JP4886952B2 - 凝集した金属酸化物/粘土支持体−活性化剤を用いたメタロセンおよび拘束幾何触媒系そしてそれらの製造方法 - Google Patents
凝集した金属酸化物/粘土支持体−活性化剤を用いたメタロセンおよび拘束幾何触媒系そしてそれらの製造方法 Download PDFInfo
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- JP4886952B2 JP4886952B2 JP2001535419A JP2001535419A JP4886952B2 JP 4886952 B2 JP4886952 B2 JP 4886952B2 JP 2001535419 A JP2001535419 A JP 2001535419A JP 2001535419 A JP2001535419 A JP 2001535419A JP 4886952 B2 JP4886952 B2 JP 4886952B2
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Classifications
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- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
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- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
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- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
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Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymerization Catalysts (AREA)
Applications Claiming Priority (3)
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| US09/432,008 | 1999-11-01 | ||
| PCT/US2000/028931 WO2001032721A1 (en) | 1999-11-01 | 2000-10-19 | Metallocene and constrained geometry catalyst systems employing agglomerated metal oxide/clay support-activator and method of their preparation |
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Families Citing this family (106)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6812182B2 (en) | 1998-10-23 | 2004-11-02 | Albemarle Corporation | Compositions formed from hydroxyaluminoxane and their use as catalyst components |
| US20040002420A1 (en) * | 1998-10-23 | 2004-01-01 | Feng-Jung Wu | Stable catalysts and co-catalyst compositions formed from hydroxyaluminoxane and their use |
| US6555494B2 (en) | 1998-10-23 | 2003-04-29 | Albemarle Corporation | Transition metal compounds having conjugate aluminoxate anions, their preparation and their use as catalyst components |
| US6492292B2 (en) | 1998-10-23 | 2002-12-10 | Albemarle Corporation | Gelatinous compositions formed from hydroxyaluminoxane, solid compositions formed therefrom, and the use of such compositions as catalyst components |
| US6399535B1 (en) * | 1999-11-01 | 2002-06-04 | W. R. Grace & Co.-Conn. | Coordination catalyst systems employing agglomerated metal oxide/clay support-activator and method of their preparation |
| JP5258077B2 (ja) * | 1999-11-01 | 2013-08-07 | ダブリュー・アール・グレイス・アンド・カンパニー−コネチカット | オレフィン重合用の活性を持った三配座不均一担持触媒 |
| US6656866B2 (en) * | 2000-12-04 | 2003-12-02 | Univation Technologies, Llc | Catalyst preparation method |
| KR100917529B1 (ko) * | 2001-04-30 | 2009-09-16 | 더블유.알. 그레이스 앤드 캄파니-콘. | 지지된 전이 금속 촉매 시스템의 제조 방법 및 그 방법에 의해 제조된 촉매 시스템 |
| KR100540049B1 (ko) * | 2001-04-30 | 2006-01-20 | 더블유.알. 그레이스 앤드 캄파니-콘. | 지지된 전이 금속 중합 촉매의 제조 방법 및 이 방법으로형성된 조성물 |
| ATE337343T1 (de) * | 2001-04-30 | 2006-09-15 | Grace W R & Co | Geträgerte dualübergangsmetallkatalysatorsysteme |
| US6734131B2 (en) | 2001-04-30 | 2004-05-11 | W. R. Grace & Co.-Conn. | Heterogeneous chromium catalysts and processes of polymerization of olefins using same |
| US6943224B2 (en) * | 2001-04-30 | 2005-09-13 | W. R. Grace & Co.-Conn. | Process for preparing supported transition metal catalyst systems and catalyst systems prepared thereby |
| US6958375B2 (en) * | 2001-04-30 | 2005-10-25 | W.R. Grace & Co.-Conn. | Chromium support-agglomerate-transition metal polymerization catalysts and processes utilizing same |
| WO2002102859A2 (en) | 2001-04-30 | 2002-12-27 | W. R. Grace & Co.-Conn. | Coordination catalyst systems employing chromium support-agglomerate and method of their preparation |
| JP3961910B2 (ja) * | 2002-07-12 | 2007-08-22 | 丸善石油化学株式会社 | オレフィン重合用触媒及びそれを用いたオレフィンの重合方法 |
| US7223822B2 (en) | 2002-10-15 | 2007-05-29 | Exxonmobil Chemical Patents Inc. | Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom |
| US7550528B2 (en) | 2002-10-15 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Functionalized olefin polymers |
| EP1620479B1 (en) | 2002-10-15 | 2013-07-24 | ExxonMobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
| US7541402B2 (en) | 2002-10-15 | 2009-06-02 | Exxonmobil Chemical Patents Inc. | Blend functionalized polyolefin adhesive |
| US7501372B2 (en) * | 2003-11-21 | 2009-03-10 | Chevron Phillips Chemical Company Lp | Catalyst compositions for producing polyolefins in the absence of cocatalysts |
| JP4133772B2 (ja) | 2003-12-01 | 2008-08-13 | 丸善石油化学株式会社 | オレフィン重合用触媒及びそれを用いたオレフィンの重合方法 |
| US7119153B2 (en) * | 2004-01-21 | 2006-10-10 | Jensen Michael D | Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength |
| DE102004006104A1 (de) * | 2004-02-06 | 2005-08-25 | Basell Polyolefine Gmbh | Verfahren zur Herstellung von geträgerten Katalysatoren für die Polymerisation |
| DE102004006113A1 (de) * | 2004-02-06 | 2005-08-25 | Basell Polyolefine Gmbh | Verfahren zur Herstellung von Trägern für Katalysatoren |
| ES2585891T3 (es) | 2004-04-28 | 2016-10-10 | Headwaters Heavy Oil, Llc | Métodos y sistemas de hidroprocesamiento en lecho en ebullición |
| US10941353B2 (en) * | 2004-04-28 | 2021-03-09 | Hydrocarbon Technology & Innovation, Llc | Methods and mixing systems for introducing catalyst precursor into heavy oil feedstock |
| US7273914B2 (en) * | 2005-08-03 | 2007-09-25 | Equistar Chemicals, Lp | Olefin polymerization methods |
| JP4794246B2 (ja) * | 2005-09-13 | 2011-10-19 | 日本ポリプロ株式会社 | オレフィン重合用触媒担体の製造方法、それを用いたオレフィン重合用触媒成分 |
| US7670984B2 (en) | 2006-01-06 | 2010-03-02 | Headwaters Technology Innovation, Llc | Hydrocarbon-soluble molybdenum catalyst precursors and methods for making same |
| US7842635B2 (en) * | 2006-01-06 | 2010-11-30 | Headwaters Technology Innovation, Llc | Hydrocarbon-soluble, bimetallic catalyst precursors and methods for making same |
| US8034232B2 (en) | 2007-10-31 | 2011-10-11 | Headwaters Technology Innovation, Llc | Methods for increasing catalyst concentration in heavy oil and/or coal resid hydrocracker |
| US7951745B2 (en) * | 2008-01-03 | 2011-05-31 | Wilmington Trust Fsb | Catalyst for hydrocracking hydrocarbons containing polynuclear aromatic compounds |
| US8142645B2 (en) | 2008-01-03 | 2012-03-27 | Headwaters Technology Innovation, Llc | Process for increasing the mono-aromatic content of polynuclear-aromatic-containing feedstocks |
| US8097149B2 (en) * | 2008-06-17 | 2012-01-17 | Headwaters Technology Innovation, Llc | Catalyst and method for hydrodesulfurization of hydrocarbons |
| US9365664B2 (en) | 2009-01-29 | 2016-06-14 | W. R. Grace & Co. -Conn. | Catalyst on silica clad alumina support |
| CA2750535A1 (en) | 2009-01-29 | 2010-08-05 | W.R. Grace & Co.-Conn. | Catalyst on silica clad alumina support |
| CA2765072A1 (en) | 2009-06-11 | 2010-12-16 | W.R. Grace & Co. -Conn. | Process of making aluminoxane and catalysts comprising thus prepared aluminoxane |
| CA2713042C (en) | 2010-08-11 | 2017-10-24 | Nova Chemicals Corporation | Method of controlling polymer architecture |
| CN103402636B (zh) | 2011-01-14 | 2016-12-14 | 格雷斯公司 | 制造改性金属茂催化剂的方法、制成的催化剂及其用途 |
| CA2734167C (en) | 2011-03-15 | 2018-03-27 | Nova Chemicals Corporation | Polyethylene film |
| CA2739969C (en) | 2011-05-11 | 2018-08-21 | Nova Chemicals Corporation | Improving reactor operability in a gas phase polymerization process |
| CA2742461C (en) | 2011-06-09 | 2018-06-12 | Nova Chemicals Corporation | Modified phosphinimine catalysts for olefin polymerization |
| US9315591B2 (en) | 2011-06-09 | 2016-04-19 | Nova Chemicals (International) S.A. | Modified phosphinimine catalysts for olefin polymerization |
| CA2742454C (en) | 2011-06-09 | 2018-06-12 | Nova Chemicals Corporation | Methods for controlling ethylene copolymer properties |
| US9221935B2 (en) | 2011-06-09 | 2015-12-29 | Nova Chemicals (International) S.A. | Modified phosphinimine catalysts for olefin polymerization |
| US9321859B2 (en) | 2011-06-09 | 2016-04-26 | Nova Chemicals (International) S.A. | Modified phosphinimine catalysts for olefin polymerization |
| US9127106B2 (en) | 2011-06-09 | 2015-09-08 | Nova Chemicals (International) S.A. | Modified phosphinimine catalysts for olefin polymerization |
| US9127094B2 (en) | 2011-06-09 | 2015-09-08 | Nova Chemicals (International) S.A. | Modified phosphinimine catalysts for olefin polymerization |
| US9243092B2 (en) | 2011-06-09 | 2016-01-26 | Nova Chemicals (International) S.A. | Modified phosphinimine catalysts for olefin polymerization |
| CA2749835C (en) | 2011-08-23 | 2018-08-21 | Nova Chemicals Corporation | Feeding highly active phosphinimine catalysts to a gas phase reactor |
| US9790440B2 (en) | 2011-09-23 | 2017-10-17 | Headwaters Technology Innovation Group, Inc. | Methods for increasing catalyst concentration in heavy oil and/or coal resid hydrocracker |
| JP5895503B2 (ja) * | 2011-12-14 | 2016-03-30 | 東ソー株式会社 | エチレン系重合体製造用触媒およびエチレン系重合体の製造方法 |
| US9403153B2 (en) | 2012-03-26 | 2016-08-02 | Headwaters Heavy Oil, Llc | Highly stable hydrocarbon-soluble molybdenum catalyst precursors and methods for making same |
| US9115233B2 (en) | 2012-06-21 | 2015-08-25 | Nova Chemicals (International) S.A. | Ethylene copolymer compositions, film and polymerization processes |
| CA2798855C (en) | 2012-06-21 | 2021-01-26 | Nova Chemicals Corporation | Ethylene copolymers having reverse comonomer incorporation |
| CA2783494C (en) | 2012-07-23 | 2019-07-30 | Nova Chemicals Corporation | Adjusting polymer composition |
| US9644157B2 (en) | 2012-07-30 | 2017-05-09 | Headwaters Heavy Oil, Llc | Methods and systems for upgrading heavy oil using catalytic hydrocracking and thermal coking |
| CA2797620C (en) | 2012-12-03 | 2019-08-27 | Nova Chemicals Corporation | Controlling resin properties in a gas phase polymerization process |
| CA2800056A1 (en) | 2012-12-24 | 2014-06-24 | Nova Chemicals Corporation | Polyethylene blend compositions |
| CA2985611C (en) | 2015-05-11 | 2021-06-01 | W.R. Grace & Co.-Conn. | Process to produce modified clay, supported metallocene polymerization catalyst, catalyst produced and use thereof |
| US10940460B2 (en) | 2015-05-11 | 2021-03-09 | W. R. Grace & Co.-Conn. | Process to produce modified clay, modified clay produced and use thereof |
| CA2891693C (en) | 2015-05-21 | 2022-01-11 | Nova Chemicals Corporation | Controlling the placement of comonomer in an ethylene copolymer |
| CA2892552C (en) | 2015-05-26 | 2022-02-15 | Victoria Ker | Process for polymerization in a fluidized bed reactor |
| CA2892882C (en) | 2015-05-27 | 2022-03-22 | Nova Chemicals Corporation | Ethylene/1-butene copolymers with enhanced resin processability |
| US10351647B2 (en) | 2015-05-29 | 2019-07-16 | Exxonmobil Chemical Patents Inc. | Polymerization process using bridged metallocene compounds supported on organoaluminum treated layered silicate supports |
| US10077325B2 (en) | 2015-06-05 | 2018-09-18 | Exxonmobil Chemical Patents Inc. | Silica supports with high aluminoxane loading capability |
| US10280233B2 (en) | 2015-06-05 | 2019-05-07 | Exxonmobil Chemical Patents Inc. | Catalyst systems and methods of making and using the same |
| US9725569B2 (en) | 2015-06-05 | 2017-08-08 | Exxonmobil Chemical Patents Inc. | Porous propylene polymers |
| US9725537B2 (en) | 2015-06-05 | 2017-08-08 | Exxonmobil Chemical Patents Inc. | High activity catalyst supportation |
| US9738779B2 (en) | 2015-06-05 | 2017-08-22 | Exxonmobil Chemical Patents Inc. | Heterophasic copolymers and sequential polymerization |
| WO2016196331A1 (en) | 2015-06-05 | 2016-12-08 | Exxonmobil Chemical Patents Inc. | Supported metallocene catalyst systems for polymerization |
| CN107709379A (zh) * | 2015-06-05 | 2018-02-16 | 埃克森美孚化学专利公司 | 单中心催化剂负载 |
| US10280235B2 (en) | 2015-06-05 | 2019-05-07 | Exxonmobil Chemical Patents Inc. | Catalyst system containing high surface area supports and sequential polymerization to produce heterophasic polymers |
| US10329360B2 (en) | 2015-06-05 | 2019-06-25 | Exxonmobil Chemical Patents Inc. | Catalyst system comprising supported alumoxane and unsupported alumoxane particles |
| US9920176B2 (en) | 2015-06-05 | 2018-03-20 | Exxonmobil Chemical Patents Inc. | Single site catalyst supportation |
| CN107922537B (zh) | 2015-06-05 | 2021-07-27 | 埃克森美孚化学专利公司 | 气相或淤浆相中多相聚合物的制备 |
| US9809664B2 (en) | 2015-06-05 | 2017-11-07 | Exxonmobil Chemical Patents Inc. | Bimodal propylene polymers and sequential polymerization |
| CN107690441A (zh) | 2015-06-05 | 2018-02-13 | 埃克森美孚化学专利公司 | 聚合物在气相或淤浆相中的单反应器制备 |
| US10294316B2 (en) | 2015-06-05 | 2019-05-21 | Exxonmobil Chemical Patents Inc. | Silica supports with high aluminoxane loading capability |
| WO2017039994A1 (en) | 2015-08-31 | 2017-03-09 | Exxonmobil Chemical Patents Inc. | Aluminum alkyls with pendant olefins on clays |
| US10618988B2 (en) | 2015-08-31 | 2020-04-14 | Exxonmobil Chemical Patents Inc. | Branched propylene polymers produced via use of vinyl transfer agents and processes for production thereof |
| WO2017039995A1 (en) | 2015-08-31 | 2017-03-09 | Exxonmobil Chemical Patents Inc. | Aluminum alkyls with pendant olefins for polyolefin reactions |
| US11414607B2 (en) | 2015-09-22 | 2022-08-16 | Hydrocarbon Technology & Innovation, Llc | Upgraded ebullated bed reactor with increased production rate of converted products |
| US11414608B2 (en) | 2015-09-22 | 2022-08-16 | Hydrocarbon Technology & Innovation, Llc | Upgraded ebullated bed reactor used with opportunity feedstocks |
| CN108137730B (zh) * | 2015-09-24 | 2021-10-29 | 埃克森美孚化学专利公司 | 使用在有机铝处理过的层状硅酸盐载体上负载的吡啶基二氨基化合物的聚合方法 |
| US9982067B2 (en) | 2015-09-24 | 2018-05-29 | Exxonmobil Chemical Patents Inc. | Polymerization process using pyridyldiamido compounds supported on organoaluminum treated layered silicate supports |
| US9975973B2 (en) | 2015-10-02 | 2018-05-22 | Exxonmobil Chemical Patents Inc. | Asymmetric fluorenyl-substituted salan catalysts |
| US9982076B2 (en) | 2015-10-02 | 2018-05-29 | Exxonmobil Chemical Patents Inc. | Supported bis phenolate transition metals complexes, production and use thereof |
| US9994657B2 (en) | 2015-10-02 | 2018-06-12 | Exxonmobil Chemical Patents Inc. | Polymerization process using bis phenolate compounds supported on organoaluminum treated layered silicate supports |
| US9994658B2 (en) | 2015-10-02 | 2018-06-12 | Exxonmobil Chemical Patents Inc. | Polymerization process using bis phenolate compounds supported on organoaluminum treated layered silicate supports |
| US10414887B2 (en) | 2015-10-02 | 2019-09-17 | Exxonmobil Chemical Patents Inc. | Supported catalyst systems and methods of using same |
| US10000593B2 (en) | 2015-10-02 | 2018-06-19 | Exxonmobil Chemical Patents Inc. | Supported Salan catalysts |
| EP3464390A1 (en) | 2016-05-27 | 2019-04-10 | ExxonMobil Chemical Patents Inc. | Metallocene catalyst compositions and polymerization process therewith |
| US11421164B2 (en) | 2016-06-08 | 2022-08-23 | Hydrocarbon Technology & Innovation, Llc | Dual catalyst system for ebullated bed upgrading to produce improved quality vacuum residue product |
| US10562987B2 (en) | 2016-06-30 | 2020-02-18 | Exxonmobil Chemical Patents Inc. | Polymers produced via use of quinolinyldiamido transition metal complexes and vinyl transfer agents |
| US10654953B2 (en) * | 2016-12-29 | 2020-05-19 | Chevron Phillips Chemical Company Lp | Methods of preparing a catalyst |
| US11267914B2 (en) | 2016-12-29 | 2022-03-08 | Chevron Phillips Chemical Company Lp | Methods of preparing a catalyst |
| US20200369803A1 (en) | 2016-12-29 | 2020-11-26 | Chevron Phillips Chemical Company Lp | Methods of Preparing a Catalyst |
| US10626200B2 (en) | 2017-02-28 | 2020-04-21 | Exxonmobil Chemical Patents Inc. | Branched EPDM polymers produced via use of vinyl transfer agents and processes for production thereof |
| WO2018160278A1 (en) | 2017-03-01 | 2018-09-07 | Exxonmobil Chemical Patents Inc. | Branched ethylene copolymers produced via use of vinyl transfer agents and processes for production thereof |
| US11118119B2 (en) | 2017-03-02 | 2021-09-14 | Hydrocarbon Technology & Innovation, Llc | Upgraded ebullated bed reactor with less fouling sediment |
| US11732203B2 (en) | 2017-03-02 | 2023-08-22 | Hydrocarbon Technology & Innovation, Llc | Ebullated bed reactor upgraded to produce sediment that causes less equipment fouling |
| CA3057131C (en) | 2018-10-17 | 2024-04-23 | Hydrocarbon Technology And Innovation, Llc | Upgraded ebullated bed reactor with no recycle buildup of asphaltenes in vacuum bottoms |
| US11339229B2 (en) | 2020-01-27 | 2022-05-24 | Formosa Plastics Corporation, U.S.A. | Process for preparing catalysts and catalyst compositions |
| WO2021154204A1 (en) | 2020-01-27 | 2021-08-05 | Formosa Plastics Corporation, U.S.A. | Process for preparing catalysts and catalyst compositions |
| CN114749174B (zh) * | 2022-04-26 | 2023-11-07 | 淮安中顺环保科技有限公司 | 一种凹凸棒土限域贵金属纳米团簇催化剂的制备方法 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH09278818A (ja) * | 1996-04-17 | 1997-10-28 | Mitsubishi Chem Corp | オレフィン重合用触媒及びオレフィン重合体製造方法 |
| JPH115810A (ja) * | 1997-04-25 | 1999-01-12 | Mitsubishi Chem Corp | 層状珪酸塩粒子及びそれを用いたオレフィン重合用触媒成分、オレフィン重合用触媒並びにオレフィン重合体の製造法 |
| JP2003515620A (ja) * | 1999-11-01 | 2003-05-07 | ダブリュ・アール・グレイス・アンド・カンパニー・コネテイカット | 凝集した金属酸化物/粘土支持体−活性化剤を用いた配位触媒系そしてそれらの製造方法 |
Family Cites Families (62)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4176090A (en) | 1975-11-18 | 1979-11-27 | W. R. Grace & Co. | Pillared interlayered clay materials useful as catalysts and sorbents |
| SE423721B (sv) | 1976-03-17 | 1982-05-24 | Stora Kopparbergs Bergslags Ab | Sett for framstellning av rastal genom direktreduktion |
| IL50548A (en) | 1976-09-23 | 1979-10-31 | Yissum Res Dev Co | Process for preparation of molecular sieves |
| US4238364A (en) | 1979-04-03 | 1980-12-09 | University Of Utah | Class of cracking catalysts acidic forms of cross-linked smectities |
| US4271043A (en) | 1979-09-04 | 1981-06-02 | W. R. Grace & Co. | Pillared interlayered clay products |
| US4248739A (en) | 1979-09-04 | 1981-02-03 | W. R. Grace & Co. | Stabilized pillared interlayered clays |
| US4375406A (en) | 1981-01-21 | 1983-03-01 | Chevron Research Company | Fibrous clay compositions containing precalcined oxides |
| US4367163A (en) | 1981-04-15 | 1983-01-04 | Research Corporation | Silica-clay complexes |
| US4629712A (en) | 1984-08-17 | 1986-12-16 | Michigan State University | Delaminated clay materials |
| US4637992A (en) | 1984-12-17 | 1987-01-20 | Shell Oil Company | Intercalated clay compositions |
| US4859648A (en) | 1984-12-28 | 1989-08-22 | Mobil Oil Corporation | Layered metal chalcogenides containing interspathic polymeric chalcogenides |
| US4761391A (en) | 1986-06-30 | 1988-08-02 | Union Oil Company Of California | Delaminated clays and their use in hydrocarbon conversion processes |
| US5241025A (en) | 1987-01-30 | 1993-08-31 | Exxon Chemical Patents Inc. | Catalyst system of enhanced productivity |
| US4995964A (en) | 1987-03-05 | 1991-02-26 | Uop | Midbarrel hydrocracking process employing rare earth pillared clays |
| US5225500A (en) | 1988-07-15 | 1993-07-06 | Fina Technology, Inc. | Process and catalyst for producing syndiotactic polyolefins |
| US5243002A (en) | 1988-07-15 | 1993-09-07 | Fina Technology, Inc. | Process and catalyst for producing syndiotactic polymers |
| JPH0278663A (ja) | 1988-09-14 | 1990-03-19 | N O K Sogo Gijutsu Kenkyusho:Kk | 2,6―エチリデンニトリロフェニルピリジン、その製造法ならびに金属塩錯体 |
| US4981825A (en) | 1989-09-12 | 1991-01-01 | Board Of Trustees Operating Michigan State University | Dried metal oxide and clay particle compositions and method for the preparation thereof |
| US5064802A (en) | 1989-09-14 | 1991-11-12 | The Dow Chemical Company | Metal complex compounds |
| ES2071086T5 (es) | 1989-10-30 | 2002-01-16 | Fina Technology | Preparacion de catalizadores metalocenicos para polimerizacion de olefina. |
| ATE137247T1 (de) | 1989-10-30 | 1996-05-15 | Fina Technology | Addition von alkylaluminium zum verbessern eines metallocenkatalysators |
| WO1992000333A2 (en) | 1990-06-22 | 1992-01-09 | Exxon Chemical Patents Inc. | Aluminum-free monocyclopentadienyl metallocene catalysts for olefin polymerization |
| JP2545006B2 (ja) | 1990-07-03 | 1996-10-16 | ザ ダウ ケミカル カンパニー | 付加重合触媒 |
| US5128291A (en) | 1990-12-11 | 1992-07-07 | Wax Michael J | Porous titania or zirconia spheres |
| US5250277A (en) | 1991-01-11 | 1993-10-05 | Mobil Oil Corp. | Crystalline oxide material |
| TW218884B (enExample) | 1991-05-01 | 1994-01-11 | Mitsubishi Kakoki Kk | |
| US5399636A (en) | 1993-06-11 | 1995-03-21 | Phillips Petroleum Company | Metallocenes and processes therefor and therewith |
| ES2108861T3 (es) | 1991-11-25 | 1998-01-01 | Exxon Chemical Patents Inc | Composiciones cataliticas polionicas de metales de transicion. |
| JPH05170429A (ja) | 1991-12-18 | 1993-07-09 | Mitsubishi Materials Corp | 粘土架橋多孔体及びその製造方法 |
| US5238892A (en) | 1992-06-15 | 1993-08-24 | Exxon Chemical Patents Inc. | Supported catalyst for 1-olefin(s) (co)polymerization |
| US5362825A (en) | 1992-07-13 | 1994-11-08 | Phillips Petroleum Company | Catalysts for polymerizing olefins and methods |
| US5395808A (en) | 1992-12-21 | 1995-03-07 | W. R. Grace & Co.-Conn. | Inorganic supports for bioremediation |
| US5403809A (en) | 1992-12-21 | 1995-04-04 | W. R. Grace & Co.-Conn. | Composite inorganic supports containing carbon for bioremediation |
| US5403799A (en) | 1992-12-21 | 1995-04-04 | W. R. Grace & Co.-Conn. | Process upset-resistant inorganic supports for bioremediation |
| BR9407034A (pt) | 1993-06-24 | 1996-03-19 | Dow Chemical Co | Complexos de titânio ( I) ou zircônio (II) e catalisadores de polimerização por adição dos mesmos |
| DE69412047T2 (de) | 1993-12-17 | 1999-04-15 | Tosoh Corp., Shinnanyo, Yamaguchi | Olefinpolymerisationkatalysator und Verfahren zur Olefinpolymerisation |
| EP0683180B1 (en) * | 1994-05-18 | 2002-03-06 | Mitsubishi Chemical Corporation | Catalyst for polymerizing an olefin and method for polymerizing the olefin |
| US5541272A (en) | 1994-06-03 | 1996-07-30 | Phillips Petroleum Company | High activity ethylene selective metallocenes |
| US5643847A (en) | 1994-08-03 | 1997-07-01 | Exxon Chemical Patents Inc. | Supported ionic catalyst composition |
| US5661097A (en) | 1994-08-12 | 1997-08-26 | The Dow Chemical Company | Supported olefin polymerization catalyst |
| SE9404160D0 (sv) | 1994-11-30 | 1994-11-30 | Jan Naeslund | Ljudarrangemang |
| US5880241A (en) | 1995-01-24 | 1999-03-09 | E. I. Du Pont De Nemours And Company | Olefin polymers |
| DE69611554T2 (de) | 1995-02-20 | 2001-07-05 | Tosoh Corp., Shinnanyo | Katalysator für die Polymerisation von Olefinen und Verfahren zur Herstellung von Olefinpolymerisaten |
| EP0791608B1 (en) | 1996-02-23 | 2000-05-10 | Tosoh Corporation | Olefin polymerization catalyst based on organometallic complexes and processes for production of polyolefins using the catalyst |
| DE69717440T2 (de) | 1996-06-21 | 2003-10-02 | W.R. Grace & Co.-Conn., New York | Aggregatträger und darauf angebrachte olefinpolymerisationskatalysatoren |
| IL129929A0 (en) | 1996-12-17 | 2000-02-29 | Du Pont | Polymerization of ethylene with specific iron or cobalt complexes novel pyridinebis (imines) and novel complexes of pyridinebis(imines) with iron and cobalt |
| US6110858A (en) | 1996-12-18 | 2000-08-29 | Tosoh Corporation | Olefin polymerization catalysts and process for producing olefin polymers |
| US5906955A (en) | 1996-12-20 | 1999-05-25 | Tosoh Corporation | Catalyst for polymerization of an olefin, and method for producing an olefin polymer |
| JP2001508107A (ja) | 1997-01-13 | 2001-06-19 | イー・アイ・デユポン・ドウ・ヌムール・アンド・カンパニー | プロピレンの重合 |
| US5807800A (en) | 1997-02-11 | 1998-09-15 | Fina Technology, Inc. | Process for producing stereospecific polymers |
| EP0874006B1 (en) | 1997-04-25 | 2001-08-08 | Mitsubishi Chemical Corporation | Phyllosilicate-supported catalyst for the polymerisation of olefins |
| JP3458656B2 (ja) | 1997-05-27 | 2003-10-20 | 東ソー株式会社 | オレフィン重合用触媒およびオレフィン重合体の製造方法 |
| JPH10338516A (ja) | 1997-06-04 | 1998-12-22 | Nikki Kagaku Kk | 粘土鉱物にインターカレートした金属酸化物の製造方法 |
| DZ2737A1 (fr) | 1998-03-12 | 2003-09-01 | Bp Chem Int Ltd | Catalyseurs de polymérisation. |
| ID27209A (id) | 1998-03-12 | 2001-03-08 | Bp Chem Int Ltd | Katalis-katalis polimerisasi |
| ID26574A (id) | 1998-03-12 | 2001-01-18 | Bp Chem Int Ltd | Katalis-katalis polimerisasi |
| JPH11292912A (ja) | 1998-04-08 | 1999-10-26 | Idemitsu Petrochem Co Ltd | オレフィン重合用触媒及びポリオレフィンの製造方法 |
| CN1127522C (zh) * | 1998-08-20 | 2003-11-12 | 出光石油化学株式会社 | 烯烃聚合物生产用催化剂、其生产方法、和烯烃聚合物的生产方法 |
| JP2000086672A (ja) | 1998-09-14 | 2000-03-28 | Idemitsu Petrochem Co Ltd | アルミノキサン、オレフィン類重合用触媒及びオレフィン系重合体の製造方法 |
| WO2001025149A2 (en) | 1999-10-07 | 2001-04-12 | The Dow Chemical Company | Silica gel composition and method for making |
| US6632894B1 (en) | 1999-12-30 | 2003-10-14 | Phillips Petroleum Company | Organometal catalyst compositions |
| US8064408B2 (en) | 2008-02-20 | 2011-11-22 | Hobbit Wave | Beamforming devices and methods |
-
1999
- 1999-11-01 US US09/432,008 patent/US6559090B1/en not_active Expired - Lifetime
-
2000
- 2000-10-19 JP JP2001535419A patent/JP4886952B2/ja not_active Expired - Fee Related
- 2000-10-19 WO PCT/US2000/028931 patent/WO2001032721A1/en not_active Ceased
- 2000-10-19 EP EP00972279A patent/EP1242478B1/en not_active Expired - Lifetime
- 2000-10-19 AU AU10962/01A patent/AU1096201A/en not_active Abandoned
- 2000-10-27 SG SG200006187A patent/SG97962A1/en unknown
-
2003
- 2003-03-06 US US10/382,742 patent/US20030171207A1/en not_active Abandoned
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH09278818A (ja) * | 1996-04-17 | 1997-10-28 | Mitsubishi Chem Corp | オレフィン重合用触媒及びオレフィン重合体製造方法 |
| JPH115810A (ja) * | 1997-04-25 | 1999-01-12 | Mitsubishi Chem Corp | 層状珪酸塩粒子及びそれを用いたオレフィン重合用触媒成分、オレフィン重合用触媒並びにオレフィン重合体の製造法 |
| JP2003515620A (ja) * | 1999-11-01 | 2003-05-07 | ダブリュ・アール・グレイス・アンド・カンパニー・コネテイカット | 凝集した金属酸化物/粘土支持体−活性化剤を用いた配位触媒系そしてそれらの製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP1242478A1 (en) | 2002-09-25 |
| US6559090B1 (en) | 2003-05-06 |
| SG97962A1 (en) | 2003-08-20 |
| JP2003513164A (ja) | 2003-04-08 |
| WO2001032721A1 (en) | 2001-05-10 |
| EP1242478B1 (en) | 2012-12-05 |
| US20030171207A1 (en) | 2003-09-11 |
| AU1096201A (en) | 2001-05-14 |
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