JP2003522261A5 - - Google Patents
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- Publication number
- JP2003522261A5 JP2003522261A5 JP2001558121A JP2001558121A JP2003522261A5 JP 2003522261 A5 JP2003522261 A5 JP 2003522261A5 JP 2001558121 A JP2001558121 A JP 2001558121A JP 2001558121 A JP2001558121 A JP 2001558121A JP 2003522261 A5 JP2003522261 A5 JP 2003522261A5
- Authority
- JP
- Japan
- Prior art keywords
- polyol
- mixture
- formula
- polyisocyanate
- polyurethane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 description 33
- 150000003077 polyols Chemical class 0.000 description 26
- 239000000203 mixture Substances 0.000 description 23
- 229920005862 polyol Polymers 0.000 description 22
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 16
- 229910052757 nitrogen Inorganic materials 0.000 description 12
- 239000005056 polyisocyanate Substances 0.000 description 11
- 229920001228 polyisocyanate Polymers 0.000 description 11
- 239000001257 hydrogen Substances 0.000 description 9
- 229910052739 hydrogen Inorganic materials 0.000 description 9
- -1 polyol compound Chemical class 0.000 description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 8
- 229910052760 oxygen Inorganic materials 0.000 description 8
- 239000001301 oxygen Substances 0.000 description 8
- 239000004814 polyurethane Substances 0.000 description 8
- 229920002635 polyurethane Polymers 0.000 description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 6
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 239000004604 Blowing Agent Substances 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 229920005830 Polyurethane Foam Polymers 0.000 description 4
- 239000003999 initiator Substances 0.000 description 4
- 239000011496 polyurethane foam Substances 0.000 description 4
- 125000006273 (C1-C3) alkyl group Chemical group 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 125000002947 alkylene group Chemical group 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 239000000806 elastomer Substances 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 239000011541 reaction mixture Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- LNWBFIVSTXCJJG-UHFFFAOYSA-N [diisocyanato(phenyl)methyl]benzene Chemical compound C=1C=CC=CC=1C(N=C=O)(N=C=O)C1=CC=CC=C1 LNWBFIVSTXCJJG-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 150000003973 alkyl amines Chemical class 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical compound OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- OHMHBGPWCHTMQE-UHFFFAOYSA-N 2,2-dichloro-1,1,1-trifluoroethane Chemical compound FC(F)(F)C(Cl)Cl OHMHBGPWCHTMQE-UHFFFAOYSA-N 0.000 description 1
- OZDGMOYKSFPLSE-UHFFFAOYSA-N 2-Methylaziridine Chemical group CC1CN1 OZDGMOYKSFPLSE-UHFFFAOYSA-N 0.000 description 1
- UOQYWMZLTNEIFI-UHFFFAOYSA-N 2-[3-aminopropyl(methyl)amino]ethanol Chemical compound OCCN(C)CCCN UOQYWMZLTNEIFI-UHFFFAOYSA-N 0.000 description 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 125000003282 alkyl amino group Chemical group 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- WVRIJHGUJNXDRZ-UHFFFAOYSA-N ethane-1,1-diamine Chemical compound CC(N)N WVRIJHGUJNXDRZ-UHFFFAOYSA-N 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- KMBPCQSCMCEPMU-UHFFFAOYSA-N n'-(3-aminopropyl)-n'-methylpropane-1,3-diamine Chemical compound NCCCN(C)CCCN KMBPCQSCMCEPMU-UHFFFAOYSA-N 0.000 description 1
- TWJYXMZUQAMMKA-UHFFFAOYSA-N n,n-dimethyl-1-(oxiran-2-yl)methanamine Chemical group CN(C)CC1CO1 TWJYXMZUQAMMKA-UHFFFAOYSA-N 0.000 description 1
- GNVRJGIVDSQCOP-UHFFFAOYSA-N n-ethyl-n-methylethanamine Chemical compound CCN(C)CC GNVRJGIVDSQCOP-UHFFFAOYSA-N 0.000 description 1
- 229920003225 polyurethane elastomer Polymers 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical group CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US18161700P | 2000-02-10 | 2000-02-10 | |
| US60/181,617 | 2000-02-10 | ||
| PCT/US2001/003484 WO2001058976A1 (en) | 2000-02-10 | 2001-02-02 | Low emission polyurethane polymers made with autocatalytic polyols |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2003522261A JP2003522261A (ja) | 2003-07-22 |
| JP2003522261A5 true JP2003522261A5 (https=) | 2008-03-21 |
| JP5059270B2 JP5059270B2 (ja) | 2012-10-24 |
Family
ID=22665044
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2001558121A Expired - Fee Related JP5059270B2 (ja) | 2000-02-10 | 2001-02-02 | 自触媒ポリオールで製造された低エミッション・ポリウレタンポリマー |
Country Status (15)
| Country | Link |
|---|---|
| EP (1) | EP1268598B1 (https=) |
| JP (1) | JP5059270B2 (https=) |
| KR (1) | KR100743734B1 (https=) |
| CN (1) | CN1288185C (https=) |
| AR (1) | AR029039A1 (https=) |
| AT (1) | ATE398147T1 (https=) |
| AU (2) | AU2001234776B2 (https=) |
| BR (1) | BR0108384B1 (https=) |
| CA (1) | CA2399835C (https=) |
| DE (1) | DE60134394D1 (https=) |
| MX (1) | MXPA02007758A (https=) |
| PL (1) | PL212979B1 (https=) |
| TR (1) | TR200201955T2 (https=) |
| WO (1) | WO2001058976A1 (https=) |
| ZA (1) | ZA200206102B (https=) |
Families Citing this family (85)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW592813B (en) * | 2001-08-15 | 2004-06-21 | Dow Global Technologies Inc | Process to manufacture polyurethane products |
| DE10337319A1 (de) | 2003-08-12 | 2005-03-17 | Basf Ag | Verfahren zur Herstellung von Polyetheralkoholen |
| JP4771367B2 (ja) * | 2003-10-28 | 2011-09-14 | 三井化学株式会社 | 軟質ポリウレタンフォームおよびその用途 |
| JP4791375B2 (ja) | 2003-12-23 | 2011-10-12 | ダウ グローバル テクノロジーズ エルエルシー | イミン結合および第3級アミンを含有する堅牢触媒(non−fugitivecatalysts)、ならびにそれから作製したポリウレタン製品 |
| DE602005003655T2 (de) * | 2004-03-31 | 2008-06-12 | Dow Global Technologies, Inc., Midland | Urethanmodifizierte isocyanatzusammensetzung und polyurethanprodukt daraus |
| KR20070004070A (ko) * | 2004-04-30 | 2007-01-05 | 다우 글로벌 테크놀로지스 인크. | 숙성 특성이 개선된 저밀도 폴리우레탄 발포체를 위한자기촉매 폴리올의 조촉매반응 |
| CN101128528B (zh) * | 2005-02-25 | 2011-10-12 | 西巴特殊化学品控股有限公司 | 氟化的化合物 |
| US7495131B2 (en) | 2005-03-18 | 2009-02-24 | Air Products And Chemicals, Inc. | Blowing catalyst compositions containing hydroxyl and surface active groups for the production of polyurethane foams |
| US20070088103A1 (en) * | 2005-10-14 | 2007-04-19 | Dow Global Technologies Inc. | Composite article and method of manufacture using an isocyanate-terminated prepolymer as binder |
| KR101365407B1 (ko) * | 2005-12-28 | 2014-02-19 | 미쓰이 가가쿠 가부시키가이샤 | 폴리올 조성물 및 저반발성 폴리우레탄 폼 |
| US8552078B2 (en) | 2006-10-17 | 2013-10-08 | Air Products And Chemicals, Inc. | Crosslinkers for improving stability of polyurethane foams |
| EP2104696B1 (en) | 2006-12-21 | 2013-09-11 | Dow Global Technologies LLC | Polyurethane catalysis based on the combination of autocatalytic polyol and urea |
| JP5628024B2 (ja) | 2007-05-15 | 2014-11-19 | ダウ グローバル テクノロジーズ エルエルシー | 高弾性発泡体 |
| EP2176063A1 (en) | 2007-08-01 | 2010-04-21 | Dow Global Technologies Inc. | Heat bonding polyurethane foams |
| US8367870B2 (en) | 2007-09-19 | 2013-02-05 | Air Products And Chemicals, Inc. | Autocatalytic polyols |
| CN102066446B (zh) | 2008-04-17 | 2013-12-04 | 陶氏环球技术有限责任公司 | 由可再生资源生产聚氨酯弹性体 |
| CN102112514B (zh) | 2008-06-10 | 2013-07-17 | 陶氏环球技术有限责任公司 | 1,3-二(氨基甲基)环己烷或1,4-二(氨基甲基)环己烷-引发的多元醇和从该多元醇制得的硬质聚氨酯泡沫体 |
| DE102008030940A1 (de) | 2008-07-02 | 2010-01-14 | Otto Bock Schaumstoffwerke Gmbh | Geschlossenzelliger Polyurethan-Weichschaum und Verfahren zu seiner Herstellung |
| BRPI1005963A2 (pt) | 2009-03-24 | 2016-02-10 | Dow Global Technologies Llc | processo para preparar uma espuma rígida de poliuretano |
| WO2011041163A1 (en) | 2009-09-29 | 2011-04-07 | Dow Global Technologies Inc. | Polyol mixtures containing a 1,3-and/or 1,4-bis(aminomethyl) cyclohexane-initiated polyol and at least one of a methylene bis (cyclohexylamine)-initiated polyol and a cyclohexanediamine-initiated polyol, and polyurethanes made therefrom |
| CN102639314B (zh) * | 2009-12-01 | 2015-04-29 | 巴斯夫欧洲公司 | 基于聚氨酯的拉挤成型树脂体系 |
| MX338585B (es) | 2010-07-09 | 2016-04-22 | Air Prod & Chem | Aditivos para mejorar el desempeño de la espuma de poliuretano. |
| CN103003326B (zh) | 2010-07-09 | 2015-12-16 | 气体产品与化学公司 | 用于生产软质聚氨酯泡沫的方法 |
| EP2622001B1 (en) | 2010-09-29 | 2016-04-20 | Dow Global Technologies LLC | High functionality aromatic polyesters, polyol blends comprising the same and resultant products therefrom |
| BR112013007779B1 (pt) * | 2010-10-01 | 2019-09-03 | Dow Global Technologies Llc | processo para produzir um poliuretano flexível e resiliente |
| JP5931913B2 (ja) | 2010-12-21 | 2016-06-08 | ダウ グローバル テクノロジーズ エルエルシー | 硬質ポリウレタンフォームの改善された低温スキン硬化のためのポリオール配合物 |
| JP2014520909A (ja) | 2011-06-29 | 2014-08-25 | ダウ グローバル テクノロジーズ エルエルシー | ポリイソシアヌレート硬質フォームの生強度を改善させるためのポリオール配合物 |
| US9968919B2 (en) | 2011-06-29 | 2018-05-15 | Evonik Degussa Gmbh | Reducing emissions in polyurethane foam |
| US9145466B2 (en) | 2011-07-07 | 2015-09-29 | Air Products And Chemicals, Inc. | Process for producing flexible polyurethane foam using natural oil polyols |
| US9447223B2 (en) | 2011-07-07 | 2016-09-20 | Air Products And Chemicals, Inc. | Additives for improving natural oil based polyurethane foam performance |
| US10106638B2 (en) | 2011-07-29 | 2018-10-23 | Evonik Degussa Gmbh | Reduced emissions low density spray polyurethane foam |
| US9273175B2 (en) | 2011-10-03 | 2016-03-01 | Air Products And Chemicals, Inc. | Tertiary amine composition and method for making the composition |
| US20140213677A1 (en) | 2011-10-14 | 2014-07-31 | Dow Global Technologies Llc | Hybrid polyester-polyether polyols for improved demold expansion in polyurethane rigid foams |
| JP6130390B2 (ja) | 2011-11-17 | 2017-05-17 | エア プロダクツ アンド ケミカルズ インコーポレイテッドAir Products And Chemicals Incorporated | 芳香族カルボン酸のテトラアルキルグアニジン塩を有する組成物、製品及び方法 |
| CN104245767B (zh) | 2012-03-30 | 2018-01-16 | 气体产品与化学公司 | 聚氨酯泡沫生产方法、预混料、制剂和产品 |
| US10023681B2 (en) | 2012-10-24 | 2018-07-17 | Evonik Degussa Gmbh | Delay action catalyst for improving the stability of polyurethane systems having halogen containing blowing agents |
| ITMI20131603A1 (it) | 2013-09-30 | 2015-03-30 | Dow Global Technologies Llc | Miscele di polioli e polioli poliesteri e preparazione di espansi poliuretanici rigidi |
| CA2934489C (en) | 2013-12-19 | 2019-08-06 | Evonik Operations Gmbh | New non-emissive amine composition for improved system shelf life stability |
| TR201905777T4 (tr) * | 2014-04-01 | 2019-05-21 | Dow Global Technologies Llc | Poliüretan ürünler yapmak için iyi üfleme-jelleşme dengesi sağlayan polieter poliol. |
| DE102014215384A1 (de) | 2014-08-05 | 2016-02-11 | Evonik Degussa Gmbh | Stickstoffhaltige Verbindungen, geeignet zur Verwendung bei der Herstellung von Polyurethanen |
| DE102014215380B4 (de) | 2014-08-05 | 2022-04-28 | Evonik Operations Gmbh | Stickstoffhaltige Verbindungen, geeignet zur Verwendung bei der Herstellung von Polyurethanen |
| DE102014215387B4 (de) | 2014-08-05 | 2020-06-10 | Evonik Operations Gmbh | Stickstoffhaltige Verbindungen, geeignet zur Verwendung bei der Herstellung von Polyurethanen |
| DE102014215382A1 (de) | 2014-08-05 | 2016-02-11 | Evonik Degussa Gmbh | Stickstoffhaltige Verbindungen, geeignet zur Verwendung bei der Herstellung von Polyurethanen |
| DE102014215383B4 (de) | 2014-08-05 | 2020-06-10 | Evonik Operations Gmbh | Stickstoffhaltige Verbindungen, geeignet zur Verwendung bei der Herstellung von Polyurethanen |
| DE102014215388A1 (de) | 2014-08-05 | 2016-02-11 | Evonik Degussa Gmbh | Stickstoffhaltige Verbindungen, geeignet zur Verwendung bei der Herstellung von Polyurethanen |
| DE102014215381B4 (de) | 2014-08-05 | 2020-06-10 | Evonik Operations Gmbh | Stickstoffhaltige Verbindungen, geeignet zur Verwendung bei der Herstellung von Polyurethanen |
| WO2016040783A1 (en) | 2014-09-12 | 2016-03-17 | Air Products And Chemicals, Inc. | Low emissions polyurethane foam made with isocyanate reactive amine crystals |
| DE102014218635A1 (de) | 2014-09-17 | 2016-03-17 | Evonik Degussa Gmbh | Herstellung von viskoelastischen Polyurethansystemen unter Einsatz von Blockpolymeren mit verknüpften Siloxanblöcken als Zellöffner |
| BR112017007389B1 (pt) | 2014-10-13 | 2022-07-19 | Evonik Operations Gmbh | Composição de catalisador e seu uso, processo para produzir poliuretano e espuma de poliuretano |
| MX2017008299A (es) * | 2014-12-22 | 2017-10-02 | Dow Global Technologies Llc | Formulaciones de espuma. |
| PL3067343T3 (pl) | 2015-03-10 | 2018-12-31 | Evonik Degussa Gmbh | Przeciwutleniacze do wytwarzania systemów PUR o niskiej emisji |
| EP3067376A1 (de) | 2015-03-11 | 2016-09-14 | Evonik Degussa GmbH | Herstellung von Polyurethansystemen unter Einsatz von Polyetherpolycarbonatpolyolen |
| EP3078696A1 (de) | 2015-04-08 | 2016-10-12 | Evonik Degussa GmbH | Herstellung emissionsarmer polyurethane |
| WO2016178793A1 (en) | 2015-05-05 | 2016-11-10 | Air Products And Chemicals, Inc. | Delayed action gelling catalyst compositions and methods for making polyurethane polymers |
| BR112017025985B1 (pt) | 2015-06-01 | 2022-07-26 | Evonik Operations Gmbh | Catalisadores de amina reativos para aplicações de poliuretano |
| US10683385B2 (en) | 2015-06-16 | 2020-06-16 | Evonik Operations Gmbh | Aldehyde scavengers for polyurethane foams |
| US10696777B2 (en) | 2015-06-16 | 2020-06-30 | Evonik Operations Gmbh | Aldehyde scavengers mixtures for polyurethane foams |
| PT3133097T (pt) | 2015-08-17 | 2022-12-02 | Evonik Operations Gmbh | Produção de espumas flexíveis de poliuretano com dureza melhorada |
| PL3219738T3 (pl) | 2016-03-15 | 2020-10-05 | Evonik Operations Gmbh | Wytwarzanie lepko-sprężystych systemów poliuretanowych z zastosowaniem polimerów blokowych z połączonymi blokami siloksanowymi jako środkami otwierającymi komórki |
| KR102320607B1 (ko) * | 2016-03-29 | 2021-11-03 | 다우 글로벌 테크놀로지스 엘엘씨 | 반 경질 폴리우레탄 발포체 및 제조 방법 |
| PL3443019T3 (pl) | 2016-04-12 | 2021-01-11 | Evonik Operations Gmbh | Kompozycje środków powierzchniowo czynnych w postaci kopolimerów siloksanowooksyalkilenowych |
| KR20190030214A (ko) | 2016-07-11 | 2019-03-21 | 에보니크 데구사 게엠베하 | 폴리우레탄 발포체의 제조에 유용한 아민 조성물 |
| CN110167986B (zh) * | 2017-01-23 | 2022-01-18 | 陶氏环球技术有限责任公司 | 柔性聚氨酯泡沫和制得方法 |
| CN107189028B (zh) * | 2017-06-23 | 2020-02-28 | 黎明化工研究设计院有限责任公司 | 一种环保高性能快速脱模聚氨酯反应注射成型组合物及其自催化扩链剂的制备方法 |
| BR112020008298A2 (pt) * | 2017-11-10 | 2020-10-20 | Dow Global Technologies Llc | sistema de espuma de poliuretano |
| CN109826785A (zh) * | 2017-11-23 | 2019-05-31 | 上海新安汽车隔音毡有限公司 | 一种汽车发动机舱内燃油泵罩盖及其制作方法 |
| EP3732226B1 (en) * | 2017-12-27 | 2023-08-09 | Dow Global Technologies LLC | Two-component solventless adhesive compositions for adhesion to metal and/or metallized substrates |
| MX2021003258A (es) * | 2018-10-08 | 2021-05-12 | Dow Global Technologies Llc | Composiciones formuladas de poliol. |
| EP3744745A1 (de) | 2019-05-28 | 2020-12-02 | Evonik Operations GmbH | Herstellung von pu-schaumstoffen |
| EP3865527A1 (de) | 2020-02-14 | 2021-08-18 | Evonik Operations GmbH | Herstellung von pu-schaumstoffen |
| CN111620996A (zh) * | 2020-06-19 | 2020-09-04 | 长春富维安道拓汽车饰件系统有限公司 | 一种低气味快速脱模聚氨酯半硬质泡沫 |
| EP3954722A1 (en) | 2020-07-30 | 2022-02-16 | Evonik Operations GmbH | Process and composition for the production of flexible polyurethane foam |
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| CN121729440A (zh) | 2023-08-18 | 2026-03-24 | 赢创运营有限公司 | 聚氨酯泡沫的抗水解性 |
| CN121752648A (zh) | 2023-08-24 | 2026-03-27 | 赢创运营有限公司 | 用于解聚聚氨酯的改进方法 |
| WO2025045680A1 (en) | 2023-08-25 | 2025-03-06 | Evonik Operations Gmbh | Method to make bicyclic guanidines |
| CN119775521B (zh) * | 2024-12-06 | 2025-11-11 | 山东大学 | 一种含动态缩醛胺键的高强度高热塑温度聚硅氧烷聚脲热塑性弹性体及其制备方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT699971A (https=) * | 1958-08-15 | |||
| DE2555535C2 (de) * | 1975-12-10 | 1978-01-05 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von Überzügen |
| JPS60228525A (ja) * | 1984-04-26 | 1985-11-13 | Toho Chem Ind Co Ltd | カチオン型水系樹脂の製造法 |
| JP2543397B2 (ja) * | 1988-08-10 | 1996-10-16 | 日本ポリウレタン工業株式会社 | 水発泡性ポリイソシアネ―ト樹脂の製造方法 |
| JP3262366B2 (ja) * | 1992-04-17 | 2002-03-04 | 花王株式会社 | ポリウレタンの製造法及びポリウレタンフォームの製造法 |
| JP3270555B2 (ja) * | 1993-01-13 | 2002-04-02 | 三井化学株式会社 | 半硬質ポリウレタンフォームの製造方法 |
| DE4315874A1 (de) | 1993-05-12 | 1994-11-17 | Basf Ag | Verfahren zur Herstellung von Polyurethan-Schaumstoffen |
| JPH0859783A (ja) * | 1994-08-24 | 1996-03-05 | Mitsuboshi Belting Ltd | 半硬質ウレタンフォーム、その製造法及び一体成形法 |
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2001
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