EP2022877A1 - Fibre composite thermosoudable et son procédé de production - Google Patents
Fibre composite thermosoudable et son procédé de production Download PDFInfo
- Publication number
- EP2022877A1 EP2022877A1 EP07743519A EP07743519A EP2022877A1 EP 2022877 A1 EP2022877 A1 EP 2022877A1 EP 07743519 A EP07743519 A EP 07743519A EP 07743519 A EP07743519 A EP 07743519A EP 2022877 A1 EP2022877 A1 EP 2022877A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- thermal
- fiber
- adhesive
- resin component
- bicomponent fiber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 177
- 238000000034 method Methods 0.000 title description 42
- 239000002131 composite material Substances 0.000 title 1
- 239000000853 adhesive Substances 0.000 claims abstract description 77
- 239000004745 nonwoven fabric Substances 0.000 claims abstract description 61
- 239000004840 adhesive resin Substances 0.000 claims abstract description 42
- 229920006223 adhesive resin Polymers 0.000 claims abstract description 42
- 229920005989 resin Polymers 0.000 claims abstract description 36
- 239000011347 resin Substances 0.000 claims abstract description 36
- 229920000139 polyethylene terephthalate Polymers 0.000 claims abstract description 32
- 239000005020 polyethylene terephthalate Substances 0.000 claims abstract description 32
- 238000002844 melting Methods 0.000 claims abstract description 24
- 230000008018 melting Effects 0.000 claims abstract description 24
- -1 polyethylene terephthalate Polymers 0.000 claims abstract description 23
- 229920005992 thermoplastic resin Polymers 0.000 claims abstract description 13
- 238000004519 manufacturing process Methods 0.000 claims abstract description 9
- 239000000306 component Substances 0.000 claims description 84
- 238000009987 spinning Methods 0.000 claims description 28
- 239000008358 core component Substances 0.000 claims description 19
- 230000002040 relaxant effect Effects 0.000 claims description 15
- 238000010622 cold drawing Methods 0.000 claims description 10
- 230000009477 glass transition Effects 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 229920001634 Copolyester Polymers 0.000 claims description 6
- 229920005672 polyolefin resin Polymers 0.000 claims description 4
- 230000001070 adhesive effect Effects 0.000 abstract description 6
- 239000013078 crystal Substances 0.000 description 8
- 229920000642 polymer Polymers 0.000 description 7
- 239000002826 coolant Substances 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 238000007334 copolymerization reaction Methods 0.000 description 5
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 229920001903 high density polyethylene Polymers 0.000 description 4
- 239000004700 high-density polyethylene Substances 0.000 description 4
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 4
- 239000004743 Polypropylene Substances 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 238000009960 carding Methods 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 229920006038 crystalline resin Polymers 0.000 description 3
- 238000002425 crystallisation Methods 0.000 description 3
- 230000008025 crystallization Effects 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- 229920001169 thermoplastic Polymers 0.000 description 3
- 239000004416 thermosoftening plastic Substances 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000001276 controlling effect Effects 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- GWTCIAGIKURVBJ-UHFFFAOYSA-L dipotassium;dodecyl phosphate Chemical compound [K+].[K+].CCCCCCCCCCCCOP([O-])([O-])=O GWTCIAGIKURVBJ-UHFFFAOYSA-L 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000004049 embossing Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 229940033623 potassium lauryl phosphate Drugs 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 2
- NIDNOXCRFUCAKQ-RNGGSSJXSA-N (1r,2r,3s,4s)-bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1[C@@H]2C=C[C@H]1[C@H](C(=O)O)[C@@H]2C(O)=O NIDNOXCRFUCAKQ-RNGGSSJXSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- ISPYQTSUDJAMAB-UHFFFAOYSA-N 2-chlorophenol Chemical compound OC1=CC=CC=C1Cl ISPYQTSUDJAMAB-UHFFFAOYSA-N 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical group OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 238000010420 art technique Methods 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 description 1
- 229940018557 citraconic acid Drugs 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- PBOFFNYRKURMFP-UHFFFAOYSA-L dipotassium;5-sulfobenzene-1,3-dicarboxylate Chemical compound [K+].[K+].OS(=O)(=O)C1=CC(C([O-])=O)=CC(C([O-])=O)=C1 PBOFFNYRKURMFP-UHFFFAOYSA-L 0.000 description 1
- 229920006240 drawn fiber Polymers 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000012681 fiber drawing Methods 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- 239000012510 hollow fiber Substances 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- LDHQCZJRKDOVOX-IHWYPQMZSA-N isocrotonic acid Chemical compound C\C=C/C(O)=O LDHQCZJRKDOVOX-IHWYPQMZSA-N 0.000 description 1
- 229920000092 linear low density polyethylene Polymers 0.000 description 1
- 239000004707 linear low-density polyethylene Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 238000002074 melt spinning Methods 0.000 description 1
- HNEGQIOMVPPMNR-NSCUHMNNSA-N mesaconic acid Chemical compound OC(=O)C(/C)=C/C(O)=O HNEGQIOMVPPMNR-NSCUHMNNSA-N 0.000 description 1
- OJURWUUOVGOHJZ-UHFFFAOYSA-N methyl 2-[(2-acetyloxyphenyl)methyl-[2-[(2-acetyloxyphenyl)methyl-(2-methoxy-2-oxoethyl)amino]ethyl]amino]acetate Chemical compound C=1C=CC=C(OC(C)=O)C=1CN(CC(=O)OC)CCN(CC(=O)OC)CC1=CC=CC=C1OC(C)=O OJURWUUOVGOHJZ-UHFFFAOYSA-N 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- HNEGQIOMVPPMNR-UHFFFAOYSA-N methylfumaric acid Natural products OC(=O)C(C)=CC(O)=O HNEGQIOMVPPMNR-UHFFFAOYSA-N 0.000 description 1
- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 description 1
- YCWSUKQGVSGXJO-NTUHNPAUSA-N nifuroxazide Chemical group C1=CC(O)=CC=C1C(=O)N\N=C\C1=CC=C([N+]([O-])=O)O1 YCWSUKQGVSGXJO-NTUHNPAUSA-N 0.000 description 1
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 238000007712 rapid solidification Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- YXTFRJVQOWZDPP-UHFFFAOYSA-M sodium;3,5-dicarboxybenzenesulfonate Chemical compound [Na+].OC(=O)C1=CC(C(O)=O)=CC(S([O-])(=O)=O)=C1 YXTFRJVQOWZDPP-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/14—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/28—Formation of filaments, threads, or the like while mixing different spinning solutions or melts during the spinning operation; Spinnerette packs therefor
- D01D5/30—Conjugate filaments; Spinnerette packs therefor
- D01D5/34—Core-skin structure; Spinnerette packs therefor
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02J—FINISHING OR DRESSING OF FILAMENTS, YARNS, THREADS, CORDS, ROPES OR THE LIKE
- D02J1/00—Modifying the structure or properties resulting from a particular structure; Modifying, retaining, or restoring the physical form or cross-sectional shape, e.g. by use of dies or squeeze rollers
- D02J1/22—Stretching or tensioning, shrinking or relaxing, e.g. by use of overfeed and underfeed apparatus, or preventing stretch
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
- D04H1/541—Composite fibres, e.g. sheath-core, sea-island or side-by-side; Mixed fibres
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2929—Bicomponent, conjugate, composite or collateral fibers or filaments [i.e., coextruded sheath-core or side-by-side type]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/637—Including strand or fiber material which is a monofilament composed of two or more polymeric materials in physically distinct relationship [e.g., sheath-core, side-by-side, islands-in-sea, fibrils-in-matrix, etc.] or composed of physical blend of chemically different polymeric materials or a physical blend of a polymeric material and a filler material
- Y10T442/641—Sheath-core multicomponent strand or fiber material
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2006133794A JP4820211B2 (ja) | 2006-05-12 | 2006-05-12 | 自己伸長性熱接着性複合繊維及びその製造方法 |
PCT/JP2007/060084 WO2007132905A1 (fr) | 2006-05-12 | 2007-05-10 | Fibre composite thermosoudable et son procédé de production |
Publications (3)
Publication Number | Publication Date |
---|---|
EP2022877A1 true EP2022877A1 (fr) | 2009-02-11 |
EP2022877A4 EP2022877A4 (fr) | 2009-05-13 |
EP2022877B1 EP2022877B1 (fr) | 2010-04-28 |
Family
ID=38693994
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP20070743519 Not-in-force EP2022877B1 (fr) | 2006-05-12 | 2007-05-10 | Fibre composite thermosoudable et son procédé de production |
Country Status (12)
Country | Link |
---|---|
US (1) | US20090227166A1 (fr) |
EP (1) | EP2022877B1 (fr) |
JP (1) | JP4820211B2 (fr) |
KR (1) | KR101357446B1 (fr) |
CN (1) | CN101443491B (fr) |
AT (1) | ATE466122T1 (fr) |
DE (1) | DE602007006180D1 (fr) |
HK (2) | HK1127376A1 (fr) |
MY (1) | MY151200A (fr) |
RU (1) | RU2440447C2 (fr) |
TW (1) | TWI410540B (fr) |
WO (1) | WO2007132905A1 (fr) |
Families Citing this family (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5444681B2 (ja) * | 2007-10-19 | 2014-03-19 | Esファイバービジョンズ株式会社 | ポリエステル系熱融着性複合繊維 |
WO2010044241A1 (fr) * | 2008-10-14 | 2010-04-22 | 株式会社ワイ・ジー・ケー | Ligne de pêche comportant un fil composite intégré contenant des fibres courtes |
CN101961920B (zh) * | 2009-07-23 | 2015-08-19 | 上海启鹏工程材料科技有限公司 | 一种热固性纤维高分子复合材料二次成型的方法 |
JP2011038207A (ja) * | 2009-08-11 | 2011-02-24 | Unitika Ltd | 複合繊維 |
JP5143110B2 (ja) * | 2009-11-25 | 2013-02-13 | 株式会社Kosuge | 吸音材 |
US9689097B2 (en) * | 2012-05-31 | 2017-06-27 | Wm. T. Burnett Ip, Llc | Nonwoven composite fabric and panel made therefrom |
JP6112816B2 (ja) | 2012-09-28 | 2017-04-12 | ユニ・チャーム株式会社 | 吸収性物品 |
JP6021566B2 (ja) | 2012-09-28 | 2016-11-09 | ユニ・チャーム株式会社 | 吸収性物品 |
US10058808B2 (en) | 2012-10-22 | 2018-08-28 | Cummins Filtration Ip, Inc. | Composite filter media utilizing bicomponent fibers |
CN103866485B (zh) * | 2012-12-11 | 2017-07-28 | 东丽纤维研究所(中国)有限公司 | 一种热粘合无纺布及其生产方法和用途 |
JP6486095B2 (ja) * | 2014-12-18 | 2019-03-20 | 花王株式会社 | 不織布の製造方法 |
KR101646560B1 (ko) * | 2014-12-30 | 2016-08-08 | 도레이케미칼 주식회사 | 알칼리 이용해성 복합섬유 유래의 초박지용 폴리에스테르 바인더 섬유 |
KR101646557B1 (ko) * | 2014-12-31 | 2016-08-08 | 도레이케미칼 주식회사 | 수 이용해성 복합섬유 유래의 초박지용 폴리에스테르 바인더 섬유 |
JP6507043B2 (ja) * | 2015-06-19 | 2019-04-24 | Tmtマシナリー株式会社 | 紡糸引取装置 |
CN105769075A (zh) * | 2016-03-21 | 2016-07-20 | 苏州韩京姬科技有限公司 | 一种蒸汽旋转拖把 |
KR102426436B1 (ko) * | 2016-09-09 | 2022-07-29 | 도레이첨단소재 주식회사 | 압축성형체용 복합섬유 및 이의 제조방법 |
JP6228699B1 (ja) * | 2017-03-31 | 2017-11-08 | Esファイバービジョンズ株式会社 | 熱融着性複合繊維およびこれを用いた不織布 |
CN107663665B (zh) * | 2017-10-19 | 2019-06-25 | 浙江恒逸高新材料有限公司 | 一种高强低收缩特亮绣花线聚酯牵伸丝的制备方法 |
CN108842201A (zh) * | 2018-08-31 | 2018-11-20 | 江苏江南高纤股份有限公司 | 原木复合短纤维、其制备方法及纺丝系统 |
US20200131693A1 (en) * | 2018-10-24 | 2020-04-30 | Cornell University | Hydrophobic/oleophobic fabrics with directional liquid transport property |
JP7241279B2 (ja) * | 2019-03-15 | 2023-03-17 | 大和紡績株式会社 | 芯鞘型複合繊維、その製造方法、およびそれを含む繊維集合物 |
JP7009577B1 (ja) * | 2020-09-01 | 2022-01-25 | Esファイバービジョンズ株式会社 | 熱接着性複合繊維、その製造方法および熱接着性複合繊維を用いた不織布 |
JP6916360B1 (ja) * | 2020-09-24 | 2021-08-11 | Esファイバービジョンズ株式会社 | 熱接着性複合繊維、その製造方法および熱接着性複合繊維を用いた不織布 |
CN113337919A (zh) * | 2021-06-11 | 2021-09-03 | 江苏惠康特种纤维有限公司 | 一种高蓬松性超柔pet与pe复合纤维及其制备方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20030134115A1 (en) * | 2001-04-04 | 2003-07-17 | Hironori Goda | Polyester based thermally adhesive composite short fiber |
EP1985729A1 (fr) * | 2006-02-06 | 2008-10-29 | Teijin Fibers Limited | Fibre conjuguée thermocollable et son procédé de production |
EP1988201A1 (fr) * | 2006-02-06 | 2008-11-05 | Teijin Fibers Limited | Procédé de production de fibre polyester destinée à des nontissés aéroliques |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS57167418A (en) * | 1981-04-03 | 1982-10-15 | Kuraray Co Ltd | Heat bonding composite spun fiber |
JPH0726252B2 (ja) * | 1988-11-16 | 1995-03-22 | 帝人株式会社 | 熱接着性複合繊維 |
JPH0726253B2 (ja) * | 1988-11-21 | 1995-03-22 | 帝人株式会社 | 熱接着性複合繊維 |
JPH06228821A (ja) * | 1993-02-01 | 1994-08-16 | Unitika Ltd | 自己伸長性複合繊維,その混繊糸及びその混繊糸からなる布帛 |
JPH1060740A (ja) * | 1996-08-15 | 1998-03-03 | Unitika Ltd | ポリエステル系自己伸長性分割型複合繊維とその混繊糸及び布帛 |
JP3322868B1 (ja) * | 2001-08-09 | 2002-09-09 | 宇部日東化成株式会社 | 不織布用繊維と不織布及びこれらの製造方法 |
JP2004204900A (ja) * | 2002-12-24 | 2004-07-22 | Denso Corp | フランジ継手構造 |
JP3989468B2 (ja) * | 2004-06-14 | 2007-10-10 | 花王株式会社 | 立体賦形不織布 |
JP4339760B2 (ja) * | 2004-07-30 | 2009-10-07 | 帝人ファイバー株式会社 | 混繊糸および織編物 |
JP4758804B2 (ja) * | 2005-04-12 | 2011-08-31 | ダイワボウホールディングス株式会社 | 不織布 |
JP4948127B2 (ja) * | 2005-12-07 | 2012-06-06 | 花王株式会社 | 熱伸長性繊維 |
JP4881026B2 (ja) * | 2006-02-06 | 2012-02-22 | 帝人ファイバー株式会社 | エアレイド不織布用熱接着性複合繊維およびその製造方法 |
JP5021938B2 (ja) * | 2006-02-06 | 2012-09-12 | 帝人ファイバー株式会社 | 熱接着性複合繊維およびその製造方法 |
JP4856435B2 (ja) * | 2006-02-06 | 2012-01-18 | 帝人ファイバー株式会社 | 熱接着性複合繊維およびその製造方法 |
-
2006
- 2006-05-12 JP JP2006133794A patent/JP4820211B2/ja not_active Expired - Fee Related
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2007
- 2007-05-10 WO PCT/JP2007/060084 patent/WO2007132905A1/fr active Application Filing
- 2007-05-10 RU RU2008148973A patent/RU2440447C2/ru not_active IP Right Cessation
- 2007-05-10 CN CN200780017154XA patent/CN101443491B/zh not_active Expired - Fee Related
- 2007-05-10 KR KR1020087029803A patent/KR101357446B1/ko not_active IP Right Cessation
- 2007-05-10 DE DE200760006180 patent/DE602007006180D1/de active Active
- 2007-05-10 AT AT07743519T patent/ATE466122T1/de not_active IP Right Cessation
- 2007-05-10 EP EP20070743519 patent/EP2022877B1/fr not_active Not-in-force
- 2007-05-10 US US12/300,428 patent/US20090227166A1/en not_active Abandoned
- 2007-05-11 TW TW96116869A patent/TWI410540B/zh not_active IP Right Cessation
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- 2008-10-29 MY MYPI20084316A patent/MY151200A/en unknown
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- 2009-06-04 HK HK09105039A patent/HK1127376A1/xx not_active IP Right Cessation
- 2009-08-13 HK HK09107464A patent/HK1129431A1/xx not_active IP Right Cessation
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20030134115A1 (en) * | 2001-04-04 | 2003-07-17 | Hironori Goda | Polyester based thermally adhesive composite short fiber |
EP1985729A1 (fr) * | 2006-02-06 | 2008-10-29 | Teijin Fibers Limited | Fibre conjuguée thermocollable et son procédé de production |
EP1988201A1 (fr) * | 2006-02-06 | 2008-11-05 | Teijin Fibers Limited | Procédé de production de fibre polyester destinée à des nontissés aéroliques |
Non-Patent Citations (1)
Title |
---|
See also references of WO2007132905A1 * |
Also Published As
Publication number | Publication date |
---|---|
RU2008148973A (ru) | 2010-06-20 |
JP2007303035A (ja) | 2007-11-22 |
JP4820211B2 (ja) | 2011-11-24 |
CN101443491B (zh) | 2011-11-16 |
CN101443491A (zh) | 2009-05-27 |
US20090227166A1 (en) | 2009-09-10 |
TWI410540B (zh) | 2013-10-01 |
RU2440447C2 (ru) | 2012-01-20 |
KR20090010229A (ko) | 2009-01-29 |
MY151200A (en) | 2014-04-30 |
EP2022877A4 (fr) | 2009-05-13 |
WO2007132905A1 (fr) | 2007-11-22 |
TW200809022A (en) | 2008-02-16 |
DE602007006180D1 (de) | 2010-06-10 |
EP2022877B1 (fr) | 2010-04-28 |
HK1129431A1 (en) | 2009-11-27 |
HK1127376A1 (en) | 2009-09-25 |
KR101357446B1 (ko) | 2014-02-03 |
ATE466122T1 (de) | 2010-05-15 |
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