DE60214172D1 - Geträgerte dualübergangsmetallkatalysatorsysteme - Google Patents
Geträgerte dualübergangsmetallkatalysatorsystemeInfo
- Publication number
- DE60214172D1 DE60214172D1 DE60214172T DE60214172T DE60214172D1 DE 60214172 D1 DE60214172 D1 DE 60214172D1 DE 60214172 T DE60214172 T DE 60214172T DE 60214172 T DE60214172 T DE 60214172T DE 60214172 D1 DE60214172 D1 DE 60214172D1
- Authority
- DE
- Germany
- Prior art keywords
- transition metal
- metal compound
- metallocene
- polymers
- tridentate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/02—Carriers therefor
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Catalysts (AREA)
- Communication Control (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US28760201P | 2001-04-30 | 2001-04-30 | |
US287602P | 2001-04-30 | ||
PCT/US2002/011385 WO2002088200A1 (en) | 2001-04-30 | 2002-04-10 | Supported dual transition metal catalyst systems |
Publications (2)
Publication Number | Publication Date |
---|---|
DE60214172D1 true DE60214172D1 (de) | 2006-10-05 |
DE60214172T2 DE60214172T2 (de) | 2007-07-12 |
Family
ID=23103602
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE60214172T Expired - Lifetime DE60214172T2 (de) | 2001-04-30 | 2002-04-10 | Geträgerte dualübergangsmetallkatalysatorsysteme |
Country Status (6)
Country | Link |
---|---|
US (1) | US6686306B2 (de) |
EP (1) | EP1399491B1 (de) |
KR (1) | KR100893971B1 (de) |
AT (1) | ATE337343T1 (de) |
DE (1) | DE60214172T2 (de) |
WO (1) | WO2002088200A1 (de) |
Families Citing this family (53)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2001032723A1 (en) * | 1999-11-01 | 2001-05-10 | W. R. Grace & Co.-Conn. | Active, heterogeneous supported bi- or tri-dentate olefin polymerisation catalyst |
US6656866B2 (en) * | 2000-12-04 | 2003-12-02 | Univation Technologies, Llc | Catalyst preparation method |
KR100880297B1 (ko) | 2001-04-30 | 2009-01-28 | 더블유.알. 그레이스 앤드 캄파니-콘. | 크롬 지지체-응집물-전이금속 중합 촉매 및 이의 사용 방법 |
US6984602B2 (en) * | 2001-05-10 | 2006-01-10 | Univation Technologies, Llc | Olefin polymerization catalysts containing a pyrrole bisimine ligand |
US6884748B2 (en) * | 2002-09-04 | 2005-04-26 | Univation Technologies, Llc | Process for producing fluorinated catalysts |
US6841500B2 (en) * | 2002-12-03 | 2005-01-11 | Equistar Chemicals, Lp | Bimetallic indenoindolyl catalysts |
WO2004055062A1 (en) * | 2002-12-17 | 2004-07-01 | O & D Trading Limited | Supported oftien polymerization catalyst |
US6812183B1 (en) * | 2003-04-23 | 2004-11-02 | Equistar Chemicals, Lp | Triple-decker catalysts based on delocalized dianionic ligands |
DE102004006104A1 (de) * | 2004-02-06 | 2005-08-25 | Basell Polyolefine Gmbh | Verfahren zur Herstellung von geträgerten Katalysatoren für die Polymerisation |
DE102004006113A1 (de) * | 2004-02-06 | 2005-08-25 | Basell Polyolefine Gmbh | Verfahren zur Herstellung von Trägern für Katalysatoren |
DE602004006223T2 (de) * | 2004-03-12 | 2008-01-17 | Saudi Basic Industries Corp. | Katalysatorzusammensetzung für die Polymerisation von Olefinen und Polymerisationsverfahren unter dessen Verwendung |
DE102004020525A1 (de) * | 2004-04-26 | 2005-11-10 | Basell Polyolefine Gmbh | Katalysatorsystem zur Olefinpolymerisation, dessen Herstellung und Verwendung |
DE102004020524A1 (de) * | 2004-04-26 | 2005-11-10 | Basell Polyolefine Gmbh | Polyethylen und Katalysatorzusammensetzung zu dessen Herstellung |
US20080139729A1 (en) * | 2004-07-14 | 2008-06-12 | Ke Wang | Nanocomposites and Process for their Production |
US7429404B2 (en) * | 2004-07-30 | 2008-09-30 | University Of Utah Research Foundation | Methods of selectively incorporating metals onto substrates |
US20060076354A1 (en) * | 2004-10-07 | 2006-04-13 | Lanzafame John F | Hydrogen storage apparatus |
EP1650231A1 (de) * | 2004-10-21 | 2006-04-26 | Total Petrochemicals Research Feluy | Polyolefine hergestellt mit Metallocen- und neuen Single-Site-Katalysatorkomponenten in einem Reaktor |
WO2006094302A1 (en) * | 2005-03-04 | 2006-09-08 | E.I. Dupont De Nemours And Company | Supported olefin polymerization catalysts |
US7273914B2 (en) * | 2005-08-03 | 2007-09-25 | Equistar Chemicals, Lp | Olefin polymerization methods |
WO2008036882A1 (en) * | 2006-09-21 | 2008-03-27 | California Institute Of Technology | Non-metallocene organometallic complexes and related methods and systems |
DE102007017903A1 (de) | 2007-04-13 | 2008-10-16 | Basell Polyolefine Gmbh | Polyethylen und Katalysatorzusammensetzung und Verfahren zu dessen Herstellung |
DE102007022052A1 (de) * | 2007-05-08 | 2008-11-13 | Basell Polyolefine Gmbh | Katalysatorsystem zur Olefinpolymerisation, Verfahren zu ihrer Herstellung, sowie ein Verfahren zur Polymerisation von a-Olefinen unter Verwendung des Katalysatorsystems |
US8435911B2 (en) * | 2008-10-16 | 2013-05-07 | Basell Polyolefine Gmbh | Hybrid catalyst composition for polymerization of olefins |
CA2713042C (en) | 2010-08-11 | 2017-10-24 | Nova Chemicals Corporation | Method of controlling polymer architecture |
WO2012097146A1 (en) | 2011-01-14 | 2012-07-19 | W. R. Grace & Co.-Conn. | Process of making modified metallocene catalyst, catalyst produced and use thereof |
CA2734167C (en) | 2011-03-15 | 2018-03-27 | Nova Chemicals Corporation | Polyethylene film |
CA2739969C (en) | 2011-05-11 | 2018-08-21 | Nova Chemicals Corporation | Improving reactor operability in a gas phase polymerization process |
US9315591B2 (en) | 2011-06-09 | 2016-04-19 | Nova Chemicals (International) S.A. | Modified phosphinimine catalysts for olefin polymerization |
US9127094B2 (en) | 2011-06-09 | 2015-09-08 | Nova Chemicals (International) S.A. | Modified phosphinimine catalysts for olefin polymerization |
CA2742454C (en) | 2011-06-09 | 2018-06-12 | Nova Chemicals Corporation | Methods for controlling ethylene copolymer properties |
US9127106B2 (en) | 2011-06-09 | 2015-09-08 | Nova Chemicals (International) S.A. | Modified phosphinimine catalysts for olefin polymerization |
US9321859B2 (en) | 2011-06-09 | 2016-04-26 | Nova Chemicals (International) S.A. | Modified phosphinimine catalysts for olefin polymerization |
US9243092B2 (en) | 2011-06-09 | 2016-01-26 | Nova Chemicals (International) S.A. | Modified phosphinimine catalysts for olefin polymerization |
CA2742461C (en) | 2011-06-09 | 2018-06-12 | Nova Chemicals Corporation | Modified phosphinimine catalysts for olefin polymerization |
US9221935B2 (en) | 2011-06-09 | 2015-12-29 | Nova Chemicals (International) S.A. | Modified phosphinimine catalysts for olefin polymerization |
CA2749835C (en) | 2011-08-23 | 2018-08-21 | Nova Chemicals Corporation | Feeding highly active phosphinimine catalysts to a gas phase reactor |
CN102964471B (zh) * | 2011-08-31 | 2015-07-01 | 中国石油化工股份有限公司 | 负载型非茂金属催化剂、其制备方法及其应用 |
US8653208B2 (en) | 2012-05-18 | 2014-02-18 | Union Carbide Chemicals & Plastics Technology Llc | Process for preparing catalysts and catalysts made thereby |
US9115233B2 (en) | 2012-06-21 | 2015-08-25 | Nova Chemicals (International) S.A. | Ethylene copolymer compositions, film and polymerization processes |
CA2798855C (en) | 2012-06-21 | 2021-01-26 | Nova Chemicals Corporation | Ethylene copolymers having reverse comonomer incorporation |
CA2783494C (en) | 2012-07-23 | 2019-07-30 | Nova Chemicals Corporation | Adjusting polymer composition |
EP2923756B1 (de) | 2012-11-26 | 2018-05-30 | Braskem S.A. | Durch hybridstütze geträgerter metallocenkatalysator, verfahren zur herstellung davon, polymerisationsverfahren zur herstellung eines ethylenhomopolymers oder copolymers mit breiter oder bimodaler molmassenverteilung, verwednung des geträgerter metallocenkatalysators und ethylenpolymer mit breiter oder bimodaler molmassenverteilung |
CA2797620C (en) | 2012-12-03 | 2019-08-27 | Nova Chemicals Corporation | Controlling resin properties in a gas phase polymerization process |
CA2800056A1 (en) | 2012-12-24 | 2014-06-24 | Nova Chemicals Corporation | Polyethylene blend compositions |
CA2891693C (en) | 2015-05-21 | 2022-01-11 | Nova Chemicals Corporation | Controlling the placement of comonomer in an ethylene copolymer |
CA2892552C (en) | 2015-05-26 | 2022-02-15 | Victoria Ker | Process for polymerization in a fluidized bed reactor |
CA2892882C (en) | 2015-05-27 | 2022-03-22 | Nova Chemicals Corporation | Ethylene/1-butene copolymers with enhanced resin processability |
US11267914B2 (en) | 2016-12-29 | 2022-03-08 | Chevron Phillips Chemical Company Lp | Methods of preparing a catalyst |
US10654953B2 (en) * | 2016-12-29 | 2020-05-19 | Chevron Phillips Chemical Company Lp | Methods of preparing a catalyst |
US20200369803A1 (en) | 2016-12-29 | 2020-11-26 | Chevron Phillips Chemical Company Lp | Methods of Preparing a Catalyst |
US20220033549A1 (en) * | 2019-01-08 | 2022-02-03 | Exxonmobil Chemical Patents Inc. | Olefin Polymerization Processes Featuring In Situ Blending of an Oil Extension |
EP4155324A3 (de) * | 2021-09-22 | 2023-05-03 | Sumitomo Chemical Company, Limited | Verfahren zur herstellung einer festen katalysatorkomponente zur olefin-polymerisation, verfahren zur herstellung eines katalysators zur olefin-polymerisation und verfahren zur herstellung eines olefin-polymers |
CN115404512A (zh) * | 2022-08-10 | 2022-11-29 | 青岛科技大学 | 一种富磷空位的铁掺杂磷化镍的制备方法及其在电解海水产氢中的应用 |
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DE69801299T2 (de) * | 1997-04-25 | 2002-04-18 | Mitsubishi Chemical Corp., Tokio/Tokyo | Phyllosilikat-geträgerter Katalysator für die Olefinenpolymerisation |
JP3458656B2 (ja) | 1997-05-27 | 2003-10-20 | 東ソー株式会社 | オレフィン重合用触媒およびオレフィン重合体の製造方法 |
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DE69918684T2 (de) | 1998-03-12 | 2004-12-02 | Bp Chemicals Ltd. | Polymerisationskatalysatoren |
MXPA00008941A (es) | 1998-03-12 | 2002-06-04 | Bp Chem Int Ltd | Catalizadores para polimerizacion. |
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WO2001042320A1 (en) * | 1999-12-10 | 2001-06-14 | The Dow Chemical Company | Treated clay compositions and olefin polymerization catalysts comprising the same |
US6632894B1 (en) * | 1999-12-30 | 2003-10-14 | Phillips Petroleum Company | Organometal catalyst compositions |
-
2002
- 2002-04-10 WO PCT/US2002/011385 patent/WO2002088200A1/en active IP Right Grant
- 2002-04-10 KR KR1020037014216A patent/KR100893971B1/ko not_active IP Right Cessation
- 2002-04-10 DE DE60214172T patent/DE60214172T2/de not_active Expired - Lifetime
- 2002-04-10 AT AT02731326T patent/ATE337343T1/de not_active IP Right Cessation
- 2002-04-10 EP EP02731326A patent/EP1399491B1/de not_active Expired - Lifetime
- 2002-04-10 US US10/120,317 patent/US6686306B2/en not_active Expired - Fee Related
Also Published As
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US6686306B2 (en) | 2004-02-03 |
ATE337343T1 (de) | 2006-09-15 |
US20030225225A1 (en) | 2003-12-04 |
KR20040015224A (ko) | 2004-02-18 |
DE60214172T2 (de) | 2007-07-12 |
WO2002088200A1 (en) | 2002-11-07 |
EP1399491B1 (de) | 2006-08-23 |
EP1399491A1 (de) | 2004-03-24 |
KR100893971B1 (ko) | 2009-04-20 |
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