JP2002530415A5 - - Google Patents

Download PDF

Info

Publication number
JP2002530415A5
JP2002530415A5 JP2000583918A JP2000583918A JP2002530415A5 JP 2002530415 A5 JP2002530415 A5 JP 2002530415A5 JP 2000583918 A JP2000583918 A JP 2000583918A JP 2000583918 A JP2000583918 A JP 2000583918A JP 2002530415 A5 JP2002530415 A5 JP 2002530415A5
Authority
JP
Japan
Prior art keywords
compound according
dimethylsilanediylbis
tert
methyl
compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2000583918A
Other languages
English (en)
Japanese (ja)
Other versions
JP5008794B2 (ja
JP2002530415A (ja
Filing date
Publication date
Application filed filed Critical
Priority claimed from PCT/EP1999/008851 external-priority patent/WO2000031090A1/de
Publication of JP2002530415A publication Critical patent/JP2002530415A/ja
Publication of JP2002530415A5 publication Critical patent/JP2002530415A5/ja
Application granted granted Critical
Publication of JP5008794B2 publication Critical patent/JP5008794B2/ja
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

JP2000583918A 1998-11-25 1999-11-18 メタロセンモノハロゲン化物 Expired - Lifetime JP5008794B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE19854350 1998-11-25
DE19854350.6 1998-11-25
PCT/EP1999/008851 WO2000031090A1 (de) 1998-11-25 1999-11-18 Metallocenmonohalogenide

Publications (3)

Publication Number Publication Date
JP2002530415A JP2002530415A (ja) 2002-09-17
JP2002530415A5 true JP2002530415A5 (enExample) 2012-06-07
JP5008794B2 JP5008794B2 (ja) 2012-08-22

Family

ID=7888955

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2000583918A Expired - Lifetime JP5008794B2 (ja) 1998-11-25 1999-11-18 メタロセンモノハロゲン化物

Country Status (11)

Country Link
US (1) US7053160B1 (enExample)
EP (2) EP1049705A1 (enExample)
JP (1) JP5008794B2 (enExample)
KR (1) KR100635413B1 (enExample)
CN (1) CN100340568C (enExample)
AU (1) AU1272100A (enExample)
BR (1) BR9906934B1 (enExample)
DE (1) DE59914158D1 (enExample)
ES (1) ES2280674T3 (enExample)
WO (1) WO2000031090A1 (enExample)
ZA (1) ZA200003597B (enExample)

Families Citing this family (103)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR9915708B1 (pt) * 1998-11-25 2010-07-13 processo para preparação de monoariloxi-metalocenos.
DE10028432A1 (de) 2000-06-13 2001-12-20 Basell Polyolefine Gmbh Auf calciniertes Hydrotalcit geträgerter Katalysatorfeststoff zur Olefinpolymerisation
JP2002088110A (ja) * 2000-09-13 2002-03-27 Denki Kagaku Kogyo Kk 重合用遷移金属触媒成分、それを用いたオレフィン−芳香族ビニル化合物重合体の製造方法
DE10145453A1 (de) 2001-09-14 2003-06-05 Basell Polyolefine Gmbh Monocyclopentadienylkomplexe mit einem kondensierten Heterocyclus
WO2003025028A1 (de) 2001-09-14 2003-03-27 Basell Polyolefine Gmbh Verfahren zur polymerisation von olefinen
AU2003242656B2 (en) * 2002-06-12 2008-04-03 Basell Polyolefine Gmbh Flexible propylene copolymer compositions having a high transparency
WO2004007570A2 (en) 2002-07-15 2004-01-22 Basell Polyolefine Gmbh Preparation of supported catalyst systems
WO2004007569A1 (en) 2002-07-15 2004-01-22 Basell Polyolefine Gmbh Preparation of catalyst systems
US7202373B2 (en) 2002-08-22 2007-04-10 Basell Polyolefine Gmbh Monocyclopentadienyl complexes
JP4390770B2 (ja) * 2002-10-25 2009-12-24 バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング rac−ジオルガノシリルビス(2−メチルベンゾ[e]インデニル)ジルコニウム化合物のラセモ選択的合成法
US7414005B2 (en) 2002-11-04 2008-08-19 Basell Polyolefine Gmbh Preparation of catalyst compositions having improved activity
EP1567560B1 (en) 2002-12-06 2011-01-19 Basell Polyolefine GmbH Organometallic transition metal compound, biscyclopentadienyl ligand system, catalyst system and process for preparing polyolefins
AU2003293887A1 (en) 2002-12-16 2004-07-09 Basell Polyolefine Gmbh Preparation of supported catalyst systems containing reduced amounts of aluminoxanes
DE60321822D1 (de) * 2002-12-20 2008-08-07 Basell Polyolefine Gmbh Monocyclopentadienylkomplexe
US7534847B2 (en) 2002-12-20 2009-05-19 Basell Polyolefine Gmbh Copolymers of ethylene with α-olefins
US7544749B2 (en) 2003-02-07 2009-06-09 Basell Polyolefine Gmbh Polymerization catalysts, organic transition metal compounds, process for preparing polyolefins and polyolefins
DE602004006976T2 (de) 2003-04-03 2008-02-14 Basell Polyolefine Gmbh Herstellung von hochmolekularen polyolefinen in gegenwart einer organischen übergangsmetallverbindung in einem gasphasen-wirbelschichtreaktor
US7507782B2 (en) 2003-05-21 2009-03-24 Basell Polyolefine Gmbh Transition-metal complexes with tridentate, nitrogen-containing ligands
JP2007506820A (ja) 2003-09-25 2007-03-22 バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング 重合触媒、ポリオレフィンの製造方法、有機遷移金属化合物及びリガンド
DE10348624A1 (de) 2003-10-15 2005-05-25 Basell Polyolefine Gmbh Geträgerte Metallalkylverbindung und Verfahren zu deren Herstellung
DE10352139A1 (de) 2003-11-04 2005-06-09 Basell Polyolefine Gmbh Organoübergangsmetallverbindung, Biscyclopentadienylligandsystem und Verfahren zur Herstellung von Polyolefinen
DE10358082A1 (de) 2003-12-10 2005-07-14 Basell Polyolefine Gmbh Organübergangsmetallverbindung, Bscyclopentadienyligandsystem, Katalysatorsystem und Hertellung von Polyolefinen
BRPI0417575A (pt) 2003-12-16 2007-03-20 Basell Polyolefine Gmbh complexo de monociclopentadienila, sistema catalisador, uso do mesmo, processos para preparar poliolefinas, e sistemas de ciclopentadieno, sistema de ciclopentadieno, e, ciclopentenona
EP1694719A2 (en) 2003-12-19 2006-08-30 Basell Polyolefine GmbH Monocyclopentadienyl complexes
KR20060118564A (ko) 2003-12-23 2006-11-23 바젤 폴리올레핀 게엠베하 올레핀 중합용 촉매계
WO2005090467A1 (en) * 2004-03-24 2005-09-29 Basell Polyolefine Gmbh Flexible propylene copolymer compositions having a high transparency
DE102004020525A1 (de) 2004-04-26 2005-11-10 Basell Polyolefine Gmbh Katalysatorsystem zur Olefinpolymerisation, dessen Herstellung und Verwendung
DE102004020524A1 (de) * 2004-04-26 2005-11-10 Basell Polyolefine Gmbh Polyethylen und Katalysatorzusammensetzung zu dessen Herstellung
ATE445650T1 (de) 2004-05-04 2009-10-15 Basell Polyolefine Gmbh Verfahren zur herstellung von ataktischen 1- butenpolymeren
DE102004027332A1 (de) 2004-06-04 2005-12-22 Basell Polyolefine Gmbh Übergangsmetallverbindung, Ligandsystem, Katalysatorsystem und Verfahren zur Herstellung von Polyolefinen
JP4644445B2 (ja) * 2004-06-08 2011-03-02 日本ポリプロ株式会社 メタロセン化合物の精製方法
DE102004032581A1 (de) 2004-07-05 2006-02-09 Basell Polyolefine Gmbh Polymerisationskatalysatoren, Hauptgruppenkoordinationsverbindungen, Verfahren zur Herstellung von Polyolefinen und Polyolefine
BRPI0513108A (pt) * 2004-07-22 2008-04-29 Basell Polyolefine Gmbh processo para produzir polìmeros de buteno-1 fracionáveis
DE102004039877A1 (de) * 2004-08-17 2006-02-23 Basell Polyolefine Gmbh Silylhalogenidsubstituierte Cyclopentadienylkomplexe der Gruppe 6
DE102004058578A1 (de) * 2004-12-03 2006-06-08 Basell Polyolefine Gmbh Verfahren zur Herstellung von Katalysatorsystemen später Übergangsmetalle
DE102004061618A1 (de) * 2004-12-17 2006-06-22 Basell Polyolefine Gmbh Monocyclopentadienylkomplexe
US7803887B2 (en) * 2005-03-18 2010-09-28 Basell Polyolefine Gmbh Metallocene compounds
KR101293405B1 (ko) * 2005-03-18 2013-08-05 바젤 폴리올레핀 게엠베하 메탈로센 화합물
EP1861435B1 (en) * 2005-03-23 2016-01-13 Basell Polyolefine GmbH Process for the polymerization of olefins
US7728086B2 (en) * 2005-03-23 2010-06-01 Basell Polyolefine Gmbh Process for the polymerization of olefins
DE102005014395A1 (de) 2005-03-24 2006-09-28 Basell Polyolefine Gmbh Monocyclopentadienylkomplexe
EP1871832B1 (en) * 2005-04-21 2012-06-13 Basell Poliolefine Italia S.r.l. Biaxially oriented propylene polymer films
DE102005019393A1 (de) 2005-04-25 2006-10-26 Basell Polyolefine Gmbh Polyethylenformmassen für Spritzgussanwendungen
DE102005019395A1 (de) * 2005-04-25 2006-10-26 Basell Polyolefine Gmbh Formmasse aus Polyethylen zur Folienherstellung und Verfahren zum Herstellen der Formmasse in Gegenwart eines Mischkatalysators
US7964679B2 (en) 2005-05-03 2011-06-21 Basell Poliolefine Italia S.R.L. Process for the polymerization of alpha olefins
WO2006120177A2 (en) 2005-05-11 2006-11-16 Basell Poliolefine Itatia S.R.L. Polymerization process for preparing polyolefin blends
US20090234084A1 (en) * 2005-06-30 2009-09-17 Basell Polyolefine Gmbh Metallocene Compounds
DE102005035477A1 (de) 2005-07-26 2007-02-01 Basell Polyolefine Gmbh Verfahren zur Steuerung der relativen Aktivität der unterschiedlichen aktiven Zentren von Hybridkatalysatoren
US20090227748A1 (en) * 2005-09-06 2009-09-10 Basell Polyolefine Gmbh Process for Preparing Olff in Polymers in the Presence of Catalyst Systems Having Photochromic Groups
DE102005056775A1 (de) * 2005-11-28 2007-05-31 Basell Polyolefine Gmbh Verfahren für den Katalysatorwechsel in einem Gasphasenwirbelschichtreaktor
DE102005057559A1 (de) * 2005-11-30 2007-05-31 Basell Polyolefine Gmbh Übergangsmetallverbindung, Ligandsystem, Katalysatorsystem und Verfahren zur Herstellung von Polyolefinen
DE102005061326A1 (de) * 2005-12-20 2007-06-21 Basell Polyolefine Gmbh Verfahren zur Herstellung von Metallocenen aus recycelten, substituierten Cyclopentadienylderivaten
DE102006001959A1 (de) 2006-01-13 2007-07-19 Basell Polyolefine Gmbh Verfahren zur Herstellung von unsymmetrischen Bis(imino)verbindungen
JP2009530341A (ja) 2006-03-17 2009-08-27 バーゼル・ポリオレフィン・ゲーエムベーハー メタロセン化合物類
JP2009533382A (ja) 2006-04-12 2009-09-17 バーゼル・ポリオレフィン・ゲーエムベーハー メタロセン化合物
JP2010500418A (ja) * 2006-04-21 2010-01-07 バーゼル・ポリオレフィン・ゲーエムベーハー エチレンプロピレンコポリマーの製造方法
US8742042B2 (en) * 2006-04-21 2014-06-03 Basell Polyolefine Gmbh Process for the preparation of ethylene copolymers
DE102006020486A1 (de) 2006-04-28 2007-10-31 Basell Polyolefine Gmbh Geträgerte Metallalkylverbindung und Verfahren zur Polymerisation von Olefinen in deren Gegenwart
JP6026716B2 (ja) * 2006-09-20 2016-11-16 アルベマール・コーポレーシヨン 触媒活性化剤、それの製造方法および触媒およびオレフィン重合におけるそれの使用
JP5584472B2 (ja) 2007-02-01 2014-09-03 バーゼル・ポリオレフィン・ゲーエムベーハー 射出成形用エチレン単峰性コポリマー及びその製造法
DE102007017903A1 (de) 2007-04-13 2008-10-16 Basell Polyolefine Gmbh Polyethylen und Katalysatorzusammensetzung und Verfahren zu dessen Herstellung
DE102007022052A1 (de) 2007-05-08 2008-11-13 Basell Polyolefine Gmbh Katalysatorsystem zur Olefinpolymerisation, Verfahren zu ihrer Herstellung, sowie ein Verfahren zur Polymerisation von a-Olefinen unter Verwendung des Katalysatorsystems
US8207281B2 (en) 2007-12-18 2012-06-26 Basell Polyolefine Gmbh Process for preparing transition metal compounds for olefins polymerization
EP2245076B1 (en) 2007-12-19 2011-08-31 Basell Polyolefine GmbH Ethylene terpolymers
WO2009080438A1 (en) 2007-12-20 2009-07-02 Basell Polyolefine Gmbh Process for obtaining polymers of ethylene and cycloolefins
US7999043B2 (en) 2007-12-24 2011-08-16 Basell Polyolefine Gmbh Multistage process for the polymerization of olefins
RU2477299C2 (ru) * 2008-02-18 2013-03-10 Баззель Полиолефине Гмбх Клеевая полимерная композиция
US9090761B2 (en) 2008-08-29 2015-07-28 Basell Polyolefine Gmbh Polyethylene for injection moldings
CA2736415A1 (en) 2008-09-25 2010-04-01 Basell Polyolefine Gmbh Impact resistant lldpe composition and films made thereof
BRPI0919740B1 (pt) 2008-09-25 2019-08-27 Basell Polyolefine Gmbh composição de lldpe resistente a impacto e películas feitas do mesmo
US8435911B2 (en) 2008-10-16 2013-05-07 Basell Polyolefine Gmbh Hybrid catalyst composition for polymerization of olefins
US8759460B2 (en) 2008-12-01 2014-06-24 Bassell Polyolefine Gmbh Process for the polymerization of ethylene, and ethylene polymers having broad molecular weight distribution and long-chain branching
WO2010069527A1 (en) 2008-12-17 2010-06-24 Basell Polyolefine Gmbh Catalyst system for olefin polymerization, its production and use
BRPI1007245A2 (pt) 2009-01-13 2016-10-18 Bassel Poliolefine Italia S R L composição polimérica
CN102282182B (zh) 2009-01-13 2014-11-12 巴塞尔聚烯烃股份有限公司 聚乙烯共聚物
US20120010377A1 (en) 2009-03-30 2012-01-12 Basell Polyolefine Gmbh Catalyst System for the Polymerization of Alpha-Olefins
EP2459600B1 (en) 2009-07-27 2013-11-20 Basell Polyolefine GmbH Organometallic transition metal compound, catalyst system and preparation of polyolefins
WO2011072851A1 (en) 2009-12-18 2011-06-23 Basell Polyolefine Gmbh Process for the preparation of supported catalysts
KR101271395B1 (ko) * 2009-12-21 2013-06-05 에스케이종합화학 주식회사 메탈로센 촉매를 이용한 에틸렌과 알파-올레핀의 공중합체를 제조하는 방법
WO2011085951A1 (en) 2010-01-15 2011-07-21 Basell Polyolefine Gmbh Oligomerization of olefins
EP2526130B1 (en) 2010-01-21 2014-04-30 Basell Polyolefine GmbH Process for the preparation of ethylene copolymer compositions in the presence of an oligomerization catalyst
WO2011147573A2 (en) 2010-05-28 2011-12-01 Basell Polyolefine Gmbh Process for preparing a supported catalyst system for olefin polymerization, the catalyst system and its use
WO2011160828A1 (en) 2010-06-25 2011-12-29 Basell Polyolefine Gmbh Process for the production of high-strength polyolefin compositions and polyolefin compositions produced by this process
WO2012055943A2 (en) 2010-10-28 2012-05-03 Basell Polyolefine Gmbh Oligomerization of olefins
CN103347910B (zh) 2010-12-22 2016-01-20 巴塞尔聚烯烃股份有限公司 控制包含至少一种后过渡金属催化剂组分和至少一种Ziegler催化剂组分的催化剂体系的活性中心的相对活性的工艺
DE102011009683A1 (de) 2011-01-28 2012-08-02 Trw Automotive Electronics & Components Gmbh Verfahren zum Montieren eines Bauteils und Befestigungsclip
US9029478B2 (en) 2011-02-07 2015-05-12 Equistar Chemicals, Lp High clarity polyethylene films
EP2606970A1 (en) 2011-12-19 2013-06-26 Basell Polyolefine GmbH Monocyclopentadienyl binuclear complexes, ligands used in their preparaion, catalyst systems comprising them and olefin polymerisation process
EP2607391A1 (en) 2011-12-21 2013-06-26 Basell Polyolefine GmbH Process for controlling the polymer composition of an ethylene copolymer obtained by a catalyst system comprising a transition metal catalyst component and a Ziegler catalyst component
EP2676972A1 (en) 2012-06-19 2013-12-25 Basell Polyolefine GmbH Process for the obtainment of a polyolefin composition
WO2014092327A1 (ko) * 2012-12-11 2014-06-19 주식회사 엘지화학 신규한 리간드 화합물, 이의 제조방법 및 상기 리간드 화합물을 포함하는 전이금속 화합물, 및 이의 제조방법
KR101583671B1 (ko) * 2012-12-11 2016-01-11 주식회사 엘지화학 리간드 화합물 및 전이금속 화합물의 제조방법
EP2743000A1 (en) 2012-12-13 2014-06-18 Basell Poliolefine Italia S.r.l. Catalyst system for the preparation of polyolefins
EP2767542A1 (en) 2013-02-18 2014-08-20 Basell Polyolefine GmbH Oligomerization catalyst
EP2842912A1 (en) 2013-08-26 2015-03-04 Basell Poliolefine Italia S.r.l. Method for improving the operability of an olefin polymerization reactor
CN105593249B (zh) 2013-10-14 2018-10-09 巴塞尔聚烯烃股份有限公司 耐热性提高的聚乙烯
MX2016004152A (es) 2013-10-15 2016-07-07 Basell Polyolefine Gmbh Polietileno para el moldeo por inyeccion.
CN105612207A (zh) 2013-10-15 2016-05-25 巴塞尔聚烯烃股份有限公司 用于注塑模制的聚乙烯组合物
KR101580591B1 (ko) 2014-06-10 2015-12-28 주식회사 엘지화학 프로필렌계 엘라스토머
US10844150B2 (en) * 2017-08-04 2020-11-24 Exxonmobil Chemical Patents Inc. Mixed catalysts with 2,6-bis(imino)pyridyl iron complexes and bridged hafnocenes
PT4069774T (pt) 2019-12-03 2024-02-05 Basell Polyolefine Gmbh Composição de polietileno para filamentos ou fibras
AU2020398364A1 (en) 2019-12-03 2022-06-16 Basell Polyolefine Gmbh Polyethylene composition for filaments or fibers
CN115894758B (zh) * 2021-09-30 2024-05-07 中国石油化工股份有限公司 乙烯-环烯烃共聚物及其制备方法

Family Cites Families (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4582924A (en) 1983-03-09 1986-04-15 Daikin Kogyo Co., Ltd. α-Fluoroalkyl carboxylic acid esters and process for preparing the same
US4752597A (en) 1985-12-12 1988-06-21 Exxon Chemical Patents Inc. New polymerization catalyst
JPH0780930B2 (ja) 1985-12-26 1995-08-30 三井石油化学工業株式会社 α−オレフインの重合方法
US5700750A (en) 1985-12-26 1997-12-23 Mitsui Petrochemical Industries, Ltd. Process for polymerization of alpha-olefins
EP0287666B1 (en) * 1986-09-24 1993-05-26 Mitsui Petrochemical Industries, Ltd. Process for polymerizing olefins
JPH0780932B2 (ja) * 1987-01-14 1995-08-30 三井石油化学工業株式会社 α−オレフインの重合方法
DE3742934A1 (de) 1987-12-18 1989-06-29 Hoechst Ag Verfahren zur herstellung einer chiralen, stereorigiden metallocen-verbindung
US5017714A (en) 1988-03-21 1991-05-21 Exxon Chemical Patents Inc. Silicon-bridged transition metal compounds
KR920006464B1 (ko) * 1988-09-14 1992-08-07 미쓰이 세끼유 가가꾸 고오교오 가부시끼가이샤 올레핀중합용 촉매성분, 올레핀중합용 촉매 및 이 올레핀중합용 촉매를 사용한 올레핀의 중합방법
IT1237398B (it) 1989-01-31 1993-06-01 Ausimont Srl Catalizzatori per la polimerizzazione di olefine.
JPH0374415A (ja) * 1989-08-15 1991-03-29 Asahi Chem Ind Co Ltd 高立体規則性ポリプロピレンの製造方法
NZ235032A (en) 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
EP0485823B1 (de) 1990-11-12 1995-03-08 Hoechst Aktiengesellschaft 2-Substituierte Bisindenylmetallocene, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren bei der Olefinpolymerisation
DE59210001D1 (de) 1991-10-15 2005-02-17 Basell Polyolefine Gmbh Verfahren zur Herstellung eines Olefinpolymers unter Verwendung von Metallocenen mit speziell substituierten Indenylliganden
EP0549900B1 (de) 1991-11-30 1996-08-21 Hoechst Aktiengesellschaft Metallocene mit benzokondensierten Indenylderivaten als Liganden, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren
TW294669B (enExample) 1992-06-27 1997-01-01 Hoechst Ag
CA2125247C (en) 1993-06-07 2001-02-20 Daisuke Fukuoka Transition metal compound, olefin polymerization catalyst component comprising said compound, olefin polymerization catalyst containing said catalyst component, process for olefinpolymerization using said catalyst , propylene homopolymer, propylene copolymer and propylene elastomer
DE4344688A1 (de) * 1993-12-27 1995-06-29 Hoechst Ag Metallocenverbindung
DE4406109A1 (de) 1994-02-25 1995-08-31 Witco Gmbh Verfahren zur Herstellung von verbrückten stereorigiden Metallocenen
TW454020B (en) * 1994-08-09 2001-09-11 Mitsui Chemicals Inc Olefin polymerization catalyst
UA47394C2 (uk) * 1995-05-16 2002-07-15 Юнівейшн Текнолоджіз, Ллс Етиленовий полімер, який має підвищену придатність до обробки та вирiб, що містить етиленовий полімер
JPH09176221A (ja) * 1995-12-27 1997-07-08 Sumitomo Chem Co Ltd オレフィン重合用触媒及びそれを使用したオレフィン重合体の製造方法
ES2152653T3 (es) * 1996-03-29 2001-02-01 Dow Chemical Co Cocatalizador de metaloceno.
US6492539B1 (en) 1997-03-07 2002-12-10 Basell Polypropylen Gmbh Preparation of preparing substituted indanones
EP1028123A3 (de) * 1997-06-10 2004-12-01 Peroxid-Chemie GmbH & Co. KG. Verfahren zur Herstellung von Metallocen-Verbindungen
JPH11292891A (ja) * 1998-04-03 1999-10-26 Kanto Chem Co Inc メタロセン化合物の新規な合成方法
BR9915708B1 (pt) * 1998-11-25 2010-07-13 processo para preparação de monoariloxi-metalocenos.

Similar Documents

Publication Publication Date Title
JP2002530415A5 (enExample)
JP3287617B2 (ja) アイソタクチツクポリオレフイン製造の方法及び触媒
JP4116148B2 (ja) 新規な遷移金属化合物、オレフィン重合用触媒成分およびα−オレフィン重合体の製造方法
JP4105783B2 (ja) 担持された触媒システム、その調製方法、及びオレフィンを重合させるための前記触媒システムの使用
JP4237263B2 (ja) ヘテロ環式縮合シクロペンタジエニド配位子を含む重合触媒系
EP1389220B1 (en) Polypropylene preparation
JP4771500B2 (ja) シンジオタクチック/アタクチックブロックポリオレフィン類、それを製造するための触媒および方法
JPH0841119A (ja) メタロセン含有触媒系の製造方法
CA2212668A1 (en) Supported chemical compound
JPH04227708A (ja) ポリオレフィンの製造方法
JP4028077B2 (ja) α−オレフィン重合用触媒
JPH09132584A (ja) メタロセン化合物
CN106414470A (zh) 作为聚合催化剂的第iva族金属的甲硅烷基二(六甲基茚基)络合物
JPH08231573A (ja) メタロセン化合物及び触媒成分としてのその使用
KR101712318B1 (ko) 메탈로센 이성질체 촉매 및 이를 이용하여 제조된 폴리올레핀 수지
JP3919837B2 (ja) 架橋メタロセンの製造方法
JP2001522856A (ja) フルベン−金属錯体の製造方法
CN112154163B (zh) 过渡金属化合物及使用其制备聚丙烯的方法
JPH1057815A (ja) 担持触媒系、その合成方法及びオレフィン重合のためのその使用
JP2001011089A (ja) 遷移金属化合物、触媒組成物、その製造方法及びオレフィン重合用としての使用
JP4202397B2 (ja) α−オレフィン重合用触媒
US20050065018A1 (en) Preparation and use of heterogeneous catalyst components for olefins polymerization
US7569713B2 (en) Hydrogenated catalyst
JP3393985B2 (ja) オレフイン重合用不均一触媒成分その製造方法及び使用
JP3176092B2 (ja) 新規遷移金属化合物及びそれを用いたポリオレフィンの製造方法