HU223575B1 - Biológiailag lebontható poliészterek, eljárás az előállításukra és alkalmazásuk - Google Patents
Biológiailag lebontható poliészterek, eljárás az előállításukra és alkalmazásuk Download PDFInfo
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- HU223575B1 HU223575B1 HU9903890A HUP9903890A HU223575B1 HU 223575 B1 HU223575 B1 HU 223575B1 HU 9903890 A HU9903890 A HU 9903890A HU P9903890 A HUP9903890 A HU P9903890A HU 223575 B1 HU223575 B1 HU 223575B1
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- mixture
- polyester
- mol
- isocyanurate
- weight
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Classifications
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/20—Polyesters having been prepared in the presence of compounds having one reactive group or more than two reactive groups
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
- C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2170/00—Compositions for adhesives
- C08G2170/20—Compositions for hot melt adhesives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2230/00—Compositions for preparing biodegradable polymers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyesters Or Polycarbonates (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Biological Depolymerization Polymers (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Polyurethanes Or Polyureas (AREA)
- Paints Or Removers (AREA)
- Artificial Filaments (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19638488A DE19638488A1 (de) | 1996-09-20 | 1996-09-20 | Biologisch abbaubare Polyester |
| PCT/EP1997/004908 WO1998012242A1 (de) | 1996-09-20 | 1997-09-19 | Biologisch abbaubare polyester |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| HUP9903890A2 HUP9903890A2 (hu) | 2000-03-28 |
| HUP9903890A3 HUP9903890A3 (en) | 2000-06-28 |
| HU223575B1 true HU223575B1 (hu) | 2004-09-28 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| HU9903890A HU223575B1 (hu) | 1996-09-20 | 1997-09-19 | Biológiailag lebontható poliészterek, eljárás az előállításukra és alkalmazásuk |
Country Status (17)
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| US (1) | US6120895A (https=) |
| EP (1) | EP0927212B1 (https=) |
| JP (1) | JP3963956B2 (https=) |
| KR (1) | KR100491653B1 (https=) |
| AT (1) | ATE194153T1 (https=) |
| AU (1) | AU4554197A (https=) |
| CA (1) | CA2266371C (https=) |
| CZ (1) | CZ294780B6 (https=) |
| DE (1) | DE19638488A1 (https=) |
| DK (1) | DK0927212T3 (https=) |
| ES (1) | ES2149012T3 (https=) |
| HU (1) | HU223575B1 (https=) |
| NO (1) | NO319412B1 (https=) |
| PL (1) | PL192638B1 (https=) |
| PT (1) | PT927212E (https=) |
| TW (1) | TW426700B (https=) |
| WO (1) | WO1998012242A1 (https=) |
Families Citing this family (126)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19817883C1 (de) * | 1998-04-08 | 1999-11-25 | Monofil Technik Gmbh | Mähfaden |
| DE19828935A1 (de) * | 1998-06-29 | 1999-12-30 | Basf Ag | Hochviskose Polyisocyanate enthaltende Zusammensetzungen |
| WO2000036014A2 (de) * | 1998-12-15 | 2000-06-22 | Wolff Walsrode Ag | Biologisch abbaubare, thermoplastische formkörper mit verbesserter hydrolysestabilität und spannungsrissbeständigkeit |
| KR20010081686A (ko) * | 2000-02-18 | 2001-08-29 | 윤여생 | 생분해성 일회용 주사기 |
| DE10010826A1 (de) | 2000-03-08 | 2001-09-13 | Basf Ag | Verfahren zur Reduktion der Wasserdampfpermeabilität von Folien oder Beschichtungen |
| AU2002217934A1 (en) * | 2000-11-30 | 2002-06-11 | Polymer Group, Inc. | High temperature polyester film extrusion |
| US6607000B2 (en) * | 2000-12-27 | 2003-08-19 | Padma Marwah | Frilly dental floss |
| DE20101127U1 (de) * | 2001-01-23 | 2001-05-31 | Riesch, Siegfried, 82467 Garmisch-Partenkirchen | Behältnis mit biegeschlaffen, folienähnlichen Behältniswänden |
| US7388058B2 (en) * | 2002-05-13 | 2008-06-17 | E.I. Du Pont De Nemours And Company | Polyester blend compositions and biodegradable films produced therefrom |
| KR100502005B1 (ko) * | 2002-09-23 | 2005-07-18 | 대한민국 | 비분산적외선 분광분석법을 이용한 시료의 생분해도측정장치 및 방법 |
| KR100481420B1 (ko) * | 2002-10-22 | 2005-04-08 | 주식회사 이래화학 | 생분해성 소재를 이용한 혈관주사용 주사바늘 |
| US7172814B2 (en) | 2003-06-03 | 2007-02-06 | Bio-Tec Biologische Naturverpackungen Gmbh & Co | Fibrous sheets coated or impregnated with biodegradable polymers or polymers blends |
| DE10336387A1 (de) * | 2003-08-06 | 2005-03-03 | Basf Ag | Biologisch abbaubare Polyestermischung |
| MXPA06002851A (es) * | 2003-09-12 | 2006-06-14 | Dow Global Technologies Inc | Proceso mejorado de calentamiento de suelo agricola con el uso de peliculas de poliuretano termoplastico aromatico. |
| WO2005044891A1 (ja) * | 2003-11-11 | 2005-05-19 | Ube Industries, Ltd. | 結晶性ポリエステルポリオール及び溶融接着剤 |
| US20050209374A1 (en) * | 2004-03-19 | 2005-09-22 | Matosky Andrew J | Anaerobically biodegradable polyesters |
| US8143368B2 (en) * | 2004-12-23 | 2012-03-27 | Massachusetts Institute Of Technology | Disposable medical supplies from hydrolytically biodegradable plastics |
| CN101098932B (zh) * | 2005-01-12 | 2011-08-17 | 巴斯福股份公司 | 可生物降解聚酯混合物 |
| DE502005004485D1 (de) * | 2005-01-12 | 2008-07-31 | Basf Se | Biologisch abbaubare polyestermischung |
| DE102005007479A1 (de) * | 2005-02-17 | 2006-08-31 | Basf Ag | Verfahren zur Compoundierung von Polycondensaten |
| DE102005053068B4 (de) * | 2005-11-04 | 2017-05-11 | Basf Se | Sebazinsäurehaltige Polyester und Polyestermischung, Verfahren zu deren Herstellung sowie ein Verzweigerbatch und die Verwendung der Polyestermischung |
| BRPI0620442A2 (pt) * | 2005-12-22 | 2012-02-22 | Basf Se | uso de um poliéster biodegradável, formulação lìquida para preparação da semente, processos para preparar formulação para tratamento de sementes, e para tratar sementes, semente, e, processo para regular o crescimento de plantas e/ou para combater vegetação indesejada e/ou para combater infestação indesejada por insetos ou ácaros em plantas e/ou para combater fungos fitopatogênicos |
| ITMI20062469A1 (it) * | 2006-12-21 | 2008-06-22 | Novamont Spa | Composizione polimerica comprendente poliolefine e copoliesteri alifatico-aromatici |
| DE502008000878D1 (de) * | 2007-02-15 | 2010-08-12 | Basf Se | Schaumlage auf basis einer biologisch abbaubaren polyestermischung |
| US8334342B2 (en) | 2008-06-18 | 2012-12-18 | Basf Se | Glyoxal and methylglyoxal as additive for polymer blends |
| WO2010012695A1 (de) | 2008-08-01 | 2010-02-04 | Basf Se | Erhöhung der hydrolysebeständigkeit von biologisch abbaubaren polyestern |
| CN102165013B (zh) | 2008-09-29 | 2013-04-24 | 巴斯夫欧洲公司 | 可生物降解的聚合物混合物 |
| AU2009295911B2 (en) † | 2008-09-29 | 2014-03-27 | Basf Se | Method for coating paper |
| WO2010034710A1 (de) * | 2008-09-29 | 2010-04-01 | Basf Se | Aliphatisch-aromatischer polyester |
| KR101731123B1 (ko) | 2008-09-29 | 2017-04-27 | 바스프 에스이 | 지방족 폴리에스테르 |
| BRPI0920167A2 (pt) * | 2008-10-14 | 2015-12-29 | Basf Se | mistura polimérica, copolímero, e, uso de copolímero |
| WO2010069804A1 (de) | 2008-12-19 | 2010-06-24 | Basf Se | Verfahren zur herstellung eines verbundbauteils durch mehrkomponentenspritzguss |
| WO2010100052A1 (de) | 2009-03-03 | 2010-09-10 | Basf Se | Verbackungsresistentes polyalkylencarbonat |
| ES2436366T3 (es) | 2009-03-20 | 2013-12-30 | Basf Se | Material biológicamente degradable de un polímero que contiene material estructural organometálico poroso |
| EP2348063B1 (en) | 2009-05-15 | 2020-04-29 | Kingfa Science & Technology Co., Ltd. | Biodegradable polyesters and preparing method thereof |
| WO2010139056A1 (en) * | 2009-06-01 | 2010-12-09 | The University Of Guelph | Lignin based materials and methods of making those |
| AU2010277618C1 (en) | 2009-07-31 | 2016-09-08 | Basf Se | Method for producing spinnable and dyeable polyester fibers |
| EP2498614B1 (en) | 2009-09-14 | 2017-11-15 | Basf Se | Dispenser comprising a polyester membrane for control of mites in bee hives |
| EP2494106A1 (de) | 2009-10-26 | 2012-09-05 | Basf Se | Verfahren zum recycling von mit biologisch abbaubaren polymeren geleimten und/oder beschichteten papierprodukten |
| MX2012005237A (es) | 2009-11-09 | 2012-06-13 | Basf Se | Proceso para la obtencion de peliculas de contraccion. |
| CA2782915A1 (en) | 2009-12-11 | 2011-06-16 | Basf Se | Rodent bait packed in a biodegradable foil |
| EP2617771B1 (de) | 2010-01-14 | 2016-04-06 | Basf Se | Verfahren zur Herstellung von expandierbaren Polymilchsäure-haltigen Granulaten |
| CN102869723A (zh) | 2010-03-24 | 2013-01-09 | 巴斯夫欧洲公司 | 制备保鲜膜的方法 |
| US20110237743A1 (en) * | 2010-03-24 | 2011-09-29 | Basf Se | Process for producing clingfilms |
| CA2792699A1 (en) | 2010-03-24 | 2011-09-29 | Basf Se | Process for film production |
| US20110237750A1 (en) * | 2010-03-24 | 2011-09-29 | Basf Se | Process for film production |
| US20120000481A1 (en) * | 2010-06-30 | 2012-01-05 | Dennis Potter | Degradable filter element for smoking article |
| EP2596044B1 (de) | 2010-07-19 | 2014-10-01 | Basf Se | Verfahren zur erhöhung des molekulargewichts von polyestern |
| KR20140000212A (ko) * | 2010-08-23 | 2014-01-02 | 바스프 에스이 | 내습성 파형 섬유보드 |
| US8999491B2 (en) | 2010-08-23 | 2015-04-07 | Basf Se | Wet-strength corrugated fiberboard |
| JP2013542292A (ja) | 2010-10-27 | 2013-11-21 | ビーエーエスエフ ソシエタス・ヨーロピア | スリットフィルムテープを製造するためのポリマー混合物の使用 |
| EP2671921B1 (en) | 2011-02-02 | 2016-10-19 | Mitsubishi Chemical Corporation | Polyester resin composition |
| CN102120870A (zh) * | 2011-02-28 | 2011-07-13 | 殷正福 | 一种可降解塑料及其生产方法 |
| WO2012126921A1 (de) | 2011-03-23 | 2012-09-27 | Basf Se | Polyester auf basis von 2-methylbernsteinsaeure |
| US8546472B2 (en) | 2011-03-23 | 2013-10-01 | Basf Se | Polyesters based on 2-methylsuccinic acid |
| CN103492280B (zh) | 2011-04-20 | 2015-09-16 | 巴斯夫欧洲公司 | 纤维素防护包装材料 |
| EP2522695A1 (de) | 2011-05-10 | 2012-11-14 | Basf Se | Biologisch abbaubare Polyesterfolie |
| US8686080B2 (en) | 2011-05-10 | 2014-04-01 | Basf Se | Biodegradable polyester film |
| KR101406909B1 (ko) * | 2011-05-13 | 2014-06-13 | 신동하 | 리그닌을 포함하는 생분해성 폴리에스테르 수지의 제조방법 |
| WO2012168324A1 (de) | 2011-06-09 | 2012-12-13 | Basf Se | Biologisch abbaubare polyestermischung |
| US8753481B2 (en) | 2011-06-10 | 2014-06-17 | Basf Se | Powder composition and use thereof for paper production |
| EP2718497A1 (de) | 2011-06-10 | 2014-04-16 | Basf Se | Pulverzusammensetzung und deren verwendung für die papierherstellung |
| US9334360B2 (en) | 2011-07-15 | 2016-05-10 | Sabic Global Technologies B.V. | Color-stabilized biodegradable aliphatic-aromatic copolyesters, methods of manufacture, and articles thereof |
| US8877862B2 (en) | 2011-07-15 | 2014-11-04 | Saudi Basic Industries Corporation | Method for color stabilization of poly(butylene-co-adipate terephthalate |
| US8933162B2 (en) | 2011-07-15 | 2015-01-13 | Saudi Basic Industries Corporation | Color-stabilized biodegradable aliphatic-aromatic copolyesters, methods of manufacture, and articles thereof |
| EP2551301A1 (de) | 2011-07-29 | 2013-01-30 | Basf Se | Biologisch abbaubare Polyesterfolie |
| EP2556953A1 (de) | 2011-08-11 | 2013-02-13 | Basf Se | Verfahren zur Herstellung eines Papier-Schaumstoffverbunds |
| US8946345B2 (en) | 2011-08-30 | 2015-02-03 | Saudi Basic Industries Corporation | Method for the preparation of (polybutylene-co-adipate terephthalate) through the in situ phosphorus containing titanium based catalyst |
| WO2013030300A1 (de) | 2011-09-02 | 2013-03-07 | Basf Se | Polypropylencarbonat-haltige schäume |
| EP2573138A1 (de) | 2011-09-21 | 2013-03-27 | Basf Se | Polyamid-Formmassen |
| EP2573142A1 (de) | 2011-09-21 | 2013-03-27 | Basf Se | Thermoplastische Formmasse mit verbesserter Kerbschlagzähigkeit |
| CN103958772A (zh) | 2011-12-01 | 2014-07-30 | 巴斯夫欧洲公司 | 使用可生物降解的聚酯纤维和/或聚碳酸亚烷基酯纤维制备含填料的纸的方法 |
| US8940135B2 (en) | 2011-12-01 | 2015-01-27 | Basf Se | Production of filled paper using biodegradable polyester fibers and/or polyalkylene carbonate fibers |
| US8901273B2 (en) | 2012-02-15 | 2014-12-02 | Saudi Basic Industries Corporation | Amorphous, high glass transition temperature copolyester compositions, methods of manufacture, and articles thereof |
| US8889820B2 (en) | 2012-02-15 | 2014-11-18 | Saudi Basic Industries Corporation | Amorphous, high glass transition temperature copolyester compositions, methods of manufacture, and articles thereof |
| US8969506B2 (en) | 2012-02-15 | 2015-03-03 | Saudi Basic Industries Corporation | Amorphous, high glass transition temperature copolyester compositions, methods of manufacture, and articles thereof |
| PT2628761E (pt) | 2012-02-17 | 2015-07-02 | Anónima Minera Catalano Aragonesa Soc | Poliestereteramida biodegradável |
| US8895660B2 (en) * | 2012-03-01 | 2014-11-25 | Saudi Basic Industries Corporation | Poly(butylene-co-adipate terephthalate), method of manufacture, and uses thereof |
| US9828461B2 (en) | 2012-03-01 | 2017-11-28 | Sabic Global Technologies B.V. | Poly(alkylene co-adipate terephthalate) prepared from recycled polyethylene terephthalate having low impurity levels |
| US9034983B2 (en) | 2012-03-01 | 2015-05-19 | Saudi Basic Industries Corporation | Poly(butylene-co-adipate terephthalate), method of manufacture and uses thereof |
| US8901243B2 (en) | 2012-03-30 | 2014-12-02 | Saudi Basic Industries Corporation | Biodegradable aliphatic-aromatic copolyesters, methods of manufacture, and articles thereof |
| WO2014001119A1 (de) | 2012-06-26 | 2014-01-03 | Basf Se | Verfahren zur herstellung von expandierbaren polymilchsäurehaltigen granulaten |
| CN104837923B (zh) | 2012-11-15 | 2018-01-02 | 巴斯夫欧洲公司 | 生物可降解的聚酯混合物 |
| US9056979B2 (en) | 2012-11-15 | 2015-06-16 | Basf Se | Biodegradable polyester mixture |
| CN103881072B (zh) * | 2012-12-22 | 2016-05-11 | 北京化工大学 | 可生物降解脂肪族—芳香族嵌段混合聚酯的制备方法 |
| EP2826817B1 (de) | 2013-07-15 | 2017-07-05 | Basf Se | Biologisch abbaubare polyestermischung |
| EP3055351B1 (de) | 2013-10-09 | 2017-09-13 | Basf Se | Verfahren zur herstellung von expandierten polyester-schaumstoffpartikeln |
| CN103642017B (zh) * | 2013-11-04 | 2016-03-30 | 金发科技股份有限公司 | 一种吹塑用聚酯弹性体及其制备方法 |
| DE102014223786A1 (de) | 2013-12-10 | 2015-06-11 | Basf Se | Polymermischung für Barrierefilm |
| ES2682683T3 (es) | 2014-04-02 | 2018-09-21 | Basf Se | Composición de poliéster |
| PT3140349T (pt) | 2014-05-09 | 2018-10-31 | Basf Se | Artigos produzidos por termoformação |
| ES2688824T3 (es) | 2014-05-09 | 2018-11-07 | Basf Se | Artículos moldeados por inyección |
| WO2016087270A1 (en) | 2014-12-04 | 2016-06-09 | Basf Se | Solid agrochemical composition for extended release of carbon dioxide |
| CN108024524B (zh) | 2015-07-13 | 2021-04-30 | 巴斯夫公司 | 具有导电诱饵基质的害虫控制和/或检测系统 |
| US11051504B2 (en) | 2015-07-13 | 2021-07-06 | Basf Corporation | Pest control and detection system with conductive bait matrix |
| PL3362516T3 (pl) | 2015-10-14 | 2020-05-18 | Basf Se | Mieszanka poliestrowa ze środkiem ogniochronnym wolnym od fluorowców |
| US20190202087A1 (en) | 2016-08-08 | 2019-07-04 | Basf Se | Method for producing expanded granular material |
| EP3523021A1 (de) | 2016-10-07 | 2019-08-14 | Basf Se | Sphärische mikropartikel |
| WO2018206352A1 (de) | 2017-05-10 | 2018-11-15 | Basf Se | Biologisch abbaubare folie für lebensmittelverpackung |
| WO2018219708A1 (de) | 2017-05-31 | 2018-12-06 | Basf Se | ALIPHATISCH-AROMATISCHER POLYESTER MIT ERHÖHTEM WEIßGRAD-INDEX |
| ES2895041T3 (es) | 2017-06-19 | 2022-02-17 | Basf Se | Película de tres capas biodegradable |
| MX2020000229A (es) | 2017-07-07 | 2020-08-17 | Basf Corp | Sistema de monitoreo de plagas con electrodos conductores. |
| WO2019011643A1 (de) | 2017-07-10 | 2019-01-17 | Basf Se | Biologisch abbaubare folie für lebensmittelverpackung |
| EP3668926B8 (de) | 2017-08-15 | 2022-03-30 | Basf Se | Spritzgussartikel enthaltend oberflächenmodifizierte silikate |
| WO2019121322A1 (de) | 2017-12-19 | 2019-06-27 | Basf Se | Geschäumte schmelzfasern |
| BR112020019798A2 (pt) | 2018-04-06 | 2021-01-05 | Basf Se | Composição de micropartículas esféricas, métodos para preparar uma composição de micropartículas esféricas e uma preparação de produto químico de aroma, micropartículas esféricas, usos das micropartículas esféricas e da preparação de produto químico de aroma, e, preparação de produto químico de aroma. |
| CN113164897A (zh) | 2018-10-30 | 2021-07-23 | 巴斯夫欧洲公司 | 制备被活性材料填充的微粒的方法 |
| US12398265B2 (en) | 2018-12-06 | 2025-08-26 | Basf Se | Method for preparing a (co)polyester |
| CN113227341A (zh) | 2018-12-19 | 2021-08-06 | 巴斯夫欧洲公司 | 包含聚乙二醇接枝共聚物和芳香化学品的成型体 |
| KR20210121200A (ko) | 2019-01-30 | 2021-10-07 | 바스프 에스이 | 전분 블렌드의 제조 방법 |
| EP3696232B1 (de) | 2019-02-15 | 2021-08-25 | Basf Se | Spritzgussartikel |
| KR102942424B1 (ko) | 2019-04-11 | 2026-03-23 | 바스프 에스이 | 폴리부틸렌 테레프탈레이트 열성형 방법 |
| WO2021009040A1 (en) | 2019-07-12 | 2021-01-21 | Basf Se | Process for producing microparticles laden with a volatile organic active |
| US20230002582A1 (en) | 2019-09-19 | 2023-01-05 | Basf Se | Enhancement of long-term properties of closed-cell rigid polyurethane foams |
| AT522596B1 (de) | 2019-11-04 | 2020-12-15 | Lenzing Plastics Gmbh & Co Kg | Zahnseide |
| JP2023523529A (ja) | 2020-03-23 | 2023-06-06 | ビーエーエスエフ ソシエタス・ヨーロピア | 飲料を製造するための成分用容器 |
| BR112022020157A2 (pt) | 2020-04-09 | 2022-11-22 | Basf Coatings Gmbh | Método para preparar um molde contendo uma camada de polissiloxano, molde contendo uma camada de polissiloxano, e, uso do molde |
| DK4146727T3 (da) | 2020-05-06 | 2024-09-30 | Basf Se | Flammehæmmende polyesterblanding |
| US20230390167A1 (en) | 2020-10-30 | 2023-12-07 | Basf Se | Process for producing microparticles laden with an aroma chemical |
| CN113512185A (zh) * | 2021-04-21 | 2021-10-19 | 江南大学 | 一种热塑性生物可降解手套材料及其制备方法 |
| TW202338038A (zh) | 2021-09-28 | 2023-10-01 | 瑞士商雀巢製品股份有限公司 | 可生物降解層壓膜及由其製成之容器 |
| CN118043197A (zh) | 2021-09-28 | 2024-05-14 | 巴斯夫欧洲公司 | 生物可降解的层压膜 |
| EP4519342A4 (en) * | 2022-05-04 | 2026-04-08 | Intrinsic Advanced Mat Llc | CONTINUOUS PRODUCTION OF BIODEGRADABLE POLYESTERS |
| WO2024074561A1 (en) | 2022-10-05 | 2024-04-11 | Basf Se | Biodegradable polymer blend and use thereof |
| CN119998384A (zh) | 2022-10-06 | 2025-05-13 | 巴斯夫欧洲公司 | 热塑性聚合物共混物及其用途 |
| CN115746275B (zh) * | 2022-12-16 | 2024-05-17 | 青岛科技大学 | 一种聚丁二酸/对苯二甲酸丁二醇酯共聚物及其制备方法 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2999851A (en) * | 1957-12-16 | 1961-09-12 | Gen Tire & Rubber Co | Isocyanate extension of very high molecular weight polyesters |
| GB1239751A (https=) * | 1967-05-23 | 1971-07-21 | ||
| US3804810A (en) * | 1970-12-30 | 1974-04-16 | Du Pont | Cross-linked polyurethanes based on aromatic/aliphatic copolyesters |
| KR900701882A (ko) * | 1988-05-20 | 1990-12-04 | 헬렌 에이. 파블릭크 | 열경화성 연신성 코팅 조성물 |
| EP0559785B1 (en) * | 1990-11-30 | 1997-03-12 | Eastman Chemical Company | Blends of aliphatic-aromatic copolyesters with cellulose ester polymers |
| JP3783732B2 (ja) * | 1992-05-29 | 2006-06-07 | 昭和高分子株式会社 | 生分解性高分子量脂肪族ポリエステルの製造方法 |
| DE4440836A1 (de) * | 1994-11-15 | 1996-05-23 | Basf Ag | Biologisch abbaubare Polymere, Verfahren zu deren Herstellung sowie deren Verwendung zur Herstellung bioabbaubarer Formkörper |
| DE4440858A1 (de) * | 1994-11-15 | 1996-05-23 | Basf Ag | Biologisch abbaubare Polymere, Verfahren zu deren Herstellung sowie deren Verwendung zur Herstellung bioabbaubarer Formkörper |
| US5484861A (en) * | 1995-01-20 | 1996-01-16 | Cheil Synthetics Inc. | Biodegradable copolyester and method for preparing the same |
-
1996
- 1996-09-20 DE DE19638488A patent/DE19638488A1/de not_active Withdrawn
-
1997
- 1997-09-19 JP JP51424998A patent/JP3963956B2/ja not_active Expired - Fee Related
- 1997-09-19 CA CA002266371A patent/CA2266371C/en not_active Expired - Fee Related
- 1997-09-19 ES ES97943850T patent/ES2149012T3/es not_active Expired - Lifetime
- 1997-09-19 WO PCT/EP1997/004908 patent/WO1998012242A1/de not_active Ceased
- 1997-09-19 US US09/254,922 patent/US6120895A/en not_active Expired - Lifetime
- 1997-09-19 AT AT97943850T patent/ATE194153T1/de not_active IP Right Cessation
- 1997-09-19 HU HU9903890A patent/HU223575B1/hu not_active IP Right Cessation
- 1997-09-19 PT PT97943850T patent/PT927212E/pt unknown
- 1997-09-19 DK DK97943850T patent/DK0927212T3/da active
- 1997-09-19 EP EP97943850A patent/EP0927212B1/de not_active Expired - Lifetime
- 1997-09-19 CZ CZ1999957A patent/CZ294780B6/cs not_active IP Right Cessation
- 1997-09-19 AU AU45541/97A patent/AU4554197A/en not_active Abandoned
- 1997-09-19 KR KR10-1999-7002353A patent/KR100491653B1/ko not_active Expired - Fee Related
- 1997-09-19 PL PL332303A patent/PL192638B1/pl not_active IP Right Cessation
- 1997-09-20 TW TW086113694A patent/TW426700B/zh not_active IP Right Cessation
-
1999
- 1999-03-19 NO NO19991354A patent/NO319412B1/no not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| ATE194153T1 (de) | 2000-07-15 |
| EP0927212B1 (de) | 2000-06-28 |
| US6120895A (en) | 2000-09-19 |
| PT927212E (pt) | 2000-12-29 |
| NO991354D0 (no) | 1999-03-19 |
| JP3963956B2 (ja) | 2007-08-22 |
| CZ95799A3 (cs) | 2000-01-12 |
| NO991354L (no) | 1999-05-20 |
| ES2149012T3 (es) | 2000-10-16 |
| DE19638488A1 (de) | 1998-03-26 |
| TW426700B (en) | 2001-03-21 |
| KR100491653B1 (ko) | 2005-05-27 |
| AU4554197A (en) | 1998-04-14 |
| CA2266371A1 (en) | 1998-03-26 |
| HUP9903890A3 (en) | 2000-06-28 |
| PL332303A1 (en) | 1999-08-30 |
| PL192638B1 (pl) | 2006-11-30 |
| JP2001500907A (ja) | 2001-01-23 |
| WO1998012242A1 (de) | 1998-03-26 |
| CA2266371C (en) | 2007-12-04 |
| NO319412B1 (no) | 2005-08-08 |
| HUP9903890A2 (hu) | 2000-03-28 |
| CZ294780B6 (cs) | 2005-03-16 |
| KR20010029529A (ko) | 2001-04-06 |
| EP0927212A1 (de) | 1999-07-07 |
| DK0927212T3 (da) | 2000-08-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| HFG4 | Patent granted, date of granting |
Effective date: 20040728 |
|
| MM4A | Lapse of definitive patent protection due to non-payment of fees |