JP2003513164A5 - - Google Patents
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- Publication number
- JP2003513164A5 JP2003513164A5 JP2001535419A JP2001535419A JP2003513164A5 JP 2003513164 A5 JP2003513164 A5 JP 2003513164A5 JP 2001535419 A JP2001535419 A JP 2001535419A JP 2001535419 A JP2001535419 A JP 2001535419A JP 2003513164 A5 JP2003513164 A5 JP 2003513164A5
- Authority
- JP
- Japan
- Prior art keywords
- activator
- catalyst
- support
- catalyst system
- catalyst precursor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003054 catalyst Substances 0.000 description 104
- 239000002245 particle Substances 0.000 description 89
- 239000012190 activator Substances 0.000 description 87
- 239000012018 catalyst precursor Substances 0.000 description 83
- 239000000463 material Substances 0.000 description 48
- 150000002902 organometallic compounds Chemical class 0.000 description 45
- 229910052809 inorganic oxide Inorganic materials 0.000 description 40
- 238000000034 method Methods 0.000 description 40
- -1 lanthanide metals Chemical class 0.000 description 38
- 125000001183 hydrocarbyl group Chemical group 0.000 description 33
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 29
- 239000004215 Carbon black (E152) Substances 0.000 description 25
- 239000007788 liquid Substances 0.000 description 25
- 230000003647 oxidation Effects 0.000 description 25
- 238000007254 oxidation reaction Methods 0.000 description 25
- 229930195733 hydrocarbon Natural products 0.000 description 24
- 150000002430 hydrocarbons Chemical class 0.000 description 24
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 24
- 230000000737 periodic effect Effects 0.000 description 24
- 229910052736 halogen Inorganic materials 0.000 description 23
- 150000002367 halogens Chemical class 0.000 description 23
- 150000003623 transition metal compounds Chemical class 0.000 description 23
- 229910052723 transition metal Inorganic materials 0.000 description 22
- 150000003624 transition metals Chemical class 0.000 description 21
- 229910052739 hydrogen Inorganic materials 0.000 description 20
- 239000001257 hydrogen Substances 0.000 description 20
- 239000004927 clay Substances 0.000 description 15
- 229910052719 titanium Inorganic materials 0.000 description 15
- 229910052726 zirconium Inorganic materials 0.000 description 15
- 238000001694 spray drying Methods 0.000 description 14
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 13
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 13
- 150000001450 anions Chemical class 0.000 description 13
- 239000012967 coordination catalyst Substances 0.000 description 13
- 230000000694 effects Effects 0.000 description 13
- 239000000203 mixture Substances 0.000 description 13
- 229910052725 zinc Inorganic materials 0.000 description 13
- 239000011701 zinc Substances 0.000 description 13
- 125000000129 anionic group Chemical group 0.000 description 12
- 229910052735 hafnium Inorganic materials 0.000 description 12
- 150000002500 ions Chemical class 0.000 description 12
- 150000007527 lewis bases Chemical class 0.000 description 12
- 229910052751 metal Inorganic materials 0.000 description 12
- 239000002184 metal Substances 0.000 description 12
- 230000007935 neutral effect Effects 0.000 description 12
- 125000000217 alkyl group Chemical group 0.000 description 11
- 150000002431 hydrogen Chemical class 0.000 description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 10
- 229910052760 oxygen Inorganic materials 0.000 description 10
- 239000001301 oxygen Substances 0.000 description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 9
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical class [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 9
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 9
- 229910052782 aluminium Inorganic materials 0.000 description 9
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 9
- 229910052799 carbon Chemical group 0.000 description 9
- 238000009826 distribution Methods 0.000 description 9
- 229910052740 iodine Inorganic materials 0.000 description 9
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 7
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 6
- 239000005977 Ethylene Substances 0.000 description 6
- 239000002879 Lewis base Substances 0.000 description 6
- 239000004698 Polyethylene Substances 0.000 description 6
- 125000003545 alkoxy group Chemical group 0.000 description 6
- 150000001993 dienes Chemical class 0.000 description 6
- 229910052747 lanthanoid Inorganic materials 0.000 description 6
- 239000000178 monomer Substances 0.000 description 6
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 description 6
- 229920000573 polyethylene Polymers 0.000 description 6
- 238000006116 polymerization reaction Methods 0.000 description 6
- 229910021647 smectite Inorganic materials 0.000 description 6
- 125000001424 substituent group Chemical group 0.000 description 6
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 5
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 5
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 5
- 229910052796 boron Inorganic materials 0.000 description 5
- 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 description 5
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 description 5
- 125000005647 linker group Chemical group 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 229910052698 phosphorus Inorganic materials 0.000 description 5
- 239000011574 phosphorus Substances 0.000 description 5
- 229910052717 sulfur Inorganic materials 0.000 description 5
- 239000011593 sulfur Substances 0.000 description 5
- 150000001336 alkenes Chemical class 0.000 description 4
- 239000002734 clay mineral Substances 0.000 description 4
- 125000003678 cyclohexadienyl group Chemical group C1(=CC=CCC1)* 0.000 description 4
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 4
- 230000000379 polymerizing effect Effects 0.000 description 4
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 3
- 229910017119 AlPO Inorganic materials 0.000 description 3
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 3
- 229910052794 bromium Inorganic materials 0.000 description 3
- 125000002091 cationic group Chemical group 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 3
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 description 3
- 229910000271 hectorite Inorganic materials 0.000 description 3
- 239000011630 iodine Substances 0.000 description 3
- 229910052901 montmorillonite Inorganic materials 0.000 description 3
- 239000002243 precursor Substances 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000005054 agglomeration Methods 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- UWVZSOVMSJARDY-IENPIDJESA-N CCCC1O[C@@H](CC)CC1 Chemical compound CCCC1O[C@@H](CC)CC1 UWVZSOVMSJARDY-IENPIDJESA-N 0.000 description 1
- VLJRJSLKASNLBZ-UHFFFAOYSA-N CC[O]1(C)CCCC1 Chemical compound CC[O]1(C)CCCC1 VLJRJSLKASNLBZ-UHFFFAOYSA-N 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 150000002602 lanthanoids Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/432,008 US6559090B1 (en) | 1999-11-01 | 1999-11-01 | Metallocene and constrained geometry catalyst systems employing agglomerated metal oxide/clay support-activator and method of their preparation |
| US09/432,008 | 1999-11-01 | ||
| PCT/US2000/028931 WO2001032721A1 (en) | 1999-11-01 | 2000-10-19 | Metallocene and constrained geometry catalyst systems employing agglomerated metal oxide/clay support-activator and method of their preparation |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2003513164A JP2003513164A (ja) | 2003-04-08 |
| JP2003513164A5 true JP2003513164A5 (enExample) | 2007-12-06 |
| JP4886952B2 JP4886952B2 (ja) | 2012-02-29 |
Family
ID=23714362
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2001535419A Expired - Fee Related JP4886952B2 (ja) | 1999-11-01 | 2000-10-19 | 凝集した金属酸化物／粘土支持体−活性化剤を用いたメタロセンおよび拘束幾何触媒系そしてそれらの製造方法 |
Country Status (6)
| Country | Link |
|---|---|
| US (2) | US6559090B1 (enExample) |
| EP (1) | EP1242478B1 (enExample) |
| JP (1) | JP4886952B2 (enExample) |
| AU (1) | AU1096201A (enExample) |
| SG (1) | SG97962A1 (enExample) |
| WO (1) | WO2001032721A1 (enExample) |
Families Citing this family (106)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6812182B2 (en) | 1998-10-23 | 2004-11-02 | Albemarle Corporation | Compositions formed from hydroxyaluminoxane and their use as catalyst components |
| US20040002420A1 (en) * | 1998-10-23 | 2004-01-01 | Feng-Jung Wu | Stable catalysts and co-catalyst compositions formed from hydroxyaluminoxane and their use |
| US6555494B2 (en) | 1998-10-23 | 2003-04-29 | Albemarle Corporation | Transition metal compounds having conjugate aluminoxate anions, their preparation and their use as catalyst components |
| US6492292B2 (en) | 1998-10-23 | 2002-12-10 | Albemarle Corporation | Gelatinous compositions formed from hydroxyaluminoxane, solid compositions formed therefrom, and the use of such compositions as catalyst components |
| US6399535B1 (en) * | 1999-11-01 | 2002-06-04 | W. R. Grace & Co.-Conn. | Coordination catalyst systems employing agglomerated metal oxide/clay support-activator and method of their preparation |
| JP5258077B2 (ja) * | 1999-11-01 | 2013-08-07 | ダブリュー・アール・グレイス・アンド・カンパニー−コネチカット | オレフィン重合用の活性を持った三配座不均一担持触媒 |
| US6656866B2 (en) * | 2000-12-04 | 2003-12-02 | Univation Technologies, Llc | Catalyst preparation method |
| KR100917529B1 (ko) * | 2001-04-30 | 2009-09-16 | 더블유.알. 그레이스 앤드 캄파니-콘. | 지지된 전이 금속 촉매 시스템의 제조 방법 및 그 방법에 의해 제조된 촉매 시스템 |
| KR100540049B1 (ko) * | 2001-04-30 | 2006-01-20 | 더블유.알. 그레이스 앤드 캄파니-콘. | 지지된 전이 금속 중합 촉매의 제조 방법 및 이 방법으로형성된 조성물 |
| ATE337343T1 (de) * | 2001-04-30 | 2006-09-15 | Grace W R & Co | Geträgerte dualübergangsmetallkatalysatorsysteme |
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| US6943224B2 (en) * | 2001-04-30 | 2005-09-13 | W. R. Grace & Co.-Conn. | Process for preparing supported transition metal catalyst systems and catalyst systems prepared thereby |
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| US7501372B2 (en) * | 2003-11-21 | 2009-03-10 | Chevron Phillips Chemical Company Lp | Catalyst compositions for producing polyolefins in the absence of cocatalysts |
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2003
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