FR2483934A1 - Procede pour empecher les degradations de resines thermoplastiques sous l'action de la chaleur ou de l'ultraviolet, et compositions de ces resines restant stables a la chaleur et a l'ultraviolet - Google Patents
Procede pour empecher les degradations de resines thermoplastiques sous l'action de la chaleur ou de l'ultraviolet, et compositions de ces resines restant stables a la chaleur et a l'ultraviolet Download PDFInfo
- Publication number
- FR2483934A1 FR2483934A1 FR8012764A FR8012764A FR2483934A1 FR 2483934 A1 FR2483934 A1 FR 2483934A1 FR 8012764 A FR8012764 A FR 8012764A FR 8012764 A FR8012764 A FR 8012764A FR 2483934 A1 FR2483934 A1 FR 2483934A1
- Authority
- FR
- France
- Prior art keywords
- hydrotalcite
- resins
- parts
- ultraviolet
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920005989 resin Polymers 0.000 title claims abstract description 47
- 239000011347 resin Substances 0.000 title claims abstract description 47
- 229920005992 thermoplastic resin Polymers 0.000 title claims abstract description 24
- 238000000034 method Methods 0.000 title claims abstract description 23
- 230000015556 catabolic process Effects 0.000 title claims abstract description 16
- 238000006731 degradation reaction Methods 0.000 title claims abstract description 16
- 239000000203 mixture Substances 0.000 title claims description 17
- 229960001545 hydrotalcite Drugs 0.000 claims abstract description 26
- 229910001701 hydrotalcite Inorganic materials 0.000 claims abstract description 26
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 24
- 150000002367 halogens Chemical class 0.000 claims abstract description 24
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 8
- 150000001450 anions Chemical class 0.000 claims abstract description 8
- 230000002401 inhibitory effect Effects 0.000 claims abstract description 8
- 238000002156 mixing Methods 0.000 claims abstract description 5
- 238000004381 surface treatment Methods 0.000 claims abstract description 5
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 claims description 23
- 230000002378 acidificating effect Effects 0.000 claims description 19
- 229920005672 polyolefin resin Polymers 0.000 claims description 7
- 239000011342 resin composition Substances 0.000 claims description 6
- 230000005855 radiation Effects 0.000 claims description 4
- 239000011163 secondary particle Substances 0.000 claims description 4
- 238000002441 X-ray diffraction Methods 0.000 claims description 2
- 229920003023 plastic Polymers 0.000 claims description 2
- 239000004033 plastic Substances 0.000 claims description 2
- 229920001187 thermosetting polymer Polymers 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 abstract description 6
- 239000002253 acid Substances 0.000 abstract description 3
- 150000001336 alkenes Chemical class 0.000 abstract description 2
- PWZFXELTLAQOKC-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide;tetrahydrate Chemical compound O.O.O.O.[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O PWZFXELTLAQOKC-UHFFFAOYSA-A 0.000 abstract 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 description 13
- 239000003054 catalyst Substances 0.000 description 12
- -1 styrene resins Chemical compound 0.000 description 12
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 11
- 229920000642 polymer Polymers 0.000 description 11
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 10
- 239000003112 inhibitor Substances 0.000 description 10
- 239000000463 material Substances 0.000 description 7
- 238000000465 moulding Methods 0.000 description 7
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 description 6
- 230000026030 halogenation Effects 0.000 description 6
- 238000005658 halogenation reaction Methods 0.000 description 6
- 239000000178 monomer Substances 0.000 description 6
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 5
- 239000013078 crystal Substances 0.000 description 5
- 229920001971 elastomer Polymers 0.000 description 5
- 239000004800 polyvinyl chloride Substances 0.000 description 5
- 229920000915 polyvinyl chloride Polymers 0.000 description 5
- 239000005060 rubber Substances 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 4
- 230000005764 inhibitory process Effects 0.000 description 4
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 4
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 4
- 239000003381 stabilizer Substances 0.000 description 4
- 229920001169 thermoplastic Polymers 0.000 description 4
- 239000004416 thermosoftening plastic Substances 0.000 description 4
- 229910052725 zinc Inorganic materials 0.000 description 4
- 239000011701 zinc Substances 0.000 description 4
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 4
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 3
- 229910015900 BF3 Inorganic materials 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 229910021627 Tin(IV) chloride Inorganic materials 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 238000005660 chlorination reaction Methods 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- NIQCNGHVCWTJSM-UHFFFAOYSA-N Dimethyl phthalate Chemical compound COC(=O)C1=CC=CC=C1C(=O)OC NIQCNGHVCWTJSM-UHFFFAOYSA-N 0.000 description 2
- ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 description 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000011358 absorbing material Substances 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- QANIADJLTJYOFI-UHFFFAOYSA-K aluminum;magnesium;carbonate;hydroxide;hydrate Chemical compound O.[OH-].[Mg+2].[Al+3].[O-]C([O-])=O QANIADJLTJYOFI-UHFFFAOYSA-K 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 239000002216 antistatic agent Substances 0.000 description 2
- 239000012736 aqueous medium Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical class [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000008240 homogeneous mixture Substances 0.000 description 2
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 2
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 125000005395 methacrylic acid group Chemical group 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 230000003472 neutralizing effect Effects 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 229920001084 poly(chloroprene) Polymers 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 229920002689 polyvinyl acetate Polymers 0.000 description 2
- 239000011118 polyvinyl acetate Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000004711 α-olefin Substances 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 1
- JZODKRWQWUWGCD-UHFFFAOYSA-N 2,5-di-tert-butylbenzene-1,4-diol Chemical compound CC(C)(C)C1=CC(O)=C(C(C)(C)C)C=C1O JZODKRWQWUWGCD-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- NRSWGNXBEVDTNI-UHFFFAOYSA-N 2-fluorooxirane Chemical class FC1CO1 NRSWGNXBEVDTNI-UHFFFAOYSA-N 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- WJQOZHYUIDYNHM-UHFFFAOYSA-N 2-tert-Butylphenol Chemical compound CC(C)(C)C1=CC=CC=C1O WJQOZHYUIDYNHM-UHFFFAOYSA-N 0.000 description 1
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- 101100283604 Caenorhabditis elegans pigk-1 gene Proteins 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 239000004801 Chlorinated PVC Substances 0.000 description 1
- 239000004709 Chlorinated polyethylene Substances 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 239000004812 Fluorinated ethylene propylene Substances 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 241000212342 Sium Species 0.000 description 1
- IYFATESGLOUGBX-YVNJGZBMSA-N Sorbitan monopalmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O IYFATESGLOUGBX-YVNJGZBMSA-N 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- AJDTZVRPEPFODZ-PAMPIZDHSA-J [Sn+4].[O-]C(=O)\C=C/C([O-])=O.[O-]C(=O)\C=C/C([O-])=O Chemical compound [Sn+4].[O-]C(=O)\C=C/C([O-])=O.[O-]C(=O)\C=C/C([O-])=O AJDTZVRPEPFODZ-PAMPIZDHSA-J 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000001340 alkali metals Chemical group 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- PPQREHKVAOVYBT-UHFFFAOYSA-H aluminium carbonate Inorganic materials [Al+3].[Al+3].[O-]C([O-])=O.[O-]C([O-])=O.[O-]C([O-])=O PPQREHKVAOVYBT-UHFFFAOYSA-H 0.000 description 1
- 229940118662 aluminum carbonate Drugs 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 150000005840 aryl radicals Chemical class 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- PZGVVCOOWYSSGB-UHFFFAOYSA-L but-2-enedioate;dioctyltin(2+) Chemical compound CCCCCCCC[Sn]1(CCCCCCCC)OC(=O)C=CC(=O)O1 PZGVVCOOWYSSGB-UHFFFAOYSA-L 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000000378 calcium silicate Substances 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 229920000457 chlorinated polyvinyl chloride Polymers 0.000 description 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
- 230000001010 compromised effect Effects 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000006298 dechlorination reaction Methods 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- FBSAITBEAPNWJG-UHFFFAOYSA-N dimethyl phthalate Natural products CC(=O)OC1=CC=CC=C1OC(C)=O FBSAITBEAPNWJG-UHFFFAOYSA-N 0.000 description 1
- 229960001826 dimethylphthalate Drugs 0.000 description 1
- IZJMRPRYDACWQA-UHFFFAOYSA-L disodium 2-sulfooctadecanoate Chemical compound [Na+].[Na+].CCCCCCCCCCCCCCCCC(C([O-])=O)S(O)(=O)=O.CCCCCCCCCCCCCCCCC(C([O-])=O)S(O)(=O)=O IZJMRPRYDACWQA-UHFFFAOYSA-L 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical class CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- IAJNXBNRYMEYAZ-UHFFFAOYSA-N ethyl 2-cyano-3,3-diphenylprop-2-enoate Chemical compound C=1C=CC=CC=1C(=C(C#N)C(=O)OCC)C1=CC=CC=C1 IAJNXBNRYMEYAZ-UHFFFAOYSA-N 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 229920001973 fluoroelastomer Polymers 0.000 description 1
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical group FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229940070765 laurate Drugs 0.000 description 1
- 239000000944 linseed oil Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- RKISUIUJZGSLEV-UHFFFAOYSA-N n-[2-(octadecanoylamino)ethyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCNC(=O)CCCCCCCCCCCCCCCCC RKISUIUJZGSLEV-UHFFFAOYSA-N 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- QUAMTGJKVDWJEQ-UHFFFAOYSA-N octabenzone Chemical compound OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 QUAMTGJKVDWJEQ-UHFFFAOYSA-N 0.000 description 1
- 229940049964 oleate Drugs 0.000 description 1
- 150000002942 palmitic acid derivatives Chemical class 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 229920009441 perflouroethylene propylene Polymers 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 239000005023 polychlorotrifluoroethylene (PCTFE) polymer Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- FYFUQDOEHQSBFN-UHFFFAOYSA-M potassium;docosanoate Chemical compound [K+].CCCCCCCCCCCCCCCCCCCCCC([O-])=O FYFUQDOEHQSBFN-UHFFFAOYSA-M 0.000 description 1
- PFMVLFSAAABWQD-UHFFFAOYSA-M potassium;octadecyl sulfate Chemical compound [K+].CCCCCCCCCCCCCCCCCCOS([O-])(=O)=O PFMVLFSAAABWQD-UHFFFAOYSA-M 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000008521 reorganization Effects 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 230000011664 signaling Effects 0.000 description 1
- MZSDGDXXBZSFTG-UHFFFAOYSA-M sodium;benzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1 MZSDGDXXBZSFTG-UHFFFAOYSA-M 0.000 description 1
- DAJSVUQLFFJUSX-UHFFFAOYSA-M sodium;dodecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCS([O-])(=O)=O DAJSVUQLFFJUSX-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000001570 sorbitan monopalmitate Substances 0.000 description 1
- 229940031953 sorbitan monopalmitate Drugs 0.000 description 1
- 235000011071 sorbitan monopalmitate Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/10—Metal compounds
- C08K3/105—Compounds containing metals of Groups 1 to 3 or of Groups 11 to 13 of the Periodic Table
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB8015792A GB2075989B (en) | 1980-05-13 | 1980-05-13 | Stabilized thermoplastic resin compositions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| FR2483934A1 true FR2483934A1 (fr) | 1981-12-11 |
| FR2483934B1 FR2483934B1 (enExample) | 1983-11-04 |
Family
ID=10513380
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FR8012764A Granted FR2483934A1 (fr) | 1980-05-13 | 1980-06-09 | Procede pour empecher les degradations de resines thermoplastiques sous l'action de la chaleur ou de l'ultraviolet, et compositions de ces resines restant stables a la chaleur et a l'ultraviolet |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US4299759A (enExample) |
| DE (1) | DE3019632C2 (enExample) |
| FR (1) | FR2483934A1 (enExample) |
| GB (1) | GB2075989B (enExample) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0189899A3 (en) * | 1985-01-29 | 1988-04-13 | Kyowa Chemical Industry Co., Ltd. | Synthetic resin composition having reduced corrosion-causing tendency and coloration |
| US5234981A (en) * | 1991-04-09 | 1993-08-10 | Rhone-Poulenc Chimie | Halogenated polymer compositions stabilized with the aid of an inorganic additive |
Families Citing this family (61)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5783538A (en) * | 1980-11-12 | 1982-05-25 | Kyowa Chem Ind Co Ltd | Polyolefin composition and agent thereof |
| JPS601241A (ja) * | 1983-06-17 | 1985-01-07 | Kyowa Chem Ind Co Ltd | 難燃性樹脂組成物 |
| JPS6060105A (ja) * | 1983-08-08 | 1985-04-06 | ザ ダウ ケミカル カンパニ− | 重合触媒の失活及び中和方法 |
| JPS6060161A (ja) * | 1983-08-08 | 1985-04-06 | ザ ダウ ケミカル カンパニ− | 重合体の処理中に放出されたハロゲンおよび酸の中和方法 |
| JPS60104141A (ja) * | 1983-11-12 | 1985-06-08 | Kyowa Chem Ind Co Ltd | 農業用フイルム |
| US4529769A (en) * | 1983-12-06 | 1985-07-16 | Phillips Petroleum Company | Poly(arylene sulfide) composition, molding method and article of manufacture |
| JPS60124653A (ja) * | 1983-12-10 | 1985-07-03 | Victor Co Of Japan Ltd | 導電性樹脂組成物 |
| FR2574805B1 (fr) * | 1984-12-19 | 1987-02-20 | Rhone Poulenc Spec Chim | Procede de stabilisation de polymeres a base de chlorure de vinyle, compositions stabilisantes pour la mise en oeuvre du procede et polymeres ainsi stabilises |
| US4611024A (en) * | 1985-02-14 | 1986-09-09 | Phillips Petroleum Co. | Propylene polymer composition containing a hydrotalcite and an acetal of an alditol |
| US5658653A (en) * | 1985-07-05 | 1997-08-19 | The Dow Chemical Company | Polymeric composites with crystalline mixed metal hydroxide particles dispersed therein |
| US4741981A (en) * | 1985-07-30 | 1988-05-03 | Ricoh Co., Ltd. | Photosensitive material for electrophotography contains organic phosphite compounds |
| NL8601411A (nl) * | 1986-06-02 | 1988-01-04 | Stamicarbon | Werkwijze voor het tegengaan van plakken van kunststoffolies. |
| FR2628114B1 (fr) * | 1988-03-07 | 1990-07-13 | M & T Chemicals Inc | Composition utilisable pour la stabilisation thermique et ultraviolette de resines thermoplastiques et resines thermoplastiques contenant une telle composition stabilisante |
| FR2637905B1 (fr) * | 1988-10-13 | 1990-12-14 | Rhone Poulenc Chimie | Compositions a base de polyamide ignifuge |
| JPH03502820A (ja) * | 1988-12-22 | 1991-06-27 | グレート・レークス・ケミカル・コーポレーション | 熱及び光に安定な難燃性熱可塑性ポリオレフィン及びポリスチレン組成物 |
| US5141980A (en) * | 1989-06-23 | 1992-08-25 | Elf Atochem North America, Inc. | Composition usable for the thermal and ultaviolet stabilization of thermoplastic resins and thermoplastic resins containing such a stabilizing composition |
| JP2794465B2 (ja) * | 1989-09-26 | 1998-09-03 | 旭電化工業株式会社 | 安定化された塩素含有樹脂組成物 |
| DE4010606A1 (de) * | 1990-04-02 | 1991-10-10 | Henkel Kgaa | Verwendung von hydrophobierten hydrotalciten als katalysatoren fuer die ethoxylierung bzw. propoxylierung |
| DE4034305A1 (de) * | 1990-10-29 | 1992-04-30 | Henkel Kgaa | Hydrophobierte doppelschichthydroxid-verbindungen, verfahren zur herstellung und ihre verwendung als alkoxylierungskatalysatoren |
| GB9026230D0 (en) * | 1990-12-03 | 1991-01-16 | Unilever Plc | Detergent composition |
| DE4103881C1 (enExample) * | 1991-02-08 | 1992-10-15 | Baerlocher Gmbh, 8000 Muenchen, De | |
| DE4103916A1 (de) * | 1991-02-08 | 1992-08-13 | Baerlocher Gmbh | Verbindungen einer bestimmten zusammensetzung, verfahren zu deren herstellung und deren verwendung |
| DE4106403A1 (de) * | 1991-02-28 | 1992-09-03 | Baerlocher Gmbh | Verbindungen einer bestimmten zusammensetzung, verfahren zu deren herstellung und deren verwendung |
| FR2675150B1 (fr) * | 1991-04-09 | 1994-06-17 | Rhone Poulenc Chimie | Compositions stabilisees de polymere halogene contenant un compose du plomb ou un organo-etain. |
| US5145674A (en) * | 1991-04-30 | 1992-09-08 | The Dow Chemical Company | Biologically-active compounds comprising a biologically-active anionic portion and a water-insoluble, inorganic cationic portion |
| DE4117034A1 (de) * | 1991-05-24 | 1992-11-26 | Henkel Kgaa | Kationische schichtverbindungen modifiziert mit polymeren |
| DE4117035A1 (de) * | 1991-05-24 | 1992-11-26 | Henkel Kgaa | Kationische, modifizierte schichtverbindungen |
| US5312859A (en) * | 1992-02-19 | 1994-05-17 | J. M. Huber Corporation | Acid acceptor for polymers containing acid moieties |
| EP0600090A1 (en) * | 1992-05-11 | 1994-06-08 | Asahi Kasei Kogyo Kabushiki Kaisha | Fluoroelastomer composition and molding produced therefrom |
| US5352723A (en) * | 1992-09-15 | 1994-10-04 | Synthetic Products Company | Stabilized vinyl halide compositions containing hydrotalcites |
| DE4238567A1 (de) * | 1992-11-16 | 1994-05-19 | Henkel Kgaa | Stabilisatormischungen für Polymerisate mit Granaten |
| US5380523A (en) * | 1993-08-17 | 1995-01-10 | University Of Kentucky Research Foundation | High energy coprecipitate of nonoxynol oligomer, PVP and iodine having contraceptive and potent anti-HIV properties |
| DE59502106D1 (de) * | 1994-02-03 | 1998-06-10 | Chemson Polymer Additive | Basische schichtgitterverbindungen |
| US5451628A (en) * | 1994-06-01 | 1995-09-19 | Synthetic Products Company | Heat stabilization of PVC compositions containing a mixed metal stabilizer and antimony trioxide |
| FR2722792B1 (fr) * | 1994-07-21 | 1996-09-06 | Ceca Sa | Compositions de type hydroxyde mixte d'aluminium et d'alcalino-terreux comme agents antichlore et anti-acides pour la stabilisation des resines thermoplastiques |
| DE19511016A1 (de) | 1995-03-25 | 1996-09-26 | Henkel Kgaa | Kationische Schichtverbindungen, deren Herstellung und deren Verwendung als PVC-Stabilisatoren |
| US5929133A (en) * | 1996-02-16 | 1999-07-27 | Hitachi Chemical Filtec, Inc. | Anti-bacterial film suitable for food packaging |
| DE19617138A1 (de) * | 1996-04-29 | 1997-11-06 | Henkel Kgaa | Kationische Schichtverbindungen, deren Herstellung und deren Verwendung als Stabilisatoren für halogenhaltige Kunststoffe |
| DE19627258C2 (de) * | 1996-07-08 | 2001-04-12 | Chemson Polymer Additive | Verfahren zur Herstellung einer schmelzbaren Stabilisatorkombination |
| ID21026A (id) | 1997-07-04 | 1999-04-08 | Kyowa Chem Ind Co Ltd | Komposisi resin sintetis yang mempunyai resisten deteriorasi panas dan benda cetakannya |
| EP0952189B2 (en) | 1997-07-22 | 2009-06-24 | Kyowa Chemical Industry Co., Ltd. | Flame retardant with resistance to thermal deterioration, resin composition, and molded article |
| US5858293A (en) * | 1997-09-30 | 1999-01-12 | Montell North America Inc. | Method for producing spunbonded materials with improved tensile strength |
| US6803401B2 (en) * | 1997-10-24 | 2004-10-12 | Reheis, Inc. | Halogen scavenger for olefin formulations |
| DE19753758A1 (de) | 1997-12-04 | 1999-06-10 | Henkel Kgaa | Verfahren zur Herstellung kationischer Schichtverbindungen |
| DE19818441C2 (de) * | 1998-04-24 | 2001-11-15 | Baerlocher Gmbh | Stabilisatorkombination für halogenhaltige thermoplastische Harzzusammensetzung |
| DE60014818T2 (de) * | 1999-10-01 | 2006-03-09 | Toda Kogyo Corp. | Auf Mg-Al basierende Hydrotalcitteilchen, Stabilisator für chlorhaltige Harze und Verfahren zur Herstellung der Teilchen |
| US6225387B1 (en) | 2000-02-17 | 2001-05-01 | Great Lakes Chemical Corporation | Stabilizer blend for organic polymer compositions; stabilized polymer compositions and method of stabilizing polymers |
| EP1548068B1 (en) * | 2002-09-13 | 2014-12-31 | Kaneka Corporation | Polymer composition containing double salt whose metal components are magnesium and aluminum |
| CN1252159C (zh) * | 2004-04-29 | 2006-04-19 | 北京化工大学 | 一种水滑石基pvc复合热稳定剂 |
| RU2389688C2 (ru) * | 2004-10-20 | 2010-05-20 | Сакай Кемикал Индастри Ко., Лтд. | Композиция гидроталькита и синтетической смолы |
| KR20080024142A (ko) * | 2005-06-07 | 2008-03-17 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 폴리올레핀 나노복합체 물질 |
| CN1769355A (zh) * | 2005-11-03 | 2006-05-10 | 北京化工大学 | 含双键有机阴离子插层水滑石及将其用作热稳定剂 |
| CN1333005C (zh) * | 2005-12-19 | 2007-08-22 | 北京化工大学 | 超分子插层结构紫外光吸收剂及其制备方法和用途 |
| DE102006055215A1 (de) * | 2006-11-21 | 2008-05-29 | Nabaltec Gmbh | Neue zinkhaltige Kalzium-Aluminium-Doppelsalze |
| US8193260B2 (en) * | 2007-02-26 | 2012-06-05 | Chemtura Corporation | Stabilization of polymers with styrenated-p-cresols |
| JP5143845B2 (ja) † | 2007-10-18 | 2013-02-13 | アイセロ化学株式会社 | 水溶性封入包材 |
| ES2432521T3 (es) | 2007-11-27 | 2013-12-04 | Basell Poliolefine Italia S.R.L. | Materiales nanocompuestos de poliolefina |
| CN101450998B (zh) * | 2008-12-30 | 2011-11-16 | 南京师范大学 | Pvc用云母/稀土盐稳定剂及其制备方法 |
| CN101492548B (zh) * | 2009-02-20 | 2011-05-18 | 中南大学 | 一种pvc用复合热稳定剂及其制备和应用 |
| WO2017078103A1 (ja) * | 2015-11-04 | 2017-05-11 | 株式会社クラレ | イソブチレン系共重合体を含む樹脂組成物及び成形体 |
| FR3112096B1 (fr) | 2020-07-02 | 2022-06-03 | Gerflor | revêtement de sol à couche d’usure ignifugée |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS507845A (enExample) * | 1973-05-24 | 1975-01-27 | ||
| JPS5263246A (en) * | 1975-11-19 | 1977-05-25 | Matsushita Electric Ind Co Ltd | Thermoplastic resin compositions |
| FR2338968A1 (fr) * | 1976-01-23 | 1977-08-19 | Kyowa Chem Ind Co Ltd | Produit d'ignifugeage mineral pour resines thermoplastiques |
| DE2739429A1 (de) * | 1976-09-02 | 1978-03-09 | Kyowa Chem Ind Co Ltd | Feuerverzoegernde thermoplastische harzmasse |
| JPS5565243A (en) * | 1978-09-20 | 1980-05-16 | Matsushita Electric Ind Co Ltd | Polyolefin high polymer compositon |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1007803B (it) * | 1974-04-09 | 1976-10-30 | Montedison Spa | Composizioni polimeriche plastifi cate a base di polimeri del cloru ro di vinile con buone caratteri stiche fisico meccaniche e con ec cellenti caratteristiche di isola mento elettrico anche a temperatu ra elevata |
| NL7512126A (nl) * | 1974-10-18 | 1976-04-21 | Mitsubishi Petrochemical Co | Werkwijze voor het bereiden van een zelfdovende harssamenstelling en daaruit vervaardigde pro- dukten. |
| US4116897A (en) * | 1974-11-11 | 1978-09-26 | Tiszai Vegy Kombinat | Compounded plastic system |
| GB1514081A (en) * | 1975-05-30 | 1978-06-14 | Kyowa Chem Ind Co Ltd | Particulate magnesium hydroxide |
| US4132691A (en) * | 1977-04-06 | 1979-01-02 | M&T Chemical Inc. | Lubricant composition for vinyl chloride polymers |
-
1980
- 1980-05-13 GB GB8015792A patent/GB2075989B/en not_active Expired
- 1980-05-16 US US06/150,651 patent/US4299759A/en not_active Expired - Lifetime
- 1980-05-22 DE DE3019632A patent/DE3019632C2/de not_active Expired
- 1980-06-09 FR FR8012764A patent/FR2483934A1/fr active Granted
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS507845A (enExample) * | 1973-05-24 | 1975-01-27 | ||
| JPS5263246A (en) * | 1975-11-19 | 1977-05-25 | Matsushita Electric Ind Co Ltd | Thermoplastic resin compositions |
| FR2338968A1 (fr) * | 1976-01-23 | 1977-08-19 | Kyowa Chem Ind Co Ltd | Produit d'ignifugeage mineral pour resines thermoplastiques |
| DE2739429A1 (de) * | 1976-09-02 | 1978-03-09 | Kyowa Chem Ind Co Ltd | Feuerverzoegernde thermoplastische harzmasse |
| JPS5565243A (en) * | 1978-09-20 | 1980-05-16 | Matsushita Electric Ind Co Ltd | Polyolefin high polymer compositon |
Non-Patent Citations (3)
| Title |
|---|
| ABJP/77 * |
| ABJP/80 * |
| CA1975 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0189899A3 (en) * | 1985-01-29 | 1988-04-13 | Kyowa Chemical Industry Co., Ltd. | Synthetic resin composition having reduced corrosion-causing tendency and coloration |
| US5234981A (en) * | 1991-04-09 | 1993-08-10 | Rhone-Poulenc Chimie | Halogenated polymer compositions stabilized with the aid of an inorganic additive |
Also Published As
| Publication number | Publication date |
|---|---|
| US4299759A (en) | 1981-11-10 |
| GB2075989B (en) | 1984-04-26 |
| DE3019632C2 (de) | 1984-02-23 |
| FR2483934B1 (enExample) | 1983-11-04 |
| GB2075989A (en) | 1981-11-25 |
| DE3019632A1 (de) | 1981-11-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| FR2483934A1 (fr) | Procede pour empecher les degradations de resines thermoplastiques sous l'action de la chaleur ou de l'ultraviolet, et compositions de ces resines restant stables a la chaleur et a l'ultraviolet | |
| US4284762A (en) | Method for inhibiting corrosion-causing tendency and coloration of halogen-containing olefin resins with hydrotalcite | |
| EP1326915B1 (en) | Polyolefin articles with long-term elevated temperature stability | |
| FI84616C (fi) | Termoplastisk och foernaetbar polymerkomposition. | |
| JPH09510238A (ja) | ポリオレフィンの加工助剤系 | |
| JPS5846146B2 (ja) | 熱可塑性樹脂組成物及び劣化防止方法 | |
| US5506308A (en) | Precure retardation of free radical cured elastomers | |
| US6197852B1 (en) | Polyolefin concentrates and composition having improved carbon black dispersion | |
| US4594382A (en) | Thermally stabilized carboxyl-containing ethylene copolymers and preparation thereof | |
| CH622816A5 (enExample) | ||
| CN112724558B (zh) | 一种复合型pvc热稳定剂及其制备方法 | |
| US5206273A (en) | Compositions and method for improving the slip of polyolefins and the adhesion of water based inks to polyolefins | |
| JPH03290470A (ja) | 熱可塑性樹脂組成物 | |
| JPH04348148A (ja) | 改質プロピレン系重合体組成物の製造方法 | |
| JP2005526160A (ja) | 加工特性が改良されたポリオレフィンフィルム | |
| KR0179443B1 (ko) | 결정질 프로필렌 중합체 조성물 | |
| FR2619386A1 (fr) | Composition de resine thermoplastique a teneur en halogene | |
| BE1010086A3 (fr) | Compositions de polymeres du fluorure de vinylidene stabilises a la chaleur. | |
| JPH01245039A (ja) | 難燃化剤及びそれを用いた難燃性樹脂組成物 | |
| CA2187378A1 (fr) | Compositions mixtes constituees d'hydrotalcite et d'hydroxyde de calcium ou d'hydroxydes de calcium et d'aluminium | |
| EP0054268B1 (en) | Process and composition for extrusion of ziegler-natta catalyzed olefin polymers | |
| JP2896615B2 (ja) | 架橋ポリオレフィン組成物の製造方法 | |
| JP3064499B2 (ja) | 変性ポリオレフィン組成物の製造方法 | |
| KR100431537B1 (ko) | 압출 가공성이 우수한 열가소성 수지 조성물 | |
| WO1996020974A1 (en) | Process for stabilizing ethylene polymers during high temperature melt processing operations |