DE69410668D1 - Olefinpolymerisationkatalysator mit mehrzähnigem Ligand - Google Patents

Olefinpolymerisationkatalysator mit mehrzähnigem Ligand

Info

Publication number
DE69410668D1
DE69410668D1 DE69410668T DE69410668T DE69410668D1 DE 69410668 D1 DE69410668 D1 DE 69410668D1 DE 69410668 T DE69410668 T DE 69410668T DE 69410668 T DE69410668 T DE 69410668T DE 69410668 D1 DE69410668 D1 DE 69410668D1
Authority
DE
Germany
Prior art keywords
polymerization catalyst
olefin polymerization
multidentate ligand
ligand olefin
multidentate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69410668T
Other languages
English (en)
Inventor
Toshiya Aoki
Tokitaka Kaneshima
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Asahi Kasei Corp
Asahi Chemical Industry Co Ltd
Original Assignee
Asahi Chemical Industry Co Ltd
Asahi Kasei Kogyo KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahi Chemical Industry Co Ltd, Asahi Kasei Kogyo KK filed Critical Asahi Chemical Industry Co Ltd
Application granted granted Critical
Publication of DE69410668D1 publication Critical patent/DE69410668D1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/02—Cp or analog bridged to a non-Cp X anionic donor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/05—Cp or analog where at least one of the carbon atoms of the coordinating ring is replaced by a heteroatom
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
DE69410668T 1993-03-23 1994-03-22 Olefinpolymerisationkatalysator mit mehrzähnigem Ligand Expired - Lifetime DE69410668D1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP8683393 1993-03-23
JP17019493 1993-07-09

Publications (1)

Publication Number Publication Date
DE69410668D1 true DE69410668D1 (de) 1998-07-09

Family

ID=26427914

Family Applications (2)

Application Number Title Priority Date Filing Date
DE69415351T Expired - Lifetime DE69415351D1 (de) 1993-03-23 1994-03-22 Olefinpolymerisationskatalysator mit mehrzähnigem Ligand
DE69410668T Expired - Lifetime DE69410668D1 (de) 1993-03-23 1994-03-22 Olefinpolymerisationkatalysator mit mehrzähnigem Ligand

Family Applications Before (1)

Application Number Title Priority Date Filing Date
DE69415351T Expired - Lifetime DE69415351D1 (de) 1993-03-23 1994-03-22 Olefinpolymerisationskatalysator mit mehrzähnigem Ligand

Country Status (6)

Country Link
US (1) US5817724A (de)
EP (2) EP0816386B1 (de)
CN (2) CN1077578C (de)
CA (1) CA2119590C (de)
DE (2) DE69415351D1 (de)
RU (1) RU2115663C1 (de)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2579895A (en) * 1994-06-07 1996-01-04 Specs And Biospecs B.V. Novel organo-metallic compounds, methods for preparing same, and a method for the polymerization of unsaturated hydrocarbons using said organo-metallic compounds as catalysts, as well as novel semi-products and catalyst preparations
US5539124A (en) * 1994-12-19 1996-07-23 Occidental Chemical Corporation Polymerization catalysts based on transition metal complexes with ligands containing pyrrolyl ring
NL1006048C2 (nl) * 1995-06-07 1998-11-17 Ind Tech Res Inst Verbinding om te worden toegepast als katalysator voor de polymerisatie van olefinen, katalysatorsamenstelling op basis van een dergelijke verbinding en werkwijze voor de polymerisatie of copolymerisatie van etheen onder toepassing van een dergelijke katalysatorsamenstelling.
DE19522013A1 (de) * 1995-06-21 1997-01-02 Hoechst Ag Übergangsmetallverbindung
GB9522859D0 (en) * 1995-11-08 1996-01-10 Borealis As Compounds
CA2200373C (en) * 1997-03-19 2005-11-15 Rupert Edward Von Haken Spence Heteroligand
CA2204803C (en) * 1997-05-08 2005-11-15 Nova Chemicals Ltd. Process to prepare bridged phosphole-cyclopentadienyl compounds
US6362294B1 (en) 1997-12-11 2002-03-26 Exxon Mobil Chemical Patents Inc. Reduced oxidation state transition metal compounds useful as olefin polymerization catalysts
US5932670A (en) * 1998-03-30 1999-08-03 Phillips Petroleum Company Polymerization catalysts and processes therefor
US6323148B1 (en) * 1998-12-04 2001-11-27 Equistar Chemicals, Lp Ethylene polymerization catalyst and catalyst system
US6171993B1 (en) * 1998-12-04 2001-01-09 Equistar Chemicals, Lp Enhanced-impact LLDPE with a shear modifiable network structure
US6180552B1 (en) 1999-04-07 2001-01-30 Equistar Chemicals, L.P. Transition metal complexes containing neutral, multidentate azacyclic ligands
EP1237954B1 (de) * 1999-11-01 2006-01-04 W. R. Grace & Co.-Conn Aktive, heterogene, geträgerte bi- oder tri-dendate polymerisationskatalysatoren
US6399535B1 (en) * 1999-11-01 2002-06-04 W. R. Grace & Co.-Conn. Coordination catalyst systems employing agglomerated metal oxide/clay support-activator and method of their preparation
US6194339B1 (en) * 1999-11-17 2001-02-27 Equistar Chemicals, Lp Ethylene polymerization catalyst and catalyst system
US20020028897A1 (en) * 2000-05-31 2002-03-07 Johnson Lynda Kaye Copolymers of ethylene and selected acrylate esters
US6391988B1 (en) 2001-04-18 2002-05-21 Equistar Chemicals L.P. Tris(pyrazoyl) based anions
US6734131B2 (en) 2001-04-30 2004-05-11 W. R. Grace & Co.-Conn. Heterogeneous chromium catalysts and processes of polymerization of olefins using same
DE60236653D1 (de) 2001-04-30 2010-07-22 Grace W R & Co Verfahren zur herstellung von geträgerten übergangsmetallpolymerisationskatalysatoren und daraus gebildete zusammensetzungen
WO2002102859A2 (en) 2001-04-30 2002-12-27 W. R. Grace & Co.-Conn. Coordination catalyst systems employing chromium support-agglomerate and method of their preparation
US6943224B2 (en) 2001-04-30 2005-09-13 W. R. Grace & Co.-Conn. Process for preparing supported transition metal catalyst systems and catalyst systems prepared thereby
EP1399491B1 (de) 2001-04-30 2006-08-23 W.R. Grace & Co.-Conn. Geträgerte dualübergangsmetallkatalysatorsysteme
SG98056A1 (en) * 2001-06-13 2003-08-20 Sumitomo Chemical Co Catalyst for addition polymerization and process for producing and addition polymer
RU2348653C2 (ru) 2003-02-21 2009-03-10 Дау Глобал Текнолоджиз Инк. Способ гомо- или сополимеризации сопряженных олефинов
US7417151B2 (en) 2004-12-10 2008-08-26 The University Of Akron Boron-based organic cations and related methods
EP1801131A1 (de) * 2005-12-22 2007-06-27 DSMIP Assets B.V. Zwitterionischer Cyclopentadiengruppe enthaltender Katalysator
SG174602A1 (en) 2009-03-30 2011-11-28 Mitsui Chemicals Inc Copolymer of olefin and conjugated diene, and process for producing same

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5055438A (en) * 1989-09-13 1991-10-08 Exxon Chemical Patents, Inc. Olefin polymerization catalysts
JP2502102B2 (ja) * 1987-10-08 1996-05-29 東燃株式会社 オレフイン重合用触媒
NZ235032A (en) * 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5021595A (en) * 1990-03-02 1991-06-04 Exxon Chemical Patents Inc. Transition metal catalyst composition for olefin polymerization
US5237069A (en) * 1990-10-26 1993-08-17 The Dow Chemical Company Hydridotris(pyrazolyl)borate metal complexes and polymerization process
US5434116A (en) * 1992-06-05 1995-07-18 Tosoh Corporation Organic transition metal compound having π-bonding heterocyclic ligand and method of polymerizing olefin by using the same
US5312794A (en) * 1992-12-29 1994-05-17 Shell Oil Company Catalyst system for olefin polymerization
US5519099A (en) * 1995-06-07 1996-05-21 Industrial Technology Research Institute Organometallic catalysts containing hydrotris(pyrazolyl) borate and cyclopentadienyl groups, and processes of employing the same

Also Published As

Publication number Publication date
EP0617052B1 (de) 1998-06-03
CN1077578C (zh) 2002-01-09
EP0816386A3 (de) 1998-01-14
RU2115663C1 (ru) 1998-07-20
EP0816386A2 (de) 1998-01-07
RU94009839A (ru) 1996-06-27
US5817724A (en) 1998-10-06
CA2119590C (en) 2001-01-23
EP0617052A3 (de) 1995-04-12
CN1322763A (zh) 2001-11-21
CA2119590A1 (en) 1994-09-24
DE69415351D1 (de) 1999-01-28
EP0617052A2 (de) 1994-09-28
EP0816386B1 (de) 1998-12-16
CN1096303A (zh) 1994-12-14

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