PL192638B1 - Sposób wytwarzania poliestrów rozkładalnych biologicznie - Google Patents
Sposób wytwarzania poliestrów rozkładalnych biologicznieInfo
- Publication number
- PL192638B1 PL192638B1 PL332303A PL33230397A PL192638B1 PL 192638 B1 PL192638 B1 PL 192638B1 PL 332303 A PL332303 A PL 332303A PL 33230397 A PL33230397 A PL 33230397A PL 192638 B1 PL192638 B1 PL 192638B1
- Authority
- PL
- Poland
- Prior art keywords
- polyester
- mixture
- isocyanurate
- weight
- polyesters
- Prior art date
Links
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 20
- 229920000229 biodegradable polyester Polymers 0.000 title claims description 38
- 239000004622 biodegradable polyester Substances 0.000 title claims description 38
- 238000000034 method Methods 0.000 title claims description 32
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- 239000000203 mixture Substances 0.000 claims abstract description 121
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 claims abstract description 34
- 150000001875 compounds Chemical class 0.000 claims abstract description 28
- 238000006243 chemical reaction Methods 0.000 claims abstract description 24
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- 125000000524 functional group Chemical group 0.000 claims abstract description 10
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- 125000003118 aryl group Chemical group 0.000 claims abstract description 9
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- 238000002156 mixing Methods 0.000 description 6
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- 238000002360 preparation method Methods 0.000 description 6
- JUJWROOIHBZHMG-UHFFFAOYSA-N pyridine Substances C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 6
- 239000003381 stabilizer Substances 0.000 description 6
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Natural products CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 5
- WFDIJRYMOXRFFG-UHFFFAOYSA-N acetic acid anhydride Natural products CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 5
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- 125000005442 diisocyanate group Chemical group 0.000 description 5
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- 239000000463 material Substances 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- 229940008841 1,6-hexamethylene diisocyanate Drugs 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- YBVKMVCZNISULF-UHFFFAOYSA-N Polyester A3 Natural products CC1CC(OC(=O)c2ccccc2)C(OC(=O)C)C3(COC(=O)C)C(OC(=O)C)C(OC(=O)c4ccccc4)C5C(O)C13OC5(C)C YBVKMVCZNISULF-UHFFFAOYSA-N 0.000 description 4
- 239000002202 Polyethylene glycol Substances 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 4
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- 238000004458 analytical method Methods 0.000 description 4
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- 238000000576 coating method Methods 0.000 description 4
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- 150000002009 diols Chemical class 0.000 description 4
- 150000002118 epoxides Chemical class 0.000 description 4
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 4
- 229920001223 polyethylene glycol Polymers 0.000 description 4
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 4
- 239000011541 reaction mixture Substances 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- 239000010936 titanium Substances 0.000 description 4
- 229910052719 titanium Inorganic materials 0.000 description 4
- 238000005809 transesterification reaction Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000011701 zinc Chemical class 0.000 description 4
- 229910052725 zinc Inorganic materials 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- SJRJJKPEHAURKC-UHFFFAOYSA-N N-Methylmorpholine Chemical compound CN1CCOCC1 SJRJJKPEHAURKC-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- 239000004721 Polyphenylene oxide Substances 0.000 description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical class [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 3
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- 239000011248 coating agent Substances 0.000 description 3
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- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
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- 150000002513 isocyanates Chemical class 0.000 description 3
- 239000011133 lead Chemical class 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
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- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 3
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- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 3
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- QPFMBZIOSGYJDE-UHFFFAOYSA-N 1,1,2,2-tetrachloroethane Chemical compound ClC(Cl)C(Cl)Cl QPFMBZIOSGYJDE-UHFFFAOYSA-N 0.000 description 2
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- RXYPXQSKLGGKOL-UHFFFAOYSA-N 1,4-dimethylpiperazine Chemical compound CN1CCN(C)CC1 RXYPXQSKLGGKOL-UHFFFAOYSA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
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Classifications
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/20—Polyesters having been prepared in the presence of compounds having one reactive group or more than two reactive groups
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
- C08G18/4208—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups
- C08G18/4211—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols
- C08G18/4216—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols from mixtures or combinations of aromatic dicarboxylic acids and aliphatic dicarboxylic acids and dialcohols
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
- C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
- C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2170/00—Compositions for adhesives
- C08G2170/20—Compositions for hot melt adhesives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2230/00—Compositions for preparing biodegradable polymers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Polyesters Or Polycarbonates (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Biological Depolymerization Polymers (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Polyurethanes Or Polyureas (AREA)
- Paints Or Removers (AREA)
- Artificial Filaments (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19638488A DE19638488A1 (de) | 1996-09-20 | 1996-09-20 | Biologisch abbaubare Polyester |
| PCT/EP1997/004908 WO1998012242A1 (de) | 1996-09-20 | 1997-09-19 | Biologisch abbaubare polyester |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| PL332303A1 PL332303A1 (en) | 1999-08-30 |
| PL192638B1 true PL192638B1 (pl) | 2006-11-30 |
Family
ID=7806283
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL332303A PL192638B1 (pl) | 1996-09-20 | 1997-09-19 | Sposób wytwarzania poliestrów rozkładalnych biologicznie |
Country Status (17)
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| US (1) | US6120895A (https=) |
| EP (1) | EP0927212B1 (https=) |
| JP (1) | JP3963956B2 (https=) |
| KR (1) | KR100491653B1 (https=) |
| AT (1) | ATE194153T1 (https=) |
| AU (1) | AU4554197A (https=) |
| CA (1) | CA2266371C (https=) |
| CZ (1) | CZ294780B6 (https=) |
| DE (1) | DE19638488A1 (https=) |
| DK (1) | DK0927212T3 (https=) |
| ES (1) | ES2149012T3 (https=) |
| HU (1) | HU223575B1 (https=) |
| NO (1) | NO319412B1 (https=) |
| PL (1) | PL192638B1 (https=) |
| PT (1) | PT927212E (https=) |
| TW (1) | TW426700B (https=) |
| WO (1) | WO1998012242A1 (https=) |
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| US20230114944A1 (en) | 2020-03-23 | 2023-04-13 | Basf Se | Container for ingredients for making beverages |
| EP4132802A1 (en) | 2020-04-09 | 2023-02-15 | BASF Coatings GmbH | Molding with structured polysiloxane layer and method for its preparation |
| ES2991323T3 (es) | 2020-05-06 | 2024-12-03 | Basf Se | Combinación de poliéster retardante de flama |
| WO2022090460A1 (en) | 2020-10-30 | 2022-05-05 | Basf Se | Process for producing microparticles laden with an aroma chemical |
| CN113512185A (zh) * | 2021-04-21 | 2021-10-19 | 江南大学 | 一种热塑性生物可降解手套材料及其制备方法 |
| ES3061518T3 (en) | 2021-09-28 | 2026-04-06 | Basf Se | Biodegradable lamination film |
| TW202338038A (zh) | 2021-09-28 | 2023-10-01 | 瑞士商雀巢製品股份有限公司 | 可生物降解層壓膜及由其製成之容器 |
| JP2025514503A (ja) * | 2022-05-04 | 2025-05-02 | イントリンシック・アドバンスト・マテリアルズ，エルエルシー | 生分解性ポリエステルの連続生産 |
| JP2025535731A (ja) | 2022-10-05 | 2025-10-28 | ビーエーエスエフ ソシエタス・ヨーロピア | 生分解性ポリマーブレンドおよびその使用 |
| EP4598995A1 (en) | 2022-10-06 | 2025-08-13 | Basf Se | Thermoplastic polymer blend and use thereof |
| CN115746275B (zh) * | 2022-12-16 | 2024-05-17 | 青岛科技大学 | 一种聚丁二酸/对苯二甲酸丁二醇酯共聚物及其制备方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2999851A (en) * | 1957-12-16 | 1961-09-12 | Gen Tire & Rubber Co | Isocyanate extension of very high molecular weight polyesters |
| GB1239751A (https=) * | 1967-05-23 | 1971-07-21 | ||
| US3804810A (en) * | 1970-12-30 | 1974-04-16 | Du Pont | Cross-linked polyurethanes based on aromatic/aliphatic copolyesters |
| WO1989011497A1 (en) * | 1988-05-20 | 1989-11-30 | Ppg Industries, Inc. | Thermoset drawable coating compositions |
| ATE150058T1 (de) * | 1990-11-30 | 1997-03-15 | Eastman Chem Co | Mischungen von aliphatisch-aromatischen copolyestern mit celluloseester-polymeren |
| JP3783732B2 (ja) * | 1992-05-29 | 2006-06-07 | 昭和高分子株式会社 | 生分解性高分子量脂肪族ポリエステルの製造方法 |
| DE4440858A1 (de) * | 1994-11-15 | 1996-05-23 | Basf Ag | Biologisch abbaubare Polymere, Verfahren zu deren Herstellung sowie deren Verwendung zur Herstellung bioabbaubarer Formkörper |
| DE4440836A1 (de) * | 1994-11-15 | 1996-05-23 | Basf Ag | Biologisch abbaubare Polymere, Verfahren zu deren Herstellung sowie deren Verwendung zur Herstellung bioabbaubarer Formkörper |
| US5484861A (en) * | 1995-01-20 | 1996-01-16 | Cheil Synthetics Inc. | Biodegradable copolyester and method for preparing the same |
-
1996
- 1996-09-20 DE DE19638488A patent/DE19638488A1/de not_active Withdrawn
-
1997
- 1997-09-19 AU AU45541/97A patent/AU4554197A/en not_active Abandoned
- 1997-09-19 CZ CZ1999957A patent/CZ294780B6/cs not_active IP Right Cessation
- 1997-09-19 AT AT97943850T patent/ATE194153T1/de not_active IP Right Cessation
- 1997-09-19 PT PT97943850T patent/PT927212E/pt unknown
- 1997-09-19 WO PCT/EP1997/004908 patent/WO1998012242A1/de not_active Ceased
- 1997-09-19 HU HU9903890A patent/HU223575B1/hu not_active IP Right Cessation
- 1997-09-19 CA CA002266371A patent/CA2266371C/en not_active Expired - Fee Related
- 1997-09-19 JP JP51424998A patent/JP3963956B2/ja not_active Expired - Fee Related
- 1997-09-19 ES ES97943850T patent/ES2149012T3/es not_active Expired - Lifetime
- 1997-09-19 US US09/254,922 patent/US6120895A/en not_active Expired - Lifetime
- 1997-09-19 PL PL332303A patent/PL192638B1/pl not_active IP Right Cessation
- 1997-09-19 KR KR10-1999-7002353A patent/KR100491653B1/ko not_active Expired - Fee Related
- 1997-09-19 EP EP97943850A patent/EP0927212B1/de not_active Expired - Lifetime
- 1997-09-19 DK DK97943850T patent/DK0927212T3/da active
- 1997-09-20 TW TW086113694A patent/TW426700B/zh not_active IP Right Cessation
-
1999
- 1999-03-19 NO NO19991354A patent/NO319412B1/no not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| CZ294780B6 (cs) | 2005-03-16 |
| HUP9903890A3 (en) | 2000-06-28 |
| WO1998012242A1 (de) | 1998-03-26 |
| NO991354L (no) | 1999-05-20 |
| ATE194153T1 (de) | 2000-07-15 |
| PL332303A1 (en) | 1999-08-30 |
| TW426700B (en) | 2001-03-21 |
| NO319412B1 (no) | 2005-08-08 |
| ES2149012T3 (es) | 2000-10-16 |
| KR100491653B1 (ko) | 2005-05-27 |
| CZ95799A3 (cs) | 2000-01-12 |
| DK0927212T3 (da) | 2000-08-28 |
| US6120895A (en) | 2000-09-19 |
| JP2001500907A (ja) | 2001-01-23 |
| HU223575B1 (hu) | 2004-09-28 |
| CA2266371C (en) | 2007-12-04 |
| PT927212E (pt) | 2000-12-29 |
| CA2266371A1 (en) | 1998-03-26 |
| AU4554197A (en) | 1998-04-14 |
| EP0927212B1 (de) | 2000-06-28 |
| DE19638488A1 (de) | 1998-03-26 |
| HUP9903890A2 (hu) | 2000-03-28 |
| JP3963956B2 (ja) | 2007-08-22 |
| KR20010029529A (ko) | 2001-04-06 |
| EP0927212A1 (de) | 1999-07-07 |
| NO991354D0 (no) | 1999-03-19 |
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| LAPS | Decisions on the lapse of the protection rights |
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