ATE337343T1 - Geträgerte dualübergangsmetallkatalysatorsysteme - Google Patents
Geträgerte dualübergangsmetallkatalysatorsystemeInfo
- Publication number
- ATE337343T1 ATE337343T1 AT02731326T AT02731326T ATE337343T1 AT E337343 T1 ATE337343 T1 AT E337343T1 AT 02731326 T AT02731326 T AT 02731326T AT 02731326 T AT02731326 T AT 02731326T AT E337343 T1 ATE337343 T1 AT E337343T1
- Authority
- AT
- Austria
- Prior art keywords
- transition metal
- metal compound
- metal catalyst
- metallocene
- polymers
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 2
- 230000009977 dual effect Effects 0.000 title abstract 2
- 229910052723 transition metal Inorganic materials 0.000 title abstract 2
- 150000003624 transition metals Chemical class 0.000 title abstract 2
- 229920000642 polymer Polymers 0.000 abstract 3
- 150000003623 transition metal compounds Chemical class 0.000 abstract 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- 229910021577 Iron(II) chloride Inorganic materials 0.000 abstract 1
- QSZGOMRHQRFORD-UHFFFAOYSA-L [Cl-].[Cl-].C=C.C1=CC2=CC=CC=C2C1[Zr+2]C1C2=CC=CC=C2C=C1 Chemical compound [Cl-].[Cl-].C=C.C1=CC2=CC=CC=C2C1[Zr+2]C1C2=CC=CC=C2C=C1 QSZGOMRHQRFORD-UHFFFAOYSA-L 0.000 abstract 1
- 239000012190 activator Substances 0.000 abstract 1
- 238000012644 addition polymerization Methods 0.000 abstract 1
- 239000004927 clay Substances 0.000 abstract 1
- 239000012967 coordination catalyst Substances 0.000 abstract 1
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 150000002902 organometallic compounds Chemical class 0.000 abstract 1
- 239000012041 precatalyst Substances 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 239000007921 spray Substances 0.000 abstract 1
- -1 tridentate 2 Chemical class 0.000 abstract 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/02—Carriers therefor
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Communication Control (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US28760201P | 2001-04-30 | 2001-04-30 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE337343T1 true ATE337343T1 (de) | 2006-09-15 |
Family
ID=23103602
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT02731326T ATE337343T1 (de) | 2001-04-30 | 2002-04-10 | Geträgerte dualübergangsmetallkatalysatorsysteme |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US6686306B2 (de) |
| EP (1) | EP1399491B1 (de) |
| KR (1) | KR100893971B1 (de) |
| AT (1) | ATE337343T1 (de) |
| DE (1) | DE60214172T2 (de) |
| WO (1) | WO2002088200A1 (de) |
Families Citing this family (53)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100710963B1 (ko) * | 1999-11-01 | 2007-04-24 | 더블유.알. 그레이스 앤드 컴파니 -씨오엔엔. | 활성의 불균일 지지된 비덴테이트 또는 트리덴테이트계의올레핀 중합 촉매 |
| US6656866B2 (en) * | 2000-12-04 | 2003-12-02 | Univation Technologies, Llc | Catalyst preparation method |
| EP1401890B1 (de) | 2001-04-30 | 2010-12-15 | W. R. Grace & Co.-Conn | Chromträgeragglomerat-übergangsmetall-polymerisationskatalysatoren und verfahren, bei denen diese zur anwendung kommen |
| CN1692118A (zh) * | 2001-05-10 | 2005-11-02 | 尤尼威蒂恩技术有限责任公司 | 包含吡咯二亚胺配位体的烯烃聚合催化剂 |
| US6884748B2 (en) * | 2002-09-04 | 2005-04-26 | Univation Technologies, Llc | Process for producing fluorinated catalysts |
| US6841500B2 (en) * | 2002-12-03 | 2005-01-11 | Equistar Chemicals, Lp | Bimetallic indenoindolyl catalysts |
| CN100549037C (zh) * | 2002-12-17 | 2009-10-14 | 英诺文尼欧洲有限公司 | 烯烃聚合载体催化剂 |
| US6812183B1 (en) * | 2003-04-23 | 2004-11-02 | Equistar Chemicals, Lp | Triple-decker catalysts based on delocalized dianionic ligands |
| DE102004006104A1 (de) * | 2004-02-06 | 2005-08-25 | Basell Polyolefine Gmbh | Verfahren zur Herstellung von geträgerten Katalysatoren für die Polymerisation |
| DE102004006113A1 (de) * | 2004-02-06 | 2005-08-25 | Basell Polyolefine Gmbh | Verfahren zur Herstellung von Trägern für Katalysatoren |
| EP1574525B1 (de) * | 2004-03-12 | 2007-05-02 | Saudi Basic Industries Corporation | Katalysatorzusammensetzung für die Polymerisation von Olefinen und Polymerisationsverfahren unter dessen Verwendung |
| DE102004020525A1 (de) | 2004-04-26 | 2005-11-10 | Basell Polyolefine Gmbh | Katalysatorsystem zur Olefinpolymerisation, dessen Herstellung und Verwendung |
| DE102004020524A1 (de) * | 2004-04-26 | 2005-11-10 | Basell Polyolefine Gmbh | Polyethylen und Katalysatorzusammensetzung zu dessen Herstellung |
| CN101010367B (zh) * | 2004-07-14 | 2010-12-15 | 新加坡科技研究局 | 纳米复合材料及其制备方法 |
| US7429404B2 (en) * | 2004-07-30 | 2008-09-30 | University Of Utah Research Foundation | Methods of selectively incorporating metals onto substrates |
| US20060076354A1 (en) * | 2004-10-07 | 2006-04-13 | Lanzafame John F | Hydrogen storage apparatus |
| EP1650231A1 (de) * | 2004-10-21 | 2006-04-26 | Total Petrochemicals Research Feluy | Polyolefine hergestellt mit Metallocen- und neuen Single-Site-Katalysatorkomponenten in einem Reaktor |
| BRPI0608063A2 (pt) * | 2005-03-04 | 2009-11-03 | Du Pont | processo para a formação de um precursor de polimerização de olefina suportado e produto do mesmo |
| US7273914B2 (en) * | 2005-08-03 | 2007-09-25 | Equistar Chemicals, Lp | Olefin polymerization methods |
| US7847099B2 (en) * | 2006-09-21 | 2010-12-07 | California Institute Of Technology | Non-metallocene organometallic complexes and related methods and systems |
| DE102007017903A1 (de) | 2007-04-13 | 2008-10-16 | Basell Polyolefine Gmbh | Polyethylen und Katalysatorzusammensetzung und Verfahren zu dessen Herstellung |
| DE102007022052A1 (de) * | 2007-05-08 | 2008-11-13 | Basell Polyolefine Gmbh | Katalysatorsystem zur Olefinpolymerisation, Verfahren zu ihrer Herstellung, sowie ein Verfahren zur Polymerisation von a-Olefinen unter Verwendung des Katalysatorsystems |
| US8435911B2 (en) * | 2008-10-16 | 2013-05-07 | Basell Polyolefine Gmbh | Hybrid catalyst composition for polymerization of olefins |
| CA2713042C (en) | 2010-08-11 | 2017-10-24 | Nova Chemicals Corporation | Method of controlling polymer architecture |
| JP6457716B2 (ja) | 2011-01-14 | 2019-01-23 | ダブリュー・アール・グレイス・アンド・カンパニー−コネチカット | 修飾メタロセン触媒の作成法、生成された触媒およびそれらの使用 |
| CA2734167C (en) | 2011-03-15 | 2018-03-27 | Nova Chemicals Corporation | Polyethylene film |
| CA2739969C (en) | 2011-05-11 | 2018-08-21 | Nova Chemicals Corporation | Improving reactor operability in a gas phase polymerization process |
| CA2742461C (en) | 2011-06-09 | 2018-06-12 | Nova Chemicals Corporation | Modified phosphinimine catalysts for olefin polymerization |
| US9127094B2 (en) | 2011-06-09 | 2015-09-08 | Nova Chemicals (International) S.A. | Modified phosphinimine catalysts for olefin polymerization |
| US9221935B2 (en) | 2011-06-09 | 2015-12-29 | Nova Chemicals (International) S.A. | Modified phosphinimine catalysts for olefin polymerization |
| CA2742454C (en) | 2011-06-09 | 2018-06-12 | Nova Chemicals Corporation | Methods for controlling ethylene copolymer properties |
| US9243092B2 (en) | 2011-06-09 | 2016-01-26 | Nova Chemicals (International) S.A. | Modified phosphinimine catalysts for olefin polymerization |
| US9315591B2 (en) | 2011-06-09 | 2016-04-19 | Nova Chemicals (International) S.A. | Modified phosphinimine catalysts for olefin polymerization |
| US9321859B2 (en) | 2011-06-09 | 2016-04-26 | Nova Chemicals (International) S.A. | Modified phosphinimine catalysts for olefin polymerization |
| US9127106B2 (en) | 2011-06-09 | 2015-09-08 | Nova Chemicals (International) S.A. | Modified phosphinimine catalysts for olefin polymerization |
| CA2749835C (en) | 2011-08-23 | 2018-08-21 | Nova Chemicals Corporation | Feeding highly active phosphinimine catalysts to a gas phase reactor |
| CN102964471B (zh) * | 2011-08-31 | 2015-07-01 | 中国石油化工股份有限公司 | 负载型非茂金属催化剂、其制备方法及其应用 |
| US8653208B2 (en) | 2012-05-18 | 2014-02-18 | Union Carbide Chemicals & Plastics Technology Llc | Process for preparing catalysts and catalysts made thereby |
| CA2798855C (en) | 2012-06-21 | 2021-01-26 | Nova Chemicals Corporation | Ethylene copolymers having reverse comonomer incorporation |
| US9115233B2 (en) | 2012-06-21 | 2015-08-25 | Nova Chemicals (International) S.A. | Ethylene copolymer compositions, film and polymerization processes |
| CA2783494C (en) | 2012-07-23 | 2019-07-30 | Nova Chemicals Corporation | Adjusting polymer composition |
| WO2014078919A1 (pt) | 2012-11-26 | 2014-05-30 | Braskem S.A. | Catalisador metaloceno suportado em suporte híbrido, processo de obtenção do mesmo, processo de polimerização para obtenção de um homopolímero ou copolímero de etileno com distribuição de massa molar ampla ou bimodal, uso do catalisador de metaloceno suportado e polímero de etileno com distribuição de massa molar ampla ou bimodal |
| CA2797620C (en) | 2012-12-03 | 2019-08-27 | Nova Chemicals Corporation | Controlling resin properties in a gas phase polymerization process |
| CA2800056A1 (en) | 2012-12-24 | 2014-06-24 | Nova Chemicals Corporation | Polyethylene blend compositions |
| CA2891693C (en) | 2015-05-21 | 2022-01-11 | Nova Chemicals Corporation | Controlling the placement of comonomer in an ethylene copolymer |
| CA2892552C (en) | 2015-05-26 | 2022-02-15 | Victoria Ker | Process for polymerization in a fluidized bed reactor |
| CA2892882C (en) | 2015-05-27 | 2022-03-22 | Nova Chemicals Corporation | Ethylene/1-butene copolymers with enhanced resin processability |
| US11267914B2 (en) | 2016-12-29 | 2022-03-08 | Chevron Phillips Chemical Company Lp | Methods of preparing a catalyst |
| US20200369803A1 (en) | 2016-12-29 | 2020-11-26 | Chevron Phillips Chemical Company Lp | Methods of Preparing a Catalyst |
| US10654953B2 (en) * | 2016-12-29 | 2020-05-19 | Chevron Phillips Chemical Company Lp | Methods of preparing a catalyst |
| WO2020146375A2 (en) * | 2019-01-08 | 2020-07-16 | Exxonmobil Chemical Patents Inc | Olefin polymerization processes featuring in situ blending of an oil extension |
| EP4155324A3 (de) * | 2021-09-22 | 2023-05-03 | Sumitomo Chemical Company, Limited | Verfahren zur herstellung einer festen katalysatorkomponente zur olefin-polymerisation, verfahren zur herstellung eines katalysators zur olefin-polymerisation und verfahren zur herstellung eines olefin-polymers |
| CN115404512B (zh) * | 2022-08-10 | 2024-11-15 | 青岛科技大学 | 一种富磷空位的铁掺杂磷化镍的制备方法及其在电解海水产氢中的应用 |
Family Cites Families (72)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4176090A (en) | 1975-11-18 | 1979-11-27 | W. R. Grace & Co. | Pillared interlayered clay materials useful as catalysts and sorbents |
| SE423721B (sv) | 1976-03-17 | 1982-05-24 | Stora Kopparbergs Bergslags Ab | Sett for framstellning av rastal genom direktreduktion |
| IL50548A (en) | 1976-09-23 | 1979-10-31 | Yissum Res Dev Co | Process for preparation of molecular sieves |
| US4238364A (en) | 1979-04-03 | 1980-12-09 | University Of Utah | Class of cracking catalysts acidic forms of cross-linked smectities |
| US4248739A (en) | 1979-09-04 | 1981-02-03 | W. R. Grace & Co. | Stabilized pillared interlayered clays |
| US4271043A (en) | 1979-09-04 | 1981-06-02 | W. R. Grace & Co. | Pillared interlayered clay products |
| US4375406A (en) | 1981-01-21 | 1983-03-01 | Chevron Research Company | Fibrous clay compositions containing precalcined oxides |
| US4367163A (en) | 1981-04-15 | 1983-01-04 | Research Corporation | Silica-clay complexes |
| US4629712A (en) | 1984-08-17 | 1986-12-16 | Michigan State University | Delaminated clay materials |
| US4637992A (en) | 1984-12-17 | 1987-01-20 | Shell Oil Company | Intercalated clay compositions |
| US4859648A (en) | 1984-12-28 | 1989-08-22 | Mobil Oil Corporation | Layered metal chalcogenides containing interspathic polymeric chalcogenides |
| US4761391A (en) | 1986-06-30 | 1988-08-02 | Union Oil Company Of California | Delaminated clays and their use in hydrocarbon conversion processes |
| US5241025A (en) | 1987-01-30 | 1993-08-31 | Exxon Chemical Patents Inc. | Catalyst system of enhanced productivity |
| US5153157A (en) | 1987-01-30 | 1992-10-06 | Exxon Chemical Patents Inc. | Catalyst system of enhanced productivity |
| US4995964A (en) | 1987-03-05 | 1991-02-26 | Uop | Midbarrel hydrocracking process employing rare earth pillared clays |
| US5225500A (en) | 1988-07-15 | 1993-07-06 | Fina Technology, Inc. | Process and catalyst for producing syndiotactic polyolefins |
| US5243002A (en) | 1988-07-15 | 1993-09-07 | Fina Technology, Inc. | Process and catalyst for producing syndiotactic polymers |
| JPH0278663A (ja) | 1988-09-14 | 1990-03-19 | N O K Sogo Gijutsu Kenkyusho:Kk | 2,6―エチリデンニトリロフェニルピリジン、その製造法ならびに金属塩錯体 |
| US4981825A (en) | 1989-09-12 | 1991-01-01 | Board Of Trustees Operating Michigan State University | Dried metal oxide and clay particle compositions and method for the preparation thereof |
| US5064802A (en) | 1989-09-14 | 1991-11-12 | The Dow Chemical Company | Metal complex compounds |
| DK0426637T4 (da) | 1989-10-30 | 2002-01-14 | Fina Technology | Fremgangsmåde til fremstilling af metallocenkatalysatorer til polymerisation af olefiner |
| ATE137247T1 (de) | 1989-10-30 | 1996-05-15 | Fina Technology | Addition von alkylaluminium zum verbessern eines metallocenkatalysators |
| JP2954351B2 (ja) | 1990-06-22 | 1999-09-27 | エクソン・ケミカル・パテンツ・インク | オレフィン重合用のアルミニウムを含まないモノシクロペンタジエニルメタロセン触媒 |
| JP2545006B2 (ja) | 1990-07-03 | 1996-10-16 | ザ ダウ ケミカル カンパニー | 付加重合触媒 |
| US5128291A (en) | 1990-12-11 | 1992-07-07 | Wax Michael J | Porous titania or zirconia spheres |
| US5250277A (en) | 1991-01-11 | 1993-10-05 | Mobil Oil Corp. | Crystalline oxide material |
| TW218884B (de) | 1991-05-01 | 1994-01-11 | Mitsubishi Kakoki Kk | |
| US5399636A (en) | 1993-06-11 | 1995-03-21 | Phillips Petroleum Company | Metallocenes and processes therefor and therewith |
| US5359015A (en) * | 1991-11-07 | 1994-10-25 | Exxon Chemical Patents Inc. | Metallocene catalysts and their production and use |
| DE69222317T2 (de) | 1991-11-25 | 1998-02-12 | Exxon Chemical Patents, Inc., Baytown, Tex. | Polyionische, uebergangsmetall enthaltende katalysatorzusammensetzung |
| JPH05170429A (ja) | 1991-12-18 | 1993-07-09 | Mitsubishi Materials Corp | 粘土架橋多孔体及びその製造方法 |
| US5238892A (en) | 1992-06-15 | 1993-08-24 | Exxon Chemical Patents Inc. | Supported catalyst for 1-olefin(s) (co)polymerization |
| US5362825A (en) | 1992-07-13 | 1994-11-08 | Phillips Petroleum Company | Catalysts for polymerizing olefins and methods |
| US5403799A (en) | 1992-12-21 | 1995-04-04 | W. R. Grace & Co.-Conn. | Process upset-resistant inorganic supports for bioremediation |
| US5403809A (en) | 1992-12-21 | 1995-04-04 | W. R. Grace & Co.-Conn. | Composite inorganic supports containing carbon for bioremediation |
| US5395808A (en) | 1992-12-21 | 1995-03-07 | W. R. Grace & Co.-Conn. | Inorganic supports for bioremediation |
| EP0617052B1 (de) | 1993-03-23 | 1998-06-03 | Asahi Kasei Kogyo Kabushiki Kaisha | Olefinpolymerisationkatalysator mit mehrzähnigem Ligand |
| DK0705269T3 (da) | 1993-06-24 | 1997-07-28 | Dow Chemical Co | Titan(II)- eller zirkonium(II)-komplekser og additionspolymerisationskatalysatorer deraf. |
| DE69412047T2 (de) | 1993-12-17 | 1999-04-15 | Tosoh Corp., Shinnanyo, Yamaguchi | Olefinpolymerisationkatalysator und Verfahren zur Olefinpolymerisation |
| EP0683180B1 (de) | 1994-05-18 | 2002-03-06 | Mitsubishi Chemical Corporation | Katalysator zur Polymerisation eines Olefins und Verfahren zum Polymerisieren des Olefins |
| US5541272A (en) | 1994-06-03 | 1996-07-30 | Phillips Petroleum Company | High activity ethylene selective metallocenes |
| US5643847A (en) | 1994-08-03 | 1997-07-01 | Exxon Chemical Patents Inc. | Supported ionic catalyst composition |
| US5661097A (en) | 1994-08-12 | 1997-08-26 | The Dow Chemical Company | Supported olefin polymerization catalyst |
| US5714424A (en) | 1995-01-09 | 1998-02-03 | W. R. Grace & Co.-Conn. | Multi-component polyolefin catalysts |
| PL322446A1 (en) | 1995-01-24 | 1998-02-02 | Du Pont | Alpha-olefines and olefinic polymers and methods of obtaining them |
| US5880241A (en) | 1995-01-24 | 1999-03-09 | E. I. Du Pont De Nemours And Company | Olefin polymers |
| EP0727443B1 (de) | 1995-02-20 | 2001-01-17 | Tosoh Corporation | Katalysator für die Polymerisation von Olefinen und Verfahren zur Herstellung von Olefinpolymerisaten |
| RU2178421C2 (ru) | 1995-11-27 | 2002-01-20 | Дзе Дау Кемикал Компани | Катализатор на носителе, содержащий связанный активатор, образующий катион |
| EP0791608B1 (de) | 1996-02-23 | 2000-05-10 | Tosoh Corporation | Olefinpolymerisationskatalysator auf Basis von organometallischen Komplexen und Verfahren zur Herstellung von Polyolefinen mit diesem Katalysator |
| DE69717440T2 (de) | 1996-06-21 | 2003-10-02 | W.R. Grace & Co.-Conn., New York | Aggregatträger und darauf angebrachte olefinpolymerisationskatalysatoren |
| IL129929A0 (en) | 1996-12-17 | 2000-02-29 | Du Pont | Polymerization of ethylene with specific iron or cobalt complexes novel pyridinebis (imines) and novel complexes of pyridinebis(imines) with iron and cobalt |
| US6110858A (en) | 1996-12-18 | 2000-08-29 | Tosoh Corporation | Olefin polymerization catalysts and process for producing olefin polymers |
| US5906955A (en) | 1996-12-20 | 1999-05-25 | Tosoh Corporation | Catalyst for polymerization of an olefin, and method for producing an olefin polymer |
| EP0951489B1 (de) | 1997-01-13 | 2004-10-06 | E.I. Du Pont De Nemours And Company | Propylenpolymerisationsverfahren |
| US5807800A (en) | 1997-02-11 | 1998-09-15 | Fina Technology, Inc. | Process for producing stereospecific polymers |
| US6048817A (en) | 1997-04-25 | 2000-04-11 | Mitsubishi Chemical Corporation | Polymerization of olefins |
| JP3458656B2 (ja) | 1997-05-27 | 2003-10-20 | 東ソー株式会社 | オレフィン重合用触媒およびオレフィン重合体の製造方法 |
| JPH10338516A (ja) | 1997-06-04 | 1998-12-22 | Nikki Kagaku Kk | 粘土鉱物にインターカレートした金属酸化物の製造方法 |
| CA2210131C (en) | 1997-07-09 | 2005-08-02 | Douglas W. Stephan | Supported phosphinimine-cp catalysts |
| NO980552D0 (no) | 1998-02-09 | 1998-02-09 | Borealis As | Katalysatorbestandel og katalysator for (ko)polymerisering av etylen, og fremgangsmåte for fremstilling av slik |
| WO1999046303A1 (en) | 1998-03-12 | 1999-09-16 | Bp Chemicals Limited | Polymerisation catalysts |
| ID27209A (id) | 1998-03-12 | 2001-03-08 | Bp Chem Int Ltd | Katalis-katalis polimerisasi |
| EP1062249B1 (de) | 1998-03-12 | 2004-10-20 | BP Chemicals Limited | Polymerisationskatalysatoren |
| JPH11292912A (ja) | 1998-04-08 | 1999-10-26 | Idemitsu Petrochem Co Ltd | オレフィン重合用触媒及びポリオレフィンの製造方法 |
| JP2000086672A (ja) | 1998-09-14 | 2000-03-28 | Idemitsu Petrochem Co Ltd | アルミノキサン、オレフィン類重合用触媒及びオレフィン系重合体の製造方法 |
| US6184171B1 (en) | 1998-10-05 | 2001-02-06 | W.R. Grace & Co. -Conn | Supported bidentate and tridentate catalyst compositions and olefin polymerization using same |
| US6620896B1 (en) | 1999-02-23 | 2003-09-16 | Eastman Chemical Company | Mixed olefin polymerization catalysts, processes employing such catalysts, and polymers obtained therefrom |
| AU1330701A (en) * | 1999-10-07 | 2001-05-10 | Dow Chemical Company, The | Silica gel composition and method for making |
| US6559090B1 (en) * | 1999-11-01 | 2003-05-06 | W. R. Grace & Co.-Conn. | Metallocene and constrained geometry catalyst systems employing agglomerated metal oxide/clay support-activator and method of their preparation |
| US6399535B1 (en) * | 1999-11-01 | 2002-06-04 | W. R. Grace & Co.-Conn. | Coordination catalyst systems employing agglomerated metal oxide/clay support-activator and method of their preparation |
| WO2001042320A1 (en) * | 1999-12-10 | 2001-06-14 | The Dow Chemical Company | Treated clay compositions and olefin polymerization catalysts comprising the same |
| US6632894B1 (en) | 1999-12-30 | 2003-10-14 | Phillips Petroleum Company | Organometal catalyst compositions |
-
2002
- 2002-04-10 KR KR1020037014216A patent/KR100893971B1/ko not_active Expired - Fee Related
- 2002-04-10 DE DE60214172T patent/DE60214172T2/de not_active Expired - Lifetime
- 2002-04-10 US US10/120,317 patent/US6686306B2/en not_active Expired - Fee Related
- 2002-04-10 EP EP02731326A patent/EP1399491B1/de not_active Expired - Lifetime
- 2002-04-10 WO PCT/US2002/011385 patent/WO2002088200A1/en not_active Ceased
- 2002-04-10 AT AT02731326T patent/ATE337343T1/de not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| US20030225225A1 (en) | 2003-12-04 |
| EP1399491B1 (de) | 2006-08-23 |
| KR100893971B1 (ko) | 2009-04-20 |
| US6686306B2 (en) | 2004-02-03 |
| WO2002088200A1 (en) | 2002-11-07 |
| DE60214172D1 (de) | 2006-10-05 |
| EP1399491A1 (de) | 2004-03-24 |
| DE60214172T2 (de) | 2007-07-12 |
| KR20040015224A (ko) | 2004-02-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| ATE337343T1 (de) | Geträgerte dualübergangsmetallkatalysatorsysteme | |
| WO2002088201A8 (en) | Process for preparing supported transition metal catalyst systems and catalyst systems prepared thereby | |
| MY121287A (en) | Cyclopentaphenanthrenyl titanium complexes and polymerization process | |
| WO2007080365A3 (en) | Supported catalyst system | |
| EP1548022A3 (de) | Übergangsmetallverbindung, Ligandensystem, Katalysatorsystem und seine Verwendung zur Polymerisation und Copolymerisation von Olefinen | |
| MY119597A (en) | Polymerisation catalysts | |
| ES2144146T3 (es) | Procedimiento para producir polimeros y copolimeros de etileno de distribucion de peso molecular bimodal. | |
| WO2002036638A3 (en) | Active non-metallocene pre-catalyst and method for tactic catalytic polymerization of alpha-olefin monomers | |
| ATE259675T1 (de) | Katalysatorsystem | |
| ATE120212T1 (de) | Katalysatorzusammensetzung für olefinpolymerisation. | |
| AU4691300A (en) | Polymerization of ethylene | |
| DE59409990D1 (de) | Verfahren zur Herstellung von Polyolefinen | |
| EP1123938A3 (de) | Organometallische Fluorenylverbindungen | |
| RU94033101A (ru) | Способ получения полимеров этилена и продукты, полученные из них | |
| CA2387877A1 (en) | Catalyst systems and their use in a polymerization process | |
| NO960350D0 (no) | Fremgangsmåte og katalysatorsystem for fremstilling av polyetylen, slike polyetylener og anvendelse av disse | |
| DE60234846D1 (de) | Übergangsmetallkatalysatoren zur olefinpolymerisation | |
| WO2003087177A3 (en) | Ethylene-styrene copolymers, complexes and catalysts with phenol-triazole ligands and processes for polymerizing therewith | |
| NO982701L (no) | Polymerisasjonskatalysatorer og fremgangsmÕter derav | |
| NO20055625D0 (no) | Katalysator for polymerisering og kopolymerisering av alfa-olenfiner | |
| CA2564486A1 (en) | Catalyst systems for producing polymers having broad molecular weight distributions and methods of making the same | |
| MY129448A (en) | Method for polymerization and copolymerization of ethylene | |
| WO2008068148A3 (en) | Method for preparing copolymers | |
| ATE394428T1 (de) | Bimetallische olefinpolymerisationskatalysatoren | |
| ATE257490T1 (de) | Katalysatorsysteme für die polymerisation und copolymerisation von alpha-olefinen |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| RER | Ceased as to paragraph 5 lit. 3 law introducing patent treaties |