JP2007516073A5 - - Google Patents
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- JP2007516073A5 JP2007516073A5 JP2006542636A JP2006542636A JP2007516073A5 JP 2007516073 A5 JP2007516073 A5 JP 2007516073A5 JP 2006542636 A JP2006542636 A JP 2006542636A JP 2006542636 A JP2006542636 A JP 2006542636A JP 2007516073 A5 JP2007516073 A5 JP 2007516073A5
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- Prior art keywords
- magnesium
- aluminum
- compound
- ratio
- degrees
- Prior art date
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- 239000000463 material Substances 0.000 claims 34
- 229910052782 aluminium Inorganic materials 0.000 claims 31
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminum Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 31
- FYYHWMGAXLPEAU-UHFFFAOYSA-N magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 31
- 229910052749 magnesium Inorganic materials 0.000 claims 31
- 239000011777 magnesium Substances 0.000 claims 31
- 150000001875 compounds Chemical class 0.000 claims 16
- HCHKCACWOHOZIP-UHFFFAOYSA-N zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 12
- 229910052725 zinc Inorganic materials 0.000 claims 12
- 239000011701 zinc Substances 0.000 claims 12
- 239000012530 fluid Substances 0.000 claims 10
- RTAQQCXQSZGOHL-UHFFFAOYSA-N titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 8
- SMYKVLBUSSNXMV-UHFFFAOYSA-J aluminum;tetrahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[Al+3] SMYKVLBUSSNXMV-UHFFFAOYSA-J 0.000 claims 6
- 229910052751 metal Inorganic materials 0.000 claims 6
- 239000002184 metal Substances 0.000 claims 6
- 238000002441 X-ray diffraction Methods 0.000 claims 5
- 239000000203 mixture Substances 0.000 claims 5
- YIXJRHPUWRPCBB-UHFFFAOYSA-N Magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 claims 4
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L MgCl2 Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims 4
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims 4
- -1 aluminum hydroxide compound Chemical class 0.000 claims 4
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium monoxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims 4
- 229910052570 clay Inorganic materials 0.000 claims 4
- 239000004927 clay Substances 0.000 claims 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims 4
- 239000007800 oxidant agent Substances 0.000 claims 4
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims 4
- 229910000505 Al2TiO5 Inorganic materials 0.000 claims 2
- 229910052684 Cerium Inorganic materials 0.000 claims 2
- 229910052692 Dysprosium Inorganic materials 0.000 claims 2
- 229910052691 Erbium Inorganic materials 0.000 claims 2
- 229910052693 Europium Inorganic materials 0.000 claims 2
- UIWYJDYFSGRHKR-UHFFFAOYSA-N Gadolinium Chemical compound [Gd] UIWYJDYFSGRHKR-UHFFFAOYSA-N 0.000 claims 2
- 229910052688 Gadolinium Inorganic materials 0.000 claims 2
- 229910052689 Holmium Inorganic materials 0.000 claims 2
- UEGPKNKPLBYCNK-UHFFFAOYSA-L Magnesium acetate Chemical compound [Mg+2].CC([O-])=O.CC([O-])=O UEGPKNKPLBYCNK-UHFFFAOYSA-L 0.000 claims 2
- ZLNQQNXFFQJAID-UHFFFAOYSA-L Magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims 2
- VTHJTEIRLNZDEV-UHFFFAOYSA-L Magnesium hydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims 2
- 229910002089 NOx Inorganic materials 0.000 claims 2
- QEFYFXOXNSNQGX-UHFFFAOYSA-N Neodymium Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 claims 2
- 229910052779 Neodymium Inorganic materials 0.000 claims 2
- 229910052777 Praseodymium Inorganic materials 0.000 claims 2
- 229910052773 Promethium Inorganic materials 0.000 claims 2
- WUAPFZMCVAUBPE-UHFFFAOYSA-N Rhenium Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims 2
- 239000005092 Ruthenium Substances 0.000 claims 2
- 229910052772 Samarium Inorganic materials 0.000 claims 2
- 229910052771 Terbium Inorganic materials 0.000 claims 2
- 229910052775 Thulium Inorganic materials 0.000 claims 2
- 229910052769 Ytterbium Inorganic materials 0.000 claims 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K [O-]P([O-])([O-])=O Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 2
- NNCOOIBIVIODKO-UHFFFAOYSA-N aluminum;hypochlorous acid Chemical compound [Al].ClO NNCOOIBIVIODKO-UHFFFAOYSA-N 0.000 claims 2
- OCVCVOQURVOMFR-UHFFFAOYSA-N aluminum;nitric acid Chemical compound [Al].O[N+]([O-])=O OCVCVOQURVOMFR-UHFFFAOYSA-N 0.000 claims 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony Chemical group [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims 2
- 229910052787 antimony Inorganic materials 0.000 claims 2
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims 2
- 229910052797 bismuth Inorganic materials 0.000 claims 2
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims 2
- 229910052793 cadmium Inorganic materials 0.000 claims 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 2
- 239000011575 calcium Substances 0.000 claims 2
- 229910052791 calcium Inorganic materials 0.000 claims 2
- 239000000292 calcium oxide Substances 0.000 claims 2
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims 2
- 229910052804 chromium Inorganic materials 0.000 claims 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims 2
- 239000011651 chromium Substances 0.000 claims 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims 2
- 229910052803 cobalt Inorganic materials 0.000 claims 2
- 239000010941 cobalt Substances 0.000 claims 2
- 229910052802 copper Inorganic materials 0.000 claims 2
- 239000010949 copper Substances 0.000 claims 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 2
- DGKQKCGUDKEUER-UHFFFAOYSA-N dialuminum;oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Al+3].[Zr+4].[Zr+4].[Zr+4] DGKQKCGUDKEUER-UHFFFAOYSA-N 0.000 claims 2
- KBQHZAAAGSGFKK-UHFFFAOYSA-N dysprosium Chemical compound [Dy] KBQHZAAAGSGFKK-UHFFFAOYSA-N 0.000 claims 2
- UYAHIZSMUZPPFV-UHFFFAOYSA-N erbium Chemical compound [Er] UYAHIZSMUZPPFV-UHFFFAOYSA-N 0.000 claims 2
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 claims 2
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims 2
- 229910052732 germanium Inorganic materials 0.000 claims 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims 2
- 229910052737 gold Inorganic materials 0.000 claims 2
- 239000010931 gold Substances 0.000 claims 2
- KJZYNXUDTRRSPN-UHFFFAOYSA-N holmium Chemical compound [Ho] KJZYNXUDTRRSPN-UHFFFAOYSA-N 0.000 claims 2
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims 2
- 229910052741 iridium Inorganic materials 0.000 claims 2
- 229910052742 iron Inorganic materials 0.000 claims 2
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims 2
- 229910052746 lanthanum Inorganic materials 0.000 claims 2
- 239000011133 lead Substances 0.000 claims 2
- 239000011654 magnesium acetate Substances 0.000 claims 2
- 229940069446 magnesium acetate Drugs 0.000 claims 2
- 235000011285 magnesium acetate Nutrition 0.000 claims 2
- 239000001095 magnesium carbonate Substances 0.000 claims 2
- 239000011776 magnesium carbonate Substances 0.000 claims 2
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims 2
- 229910001629 magnesium chloride Inorganic materials 0.000 claims 2
- 239000000347 magnesium hydroxide Substances 0.000 claims 2
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims 2
- GMDNUWQNDQDBNQ-UHFFFAOYSA-L magnesium;diformate Chemical compound [Mg+2].[O-]C=O.[O-]C=O GMDNUWQNDQDBNQ-UHFFFAOYSA-L 0.000 claims 2
- PWHULOQIROXLJO-UHFFFAOYSA-N manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims 2
- 229910052748 manganese Inorganic materials 0.000 claims 2
- 239000011572 manganese Substances 0.000 claims 2
- 229910044991 metal oxide Inorganic materials 0.000 claims 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims 2
- 229910052750 molybdenum Inorganic materials 0.000 claims 2
- 239000011733 molybdenum Substances 0.000 claims 2
- 229910052759 nickel Inorganic materials 0.000 claims 2
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims 2
- 229910052758 niobium Inorganic materials 0.000 claims 2
- 239000010955 niobium Substances 0.000 claims 2
- 229910052762 osmium Inorganic materials 0.000 claims 2
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 claims 2
- 230000001590 oxidative Effects 0.000 claims 2
- CNRZQDQNVUKEJG-UHFFFAOYSA-N oxo-bis(oxoalumanyloxy)titanium Chemical compound O=[Al]O[Ti](=O)O[Al]=O CNRZQDQNVUKEJG-UHFFFAOYSA-N 0.000 claims 2
- 229910052763 palladium Inorganic materials 0.000 claims 2
- 239000010452 phosphate Substances 0.000 claims 2
- 229910052697 platinum Inorganic materials 0.000 claims 2
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 claims 2
- VQMWBBYLQSCNPO-UHFFFAOYSA-N promethium Chemical compound [Pm] VQMWBBYLQSCNPO-UHFFFAOYSA-N 0.000 claims 2
- 229910052702 rhenium Inorganic materials 0.000 claims 2
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims 2
- 229910052703 rhodium Inorganic materials 0.000 claims 2
- 239000010948 rhodium Substances 0.000 claims 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims 2
- 229910052707 ruthenium Inorganic materials 0.000 claims 2
- KZUNJOHGWZRPMI-UHFFFAOYSA-N samarium Chemical compound [Sm] KZUNJOHGWZRPMI-UHFFFAOYSA-N 0.000 claims 2
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 claims 2
- 229910052706 scandium Inorganic materials 0.000 claims 2
- BUGBHKTXTAQXES-UHFFFAOYSA-N selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 claims 2
- 229910052711 selenium Inorganic materials 0.000 claims 2
- 239000011669 selenium Substances 0.000 claims 2
- 229910052710 silicon Inorganic materials 0.000 claims 2
- 239000010703 silicon Substances 0.000 claims 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 2
- 229910052709 silver Inorganic materials 0.000 claims 2
- 239000004332 silver Substances 0.000 claims 2
- BQCADISMDOOEFD-UHFFFAOYSA-N silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims 2
- 229910052596 spinel Inorganic materials 0.000 claims 2
- 239000011029 spinel Substances 0.000 claims 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 2
- 229910052717 sulfur Inorganic materials 0.000 claims 2
- 239000011593 sulfur Substances 0.000 claims 2
- 229910052815 sulfur oxide Inorganic materials 0.000 claims 2
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims 2
- 229910052715 tantalum Inorganic materials 0.000 claims 2
- 229910052714 tellurium Inorganic materials 0.000 claims 2
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 claims 2
- GZCRRIHWUXGPOV-UHFFFAOYSA-N terbium Chemical compound [Tb] GZCRRIHWUXGPOV-UHFFFAOYSA-N 0.000 claims 2
- 229910052718 tin Inorganic materials 0.000 claims 2
- 239000011135 tin Substances 0.000 claims 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N tin hydride Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims 2
- 239000010936 titanium Substances 0.000 claims 2
- 229910052719 titanium Inorganic materials 0.000 claims 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims 2
- 229910052721 tungsten Inorganic materials 0.000 claims 2
- 239000010937 tungsten Substances 0.000 claims 2
- 229910052720 vanadium Inorganic materials 0.000 claims 2
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium(0) Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims 2
- NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 claims 2
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims 2
- 229910052727 yttrium Inorganic materials 0.000 claims 2
- 239000010457 zeolite Substances 0.000 claims 2
- 230000001747 exhibiting Effects 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
Claims (46)
- 流体流からのSOx、NOx及びCOの排出を低減させるための方法において、前記方法は、マグネシウム及びアルミニウムからなるとともに約43度及び約62度の2θピーク位置にて少なくとも反射を示すX線回折パターンを有する材料を前記流体流に接触させる工程を含み、前記材料中におけるマグネシウム対アルミニウムの比率は、約1:1乃至約10:1である方法。
- 前記材料は、該材料を前記流体流と接触させる前に加熱される請求項1に記載の方法。
- 前記マグネシウム対アルミニウムの比率は、約1:1乃至約6:1である請求項1に記載の方法。
- 前記マグネシウム対アルミニウムの比率は、約1.5:1乃至約10:1である請求項1に記載の方法。
- 前記マグネシウム対アルミニウムの比率は、約1.5:1乃至約6:1である請求項4に記載の方法。
- 前記マグネシウム対アルミニウムの比率は、約1.8:1乃至約5:1である請求項5に記載の方法。
- 前記マグネシウム対アルミニウムの比率は、約2:1乃至約4:1である請求項6に記載の方法。
- 前記材料は形状体である請求項1に記載の方法。
- 前記形状体は乾燥した形状体である請求項8に記載の方法。
- 前記形状体は焼成した形状体である請求項8に記載の方法。
- 前記材料は、酸化物当量として計算した場合、約40重量%以上のマグネシウムを含む請求項1に記載の方法。
- 前記材料は、少なくとも一つの金属酸化剤を更に含む請求項1に記載の方法。
- 前記金属酸化剤中の金属は、アンチモン、ビスマス、カドミウム、セリウム、クロム、コバルト、銅、ジスプロシウム、エルビウム、ユーロピウム、ガドリニウム、ゲルマニウム、金、ホルミウム、イリジウム、鉄、ランタン、鉛、マンガン、モリブデン、ネオジム、ニッケル、ニオブ、オスミウム、パラジウム、白金、プラセオジム、プロメチウム、レニウム、ロジウム、ルテニウム、サマリウム、スカンジウム、セレン、ケイ素、銀、硫黄、タンタル、テルル、テルビウム、スズ、チタン、タングステン、ツリウム、バナジウム、イッテルビウム、イットリウム、亜鉛又はそれらの二つ以上の混合物である請求項12に記載の方法。
- 前記材料は支持体を更に含む請求項1に記載の方法。
- 前記支持体は、スピネル、ハイドロタルサイト様化合物、酢酸マグネシウム、硝酸マグネシウム、塩化マグネシウム、水酸化マグネシウム、炭酸マグネシウム、ギ酸マグネシウム、チタン酸アルミニウム、チタン酸亜鉛、ジルコン酸アルミニウム、酸化カルシウム、アルミン酸カルシウム、アルミニウムニトロハイドレート、水酸化アルミニウム化合物、アルミニウム含有金属酸化物化合物、アルミニウムクロロハイドレート、チタニア、ジルコニア、粘土、粘土リン酸塩材料、ゼオライト又はそれらの二つ以上の混合物を含む請求項14に記載の方法。
- 前記支持体は、チタン酸亜鉛、アルミン酸亜鉛又はチタン酸亜鉛/アルミン酸亜鉛である請求項14に記載の方法。
- 前記流体流はFCCユニットの流体流である請求項1に記載の方法。
- 流体流からのSOx、NOx及びCOの排出を低減させるための方法において、前記方法は前記流体流に化合物を接触させる工程を含み、前記化合物は、(i)マグネシウム及びアルミニウムからなるとともに約43度及び約62度の2θピーク位置にて少なくとも反射を示すX線回折パターンを有する材料であって、該材料中におけるマグネシウム対アルミニウムの比率が約1:1乃至約10:1である材料と、(ii)約1重量%乃至約75重量%のハイドロタルサイト様化合物とを含む、方法。
- 前記化合物は、該化合物を前記流体流と接触させる前に加熱される請求項18に記載の方法。
- 前記マグネシウム対アルミニウムの比率は、約1:1乃至約6:1である請求項18に記載の方法。
- 前記マグネシウム対アルミニウムの比率は、約1.5:1乃至約10:1である請求項18に記載の方法。
- 前記マグネシウム対アルミニウムの比率は、約1.5:1乃至約6:1である請求項21に記載の方法。
- 前記マグネシウム対アルミニウムの比率は、約1.8:1乃至約5:1である請求項22に記載の方法。
- 前記マグネシウム対アルミニウムの比率は、約2:1乃至約4:1である請求項23に記載の方法。
- 前記化合物は形状体である請求項18に記載の方法。
- 前記形状体は乾燥した形状体である請求項25に記載の方法。
- 前記形状体は焼成した形状体である請求項25に記載の方法。
- 前記材料は、酸化物当量として計算した場合、約40重量%以上のマグネシウムを含む請求項18に記載の方法。
- 前記化合物は、(i)マグネシウム及びアルミニウムからなるとともに約43度及び約62度の2θピーク位置にて少なくとも反射を示すX線回折パターンを有する材料であって該材料中におけるマグネシウム対アルミニウムの比率が約1:1乃至約10:1である材料を約99重量%乃至約50重量%と、(ii)ハイドロタルサイト様化合物を約1重量%乃至約50重量%と、からなる請求項18に記載の方法。
- 前記材料における前記マグネシウム対アルミニウムの比率は、約1:1乃至約6:1である請求項29に記載の方法。
- 前記材料における前記マグネシウム対アルミニウムの比率は、約1.5:1乃至約10:1である請求項29に記載の方法。
- 前記材料における前記マグネシウム対アルミニウムの比率は、約1.5:1乃至約6:1である請求項31に記載の方法。
- 前記化合物は、(i)マグネシウム及びアルミニウムからなるとともに約43度及び約62度の2θピーク位置にて少なくとも反射を示すX線回折パターンを有する材料であって該材料中におけるマグネシウム対アルミニウムの比率が約1:1乃至約10:1である材料を約99重量%乃至約75重量%と、(ii)ハイドロタルサイト様化合物を約1重量%乃至約25重量%と、からなる請求項29に記載の方法。
- 前記材料における前記マグネシウム対アルミニウムの比率は、約1:1乃至約6:1である請求項33に記載の方法。
- 前記材料における前記マグネシウム対アルミニウムの比率は、約1.5:1乃至約10:1である請求項33に記載の方法。
- 前記材料における前記マグネシウム対アルミニウムの比率は、約1.5:1乃至約6:1である請求項35に記載の方法。
- 前記化合物は、(i)マグネシウム及びアルミニウムからなるとともに約43度及び約62度の2θピーク位置にて少なくとも反射を示すX線回折パターンを有する材料であって該材料中におけるマグネシウム対アルミニウムの比率が約1:1乃至約10:1である材料を約95重量%乃至約75重量%と、(ii)ハイドロタルサイト様化合物を約5重量%乃至約25重量%と、からなる請求項33に記載の方法。
- 前記材料における前記マグネシウム対アルミニウムの比率は、約1:1乃至約6:1である請求項37に記載の方法。
- 前記材料における前記マグネシウム対アルミニウムの比率は、約1.5:1乃至約10:1である請求項37に記載の方法。
- 前記材料における前記マグネシウム対アルミニウムの比率は、約1.5:1乃至約6:1である請求項39に記載の方法。
- 前記化合物は、少なくとも一つの金属酸化剤を更に含む請求項18に記載の方法。
- 前記金属酸化剤中の金属は、アンチモン、ビスマス、カドミウム、セリウム、クロム、コバルト、銅、ジスプロシウム、エルビウム、ユーロピウム、ガドリニウム、ゲルマニウム、金、ホルミウム、イリジウム、鉄、ランタン、鉛、マンガン、モリブデン、ネオジム、ニッケル、ニオブ、オスミウム、パラジウム、白金、プラセオジム、プロメチウム、レニウム、ロジウム、ルテニウム、サマリウム、スカンジウム、セレン、ケイ素、銀、硫黄、タンタル、テルル、テルビウム、スズ、チタン、タングステン、ツリウム、バナジウム、イッテルビウム、イットリウム、亜鉛又はそれらの二つ以上の混合物である請求項41に記載の方法。
- 前記化合物は、支持体を更に含む請求項18に記載の方法。
- 前記支持体は、スピネル、ハイドロタルサイト様化合物、酢酸マグネシウム、硝酸マグネシウム、塩化マグネシウム、水酸化マグネシウム、炭酸マグネシウム、ギ酸マグネシウム、チタン酸アルミニウム、チタン酸亜鉛、ジルコン酸アルミニウム、酸化カルシウム、アルミン酸カルシウム、アルミニウムニトロハイドレート、水酸化アルミニウム化合物、アルミニウム含有金属酸化物化合物、アルミニウムクロロハイドレート、チタニア、ジルコニア、粘土、粘土リン酸塩材料、ゼオライト又はそれらの二つ以上の混合物を含む請求項43に記載の方法。
- 前記支持体は、チタン酸亜鉛、アルミン酸亜鉛又はチタン酸亜鉛/アルミン酸亜鉛である請求項44に記載の方法。
- 前記流体流はFCCユニットの流体流である請求項18に記載の方法。
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2004
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- 2004-11-22 ZA ZA200604817A patent/ZA200604817B/en unknown
- 2004-11-22 WO PCT/US2004/039706 patent/WO2005060519A2/en active Application Filing
- 2004-11-22 AU AU2004304919A patent/AU2004304919C1/en not_active Ceased
- 2004-11-22 KR KR1020067013559A patent/KR100912041B1/ko active IP Right Grant
- 2004-11-22 CN CN2004800360162A patent/CN1890021B/zh active Active
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- 2004-11-22 JP JP2006542636A patent/JP2007516073A/ja active Pending
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