポリエチレン(PE)、ポリフッ化ビニル(PVF)、ポリフッ化ビニリデン(PVDF)、ガラス、または前述の少なくとも1種を含む組み合わせを含むことを特徴とする、方法。
- 請求項12から13のいずれか1項に記載の多層シートであって、前記紫外線硬化性コーティング層が光開始剤をさらに含み、前記総重量の3%〜7%が前記光開始剤で構成されることを特徴とする、多層シート。
- 請求項12から14のいずれか1項に記載の方法であって、前記多層シートを熱成形して熱成形品を形成する工程をさらに含むことを特徴とする、方法。
- 請求項15に記載の方法であって、前記熱成形する工程が、
前記多層シートを金型のクランプ上に置く工程、
前記多層シートを前記クランプに固定する工程、
前記金型を上昇させることによって、前記多層シートを前記クランプから押出す工程、
前記金型を下降させる工程、
前記多層シートを加熱すると同時に、減圧を開始し、前記金型を上昇させて、前記熱成形品を形成する工程
を含むことを特徴とする、方法。 - 請求項12から16のいずれか1項に記載の方法であって、前記紫外線硬化性コーティング層が、ASTM D3359に従って測定された5Bの接着強度でポリカーボネート基材に接着することができることを特徴とする、方法。
- 請求項12から17のいずれか1項に記載の方法であって、前記熱成形品が、CIE標準光源Cを使用してASTM D1003手順Aに従って測定された、80%以上の透過率を有することを特徴とする、方法。
- 請求項12から18のいずれか1項に記載の方法であって、前記熱成形品の表面抵抗率が60オーム以下であることを特徴とする、方法。
- 請求項12から19のいずれか1項に記載の方法であって、前記熱成形品が、動的機械分析によって測定したときに130℃以下の温度で20%以下の伸びを有することを特徴とする、方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201462034227P | 2014-08-07 | 2014-08-07 | |
US62/034,227 | 2014-08-07 | ||
PCT/IB2015/052886 WO2016020766A1 (en) | 2014-08-07 | 2015-04-20 | Conductive multilayer sheet for thermal forming applications |
Publications (1)
Publication Number | Publication Date |
---|---|
JP2017523066A true JP2017523066A (ja) | 2017-08-17 |
Family
ID=53373508
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2017506697A Pending JP2017523066A (ja) | 2014-08-07 | 2015-04-20 | 熱成形用途のための導電性多層シート |
Country Status (6)
Country | Link |
---|---|
US (1) | US10227465B2 (ja) |
EP (1) | EP3177677A1 (ja) |
JP (1) | JP2017523066A (ja) |
KR (1) | KR20170041809A (ja) |
CN (1) | CN106661255A (ja) |
WO (1) | WO2016020766A1 (ja) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106715615A (zh) * | 2014-04-22 | 2017-05-24 | 沙特基础工业全球技术有限公司 | 用于将纳米尺寸的金属颗粒涂覆于聚合物表面的可紫外线固化转移涂层 |
CN108025535A (zh) * | 2015-09-14 | 2018-05-11 | 沙特基础工业全球技术有限公司 | 用于热成型和注射模制应用的导电多层片材 |
EP3356136A1 (en) * | 2015-09-28 | 2018-08-08 | SABIC Global Technologies B.V. | Integrated transparent conductive films for thermal forming applications |
FR3052594B1 (fr) | 2016-06-10 | 2018-11-23 | Commissariat A L'energie Atomique Et Aux Energies Alternatives | Dispositif a piste electriquement conductrice et procede de fabrication du dispositif |
FR3057270A1 (fr) * | 2016-10-11 | 2018-04-13 | A Et A - Mader | Vernis photopolymeres thermoformables et anti-rayures |
KR102065717B1 (ko) * | 2016-12-26 | 2020-01-13 | 주식회사 엘지화학 | 편광자 보호 필름, 이를 포함하는 편광판, 상기 편광판을 포함하는 액정 디스플레이 장치, 및 편광자 보호 필름용 코팅 조성물 |
FR3061800B1 (fr) * | 2017-01-12 | 2019-05-31 | Commissariat A L'energie Atomique Et Aux Energies Alternatives | Dispositif comprenant un substrat apte a etre thermoforme sur lequel est agence un organe electriquement conducteur |
KR20210075659A (ko) * | 2019-12-13 | 2021-06-23 | 주식회사 동진쎄미켐 | 경화 후 열 성형이 가능한 코팅 조성물 및 이를 이용한 플라스틱 제품 |
KR20240020737A (ko) | 2022-08-08 | 2024-02-16 | 현대자동차주식회사 | 불소계 화합물을 포함하는 자동차 내장부품용 내지문오염 필름 및 이의 제조방법 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2005298619A (ja) * | 2004-04-09 | 2005-10-27 | Tsutsunaka Plast Ind Co Ltd | 紫外線硬化型塗料 |
JP2006063162A (ja) * | 2004-08-26 | 2006-03-09 | Tsutsunaka Plast Ind Co Ltd | 紫外線硬化型塗料 |
JP2006341595A (ja) * | 2005-05-10 | 2006-12-21 | Dainippon Ink & Chem Inc | 熱成形用シートの成形方法および成形装置 |
JP2007284485A (ja) * | 2006-04-13 | 2007-11-01 | Tsutsunaka Plast Ind Co Ltd | 紫外線硬化型塗料 |
JP2009009859A (ja) * | 2007-06-28 | 2009-01-15 | Tdk Corp | インモールド成形用導電性フィルム及び透明導電層付きプラスチック成形品の製造方法 |
WO2011142360A1 (ja) * | 2010-05-13 | 2011-11-17 | 日立化成工業株式会社 | 感光性導電フィルム、導電膜の形成方法及び導電パターンの形成方法 |
WO2012137883A1 (ja) * | 2011-04-06 | 2012-10-11 | 帝人株式会社 | 透明導電性積層体及び透明タッチパネル |
Family Cites Families (80)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IL106958A (en) | 1993-09-09 | 1996-06-18 | Ultrafine Techn Ltd | Method of producing high-purity ultra-fine metal powder |
US5631311A (en) | 1994-08-18 | 1997-05-20 | E. I. Du Pont De Nemours And Company | Transparent static dissipative formulations for coatings |
JP4189611B2 (ja) | 1998-06-01 | 2008-12-03 | 三菱瓦斯化学株式会社 | 熱成形性に優れた硬化性塗料 |
JP3469499B2 (ja) | 1999-03-16 | 2003-11-25 | 住友ベークライト株式会社 | ダイアタッチペースト |
DE60029253T2 (de) | 1999-12-20 | 2007-06-28 | New Venture Holdings, L.L.C., Sterling Heigths | Methode zum lackieren von smc-teilen |
KR20040089094A (ko) | 2001-12-20 | 2004-10-20 | 아베카 인코포레이션 | 반응된 알루미늄 또는 구리 나노 입자의 제조 방법 |
US7601406B2 (en) | 2002-06-13 | 2009-10-13 | Cima Nanotech Israel Ltd. | Nano-powder-based coating and ink compositions |
US7736693B2 (en) | 2002-06-13 | 2010-06-15 | Cima Nanotech Israel Ltd. | Nano-powder-based coating and ink compositions |
CN1322075C (zh) | 2002-06-13 | 2007-06-20 | 耐诺泡德斯工业有限公司 | 导电的透明纳米涂层与纳米油墨的制造方法以及该方法制得的纳米粉末涂层和油墨 |
US7566360B2 (en) | 2002-06-13 | 2009-07-28 | Cima Nanotech Israel Ltd. | Nano-powder-based coating and ink compositions |
DE10393018T5 (de) | 2002-08-08 | 2005-08-25 | Dai Nippon Printing Co., Ltd. | Blatt zur elektromagnetischen Abschirmung |
JP4161182B2 (ja) | 2002-10-08 | 2008-10-08 | 三菱瓦斯化学株式会社 | 硬化被膜を有するポリカーボネート樹脂積層体の製造方法。 |
JP4194963B2 (ja) | 2004-03-11 | 2008-12-10 | 信越ポリマー株式会社 | 照光式押釦スイッチ用部材の製造方法 |
US20070298253A1 (en) | 2004-09-17 | 2007-12-27 | Kenji Hata | Transparent Conductive Carbon Nanotube Film and a Method for Producing the Same |
JP2008520463A (ja) | 2004-11-19 | 2008-06-19 | アクゾ ノーベル ナムローゼ フェンノートシャップ | 可撓性の、機械的に補償された透明積層物質を調製する方法 |
CN1304506C (zh) | 2004-11-22 | 2007-03-14 | 中国化工建设总公司常州涂料化工研究院 | 用于转移涂装的紫外光固化涂料 |
JP4499150B2 (ja) | 2005-02-01 | 2010-07-07 | 三井化学株式会社 | 部材の接合方法および複合フィルム、ならびにそれらの用途 |
KR101300442B1 (ko) | 2005-06-10 | 2013-08-27 | 시마 나노 테크 이스라엘 리미티드 | 강화 투명 전도성 코팅 및 이의 제조 방법 |
TWI604466B (zh) | 2005-08-12 | 2017-11-01 | 凱姆控股有限公司 | 以奈米線爲主之透明導體 |
CN101326207B (zh) | 2005-12-06 | 2010-12-01 | 三菱丽阳株式会社 | 含碳纳米管组合物、复合体及它们的制造方法 |
JP4794392B2 (ja) | 2006-08-21 | 2011-10-19 | 富士通コンポーネント株式会社 | 曲面を有するタッチパネル及びその製造方法 |
US20090004478A1 (en) * | 2007-06-29 | 2009-01-01 | 3M Innovative Properties Company | Flexible hardcoat compositions, articles, and methods |
EP2173795B1 (en) * | 2007-08-02 | 2017-11-22 | Dupont Teijin Films U.S. Limited Partnership | Coated polyester film |
JP5431960B2 (ja) | 2007-12-07 | 2014-03-05 | 大同塗料株式会社 | カーボンナノチューブ含有導電体の製造方法 |
CN101952973B (zh) | 2007-12-20 | 2012-09-26 | 西玛耐诺技术以色列有限公司 | 具有用纳米颗粒形成的透明电极的光伏装置 |
KR20100099737A (ko) | 2007-12-20 | 2010-09-13 | 시마 나노 테크 이스라엘 리미티드 | 미세구조 재료 및 이의 제조 방법 |
KR101403187B1 (ko) | 2008-02-19 | 2014-06-02 | 삼성전자주식회사 | 감광성 조성물, 이를 이용한 미세 가공 방법 및 그에 의해형성된 미세 가공물 |
TW201006561A (en) | 2008-05-05 | 2010-02-16 | Cima Nanotech Israel Ltd | Feeding system for coating multiphase liquids |
EP2305451B1 (en) | 2008-05-13 | 2013-11-20 | Mitsubishi Gas Chemical Company, Inc. | Bendable polycarbonate resin laminate, optically transparent electromagnetic wave shield laminate, and manufacturing method thereof |
CN102026918B (zh) | 2008-05-16 | 2014-08-27 | 住友电气工业株式会社 | 制备碳线的方法、制备线组件的方法、制备导电膜的方法、制备导电基底的方法、透明导电板及其制备方法以及制备石墨膜的方法 |
WO2009149249A1 (en) | 2008-06-06 | 2009-12-10 | Cima Nanotech Israel Ltd. | Processes for making transparent conductive coatings |
US20100003523A1 (en) | 2008-07-02 | 2010-01-07 | Sabic Innovative Plastics Ip B.V. | Coated Film for Insert Mold Decoration, Methods for Using the Same, and Articles Made Thereby |
WO2010001591A1 (ja) | 2008-07-04 | 2010-01-07 | 戸田工業株式会社 | 透明導電性転写版の製造方法、透明導電性転写版、透明導電性転写版を用いた透明導電性基材の製造方法、透明導電性基材、および透明導電性基材を用いた成形体 |
JP5343452B2 (ja) | 2008-08-26 | 2013-11-13 | Dic株式会社 | 光ディスク用紫外線硬化型組成物および光ディスク |
KR100983219B1 (ko) | 2008-12-05 | 2010-09-20 | 조근호 | 직접인쇄방식에 의한 인쇄회로기판의 제조방법 및 이에 의하여 제조된 인쇄회로기판 |
JP2010244772A (ja) | 2009-04-03 | 2010-10-28 | Sony Corp | 静電容量式タッチ部材及びその製造方法、並びに静電容量式タッチ検出装置 |
JP5371840B2 (ja) | 2009-04-15 | 2013-12-18 | 信越ポリマー株式会社 | 静電容量センサ及びその製造方法 |
DE102009019412A1 (de) | 2009-04-29 | 2010-11-04 | Fa. Austria Technologie & Systemtechnik Ag | Verfahren zur Herstellung einer Leiterplatte mit LEDs und gedruckter Reflektorfläche sowie Leiterplatte, hergestellt nach dem Verfahren |
CN101920955B (zh) | 2009-06-09 | 2012-09-19 | 清华大学 | 碳纳米管膜保护结构及其制备方法 |
JP5158989B2 (ja) | 2009-06-11 | 2013-03-06 | 高知県 | 転写シートを用いた成形品への加飾膜形成方法 |
JP5472299B2 (ja) | 2009-06-24 | 2014-04-16 | コニカミノルタ株式会社 | 透明電極、該透明電極に用いられる導電性繊維の精製方法、及び有機エレクトロルミネッセンス素子 |
JP2011121183A (ja) | 2009-12-08 | 2011-06-23 | Sony Corp | 成形品及びその製造方法 |
CN103824516B (zh) * | 2009-12-17 | 2016-08-17 | 3M创新有限公司 | 显示面板组件 |
US9248468B2 (en) * | 2010-01-15 | 2016-02-02 | Texas Research International, Inc. | Ultraviolet light curing compositions for composite repair |
JP2011178910A (ja) | 2010-03-02 | 2011-09-15 | Nissha Printing Co Ltd | グラビア印刷適性を有する活性エネルギー線硬化型ハードコート樹脂組成物 |
TWI573846B (zh) | 2010-03-09 | 2017-03-11 | 西瑪奈米技術以色列有限公司 | 形成具有燒結添加物之透明導電塗層的方法 |
US20110287196A1 (en) * | 2010-05-19 | 2011-11-24 | Robert Shaw | Electro-optical switchable window |
JP2013542455A (ja) | 2010-08-18 | 2013-11-21 | スリーエム イノベイティブ プロパティズ カンパニー | 応力緩和光学接着剤を含む光学アセンブリ及びそれを作製する方法 |
KR101226696B1 (ko) | 2011-10-31 | 2013-01-25 | 장성용 | 원터치 장착식 인조네일 |
WO2012133367A1 (ja) | 2011-03-28 | 2012-10-04 | 東レ株式会社 | 導電積層体およびタッチパネル |
US20140255661A1 (en) | 2011-06-10 | 2014-09-11 | Joseph Masrud | Process for producing patterned coatings |
FR2977712A1 (fr) | 2011-07-05 | 2013-01-11 | Hutchinson | Electrode transparente conductrice multicouche et procede de fabrication associe |
KR20140070609A (ko) | 2011-09-19 | 2014-06-10 | 시마 나노 테크 이스라엘 리미티드 | 투명 도전성 코팅의 제조 방법 |
TWI581135B (zh) | 2011-09-30 | 2017-05-01 | 加拿都公司 | 觸感薄膜、觸感裝置及電子裝置 |
TW201325335A (zh) | 2011-10-29 | 2013-06-16 | Cima Nanotech Israel Ltd | 經圖案化基材上之導電網路 |
TWI584485B (zh) | 2011-10-29 | 2017-05-21 | 西瑪奈米技術以色列有限公司 | 於基材上對齊的網路 |
WO2013077358A1 (ja) | 2011-11-22 | 2013-05-30 | 日立化成株式会社 | 感光性樹脂組成物、これを用いた感光性樹脂フィルム、並びにこれらを用いた電子部品 |
JP2013119553A (ja) | 2011-12-06 | 2013-06-17 | Mitsubishi Chemicals Corp | ハードコート層の下地として使用する下層形成用塗料、及び該下層形成用塗料を塗布して形成した積層体 |
CN102527621B (zh) | 2011-12-27 | 2014-07-09 | 浙江科创新材料科技有限公司 | 一种雾度可调柔性透明导电薄膜的制备方法 |
JP2013171750A (ja) | 2012-02-22 | 2013-09-02 | Toray Ind Inc | 透明面状発熱体及びその製造方法 |
TWI648751B (zh) | 2012-02-28 | 2019-01-21 | 以色列商客利福薄膜技術有限公司 | 在彈性基材上之透明導電塗層 |
EP2634208A1 (en) | 2012-02-28 | 2013-09-04 | Bayer MaterialScience AG | Process for the production of low stress and optical quality film for use in opto-electronic devices |
JP5916516B2 (ja) | 2012-05-29 | 2016-05-11 | 日本写真印刷株式会社 | 3次元曲面タッチパネル及びこれを用いた電子機器筐体 |
US20130323411A1 (en) | 2012-06-01 | 2013-12-05 | Nuovo Film Inc. | Low Haze Transparent Conductive Electrodes and Method of Making the Same |
US20130344296A1 (en) | 2012-06-22 | 2013-12-26 | Sabic Innovative Plastics Ip B.V. | Coated film for insert mold decoration, methods for using the same, and articles made thereby |
TWI623597B (zh) | 2012-08-16 | 2018-05-11 | 西瑪奈米技術以色列有限公司 | 用於製造透明導電塗層之乳液 |
JP2014046622A (ja) | 2012-08-31 | 2014-03-17 | Dexerials Corp | 透明導電体、入力装置および電子機器 |
CN103013416B (zh) | 2012-12-19 | 2014-01-01 | 苏州威仕科贸有限公司 | 一种光敏感型玻璃贴膜粘合剂 |
KR101594213B1 (ko) * | 2013-01-18 | 2016-02-16 | (주)엘지하우시스 | 투명 수지 시트 및 이를 포함하는 터치 스크린 패널 |
CN105027690A (zh) | 2013-01-31 | 2015-11-04 | 耶路撒冷希伯来大学伊森姆研究发展有限公司 | 三维导电性图案和用于制造三维导电性图案的油墨 |
US20140267946A1 (en) | 2013-03-16 | 2014-09-18 | Teco Nanotech Co., Ltd. | Touch member and method of manufacturing the same |
JP2015069267A (ja) | 2013-09-27 | 2015-04-13 | デクセリアルズ株式会社 | 静電容量型曲面形状タッチパネル及びその製造方法 |
CN105975126A (zh) | 2013-09-29 | 2016-09-28 | 宸鸿科技(厦门)有限公司 | 触控面板及其制作方法 |
EP3094694A1 (en) | 2014-01-13 | 2016-11-23 | Eastman Kodak Company | Coated nano-particle catalytically active composite inks |
TWI665087B (zh) | 2014-02-19 | 2019-07-11 | 荷蘭商薩比克全球科技公司 | 多層板、彼之製造和使用方法、及包含該多層板之物件 |
WO2015125339A1 (ja) | 2014-02-24 | 2015-08-27 | 富士フイルム株式会社 | タッチセンサ、タッチデバイス及びタッチセンサの製造方法 |
US9587132B2 (en) | 2014-03-20 | 2017-03-07 | E I Du Pont De Nemours And Company | Thermoformable polymer thick film transparent conductor and its use in capacitive switch circuits |
US9207824B2 (en) | 2014-03-25 | 2015-12-08 | Hailiang Wang | Systems and methods for touch sensors on polymer lenses |
JP2017518897A (ja) | 2014-04-22 | 2017-07-13 | サビック グローバル テクノロジーズ ベスローテン フェンノートシャップ | 可撓性の透明な一体型導電性フィルム |
CN106715615A (zh) | 2014-04-22 | 2017-05-24 | 沙特基础工业全球技术有限公司 | 用于将纳米尺寸的金属颗粒涂覆于聚合物表面的可紫外线固化转移涂层 |
-
2015
- 2015-04-20 US US15/502,312 patent/US10227465B2/en active Active
- 2015-04-20 JP JP2017506697A patent/JP2017523066A/ja active Pending
- 2015-04-20 CN CN201580040373.4A patent/CN106661255A/zh active Pending
- 2015-04-20 KR KR1020177006131A patent/KR20170041809A/ko unknown
- 2015-04-20 EP EP15728156.9A patent/EP3177677A1/en not_active Withdrawn
- 2015-04-20 WO PCT/IB2015/052886 patent/WO2016020766A1/en active Application Filing
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2005298619A (ja) * | 2004-04-09 | 2005-10-27 | Tsutsunaka Plast Ind Co Ltd | 紫外線硬化型塗料 |
JP2006063162A (ja) * | 2004-08-26 | 2006-03-09 | Tsutsunaka Plast Ind Co Ltd | 紫外線硬化型塗料 |
JP2006341595A (ja) * | 2005-05-10 | 2006-12-21 | Dainippon Ink & Chem Inc | 熱成形用シートの成形方法および成形装置 |
JP2007284485A (ja) * | 2006-04-13 | 2007-11-01 | Tsutsunaka Plast Ind Co Ltd | 紫外線硬化型塗料 |
JP2009009859A (ja) * | 2007-06-28 | 2009-01-15 | Tdk Corp | インモールド成形用導電性フィルム及び透明導電層付きプラスチック成形品の製造方法 |
WO2011142360A1 (ja) * | 2010-05-13 | 2011-11-17 | 日立化成工業株式会社 | 感光性導電フィルム、導電膜の形成方法及び導電パターンの形成方法 |
WO2012137883A1 (ja) * | 2011-04-06 | 2012-10-11 | 帝人株式会社 | 透明導電性積層体及び透明タッチパネル |
Also Published As
Publication number | Publication date |
---|---|
CN106661255A (zh) | 2017-05-10 |
US20170226303A1 (en) | 2017-08-10 |
US10227465B2 (en) | 2019-03-12 |
EP3177677A1 (en) | 2017-06-14 |
WO2016020766A1 (en) | 2016-02-11 |
KR20170041809A (ko) | 2017-04-17 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP2017523066A (ja) | 熱成形用途のための導電性多層シート | |
TWI664645B (zh) | 集成透明導電膜、包含彼之觸控螢幕、及從彼熱成型物件之方法 | |
JP6526714B2 (ja) | ナノメートルサイズの金属粒子をポリマー表面に塗布するための紫外線硬化性転写コーティング | |
JP6615767B2 (ja) | 多層シート、該多層シートの製造方法および使用方法、ならびに該多層シートを含む物品 | |
KR101931399B1 (ko) | 적층 필름 및 성형체 | |
TWI542600B (zh) | 用於連續線內產製經塗覆之聚合型基材或層合體之方法 | |
CN112534009A (zh) | 硬涂层组合物、叠层体膜和固化膜 | |
TWI617457B (zh) | 用於熱成型及射出模塑應用之導電多層板 | |
TWI618759B (zh) | 可金屬化之抗刮且抗溶劑之薄膜 | |
KR20160146839A (ko) | 집적 플랙서블 투명 전도성 필름 | |
KR20180086209A (ko) | 전도성 나노입자 분산 프라이머 조성물 및 상기 제조 및 사용 방법 | |
JP6683836B2 (ja) | ガスバリアフィルムおよびガスバリアフィルムの製造方法 | |
JP7230411B2 (ja) | 積層体および樹脂フィルム | |
TW201819548A (zh) | 導電奈米粒子分散底漆組成物及其製造方法與使用 | |
JP7346881B2 (ja) | 積層体および樹脂フィルム | |
JP2020116940A (ja) | 離型フィルム及び積層体 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20180413 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20190215 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20190226 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20190524 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20191105 |
|
A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20200602 |