DE3019632C2 - Verwendung eines Hydrotalcits bestimmter Zusammensetzung zur Inhibierung des thermischen oder Ultraviolett-Abbaus von thermoplastischen Harzen - Google Patents
Verwendung eines Hydrotalcits bestimmter Zusammensetzung zur Inhibierung des thermischen oder Ultraviolett-Abbaus von thermoplastischen HarzenInfo
- Publication number
- DE3019632C2 DE3019632C2 DE3019632A DE3019632A DE3019632C2 DE 3019632 C2 DE3019632 C2 DE 3019632C2 DE 3019632 A DE3019632 A DE 3019632A DE 3019632 A DE3019632 A DE 3019632A DE 3019632 C2 DE3019632 C2 DE 3019632C2
- Authority
- DE
- Germany
- Prior art keywords
- hydrotalcite
- resins
- thermal
- weight
- thermoplastic resins
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920005992 thermoplastic resin Polymers 0.000 title claims description 28
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 title claims description 26
- 229960001545 hydrotalcite Drugs 0.000 title claims description 26
- 229910001701 hydrotalcite Inorganic materials 0.000 title claims description 26
- 230000015556 catabolic process Effects 0.000 title claims description 16
- 238000006731 degradation reaction Methods 0.000 title claims description 16
- 239000000203 mixture Substances 0.000 title description 6
- 230000002401 inhibitory effect Effects 0.000 title description 5
- 229910052736 halogen Inorganic materials 0.000 claims description 25
- 150000002367 halogens Chemical class 0.000 claims description 25
- 230000002378 acidificating effect Effects 0.000 claims description 17
- 239000003054 catalyst Substances 0.000 claims description 9
- 150000001450 anions Chemical class 0.000 claims description 6
- 239000004094 surface-active agent Substances 0.000 claims description 6
- 238000005658 halogenation reaction Methods 0.000 claims description 5
- 239000000178 monomer Substances 0.000 claims description 5
- 229920005672 polyolefin resin Polymers 0.000 claims description 5
- 238000004381 surface treatment Methods 0.000 claims description 5
- 239000011163 secondary particle Substances 0.000 claims description 4
- 238000002441 X-ray diffraction Methods 0.000 claims description 3
- 125000003118 aryl group Chemical group 0.000 claims description 2
- 229920005989 resin Polymers 0.000 description 40
- 239000011347 resin Substances 0.000 description 40
- 229920001577 copolymer Polymers 0.000 description 19
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 13
- 229920000642 polymer Polymers 0.000 description 10
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- -1 polyethylene Polymers 0.000 description 8
- 239000003112 inhibitor Substances 0.000 description 7
- 230000005764 inhibitory process Effects 0.000 description 7
- 239000004800 polyvinyl chloride Substances 0.000 description 7
- 229920000915 polyvinyl chloride Polymers 0.000 description 7
- 239000011342 resin composition Substances 0.000 description 7
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 description 6
- 239000013078 crystal Substances 0.000 description 6
- 229920001971 elastomer Polymers 0.000 description 6
- 239000005060 rubber Substances 0.000 description 6
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 5
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 239000003945 anionic surfactant Substances 0.000 description 4
- 238000000354 decomposition reaction Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 238000000465 moulding Methods 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 4
- 239000003381 stabilizer Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 229920001169 thermoplastic Polymers 0.000 description 4
- 239000004416 thermosoftening plastic Substances 0.000 description 4
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 3
- 229910015900 BF3 Inorganic materials 0.000 description 3
- 239000004793 Polystyrene Substances 0.000 description 3
- 229910021627 Tin(IV) chloride Inorganic materials 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 239000003063 flame retardant Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 230000002829 reductive effect Effects 0.000 description 3
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 3
- ZBBLRPRYYSJUCZ-GRHBHMESSA-L (z)-but-2-enedioate;dibutyltin(2+) Chemical compound [O-]C(=O)\C=C/C([O-])=O.CCCC[Sn+2]CCCC ZBBLRPRYYSJUCZ-GRHBHMESSA-L 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000004801 Chlorinated PVC Substances 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 2
- NIQCNGHVCWTJSM-UHFFFAOYSA-N Dimethyl phthalate Chemical compound COC(=O)C1=CC=CC=C1C(=O)OC NIQCNGHVCWTJSM-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- 239000006096 absorbing agent Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 150000001342 alkaline earth metals Chemical class 0.000 description 2
- QANIADJLTJYOFI-UHFFFAOYSA-K aluminum;magnesium;carbonate;hydroxide;hydrate Chemical compound O.[OH-].[Mg+2].[Al+3].[O-]C([O-])=O QANIADJLTJYOFI-UHFFFAOYSA-K 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 239000002216 antistatic agent Substances 0.000 description 2
- 239000012736 aqueous medium Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 229920000457 chlorinated polyvinyl chloride Polymers 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 238000006298 dechlorination reaction Methods 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 description 2
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical group FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 2
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 2
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 125000005395 methacrylic acid group Chemical group 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 229920002959 polymer blend Polymers 0.000 description 2
- 229920002689 polyvinyl acetate Polymers 0.000 description 2
- 239000011118 polyvinyl acetate Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- BHMLFPOTZYRDKA-IRXDYDNUSA-N (2s)-2-[(s)-(2-iodophenoxy)-phenylmethyl]morpholine Chemical compound IC1=CC=CC=C1O[C@@H](C=1C=CC=CC=1)[C@H]1OCCNC1 BHMLFPOTZYRDKA-IRXDYDNUSA-N 0.000 description 1
- KAKVFSYQVNHFBS-UHFFFAOYSA-N (5-hydroxycyclopenten-1-yl)-phenylmethanone Chemical compound OC1CCC=C1C(=O)C1=CC=CC=C1 KAKVFSYQVNHFBS-UHFFFAOYSA-N 0.000 description 1
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 description 1
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 1
- WZUNUACWCJJERC-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)butyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(CC)(CO)CO WZUNUACWCJJERC-UHFFFAOYSA-N 0.000 description 1
- JZODKRWQWUWGCD-UHFFFAOYSA-N 2,5-di-tert-butylbenzene-1,4-diol Chemical compound CC(C)(C)C1=CC(O)=C(C(C)(C)C)C=C1O JZODKRWQWUWGCD-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- XHALKWMTKWHQLO-UHFFFAOYSA-N 2-tert-butyl-4-(3-tert-butyl-4-hydroxyphenyl)sulfanylphenol Chemical compound C1=C(O)C(C(C)(C)C)=CC(SC=2C=C(C(O)=CC=2)C(C)(C)C)=C1 XHALKWMTKWHQLO-UHFFFAOYSA-N 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 241000283153 Cetacea Species 0.000 description 1
- 239000004709 Chlorinated polyethylene Substances 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- BCKXLBQYZLBQEK-KVVVOXFISA-M Sodium oleate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCC([O-])=O BCKXLBQYZLBQEK-KVVVOXFISA-M 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- AJDTZVRPEPFODZ-PAMPIZDHSA-J [Sn+4].[O-]C(=O)\C=C/C([O-])=O.[O-]C(=O)\C=C/C([O-])=O Chemical compound [Sn+4].[O-]C(=O)\C=C/C([O-])=O.[O-]C(=O)\C=C/C([O-])=O AJDTZVRPEPFODZ-PAMPIZDHSA-J 0.000 description 1
- XQBCVRSTVUHIGH-UHFFFAOYSA-L [dodecanoyloxy(dioctyl)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCCCCCC)(CCCCCCCC)OC(=O)CCCCCCCCCCC XQBCVRSTVUHIGH-UHFFFAOYSA-L 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001340 alkali metals Chemical group 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- PZGVVCOOWYSSGB-UHFFFAOYSA-L but-2-enedioate;dioctyltin(2+) Chemical compound CCCCCCCC[Sn]1(CCCCCCCC)OC(=O)C=CC(=O)O1 PZGVVCOOWYSSGB-UHFFFAOYSA-L 0.000 description 1
- QHIWVLPBUQWDMQ-UHFFFAOYSA-N butyl prop-2-enoate;methyl 2-methylprop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.COC(=O)C(C)=C.CCCCOC(=O)C=C QHIWVLPBUQWDMQ-UHFFFAOYSA-N 0.000 description 1
- 150000001669 calcium Chemical class 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000000378 calcium silicate Substances 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- HENMSNJYDGNBMU-UHFFFAOYSA-M calcium;zinc;octadecanoate Chemical compound [Ca+2].[Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O HENMSNJYDGNBMU-UHFFFAOYSA-M 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- UQLDLKMNUJERMK-UHFFFAOYSA-L di(octadecanoyloxy)lead Chemical compound [Pb+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O UQLDLKMNUJERMK-UHFFFAOYSA-L 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- FBSAITBEAPNWJG-UHFFFAOYSA-N dimethyl phthalate Natural products CC(=O)OC1=CC=CC=C1OC(C)=O FBSAITBEAPNWJG-UHFFFAOYSA-N 0.000 description 1
- 229960001826 dimethylphthalate Drugs 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- MCPKSFINULVDNX-UHFFFAOYSA-N drometrizole Chemical compound CC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 MCPKSFINULVDNX-UHFFFAOYSA-N 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- WZHKDGJSXCTSCK-UHFFFAOYSA-N hept-3-ene Chemical compound CCCC=CCC WZHKDGJSXCTSCK-UHFFFAOYSA-N 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 238000007602 hot air drying Methods 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 150000002476 indolines Chemical class 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000000944 linseed oil Substances 0.000 description 1
- 235000021388 linseed oil Nutrition 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- RKISUIUJZGSLEV-UHFFFAOYSA-N n-[2-(octadecanoylamino)ethyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCNC(=O)CCCCCCCCCCCCCCCCC RKISUIUJZGSLEV-UHFFFAOYSA-N 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- QUAMTGJKVDWJEQ-UHFFFAOYSA-N octabenzone Chemical compound OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 QUAMTGJKVDWJEQ-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229940096992 potassium oleate Drugs 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- MLICVSDCCDDWMD-KVVVOXFISA-M potassium;(z)-octadec-9-enoate Chemical compound [K+].CCCCCCCC\C=C/CCCCCCCC([O-])=O MLICVSDCCDDWMD-KVVVOXFISA-M 0.000 description 1
- FYFUQDOEHQSBFN-UHFFFAOYSA-M potassium;docosanoate Chemical compound [K+].CCCCCCCCCCCCCCCCCCCCCC([O-])=O FYFUQDOEHQSBFN-UHFFFAOYSA-M 0.000 description 1
- MQOCIYICOGDBSG-UHFFFAOYSA-M potassium;hexadecanoate Chemical compound [K+].CCCCCCCCCCCCCCCC([O-])=O MQOCIYICOGDBSG-UHFFFAOYSA-M 0.000 description 1
- PFMVLFSAAABWQD-UHFFFAOYSA-M potassium;octadecyl sulfate Chemical compound [K+].CCCCCCCCCCCCCCCCCCOS([O-])(=O)=O PFMVLFSAAABWQD-UHFFFAOYSA-M 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 230000002000 scavenging effect Effects 0.000 description 1
- BTURAGWYSMTVOW-UHFFFAOYSA-M sodium dodecanoate Chemical compound [Na+].CCCCCCCCCCCC([O-])=O BTURAGWYSMTVOW-UHFFFAOYSA-M 0.000 description 1
- 229940082004 sodium laurate Drugs 0.000 description 1
- 229940045870 sodium palmitate Drugs 0.000 description 1
- HFQQZARZPUDIFP-UHFFFAOYSA-M sodium;2-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O HFQQZARZPUDIFP-UHFFFAOYSA-M 0.000 description 1
- GGXKEBACDBNFAF-UHFFFAOYSA-M sodium;hexadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCC([O-])=O GGXKEBACDBNFAF-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- WGKLOLBTFWFKOD-UHFFFAOYSA-N tris(2-nonylphenyl) phosphite Chemical compound CCCCCCCCCC1=CC=CC=C1OP(OC=1C(=CC=CC=1)CCCCCCCCC)OC1=CC=CC=C1CCCCCCCCC WGKLOLBTFWFKOD-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 229920001959 vinylidene polymer Polymers 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/10—Metal compounds
- C08K3/105—Compounds containing metals of Groups 1 to 3 or of Groups 11 to 13 of the Periodic Table
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB8015792A GB2075989B (en) | 1980-05-13 | 1980-05-13 | Stabilized thermoplastic resin compositions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE3019632A1 DE3019632A1 (de) | 1981-11-26 |
| DE3019632C2 true DE3019632C2 (de) | 1984-02-23 |
Family
ID=10513380
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE3019632A Expired DE3019632C2 (de) | 1980-05-13 | 1980-05-22 | Verwendung eines Hydrotalcits bestimmter Zusammensetzung zur Inhibierung des thermischen oder Ultraviolett-Abbaus von thermoplastischen Harzen |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US4299759A (enExample) |
| DE (1) | DE3019632C2 (enExample) |
| FR (1) | FR2483934A1 (enExample) |
| GB (1) | GB2075989B (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4103881C1 (enExample) * | 1991-02-08 | 1992-10-15 | Baerlocher Gmbh, 8000 Muenchen, De |
Families Citing this family (62)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5783538A (en) * | 1980-11-12 | 1982-05-25 | Kyowa Chem Ind Co Ltd | Polyolefin composition and agent thereof |
| JPS601241A (ja) * | 1983-06-17 | 1985-01-07 | Kyowa Chem Ind Co Ltd | 難燃性樹脂組成物 |
| JPS6060105A (ja) * | 1983-08-08 | 1985-04-06 | ザ ダウ ケミカル カンパニ− | 重合触媒の失活及び中和方法 |
| JPS6060161A (ja) * | 1983-08-08 | 1985-04-06 | ザ ダウ ケミカル カンパニ− | 重合体の処理中に放出されたハロゲンおよび酸の中和方法 |
| JPS60104141A (ja) * | 1983-11-12 | 1985-06-08 | Kyowa Chem Ind Co Ltd | 農業用フイルム |
| US4529769A (en) * | 1983-12-06 | 1985-07-16 | Phillips Petroleum Company | Poly(arylene sulfide) composition, molding method and article of manufacture |
| JPS60124653A (ja) * | 1983-12-10 | 1985-07-03 | Victor Co Of Japan Ltd | 導電性樹脂組成物 |
| FR2574805B1 (fr) * | 1984-12-19 | 1987-02-20 | Rhone Poulenc Spec Chim | Procede de stabilisation de polymeres a base de chlorure de vinyle, compositions stabilisantes pour la mise en oeuvre du procede et polymeres ainsi stabilises |
| JPS61174270A (ja) * | 1985-01-29 | 1986-08-05 | Kyowa Chem Ind Co Ltd | 耐発錆性ないし耐着色性賦与剤 |
| US4611024A (en) * | 1985-02-14 | 1986-09-09 | Phillips Petroleum Co. | Propylene polymer composition containing a hydrotalcite and an acetal of an alditol |
| US5658653A (en) * | 1985-07-05 | 1997-08-19 | The Dow Chemical Company | Polymeric composites with crystalline mixed metal hydroxide particles dispersed therein |
| US4741981A (en) * | 1985-07-30 | 1988-05-03 | Ricoh Co., Ltd. | Photosensitive material for electrophotography contains organic phosphite compounds |
| NL8601411A (nl) * | 1986-06-02 | 1988-01-04 | Stamicarbon | Werkwijze voor het tegengaan van plakken van kunststoffolies. |
| FR2628114B1 (fr) * | 1988-03-07 | 1990-07-13 | M & T Chemicals Inc | Composition utilisable pour la stabilisation thermique et ultraviolette de resines thermoplastiques et resines thermoplastiques contenant une telle composition stabilisante |
| FR2637905B1 (fr) * | 1988-10-13 | 1990-12-14 | Rhone Poulenc Chimie | Compositions a base de polyamide ignifuge |
| JPH03502820A (ja) * | 1988-12-22 | 1991-06-27 | グレート・レークス・ケミカル・コーポレーション | 熱及び光に安定な難燃性熱可塑性ポリオレフィン及びポリスチレン組成物 |
| US5141980A (en) * | 1989-06-23 | 1992-08-25 | Elf Atochem North America, Inc. | Composition usable for the thermal and ultaviolet stabilization of thermoplastic resins and thermoplastic resins containing such a stabilizing composition |
| JP2794465B2 (ja) * | 1989-09-26 | 1998-09-03 | 旭電化工業株式会社 | 安定化された塩素含有樹脂組成物 |
| DE4010606A1 (de) * | 1990-04-02 | 1991-10-10 | Henkel Kgaa | Verwendung von hydrophobierten hydrotalciten als katalysatoren fuer die ethoxylierung bzw. propoxylierung |
| DE4034305A1 (de) * | 1990-10-29 | 1992-04-30 | Henkel Kgaa | Hydrophobierte doppelschichthydroxid-verbindungen, verfahren zur herstellung und ihre verwendung als alkoxylierungskatalysatoren |
| GB9026230D0 (en) * | 1990-12-03 | 1991-01-16 | Unilever Plc | Detergent composition |
| DE4103916A1 (de) * | 1991-02-08 | 1992-08-13 | Baerlocher Gmbh | Verbindungen einer bestimmten zusammensetzung, verfahren zu deren herstellung und deren verwendung |
| DE4106403A1 (de) * | 1991-02-28 | 1992-09-03 | Baerlocher Gmbh | Verbindungen einer bestimmten zusammensetzung, verfahren zu deren herstellung und deren verwendung |
| FR2675150B1 (fr) * | 1991-04-09 | 1994-06-17 | Rhone Poulenc Chimie | Compositions stabilisees de polymere halogene contenant un compose du plomb ou un organo-etain. |
| FR2675149B1 (fr) * | 1991-04-09 | 1994-06-24 | Rhone Poulenc Chimie | Compositions de polymere halogene stabilisees a l'aide d'un additif mineral. |
| US5145674A (en) * | 1991-04-30 | 1992-09-08 | The Dow Chemical Company | Biologically-active compounds comprising a biologically-active anionic portion and a water-insoluble, inorganic cationic portion |
| DE4117034A1 (de) * | 1991-05-24 | 1992-11-26 | Henkel Kgaa | Kationische schichtverbindungen modifiziert mit polymeren |
| DE4117035A1 (de) * | 1991-05-24 | 1992-11-26 | Henkel Kgaa | Kationische, modifizierte schichtverbindungen |
| US5312859A (en) * | 1992-02-19 | 1994-05-17 | J. M. Huber Corporation | Acid acceptor for polymers containing acid moieties |
| EP0600090A1 (en) * | 1992-05-11 | 1994-06-08 | Asahi Kasei Kogyo Kabushiki Kaisha | Fluoroelastomer composition and molding produced therefrom |
| US5352723A (en) * | 1992-09-15 | 1994-10-04 | Synthetic Products Company | Stabilized vinyl halide compositions containing hydrotalcites |
| DE4238567A1 (de) * | 1992-11-16 | 1994-05-19 | Henkel Kgaa | Stabilisatormischungen für Polymerisate mit Granaten |
| US5380523A (en) * | 1993-08-17 | 1995-01-10 | University Of Kentucky Research Foundation | High energy coprecipitate of nonoxynol oligomer, PVP and iodine having contraceptive and potent anti-HIV properties |
| DE59502106D1 (de) * | 1994-02-03 | 1998-06-10 | Chemson Polymer Additive | Basische schichtgitterverbindungen |
| US5451628A (en) * | 1994-06-01 | 1995-09-19 | Synthetic Products Company | Heat stabilization of PVC compositions containing a mixed metal stabilizer and antimony trioxide |
| FR2722792B1 (fr) * | 1994-07-21 | 1996-09-06 | Ceca Sa | Compositions de type hydroxyde mixte d'aluminium et d'alcalino-terreux comme agents antichlore et anti-acides pour la stabilisation des resines thermoplastiques |
| DE19511016A1 (de) | 1995-03-25 | 1996-09-26 | Henkel Kgaa | Kationische Schichtverbindungen, deren Herstellung und deren Verwendung als PVC-Stabilisatoren |
| US5929133A (en) * | 1996-02-16 | 1999-07-27 | Hitachi Chemical Filtec, Inc. | Anti-bacterial film suitable for food packaging |
| DE19617138A1 (de) * | 1996-04-29 | 1997-11-06 | Henkel Kgaa | Kationische Schichtverbindungen, deren Herstellung und deren Verwendung als Stabilisatoren für halogenhaltige Kunststoffe |
| DE19627258C2 (de) * | 1996-07-08 | 2001-04-12 | Chemson Polymer Additive | Verfahren zur Herstellung einer schmelzbaren Stabilisatorkombination |
| ID21026A (id) | 1997-07-04 | 1999-04-08 | Kyowa Chem Ind Co Ltd | Komposisi resin sintetis yang mempunyai resisten deteriorasi panas dan benda cetakannya |
| EP0952189B2 (en) | 1997-07-22 | 2009-06-24 | Kyowa Chemical Industry Co., Ltd. | Flame retardant with resistance to thermal deterioration, resin composition, and molded article |
| US5858293A (en) * | 1997-09-30 | 1999-01-12 | Montell North America Inc. | Method for producing spunbonded materials with improved tensile strength |
| US6803401B2 (en) * | 1997-10-24 | 2004-10-12 | Reheis, Inc. | Halogen scavenger for olefin formulations |
| DE19753758A1 (de) | 1997-12-04 | 1999-06-10 | Henkel Kgaa | Verfahren zur Herstellung kationischer Schichtverbindungen |
| DE19818441C2 (de) * | 1998-04-24 | 2001-11-15 | Baerlocher Gmbh | Stabilisatorkombination für halogenhaltige thermoplastische Harzzusammensetzung |
| DE60014818T2 (de) * | 1999-10-01 | 2006-03-09 | Toda Kogyo Corp. | Auf Mg-Al basierende Hydrotalcitteilchen, Stabilisator für chlorhaltige Harze und Verfahren zur Herstellung der Teilchen |
| US6225387B1 (en) | 2000-02-17 | 2001-05-01 | Great Lakes Chemical Corporation | Stabilizer blend for organic polymer compositions; stabilized polymer compositions and method of stabilizing polymers |
| EP1548068B1 (en) * | 2002-09-13 | 2014-12-31 | Kaneka Corporation | Polymer composition containing double salt whose metal components are magnesium and aluminum |
| CN1252159C (zh) * | 2004-04-29 | 2006-04-19 | 北京化工大学 | 一种水滑石基pvc复合热稳定剂 |
| RU2389688C2 (ru) * | 2004-10-20 | 2010-05-20 | Сакай Кемикал Индастри Ко., Лтд. | Композиция гидроталькита и синтетической смолы |
| KR20080024142A (ko) * | 2005-06-07 | 2008-03-17 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 폴리올레핀 나노복합체 물질 |
| CN1769355A (zh) * | 2005-11-03 | 2006-05-10 | 北京化工大学 | 含双键有机阴离子插层水滑石及将其用作热稳定剂 |
| CN1333005C (zh) * | 2005-12-19 | 2007-08-22 | 北京化工大学 | 超分子插层结构紫外光吸收剂及其制备方法和用途 |
| DE102006055215A1 (de) * | 2006-11-21 | 2008-05-29 | Nabaltec Gmbh | Neue zinkhaltige Kalzium-Aluminium-Doppelsalze |
| US8193260B2 (en) * | 2007-02-26 | 2012-06-05 | Chemtura Corporation | Stabilization of polymers with styrenated-p-cresols |
| JP5143845B2 (ja) † | 2007-10-18 | 2013-02-13 | アイセロ化学株式会社 | 水溶性封入包材 |
| ES2432521T3 (es) | 2007-11-27 | 2013-12-04 | Basell Poliolefine Italia S.R.L. | Materiales nanocompuestos de poliolefina |
| CN101450998B (zh) * | 2008-12-30 | 2011-11-16 | 南京师范大学 | Pvc用云母/稀土盐稳定剂及其制备方法 |
| CN101492548B (zh) * | 2009-02-20 | 2011-05-18 | 中南大学 | 一种pvc用复合热稳定剂及其制备和应用 |
| WO2017078103A1 (ja) * | 2015-11-04 | 2017-05-11 | 株式会社クラレ | イソブチレン系共重合体を含む樹脂組成物及び成形体 |
| FR3112096B1 (fr) | 2020-07-02 | 2022-06-03 | Gerflor | revêtement de sol à couche d’usure ignifugée |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5239622B2 (enExample) * | 1973-05-24 | 1977-10-06 | ||
| IT1007803B (it) * | 1974-04-09 | 1976-10-30 | Montedison Spa | Composizioni polimeriche plastifi cate a base di polimeri del cloru ro di vinile con buone caratteri stiche fisico meccaniche e con ec cellenti caratteristiche di isola mento elettrico anche a temperatu ra elevata |
| NL7512126A (nl) * | 1974-10-18 | 1976-04-21 | Mitsubishi Petrochemical Co | Werkwijze voor het bereiden van een zelfdovende harssamenstelling en daaruit vervaardigde pro- dukten. |
| US4116897A (en) * | 1974-11-11 | 1978-09-26 | Tiszai Vegy Kombinat | Compounded plastic system |
| GB1514081A (en) * | 1975-05-30 | 1978-06-14 | Kyowa Chem Ind Co Ltd | Particulate magnesium hydroxide |
| JPS5263246A (en) * | 1975-11-19 | 1977-05-25 | Matsushita Electric Ind Co Ltd | Thermoplastic resin compositions |
| JPS5290192A (en) * | 1976-01-23 | 1977-07-28 | Kyowa Kagaku Kougiyou Kk | Inorganic flame resisting agent |
| US4154718A (en) * | 1976-09-02 | 1979-05-15 | Kyowa Chemical Industry Co. Ltd. | Fire-retardant thermoplastic resin composition |
| US4132691A (en) * | 1977-04-06 | 1979-01-02 | M&T Chemical Inc. | Lubricant composition for vinyl chloride polymers |
| JPS5565243A (en) * | 1978-09-20 | 1980-05-16 | Matsushita Electric Ind Co Ltd | Polyolefin high polymer compositon |
-
1980
- 1980-05-13 GB GB8015792A patent/GB2075989B/en not_active Expired
- 1980-05-16 US US06/150,651 patent/US4299759A/en not_active Expired - Lifetime
- 1980-05-22 DE DE3019632A patent/DE3019632C2/de not_active Expired
- 1980-06-09 FR FR8012764A patent/FR2483934A1/fr active Granted
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4103881C1 (enExample) * | 1991-02-08 | 1992-10-15 | Baerlocher Gmbh, 8000 Muenchen, De |
Also Published As
| Publication number | Publication date |
|---|---|
| US4299759A (en) | 1981-11-10 |
| FR2483934A1 (fr) | 1981-12-11 |
| GB2075989B (en) | 1984-04-26 |
| FR2483934B1 (enExample) | 1983-11-04 |
| GB2075989A (en) | 1981-11-25 |
| DE3019632A1 (de) | 1981-11-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE3019632C2 (de) | Verwendung eines Hydrotalcits bestimmter Zusammensetzung zur Inhibierung des thermischen oder Ultraviolett-Abbaus von thermoplastischen Harzen | |
| DE4002988C2 (enExample) | ||
| DE69826629T2 (de) | Synthetische harzzusammensetzung beständig gegen thermische zersetzung und geformte artikel | |
| DE4106404C2 (de) | Calcium-Aluminium-Hydroxid-Dicarboxylate, Verfahren zu deren Herstellung und deren Verwendung | |
| DE2917496C2 (de) | Vulkanisierbare fluorierte Kautschukmasse | |
| DE4106411C2 (de) | Basische Calcium-Aluminium-Hydroxy-Phosphite, Verfahren zu deren Herstellung und deren Verwendung | |
| DE2659411A1 (de) | Feuerverzoegernde thermoplastische harzmasse | |
| DE3941902C1 (enExample) | ||
| DE2624065A1 (de) | Neue magnesiumhydroxide | |
| DE69604880T2 (de) | Stabilisator für halogenhaltige harze und verfahren zu deren herstellung, halogen enthaltende harzzusammensetzung und verbundhydroxidsalz | |
| DE1138943B (de) | Verfahren zur Herstellung chlorierter kautschukartiger Mischpolymerisate von Isoolefinen mit Multiolefinen | |
| DE60021030T2 (de) | Kalziumhydroxid und Verfahren zur dessen Herstellung | |
| EP0025544B1 (de) | Thermoplastische Masse | |
| DE4117034A1 (de) | Kationische schichtverbindungen modifiziert mit polymeren | |
| DE964542C (de) | Vulkanisiermittel | |
| EP0069278B1 (de) | Verwendung von Zinksalzen des Mercaptobenzimidazols und Dithiophosphorsäureesters bei der Herstellung von Nitrilkautschuk-Polyvinylchlorid-Abmischungen | |
| DE2802531C2 (enExample) | ||
| DE68928674T2 (de) | Zusammensetzung zur Wärme- und Ultraviolettstabilisierung von thermoplastischen Harzen und thermoplastische Harze, die eine solche Stabilisatorzusammensetzung enthalten | |
| DE4103881C1 (enExample) | ||
| DE69516630T2 (de) | Harzzusammensetzung und Formkörper | |
| EP0644915B1 (de) | Verwendung von katoiten als stabilisatoren für polymere | |
| DE2856075A1 (de) | Vulkanisierbare fluorelastomermischungen und verfahren zu ihrer herstellung | |
| DE19860798A1 (de) | Zusammensetzung, enthaltend mindestens ein halogenhaltiges Polymer und einen Stabilisator | |
| DE69231571T2 (de) | Thermostabiles Ethylen-Kohlenmonoxid-Copolymer | |
| DE2652408C3 (de) | Wärmestabilisierung von Formmassen auf der Basis von Vinylchloridhomo- oder-copolymerisaten |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OP8 | Request for examination as to paragraph 44 patent law | ||
| D2 | Grant after examination | ||
| 8364 | No opposition during term of opposition |