ES2071086T5 - Preparacion de catalizadores metalocenicos para polimerizacion de olefina. - Google Patents

Preparacion de catalizadores metalocenicos para polimerizacion de olefina.

Info

Publication number
ES2071086T5
ES2071086T5 ES90870174T ES90870174T ES2071086T5 ES 2071086 T5 ES2071086 T5 ES 2071086T5 ES 90870174 T ES90870174 T ES 90870174T ES 90870174 T ES90870174 T ES 90870174T ES 2071086 T5 ES2071086 T5 ES 2071086T5
Authority
ES
Spain
Prior art keywords
catalysts
metallocene
compound
cation
produce
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES90870174T
Other languages
English (en)
Other versions
ES2071086T3 (es
Inventor
John A Ewen
Michael J Elder
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fina Technology Inc
Original Assignee
Fina Technology Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=23660575&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2071086(T5) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Fina Technology Inc filed Critical Fina Technology Inc
Publication of ES2071086T3 publication Critical patent/ES2071086T3/es
Application granted granted Critical
Publication of ES2071086T5 publication Critical patent/ES2071086T5/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61908—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/61922—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/61927—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63908—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

ESTA INVENCION UTILIZA UN NUEVO METODO DE PRODUCCION DE COMPUESTOS DE METALOCENO IONICO. ESTOS COMPUESTOS SON UTILES COMO CATALIZADORES PARA LA POLIMERIZACION DE OLEFINAS, PRINCIPALMENTE PROPILENO. ESTE METODO UTILIZA UN AGENTE IONIZANTE QUE IONIZA EL COMPUESTO DE METALOCENO NEUTRO. EL COMPUESTO IONICO IONIZANTE NO CONTIENE UN PROTON ACTIVO Y CONTIENE UN CATRON CARBONIO, OXONIO O SULFORIO. EL ANION DEL COMPUESTO IONICO IONIZADO NO ESTA COORDINADO O ESTA COORDINADO SOLO DE FORMA FLOJA AL CATION METALOCENO Y ES NO-REACTIVO QUIMICAMENTE CON EL CATION METALOCENO . UN COMPUESTO ASI ES TRIFENILCARBENIO TETRAQUIS (PENTAFLUOROFENIL) EL PROCESO DE PRODUCCION DE CATALIZADORES CON ESTA INVENCION PRODUCE CATALIZADORES CON ALTA ACTIVIDAD Y NO PRODUCE SUBPRODUCTOS QUE PUEDAN INHIBIR LA ACTIVIDAD CATALITICA. ESTA NUEVA SINTESIS ES UNA REACCION LIMPIA QUE NO PRODUCE UNA BASE LEWIS. EL PROCESO GENERA CATALIZADORES ACTIVOS ELIMINANDO UN ANION DE METILO DE UN GRUPO DERIVADO METALOCENO IV.
ES90870174T 1989-10-30 1990-10-09 Preparacion de catalizadores metalocenicos para polimerizacion de olefina. Expired - Lifetime ES2071086T5 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US41904689A 1989-10-30 1989-10-30

Publications (2)

Publication Number Publication Date
ES2071086T3 ES2071086T3 (es) 1995-06-16
ES2071086T5 true ES2071086T5 (es) 2002-01-16

Family

ID=23660575

Family Applications (1)

Application Number Title Priority Date Filing Date
ES90870174T Expired - Lifetime ES2071086T5 (es) 1989-10-30 1990-10-09 Preparacion de catalizadores metalocenicos para polimerizacion de olefina.

Country Status (10)

Country Link
EP (1) EP0426637B2 (es)
JP (2) JP2943310B2 (es)
KR (1) KR0165843B1 (es)
CN (2) CN1028641C (es)
AT (1) ATE120768T1 (es)
CA (1) CA2027123C (es)
DE (1) DE69018376T3 (es)
DK (1) DK0426637T4 (es)
ES (1) ES2071086T5 (es)
GR (1) GR3015700T3 (es)

Families Citing this family (294)

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EP0426637A3 (en) 1991-08-07
DE69018376T3 (de) 2002-05-16
ES2071086T3 (es) 1995-06-16
JP3224789B2 (ja) 2001-11-05
CN1028641C (zh) 1995-05-31
CN1033457C (zh) 1996-12-04
EP0426637B2 (en) 2001-09-26
CN1105673A (zh) 1995-07-26
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DE69018376T2 (de) 1995-09-28
CA2027123A1 (en) 1991-05-01
EP0426637B1 (en) 1995-04-05
CA2027123C (en) 2001-09-04
DK0426637T4 (da) 2002-01-14
KR0165843B1 (ko) 1999-03-20
KR910007970A (ko) 1991-05-30
GR3015700T3 (en) 1995-07-31
CN1051311A (zh) 1991-05-15
ATE120768T1 (de) 1995-04-15
JPH11315111A (ja) 1999-11-16
DE69018376D1 (de) 1995-05-11
JPH03207703A (ja) 1991-09-11
JP2943310B2 (ja) 1999-08-30
EP0426637A2 (en) 1991-05-08

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