DE19638488A1 - Biologisch abbaubare Polyester - Google Patents

Biologisch abbaubare Polyester

Info

Publication number
DE19638488A1
DE19638488A1 DE19638488A DE19638488A DE19638488A1 DE 19638488 A1 DE19638488 A1 DE 19638488A1 DE 19638488 A DE19638488 A DE 19638488A DE 19638488 A DE19638488 A DE 19638488A DE 19638488 A1 DE19638488 A1 DE 19638488A1
Authority
DE
Germany
Prior art keywords
mixture
polyester
mol
aromatic
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
DE19638488A
Other languages
German (de)
English (en)
Inventor
Christoph Kowitz
Peter Bauer
Dieter Bernhard Beimborn
Bernd Bruchmann
Uwe Faller
Martin Laun
Udo Pagga
Gunter Pipper
Volker Warzelhan
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority to DE19638488A priority Critical patent/DE19638488A1/de
Priority to AT97943850T priority patent/ATE194153T1/de
Priority to AU45541/97A priority patent/AU4554197A/en
Priority to PL332303A priority patent/PL192638B1/pl
Priority to CZ1999957A priority patent/CZ294780B6/cs
Priority to HU9903890A priority patent/HU223575B1/hu
Priority to DK97943850T priority patent/DK0927212T3/da
Priority to EP97943850A priority patent/EP0927212B1/de
Priority to PCT/EP1997/004908 priority patent/WO1998012242A1/de
Priority to PT97943850T priority patent/PT927212E/pt
Priority to ES97943850T priority patent/ES2149012T3/es
Priority to US09/254,922 priority patent/US6120895A/en
Priority to CA002266371A priority patent/CA2266371C/en
Priority to KR10-1999-7002353A priority patent/KR100491653B1/ko
Priority to JP51424998A priority patent/JP3963956B2/ja
Priority to TW086113694A priority patent/TW426700B/zh
Publication of DE19638488A1 publication Critical patent/DE19638488A1/de
Priority to NO19991354A priority patent/NO319412B1/no
Withdrawn legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/42Polycondensates having carboxylic or carbonic ester groups in the main chain
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16Dicarboxylic acids and dihydroxy compounds
    • C08G63/20Polyesters having been prepared in the presence of compounds having one reactive group or more than two reactive groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/42Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4205Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
    • C08G18/4208Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups
    • C08G18/4211Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols
    • C08G18/4216Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols from mixtures or combinations of aromatic dicarboxylic acids and aliphatic dicarboxylic acids and dialcohols
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/74Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/77Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78Nitrogen
    • C08G18/79Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C08G18/791Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2170/00Compositions for adhesives
    • C08G2170/20Compositions for hot melt adhesives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2230/00Compositions for preparing biodegradable polymers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913Rod, strand, filament or fiber

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Biological Depolymerization Polymers (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Paints Or Removers (AREA)
  • Artificial Filaments (AREA)
DE19638488A 1996-09-20 1996-09-20 Biologisch abbaubare Polyester Withdrawn DE19638488A1 (de)

Priority Applications (17)

Application Number Priority Date Filing Date Title
DE19638488A DE19638488A1 (de) 1996-09-20 1996-09-20 Biologisch abbaubare Polyester
PT97943850T PT927212E (pt) 1996-09-20 1997-09-19 Poliesteres biodegradaveis
ES97943850T ES2149012T3 (es) 1996-09-20 1997-09-19 Poliesteres biodegradables.
PL332303A PL192638B1 (pl) 1996-09-20 1997-09-19 Sposób wytwarzania poliestrów rozkładalnych biologicznie
CZ1999957A CZ294780B6 (cs) 1996-09-20 1997-09-19 Biodegradovatelné polyestery
HU9903890A HU223575B1 (hu) 1996-09-20 1997-09-19 Biológiailag lebontható poliészterek, eljárás az előállításukra és alkalmazásuk
DK97943850T DK0927212T3 (da) 1996-09-20 1997-09-19 Biologisk nedbrydelige polyestere
EP97943850A EP0927212B1 (de) 1996-09-20 1997-09-19 Biologisch abbaubare polyester
PCT/EP1997/004908 WO1998012242A1 (de) 1996-09-20 1997-09-19 Biologisch abbaubare polyester
AT97943850T ATE194153T1 (de) 1996-09-20 1997-09-19 Biologisch abbaubare polyester
AU45541/97A AU4554197A (en) 1996-09-20 1997-09-19 Biodegradable polyesters
US09/254,922 US6120895A (en) 1996-09-20 1997-09-19 Biodegradable polyesters
CA002266371A CA2266371C (en) 1996-09-20 1997-09-19 Biodegradable polyesters
KR10-1999-7002353A KR100491653B1 (ko) 1996-09-20 1997-09-19 생분해성 폴리에스테르
JP51424998A JP3963956B2 (ja) 1996-09-20 1997-09-19 生分解性ポリエステル
TW086113694A TW426700B (en) 1996-09-20 1997-09-20 Biodegradable polyesters
NO19991354A NO319412B1 (no) 1996-09-20 1999-03-19 Biodegraderbare polyestere

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19638488A DE19638488A1 (de) 1996-09-20 1996-09-20 Biologisch abbaubare Polyester

Publications (1)

Publication Number Publication Date
DE19638488A1 true DE19638488A1 (de) 1998-03-26

Family

ID=7806283

Family Applications (1)

Application Number Title Priority Date Filing Date
DE19638488A Withdrawn DE19638488A1 (de) 1996-09-20 1996-09-20 Biologisch abbaubare Polyester

Country Status (17)

Country Link
US (1) US6120895A (https=)
EP (1) EP0927212B1 (https=)
JP (1) JP3963956B2 (https=)
KR (1) KR100491653B1 (https=)
AT (1) ATE194153T1 (https=)
AU (1) AU4554197A (https=)
CA (1) CA2266371C (https=)
CZ (1) CZ294780B6 (https=)
DE (1) DE19638488A1 (https=)
DK (1) DK0927212T3 (https=)
ES (1) ES2149012T3 (https=)
HU (1) HU223575B1 (https=)
NO (1) NO319412B1 (https=)
PL (1) PL192638B1 (https=)
PT (1) PT927212E (https=)
TW (1) TW426700B (https=)
WO (1) WO1998012242A1 (https=)

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19817883C1 (de) * 1998-04-08 1999-11-25 Monofil Technik Gmbh Mähfaden
WO2001060437A1 (en) * 2000-02-18 2001-08-23 Boo Yoon Tech, Inc. Biodegradable disposable syringe
WO2001066630A1 (de) * 2000-03-08 2001-09-13 Basf Aktiengesellschaft Verfahren zur reduktion der wasserdampfpermeabilität von folien oder beschichtungen
WO2000036014A3 (de) * 1998-12-15 2001-11-29 Wolff Walsrode Ag Biologisch abbaubare, thermoplastische formkörper mit verbesserter hydrolysestabilität und spannungsrissbeständigkeit
WO2012025470A1 (de) * 2010-08-23 2012-03-01 Basf Se Nassfeste wellpappe
WO2013130173A1 (en) * 2012-03-01 2013-09-06 Saudi Basic Industries Corporation Poly(butylene-co-adipate terephthalate), method of manufacture, and uses thereof
WO2013130174A1 (en) * 2012-03-01 2013-09-06 Saudi Basic Industries Corporation Poly(butylene-co-adipate terephthalate), method of manufacture and uses thereof
US8889820B2 (en) 2012-02-15 2014-11-18 Saudi Basic Industries Corporation Amorphous, high glass transition temperature copolyester compositions, methods of manufacture, and articles thereof
US8901243B2 (en) 2012-03-30 2014-12-02 Saudi Basic Industries Corporation Biodegradable aliphatic-aromatic copolyesters, methods of manufacture, and articles thereof
US8901273B2 (en) 2012-02-15 2014-12-02 Saudi Basic Industries Corporation Amorphous, high glass transition temperature copolyester compositions, methods of manufacture, and articles thereof
US8933162B2 (en) 2011-07-15 2015-01-13 Saudi Basic Industries Corporation Color-stabilized biodegradable aliphatic-aromatic copolyesters, methods of manufacture, and articles thereof
US8946345B2 (en) 2011-08-30 2015-02-03 Saudi Basic Industries Corporation Method for the preparation of (polybutylene-co-adipate terephthalate) through the in situ phosphorus containing titanium based catalyst
US8969506B2 (en) 2012-02-15 2015-03-03 Saudi Basic Industries Corporation Amorphous, high glass transition temperature copolyester compositions, methods of manufacture, and articles thereof
US9334360B2 (en) 2011-07-15 2016-05-10 Sabic Global Technologies B.V. Color-stabilized biodegradable aliphatic-aromatic copolyesters, methods of manufacture, and articles thereof
DE102005053068B4 (de) * 2005-11-04 2017-05-11 Basf Se Sebazinsäurehaltige Polyester und Polyestermischung, Verfahren zu deren Herstellung sowie ein Verzweigerbatch und die Verwendung der Polyestermischung
US9828461B2 (en) 2012-03-01 2017-11-28 Sabic Global Technologies B.V. Poly(alkylene co-adipate terephthalate) prepared from recycled polyethylene terephthalate having low impurity levels
WO2021087536A1 (de) 2019-11-04 2021-05-14 Lenzing Plastics Gmbh & Co Kg Zahnseide

Families Citing this family (109)

* Cited by examiner, † Cited by third party
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DE19828935A1 (de) * 1998-06-29 1999-12-30 Basf Ag Hochviskose Polyisocyanate enthaltende Zusammensetzungen
AU2002217934A1 (en) * 2000-11-30 2002-06-11 Polymer Group, Inc. High temperature polyester film extrusion
US6607000B2 (en) * 2000-12-27 2003-08-19 Padma Marwah Frilly dental floss
DE20101127U1 (de) * 2001-01-23 2001-05-31 Riesch, Siegfried, 82467 Garmisch-Partenkirchen Behältnis mit biegeschlaffen, folienähnlichen Behältniswänden
US7388058B2 (en) * 2002-05-13 2008-06-17 E.I. Du Pont De Nemours And Company Polyester blend compositions and biodegradable films produced therefrom
KR100502005B1 (ko) * 2002-09-23 2005-07-18 대한민국 비분산적외선 분광분석법을 이용한 시료의 생분해도측정장치 및 방법
KR100481420B1 (ko) * 2002-10-22 2005-04-08 주식회사 이래화학 생분해성 소재를 이용한 혈관주사용 주사바늘
US7172814B2 (en) 2003-06-03 2007-02-06 Bio-Tec Biologische Naturverpackungen Gmbh & Co Fibrous sheets coated or impregnated with biodegradable polymers or polymers blends
DE10336387A1 (de) * 2003-08-06 2005-03-03 Basf Ag Biologisch abbaubare Polyestermischung
MXPA06002851A (es) * 2003-09-12 2006-06-14 Dow Global Technologies Inc Proceso mejorado de calentamiento de suelo agricola con el uso de peliculas de poliuretano termoplastico aromatico.
WO2005044891A1 (ja) * 2003-11-11 2005-05-19 Ube Industries, Ltd. 結晶性ポリエステルポリオール及び溶融接着剤
US20050209374A1 (en) * 2004-03-19 2005-09-22 Matosky Andrew J Anaerobically biodegradable polyesters
US8143368B2 (en) * 2004-12-23 2012-03-27 Massachusetts Institute Of Technology Disposable medical supplies from hydrolytically biodegradable plastics
CN101098932B (zh) * 2005-01-12 2011-08-17 巴斯福股份公司 可生物降解聚酯混合物
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ITMI20062469A1 (it) * 2006-12-21 2008-06-22 Novamont Spa Composizione polimerica comprendente poliolefine e copoliesteri alifatico-aromatici
DE502008000878D1 (de) * 2007-02-15 2010-08-12 Basf Se Schaumlage auf basis einer biologisch abbaubaren polyestermischung
US8334342B2 (en) 2008-06-18 2012-12-18 Basf Se Glyoxal and methylglyoxal as additive for polymer blends
WO2010012695A1 (de) 2008-08-01 2010-02-04 Basf Se Erhöhung der hydrolysebeständigkeit von biologisch abbaubaren polyestern
CN102165013B (zh) 2008-09-29 2013-04-24 巴斯夫欧洲公司 可生物降解的聚合物混合物
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WO2010034710A1 (de) * 2008-09-29 2010-04-01 Basf Se Aliphatisch-aromatischer polyester
KR101731123B1 (ko) 2008-09-29 2017-04-27 바스프 에스이 지방족 폴리에스테르
BRPI0920167A2 (pt) * 2008-10-14 2015-12-29 Basf Se mistura polimérica, copolímero, e, uso de copolímero
WO2010069804A1 (de) 2008-12-19 2010-06-24 Basf Se Verfahren zur herstellung eines verbundbauteils durch mehrkomponentenspritzguss
WO2010100052A1 (de) 2009-03-03 2010-09-10 Basf Se Verbackungsresistentes polyalkylencarbonat
ES2436366T3 (es) 2009-03-20 2013-12-30 Basf Se Material biológicamente degradable de un polímero que contiene material estructural organometálico poroso
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EP2498614B1 (en) 2009-09-14 2017-11-15 Basf Se Dispenser comprising a polyester membrane for control of mites in bee hives
EP2494106A1 (de) 2009-10-26 2012-09-05 Basf Se Verfahren zum recycling von mit biologisch abbaubaren polymeren geleimten und/oder beschichteten papierprodukten
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CA2792699A1 (en) 2010-03-24 2011-09-29 Basf Se Process for film production
US20110237750A1 (en) * 2010-03-24 2011-09-29 Basf Se Process for film production
US20120000481A1 (en) * 2010-06-30 2012-01-05 Dennis Potter Degradable filter element for smoking article
EP2596044B1 (de) 2010-07-19 2014-10-01 Basf Se Verfahren zur erhöhung des molekulargewichts von polyestern
US8999491B2 (en) 2010-08-23 2015-04-07 Basf Se Wet-strength corrugated fiberboard
JP2013542292A (ja) 2010-10-27 2013-11-21 ビーエーエスエフ ソシエタス・ヨーロピア スリットフィルムテープを製造するためのポリマー混合物の使用
EP2671921B1 (en) 2011-02-02 2016-10-19 Mitsubishi Chemical Corporation Polyester resin composition
CN102120870A (zh) * 2011-02-28 2011-07-13 殷正福 一种可降解塑料及其生产方法
WO2012126921A1 (de) 2011-03-23 2012-09-27 Basf Se Polyester auf basis von 2-methylbernsteinsaeure
US8546472B2 (en) 2011-03-23 2013-10-01 Basf Se Polyesters based on 2-methylsuccinic acid
CN103492280B (zh) 2011-04-20 2015-09-16 巴斯夫欧洲公司 纤维素防护包装材料
EP2522695A1 (de) 2011-05-10 2012-11-14 Basf Se Biologisch abbaubare Polyesterfolie
US8686080B2 (en) 2011-05-10 2014-04-01 Basf Se Biodegradable polyester film
KR101406909B1 (ko) * 2011-05-13 2014-06-13 신동하 리그닌을 포함하는 생분해성 폴리에스테르 수지의 제조방법
WO2012168324A1 (de) 2011-06-09 2012-12-13 Basf Se Biologisch abbaubare polyestermischung
US8753481B2 (en) 2011-06-10 2014-06-17 Basf Se Powder composition and use thereof for paper production
EP2718497A1 (de) 2011-06-10 2014-04-16 Basf Se Pulverzusammensetzung und deren verwendung für die papierherstellung
US8877862B2 (en) 2011-07-15 2014-11-04 Saudi Basic Industries Corporation Method for color stabilization of poly(butylene-co-adipate terephthalate
EP2551301A1 (de) 2011-07-29 2013-01-30 Basf Se Biologisch abbaubare Polyesterfolie
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WO2013030300A1 (de) 2011-09-02 2013-03-07 Basf Se Polypropylencarbonat-haltige schäume
EP2573138A1 (de) 2011-09-21 2013-03-27 Basf Se Polyamid-Formmassen
EP2573142A1 (de) 2011-09-21 2013-03-27 Basf Se Thermoplastische Formmasse mit verbesserter Kerbschlagzähigkeit
CN103958772A (zh) 2011-12-01 2014-07-30 巴斯夫欧洲公司 使用可生物降解的聚酯纤维和/或聚碳酸亚烷基酯纤维制备含填料的纸的方法
US8940135B2 (en) 2011-12-01 2015-01-27 Basf Se Production of filled paper using biodegradable polyester fibers and/or polyalkylene carbonate fibers
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WO2014001119A1 (de) 2012-06-26 2014-01-03 Basf Se Verfahren zur herstellung von expandierbaren polymilchsäurehaltigen granulaten
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