JP2003515620A5 - - Google Patents
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- JP2003515620A5 JP2003515620A5 JP2001535420A JP2001535420A JP2003515620A5 JP 2003515620 A5 JP2003515620 A5 JP 2003515620A5 JP 2001535420 A JP2001535420 A JP 2001535420A JP 2001535420 A JP2001535420 A JP 2001535420A JP 2003515620 A5 JP2003515620 A5 JP 2003515620A5
- Authority
- JP
- Japan
- Prior art keywords
- activator
- catalyst
- support
- group
- hydrocarbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000003054 catalyst Substances 0.000 description 99
- 239000012190 activator Substances 0.000 description 86
- 239000012018 catalyst precursor Substances 0.000 description 75
- 239000004215 Carbon black (E152) Substances 0.000 description 65
- 229930195733 hydrocarbon Natural products 0.000 description 65
- 150000002430 hydrocarbons Chemical class 0.000 description 64
- 239000002245 particle Substances 0.000 description 57
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 52
- 239000000463 material Substances 0.000 description 48
- 150000002902 organometallic compounds Chemical class 0.000 description 47
- 230000003647 oxidation Effects 0.000 description 36
- 238000007254 oxidation reaction Methods 0.000 description 36
- 229910052736 halogen Inorganic materials 0.000 description 35
- 150000002367 halogens Chemical class 0.000 description 35
- 229910052809 inorganic oxide Inorganic materials 0.000 description 35
- 238000000034 method Methods 0.000 description 33
- 150000003623 transition metal compounds Chemical class 0.000 description 30
- 229910052739 hydrogen Inorganic materials 0.000 description 25
- 239000001257 hydrogen Substances 0.000 description 25
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 23
- 239000007788 liquid Substances 0.000 description 23
- 229910052723 transition metal Inorganic materials 0.000 description 23
- 239000003446 ligand Substances 0.000 description 22
- 150000003624 transition metals Chemical class 0.000 description 22
- 239000004927 clay Substances 0.000 description 20
- 229910052742 iron Inorganic materials 0.000 description 20
- 150000002431 hydrogen Chemical class 0.000 description 19
- 229910052759 nickel Inorganic materials 0.000 description 19
- 229910052763 palladium Inorganic materials 0.000 description 19
- 125000001183 hydrocarbyl group Chemical group 0.000 description 16
- 229910052757 nitrogen Inorganic materials 0.000 description 16
- 230000000737 periodic effect Effects 0.000 description 16
- 230000000694 effects Effects 0.000 description 14
- 125000000623 heterocyclic group Chemical group 0.000 description 14
- 150000002500 ions Chemical class 0.000 description 13
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 12
- 229910004298 SiO 2 Inorganic materials 0.000 description 12
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 12
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 12
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 12
- 125000000217 alkyl group Chemical group 0.000 description 12
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 12
- 229910052804 chromium Inorganic materials 0.000 description 12
- 239000012967 coordination catalyst Substances 0.000 description 12
- 229910052735 hafnium Inorganic materials 0.000 description 12
- 229910052741 iridium Inorganic materials 0.000 description 12
- 229910052748 manganese Inorganic materials 0.000 description 12
- 229910052762 osmium Inorganic materials 0.000 description 12
- 229910052760 oxygen Inorganic materials 0.000 description 12
- 239000001301 oxygen Substances 0.000 description 12
- 229910052698 phosphorus Inorganic materials 0.000 description 12
- 239000011574 phosphorus Substances 0.000 description 12
- 229910052697 platinum Inorganic materials 0.000 description 12
- 229910052703 rhodium Inorganic materials 0.000 description 12
- 229910052707 ruthenium Inorganic materials 0.000 description 12
- 229910052717 sulfur Inorganic materials 0.000 description 12
- 239000011593 sulfur Substances 0.000 description 12
- 229910052719 titanium Inorganic materials 0.000 description 12
- 229910052720 vanadium Inorganic materials 0.000 description 12
- 229910052725 zinc Inorganic materials 0.000 description 12
- 239000011701 zinc Substances 0.000 description 12
- 229910052726 zirconium Inorganic materials 0.000 description 12
- 238000001694 spray drying Methods 0.000 description 9
- 229910021647 smectite Inorganic materials 0.000 description 8
- 229910052782 aluminium Inorganic materials 0.000 description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 7
- 150000001450 anions Chemical class 0.000 description 7
- 150000001768 cations Chemical class 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- 239000002243 precursor Substances 0.000 description 7
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 6
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 6
- 229910017119 AlPO Inorganic materials 0.000 description 6
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 6
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical class [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 6
- 239000004698 Polyethylene Substances 0.000 description 6
- 229910010413 TiO 2 Inorganic materials 0.000 description 6
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 6
- 229910052794 bromium Inorganic materials 0.000 description 6
- 239000000460 chlorine Substances 0.000 description 6
- 229910052801 chlorine Inorganic materials 0.000 description 6
- 238000009826 distribution Methods 0.000 description 6
- 229910052740 iodine Inorganic materials 0.000 description 6
- 239000011630 iodine Substances 0.000 description 6
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 6
- 239000000178 monomer Substances 0.000 description 6
- -1 polyethylene Polymers 0.000 description 6
- 229920000573 polyethylene Polymers 0.000 description 6
- 238000006116 polymerization reaction Methods 0.000 description 6
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 5
- 239000005977 Ethylene Substances 0.000 description 5
- 239000002734 clay mineral Substances 0.000 description 5
- 150000001336 alkenes Chemical class 0.000 description 4
- 125000003545 alkoxy group Chemical group 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 125000000743 hydrocarbylene group Chemical group 0.000 description 4
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 4
- 230000002776 aggregation Effects 0.000 description 3
- 229910017052 cobalt Inorganic materials 0.000 description 3
- 239000010941 cobalt Substances 0.000 description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 3
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 description 3
- 229910000271 hectorite Inorganic materials 0.000 description 3
- 229910052901 montmorillonite Inorganic materials 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000005054 agglomeration Methods 0.000 description 2
- 230000004931 aggregating effect Effects 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 125000003341 7 membered heterocyclic group Chemical group 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000012968 metallocene catalyst Substances 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/431,771 | 1999-11-01 | ||
| US09/431,771 US6399535B1 (en) | 1999-11-01 | 1999-11-01 | Coordination catalyst systems employing agglomerated metal oxide/clay support-activator and method of their preparation |
| PCT/US2000/028938 WO2001032722A1 (en) | 1999-11-01 | 2000-10-19 | Coordination catalyst systems employing agglomerated metal oxide/clay support-activator and method of their preparation |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2003515620A JP2003515620A (ja) | 2003-05-07 |
| JP2003515620A5 true JP2003515620A5 (enExample) | 2007-12-06 |
| JP4773660B2 JP4773660B2 (ja) | 2011-09-14 |
Family
ID=23713360
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2001535420A Expired - Fee Related JP4773660B2 (ja) | 1999-11-01 | 2000-10-19 | 凝集した金属酸化物／粘土支持体−活性化剤を用いた配位触媒系そしてそれらの製造方法 |
Country Status (6)
| Country | Link |
|---|---|
| US (2) | US6399535B1 (enExample) |
| EP (1) | EP1246852A1 (enExample) |
| JP (1) | JP4773660B2 (enExample) |
| AU (1) | AU1216001A (enExample) |
| SG (1) | SG88794A1 (enExample) |
| WO (1) | WO2001032722A1 (enExample) |
Families Citing this family (79)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NZ235032A (en) * | 1989-08-31 | 1993-04-28 | Dow Chemical Co | Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component |
| US6492292B2 (en) | 1998-10-23 | 2002-12-10 | Albemarle Corporation | Gelatinous compositions formed from hydroxyaluminoxane, solid compositions formed therefrom, and the use of such compositions as catalyst components |
| US20040002420A1 (en) * | 1998-10-23 | 2004-01-01 | Feng-Jung Wu | Stable catalysts and co-catalyst compositions formed from hydroxyaluminoxane and their use |
| US6812182B2 (en) | 1998-10-23 | 2004-11-02 | Albemarle Corporation | Compositions formed from hydroxyaluminoxane and their use as catalyst components |
| US6555494B2 (en) | 1998-10-23 | 2003-04-29 | Albemarle Corporation | Transition metal compounds having conjugate aluminoxate anions, their preparation and their use as catalyst components |
| US6559090B1 (en) * | 1999-11-01 | 2003-05-06 | W. R. Grace & Co.-Conn. | Metallocene and constrained geometry catalyst systems employing agglomerated metal oxide/clay support-activator and method of their preparation |
| JP5258077B2 (ja) * | 1999-11-01 | 2013-08-07 | ダブリュー・アール・グレイス・アンド・カンパニー−コネチカット | オレフィン重合用の活性を持った三配座不均一担持触媒 |
| US6632894B1 (en) * | 1999-12-30 | 2003-10-14 | Phillips Petroleum Company | Organometal catalyst compositions |
| US6656866B2 (en) * | 2000-12-04 | 2003-12-02 | Univation Technologies, Llc | Catalyst preparation method |
| US6734131B2 (en) | 2001-04-30 | 2004-05-11 | W. R. Grace & Co.-Conn. | Heterogeneous chromium catalysts and processes of polymerization of olefins using same |
| WO2002102859A2 (en) * | 2001-04-30 | 2002-12-27 | W. R. Grace & Co.-Conn. | Coordination catalyst systems employing chromium support-agglomerate and method of their preparation |
| KR100917529B1 (ko) * | 2001-04-30 | 2009-09-16 | 더블유.알. 그레이스 앤드 캄파니-콘. | 지지된 전이 금속 촉매 시스템의 제조 방법 및 그 방법에 의해 제조된 촉매 시스템 |
| KR100540049B1 (ko) * | 2001-04-30 | 2006-01-20 | 더블유.알. 그레이스 앤드 캄파니-콘. | 지지된 전이 금속 중합 촉매의 제조 방법 및 이 방법으로형성된 조성물 |
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| GB0209317D0 (en) * | 2002-04-24 | 2002-06-05 | Bp Chem Int Ltd | Polymerisation catalyst |
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| US7271121B2 (en) * | 2005-07-21 | 2007-09-18 | Chevron Phillips Chemical Company Lp | Diimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization |
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| US9127106B2 (en) | 2011-06-09 | 2015-09-08 | Nova Chemicals (International) S.A. | Modified phosphinimine catalysts for olefin polymerization |
| US9315591B2 (en) | 2011-06-09 | 2016-04-19 | Nova Chemicals (International) S.A. | Modified phosphinimine catalysts for olefin polymerization |
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| CA2800056A1 (en) | 2012-12-24 | 2014-06-24 | Nova Chemicals Corporation | Polyethylene blend compositions |
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| US10940460B2 (en) | 2015-05-11 | 2021-03-09 | W. R. Grace & Co.-Conn. | Process to produce modified clay, modified clay produced and use thereof |
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| US10618988B2 (en) | 2015-08-31 | 2020-04-14 | Exxonmobil Chemical Patents Inc. | Branched propylene polymers produced via use of vinyl transfer agents and processes for production thereof |
| WO2017039994A1 (en) | 2015-08-31 | 2017-03-09 | Exxonmobil Chemical Patents Inc. | Aluminum alkyls with pendant olefins on clays |
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| CN108137730B (zh) | 2015-09-24 | 2021-10-29 | 埃克森美孚化学专利公司 | 使用在有机铝处理过的层状硅酸盐载体上负载的吡啶基二氨基化合物的聚合方法 |
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| WO2017058390A1 (en) * | 2015-10-02 | 2017-04-06 | Exxonmobil Chemical Patents Inc. | Polymerization process using bis phenolate compounds supported on organoaluminum treated layered silicate supports |
| US10000593B2 (en) | 2015-10-02 | 2018-06-19 | Exxonmobil Chemical Patents Inc. | Supported Salan catalysts |
| US9982076B2 (en) | 2015-10-02 | 2018-05-29 | Exxonmobil Chemical Patents Inc. | Supported bis phenolate transition metals complexes, production and use thereof |
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| US10414887B2 (en) | 2015-10-02 | 2019-09-17 | Exxonmobil Chemical Patents Inc. | Supported catalyst systems and methods of using same |
| US10562987B2 (en) | 2016-06-30 | 2020-02-18 | Exxonmobil Chemical Patents Inc. | Polymers produced via use of quinolinyldiamido transition metal complexes and vinyl transfer agents |
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| US10626200B2 (en) | 2017-02-28 | 2020-04-21 | Exxonmobil Chemical Patents Inc. | Branched EPDM polymers produced via use of vinyl transfer agents and processes for production thereof |
| WO2018160278A1 (en) | 2017-03-01 | 2018-09-07 | Exxonmobil Chemical Patents Inc. | Branched ethylene copolymers produced via use of vinyl transfer agents and processes for production thereof |
| WO2021011632A1 (en) * | 2019-07-18 | 2021-01-21 | Exxonmobil Chemical Patents Inc. | Mixed catalyst system |
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-
1999
- 1999-11-01 US US09/431,771 patent/US6399535B1/en not_active Expired - Lifetime
-
2000
- 2000-10-19 JP JP2001535420A patent/JP4773660B2/ja not_active Expired - Fee Related
- 2000-10-19 EP EP00973673A patent/EP1246852A1/en not_active Withdrawn
- 2000-10-19 AU AU12160/01A patent/AU1216001A/en not_active Abandoned
- 2000-10-19 WO PCT/US2000/028938 patent/WO2001032722A1/en not_active Ceased
- 2000-10-27 SG SG200006191A patent/SG88794A1/en unknown
-
2002
- 2002-04-01 US US10/113,761 patent/US20030096698A1/en not_active Abandoned
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