JP4773660B2 - 凝集した金属酸化物/粘土支持体−活性化剤を用いた配位触媒系そしてそれらの製造方法 - Google Patents
凝集した金属酸化物/粘土支持体−活性化剤を用いた配位触媒系そしてそれらの製造方法 Download PDFInfo
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- JP4773660B2 JP4773660B2 JP2001535420A JP2001535420A JP4773660B2 JP 4773660 B2 JP4773660 B2 JP 4773660B2 JP 2001535420 A JP2001535420 A JP 2001535420A JP 2001535420 A JP2001535420 A JP 2001535420A JP 4773660 B2 JP4773660 B2 JP 4773660B2
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- Prior art keywords
- catalyst
- activator
- support
- clay
- hydrocarbon
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- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- QHGNHLZPVBIIPX-UHFFFAOYSA-N tin(ii) oxide Chemical class [Sn]=O QHGNHLZPVBIIPX-UHFFFAOYSA-N 0.000 description 1
- 150000003609 titanium compounds Chemical class 0.000 description 1
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- CWBIFDGMOSWLRQ-UHFFFAOYSA-N trimagnesium;hydroxy(trioxido)silane;hydrate Chemical compound O.[Mg+2].[Mg+2].[Mg+2].O[Si]([O-])([O-])[O-].O[Si]([O-])([O-])[O-] CWBIFDGMOSWLRQ-UHFFFAOYSA-N 0.000 description 1
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 1
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- OBROYCQXICMORW-UHFFFAOYSA-N tripropoxyalumane Chemical compound [Al+3].CCC[O-].CCC[O-].CCC[O-] OBROYCQXICMORW-UHFFFAOYSA-N 0.000 description 1
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- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
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- 125000005023 xylyl group Chemical group 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
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Classifications
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerization Catalysts (AREA)
Applications Claiming Priority (3)
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| US09/431,771 | 1999-11-01 | ||
| US09/431,771 US6399535B1 (en) | 1999-11-01 | 1999-11-01 | Coordination catalyst systems employing agglomerated metal oxide/clay support-activator and method of their preparation |
| PCT/US2000/028938 WO2001032722A1 (en) | 1999-11-01 | 2000-10-19 | Coordination catalyst systems employing agglomerated metal oxide/clay support-activator and method of their preparation |
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| JP2003515620A JP2003515620A (ja) | 2003-05-07 |
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| JP (1) | JP4773660B2 (enExample) |
| AU (1) | AU1216001A (enExample) |
| SG (1) | SG88794A1 (enExample) |
| WO (1) | WO2001032722A1 (enExample) |
Families Citing this family (79)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NZ235032A (en) * | 1989-08-31 | 1993-04-28 | Dow Chemical Co | Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component |
| US6492292B2 (en) | 1998-10-23 | 2002-12-10 | Albemarle Corporation | Gelatinous compositions formed from hydroxyaluminoxane, solid compositions formed therefrom, and the use of such compositions as catalyst components |
| US20040002420A1 (en) * | 1998-10-23 | 2004-01-01 | Feng-Jung Wu | Stable catalysts and co-catalyst compositions formed from hydroxyaluminoxane and their use |
| US6812182B2 (en) | 1998-10-23 | 2004-11-02 | Albemarle Corporation | Compositions formed from hydroxyaluminoxane and their use as catalyst components |
| US6555494B2 (en) | 1998-10-23 | 2003-04-29 | Albemarle Corporation | Transition metal compounds having conjugate aluminoxate anions, their preparation and their use as catalyst components |
| US6559090B1 (en) * | 1999-11-01 | 2003-05-06 | W. R. Grace & Co.-Conn. | Metallocene and constrained geometry catalyst systems employing agglomerated metal oxide/clay support-activator and method of their preparation |
| JP5258077B2 (ja) * | 1999-11-01 | 2013-08-07 | ダブリュー・アール・グレイス・アンド・カンパニー−コネチカット | オレフィン重合用の活性を持った三配座不均一担持触媒 |
| US6632894B1 (en) * | 1999-12-30 | 2003-10-14 | Phillips Petroleum Company | Organometal catalyst compositions |
| US6656866B2 (en) * | 2000-12-04 | 2003-12-02 | Univation Technologies, Llc | Catalyst preparation method |
| US6734131B2 (en) | 2001-04-30 | 2004-05-11 | W. R. Grace & Co.-Conn. | Heterogeneous chromium catalysts and processes of polymerization of olefins using same |
| WO2002102859A2 (en) * | 2001-04-30 | 2002-12-27 | W. R. Grace & Co.-Conn. | Coordination catalyst systems employing chromium support-agglomerate and method of their preparation |
| KR100917529B1 (ko) * | 2001-04-30 | 2009-09-16 | 더블유.알. 그레이스 앤드 캄파니-콘. | 지지된 전이 금속 촉매 시스템의 제조 방법 및 그 방법에 의해 제조된 촉매 시스템 |
| KR100540049B1 (ko) * | 2001-04-30 | 2006-01-20 | 더블유.알. 그레이스 앤드 캄파니-콘. | 지지된 전이 금속 중합 촉매의 제조 방법 및 이 방법으로형성된 조성물 |
| US6958375B2 (en) * | 2001-04-30 | 2005-10-25 | W.R. Grace & Co.-Conn. | Chromium support-agglomerate-transition metal polymerization catalysts and processes utilizing same |
| ATE337343T1 (de) * | 2001-04-30 | 2006-09-15 | Grace W R & Co | Geträgerte dualübergangsmetallkatalysatorsysteme |
| US6943224B2 (en) * | 2001-04-30 | 2005-09-13 | W. R. Grace & Co.-Conn. | Process for preparing supported transition metal catalyst systems and catalyst systems prepared thereby |
| EP1430088B1 (de) * | 2001-09-14 | 2008-10-22 | Basell Polyolefine GmbH | Verfahren zur polymerisation von olefinen |
| MXPA04006611A (es) * | 2002-01-09 | 2004-10-04 | Du Pont | Catalizador para polimerizacion de olefinas. |
| US6646072B2 (en) * | 2002-01-23 | 2003-11-11 | Equistar Chemicals, Lp | Process for making polyolefin compositions containing exfoliated clay |
| GB0209317D0 (en) * | 2002-04-24 | 2002-06-05 | Bp Chem Int Ltd | Polymerisation catalyst |
| KR20060013486A (ko) * | 2003-02-24 | 2006-02-10 | 차이나 페트로리움 앤드 케미컬 코포레이션 | 프로필렌 중합용 촉매의 복합 담체, 촉매 성분 및 이를포함하는 촉매 |
| BRPI0413961A (pt) * | 2003-09-11 | 2006-10-31 | Basell Polyolefine Gmbh | processo multi-etapas para preparar copolìmeros heterofásicos de propileno |
| US20050187418A1 (en) * | 2004-02-19 | 2005-08-25 | Small Brooke L. | Olefin oligomerization |
| US20070043181A1 (en) * | 2005-08-19 | 2007-02-22 | Knudsen Ronald D | Methods of preparation of an olefin oligomerization catalyst |
| US9550841B2 (en) | 2004-02-20 | 2017-01-24 | Chevron Phillips Chemical Company Lp | Methods of preparation of an olefin oligomerization catalyst |
| US7384886B2 (en) * | 2004-02-20 | 2008-06-10 | Chevron Phillips Chemical Company Lp | Methods of preparation of an olefin oligomerization catalyst |
| EP1773895B1 (en) * | 2004-07-09 | 2011-12-28 | E.I. Du Pont De Nemours And Company | Catalysts for olefin polymerization or oligomerization |
| US20060040822A1 (en) * | 2004-08-23 | 2006-02-23 | Shveima Joseph S | Catalyst compositions, processes, and products utilizing pillared clays |
| US7358410B2 (en) * | 2004-12-30 | 2008-04-15 | Exxonmobil Chemical Patents Inc. | Processes for forming polypropylene from an oxygenate-contaminated monomer feedstock |
| EP1856164A1 (en) * | 2005-03-04 | 2007-11-21 | E.I. Dupont De Nemours And Company | Supported olefin polymerization catalysts |
| US7268096B2 (en) * | 2005-07-21 | 2007-09-11 | Chevron Phillips Chemical Company Lp | Diimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization |
| US7727926B2 (en) * | 2005-07-21 | 2010-06-01 | Chevron Phillips Chemical Company Lp | Diimine metal complexes, methods of synthesis, and method of using in oligomerization and polymerization |
| US7271121B2 (en) * | 2005-07-21 | 2007-09-18 | Chevron Phillips Chemical Company Lp | Diimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization |
| US7273914B2 (en) * | 2005-08-03 | 2007-09-25 | Equistar Chemicals, Lp | Olefin polymerization methods |
| EP1767549A1 (en) | 2005-09-20 | 2007-03-28 | Ineos Europe Limited | Polymerisation catalysts |
| US9365664B2 (en) | 2009-01-29 | 2016-06-14 | W. R. Grace & Co. -Conn. | Catalyst on silica clad alumina support |
| CA2750535A1 (en) | 2009-01-29 | 2010-08-05 | W.R. Grace & Co.-Conn. | Catalyst on silica clad alumina support |
| BR112012032827B1 (pt) * | 2010-06-24 | 2019-01-02 | Pq Corp | processo para a preparação de partículas de suporte de catalisador, partícula do suporte de catalisador, precursor de catalisador, catalisador de polimerização de olefina, método para a polimerização de um ou mais a-alcenos c2 a c8, e, uso de um catalisador de polimerização de olefina |
| CA2713042C (en) | 2010-08-11 | 2017-10-24 | Nova Chemicals Corporation | Method of controlling polymer architecture |
| CA2734167C (en) | 2011-03-15 | 2018-03-27 | Nova Chemicals Corporation | Polyethylene film |
| CA2739969C (en) | 2011-05-11 | 2018-08-21 | Nova Chemicals Corporation | Improving reactor operability in a gas phase polymerization process |
| US9127106B2 (en) | 2011-06-09 | 2015-09-08 | Nova Chemicals (International) S.A. | Modified phosphinimine catalysts for olefin polymerization |
| US9315591B2 (en) | 2011-06-09 | 2016-04-19 | Nova Chemicals (International) S.A. | Modified phosphinimine catalysts for olefin polymerization |
| US9221935B2 (en) | 2011-06-09 | 2015-12-29 | Nova Chemicals (International) S.A. | Modified phosphinimine catalysts for olefin polymerization |
| US9127094B2 (en) | 2011-06-09 | 2015-09-08 | Nova Chemicals (International) S.A. | Modified phosphinimine catalysts for olefin polymerization |
| CA2742461C (en) | 2011-06-09 | 2018-06-12 | Nova Chemicals Corporation | Modified phosphinimine catalysts for olefin polymerization |
| US9321859B2 (en) | 2011-06-09 | 2016-04-26 | Nova Chemicals (International) S.A. | Modified phosphinimine catalysts for olefin polymerization |
| US9243092B2 (en) | 2011-06-09 | 2016-01-26 | Nova Chemicals (International) S.A. | Modified phosphinimine catalysts for olefin polymerization |
| CA2742454C (en) | 2011-06-09 | 2018-06-12 | Nova Chemicals Corporation | Methods for controlling ethylene copolymer properties |
| CA2749835C (en) | 2011-08-23 | 2018-08-21 | Nova Chemicals Corporation | Feeding highly active phosphinimine catalysts to a gas phase reactor |
| US9586872B2 (en) | 2011-12-30 | 2017-03-07 | Chevron Phillips Chemical Company Lp | Olefin oligomerization methods |
| US9115233B2 (en) | 2012-06-21 | 2015-08-25 | Nova Chemicals (International) S.A. | Ethylene copolymer compositions, film and polymerization processes |
| CA2798855C (en) | 2012-06-21 | 2021-01-26 | Nova Chemicals Corporation | Ethylene copolymers having reverse comonomer incorporation |
| CA2797620C (en) | 2012-12-03 | 2019-08-27 | Nova Chemicals Corporation | Controlling resin properties in a gas phase polymerization process |
| CA2800056A1 (en) | 2012-12-24 | 2014-06-24 | Nova Chemicals Corporation | Polyethylene blend compositions |
| CA2985611C (en) | 2015-05-11 | 2021-06-01 | W.R. Grace & Co.-Conn. | Process to produce modified clay, supported metallocene polymerization catalyst, catalyst produced and use thereof |
| US10940460B2 (en) | 2015-05-11 | 2021-03-09 | W. R. Grace & Co.-Conn. | Process to produce modified clay, modified clay produced and use thereof |
| CA2891693C (en) | 2015-05-21 | 2022-01-11 | Nova Chemicals Corporation | Controlling the placement of comonomer in an ethylene copolymer |
| CA2892552C (en) | 2015-05-26 | 2022-02-15 | Victoria Ker | Process for polymerization in a fluidized bed reactor |
| CA2892882C (en) | 2015-05-27 | 2022-03-22 | Nova Chemicals Corporation | Ethylene/1-butene copolymers with enhanced resin processability |
| US10351647B2 (en) | 2015-05-29 | 2019-07-16 | Exxonmobil Chemical Patents Inc. | Polymerization process using bridged metallocene compounds supported on organoaluminum treated layered silicate supports |
| US10618988B2 (en) | 2015-08-31 | 2020-04-14 | Exxonmobil Chemical Patents Inc. | Branched propylene polymers produced via use of vinyl transfer agents and processes for production thereof |
| WO2017039994A1 (en) | 2015-08-31 | 2017-03-09 | Exxonmobil Chemical Patents Inc. | Aluminum alkyls with pendant olefins on clays |
| WO2017039995A1 (en) | 2015-08-31 | 2017-03-09 | Exxonmobil Chemical Patents Inc. | Aluminum alkyls with pendant olefins for polyolefin reactions |
| US9982067B2 (en) | 2015-09-24 | 2018-05-29 | Exxonmobil Chemical Patents Inc. | Polymerization process using pyridyldiamido compounds supported on organoaluminum treated layered silicate supports |
| CN108137730B (zh) | 2015-09-24 | 2021-10-29 | 埃克森美孚化学专利公司 | 使用在有机铝处理过的层状硅酸盐载体上负载的吡啶基二氨基化合物的聚合方法 |
| US9994657B2 (en) | 2015-10-02 | 2018-06-12 | Exxonmobil Chemical Patents Inc. | Polymerization process using bis phenolate compounds supported on organoaluminum treated layered silicate supports |
| US9994658B2 (en) | 2015-10-02 | 2018-06-12 | Exxonmobil Chemical Patents Inc. | Polymerization process using bis phenolate compounds supported on organoaluminum treated layered silicate supports |
| US9975973B2 (en) | 2015-10-02 | 2018-05-22 | Exxonmobil Chemical Patents Inc. | Asymmetric fluorenyl-substituted salan catalysts |
| WO2017058390A1 (en) * | 2015-10-02 | 2017-04-06 | Exxonmobil Chemical Patents Inc. | Polymerization process using bis phenolate compounds supported on organoaluminum treated layered silicate supports |
| US10000593B2 (en) | 2015-10-02 | 2018-06-19 | Exxonmobil Chemical Patents Inc. | Supported Salan catalysts |
| US9982076B2 (en) | 2015-10-02 | 2018-05-29 | Exxonmobil Chemical Patents Inc. | Supported bis phenolate transition metals complexes, production and use thereof |
| WO2017058391A1 (en) * | 2015-10-02 | 2017-04-06 | Exxonmobil Chemical Patents Inc. | Polymerization process using bis phenolate compounds supported on organoaluminum treated layered silicate supports |
| US10414887B2 (en) | 2015-10-02 | 2019-09-17 | Exxonmobil Chemical Patents Inc. | Supported catalyst systems and methods of using same |
| US10562987B2 (en) | 2016-06-30 | 2020-02-18 | Exxonmobil Chemical Patents Inc. | Polymers produced via use of quinolinyldiamido transition metal complexes and vinyl transfer agents |
| US9944661B2 (en) | 2016-08-09 | 2018-04-17 | Chevron Phillips Chemical Company Lp | Olefin hydroboration |
| US10626200B2 (en) | 2017-02-28 | 2020-04-21 | Exxonmobil Chemical Patents Inc. | Branched EPDM polymers produced via use of vinyl transfer agents and processes for production thereof |
| WO2018160278A1 (en) | 2017-03-01 | 2018-09-07 | Exxonmobil Chemical Patents Inc. | Branched ethylene copolymers produced via use of vinyl transfer agents and processes for production thereof |
| WO2021011632A1 (en) * | 2019-07-18 | 2021-01-21 | Exxonmobil Chemical Patents Inc. | Mixed catalyst system |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4981825A (en) * | 1989-09-12 | 1991-01-01 | Board Of Trustees Operating Michigan State University | Dried metal oxide and clay particle compositions and method for the preparation thereof |
| JPH10513489A (ja) * | 1995-01-24 | 1998-12-22 | イー・アイ・デュポン・ドゥ・ヌムール・アンド・カンパニー | α−オレフィン類およびオレフィンポリマー類、およびその製法 |
| JP2003513164A (ja) * | 1999-11-01 | 2003-04-08 | ダブリュー・アール・グレイス・アンド・カンパニー−コネチカット | 凝集した金属酸化物/粘土支持体−活性化剤を用いたメタロセンおよび拘束幾何触媒系そしてそれらの製造方法 |
Family Cites Families (54)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2061290A1 (de) * | 1970-12-12 | 1972-06-15 | Basf Ag | Katalysatorsystem fuer die Polymerisation von Olefinen |
| US4176090A (en) | 1975-11-18 | 1979-11-27 | W. R. Grace & Co. | Pillared interlayered clay materials useful as catalysts and sorbents |
| IL50548A (en) | 1976-09-23 | 1979-10-31 | Yissum Res Dev Co | Process for preparation of molecular sieves |
| US4238364A (en) | 1979-04-03 | 1980-12-09 | University Of Utah | Class of cracking catalysts acidic forms of cross-linked smectities |
| US4248739A (en) | 1979-09-04 | 1981-02-03 | W. R. Grace & Co. | Stabilized pillared interlayered clays |
| US4271043A (en) | 1979-09-04 | 1981-06-02 | W. R. Grace & Co. | Pillared interlayered clay products |
| US4375406A (en) | 1981-01-21 | 1983-03-01 | Chevron Research Company | Fibrous clay compositions containing precalcined oxides |
| US4367163A (en) | 1981-04-15 | 1983-01-04 | Research Corporation | Silica-clay complexes |
| US4629712A (en) | 1984-08-17 | 1986-12-16 | Michigan State University | Delaminated clay materials |
| US4637992A (en) | 1984-12-17 | 1987-01-20 | Shell Oil Company | Intercalated clay compositions |
| US4859648A (en) | 1984-12-28 | 1989-08-22 | Mobil Oil Corporation | Layered metal chalcogenides containing interspathic polymeric chalcogenides |
| US4761391A (en) | 1986-06-30 | 1988-08-02 | Union Oil Company Of California | Delaminated clays and their use in hydrocarbon conversion processes |
| US5241025A (en) | 1987-01-30 | 1993-08-31 | Exxon Chemical Patents Inc. | Catalyst system of enhanced productivity |
| US4995964A (en) | 1987-03-05 | 1991-02-26 | Uop | Midbarrel hydrocracking process employing rare earth pillared clays |
| US5225500A (en) | 1988-07-15 | 1993-07-06 | Fina Technology, Inc. | Process and catalyst for producing syndiotactic polyolefins |
| US5243002A (en) | 1988-07-15 | 1993-09-07 | Fina Technology, Inc. | Process and catalyst for producing syndiotactic polymers |
| JPH0278663A (ja) | 1988-09-14 | 1990-03-19 | N O K Sogo Gijutsu Kenkyusho:Kk | 2,6―エチリデンニトリロフェニルピリジン、その製造法ならびに金属塩錯体 |
| US5064802A (en) | 1989-09-14 | 1991-11-12 | The Dow Chemical Company | Metal complex compounds |
| ATE137247T1 (de) | 1989-10-30 | 1996-05-15 | Fina Technology | Addition von alkylaluminium zum verbessern eines metallocenkatalysators |
| ES2071086T5 (es) | 1989-10-30 | 2002-01-16 | Fina Technology | Preparacion de catalizadores metalocenicos para polimerizacion de olefina. |
| JP2545006B2 (ja) | 1990-07-03 | 1996-10-16 | ザ ダウ ケミカル カンパニー | 付加重合触媒 |
| US5128291A (en) | 1990-12-11 | 1992-07-07 | Wax Michael J | Porous titania or zirconia spheres |
| US5250277A (en) | 1991-01-11 | 1993-10-05 | Mobil Oil Corp. | Crystalline oxide material |
| TW218884B (enExample) * | 1991-05-01 | 1994-01-11 | Mitsubishi Kakoki Kk | |
| US5399636A (en) | 1993-06-11 | 1995-03-21 | Phillips Petroleum Company | Metallocenes and processes therefor and therewith |
| ES2108861T3 (es) | 1991-11-25 | 1998-01-01 | Exxon Chemical Patents Inc | Composiciones cataliticas polionicas de metales de transicion. |
| JPH05170429A (ja) | 1991-12-18 | 1993-07-09 | Mitsubishi Materials Corp | 粘土架橋多孔体及びその製造方法 |
| US5238892A (en) | 1992-06-15 | 1993-08-24 | Exxon Chemical Patents Inc. | Supported catalyst for 1-olefin(s) (co)polymerization |
| US5362825A (en) | 1992-07-13 | 1994-11-08 | Phillips Petroleum Company | Catalysts for polymerizing olefins and methods |
| US5403799A (en) | 1992-12-21 | 1995-04-04 | W. R. Grace & Co.-Conn. | Process upset-resistant inorganic supports for bioremediation |
| US5403809A (en) | 1992-12-21 | 1995-04-04 | W. R. Grace & Co.-Conn. | Composite inorganic supports containing carbon for bioremediation |
| US5395808A (en) | 1992-12-21 | 1995-03-07 | W. R. Grace & Co.-Conn. | Inorganic supports for bioremediation |
| EP0617052B1 (en) * | 1993-03-23 | 1998-06-03 | Asahi Kasei Kogyo Kabushiki Kaisha | Olefin polymerization catalyst having a multidentate ligand |
| DE69412047T2 (de) * | 1993-12-17 | 1999-04-15 | Tosoh Corp., Shinnanyo, Yamaguchi | Olefinpolymerisationkatalysator und Verfahren zur Olefinpolymerisation |
| EP0683180B1 (en) * | 1994-05-18 | 2002-03-06 | Mitsubishi Chemical Corporation | Catalyst for polymerizing an olefin and method for polymerizing the olefin |
| US5643847A (en) | 1994-08-03 | 1997-07-01 | Exxon Chemical Patents Inc. | Supported ionic catalyst composition |
| US5661097A (en) | 1994-08-12 | 1997-08-26 | The Dow Chemical Company | Supported olefin polymerization catalyst |
| US5880241A (en) | 1995-01-24 | 1999-03-09 | E. I. Du Pont De Nemours And Company | Olefin polymers |
| DE69611554T2 (de) | 1995-02-20 | 2001-07-05 | Tosoh Corp., Shinnanyo | Katalysator für die Polymerisation von Olefinen und Verfahren zur Herstellung von Olefinpolymerisaten |
| WO1997019959A1 (en) | 1995-11-27 | 1997-06-05 | The Dow Chemical Company | Supported catalyst containing tethered cation forming activator |
| EP0791608B1 (en) | 1996-02-23 | 2000-05-10 | Tosoh Corporation | Olefin polymerization catalyst based on organometallic complexes and processes for production of polyolefins using the catalyst |
| DE69717440T2 (de) | 1996-06-21 | 2003-10-02 | W.R. Grace & Co.-Conn., New York | Aggregatträger und darauf angebrachte olefinpolymerisationskatalysatoren |
| IL129929A0 (en) | 1996-12-17 | 2000-02-29 | Du Pont | Polymerization of ethylene with specific iron or cobalt complexes novel pyridinebis (imines) and novel complexes of pyridinebis(imines) with iron and cobalt |
| US6110858A (en) | 1996-12-18 | 2000-08-29 | Tosoh Corporation | Olefin polymerization catalysts and process for producing olefin polymers |
| US5906955A (en) | 1996-12-20 | 1999-05-25 | Tosoh Corporation | Catalyst for polymerization of an olefin, and method for producing an olefin polymer |
| JP2001508107A (ja) | 1997-01-13 | 2001-06-19 | イー・アイ・デユポン・ドウ・ヌムール・アンド・カンパニー | プロピレンの重合 |
| US5807800A (en) | 1997-02-11 | 1998-09-15 | Fina Technology, Inc. | Process for producing stereospecific polymers |
| JP3458656B2 (ja) | 1997-05-27 | 2003-10-20 | 東ソー株式会社 | オレフィン重合用触媒およびオレフィン重合体の製造方法 |
| CA2289633A1 (en) | 1997-06-09 | 1998-12-17 | Stephen James Mclain | Polymerization of olefins |
| ID27209A (id) | 1998-03-12 | 2001-03-08 | Bp Chem Int Ltd | Katalis-katalis polimerisasi |
| DZ2737A1 (fr) | 1998-03-12 | 2003-09-01 | Bp Chem Int Ltd | Catalyseurs de polymérisation. |
| ID26574A (id) | 1998-03-12 | 2001-01-18 | Bp Chem Int Ltd | Katalis-katalis polimerisasi |
| JPH11338516A (ja) | 1998-05-26 | 1999-12-10 | Yaskawa Electric Corp | 位置制御装置 |
| WO2001025149A2 (en) | 1999-10-07 | 2001-04-12 | The Dow Chemical Company | Silica gel composition and method for making |
-
1999
- 1999-11-01 US US09/431,771 patent/US6399535B1/en not_active Expired - Lifetime
-
2000
- 2000-10-19 JP JP2001535420A patent/JP4773660B2/ja not_active Expired - Fee Related
- 2000-10-19 EP EP00973673A patent/EP1246852A1/en not_active Withdrawn
- 2000-10-19 AU AU12160/01A patent/AU1216001A/en not_active Abandoned
- 2000-10-19 WO PCT/US2000/028938 patent/WO2001032722A1/en not_active Ceased
- 2000-10-27 SG SG200006191A patent/SG88794A1/en unknown
-
2002
- 2002-04-01 US US10/113,761 patent/US20030096698A1/en not_active Abandoned
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4981825A (en) * | 1989-09-12 | 1991-01-01 | Board Of Trustees Operating Michigan State University | Dried metal oxide and clay particle compositions and method for the preparation thereof |
| JPH10513489A (ja) * | 1995-01-24 | 1998-12-22 | イー・アイ・デュポン・ドゥ・ヌムール・アンド・カンパニー | α−オレフィン類およびオレフィンポリマー類、およびその製法 |
| JP2003513164A (ja) * | 1999-11-01 | 2003-04-08 | ダブリュー・アール・グレイス・アンド・カンパニー−コネチカット | 凝集した金属酸化物/粘土支持体−活性化剤を用いたメタロセンおよび拘束幾何触媒系そしてそれらの製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| AU1216001A (en) | 2001-05-14 |
| US6399535B1 (en) | 2002-06-04 |
| WO2001032722A1 (en) | 2001-05-10 |
| US20030096698A1 (en) | 2003-05-22 |
| SG88794A1 (en) | 2002-05-21 |
| JP2003515620A (ja) | 2003-05-07 |
| EP1246852A1 (en) | 2002-10-09 |
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