DE60011122T2 - Röntgenundurchlässige dentalmaterialien mit nano-teilchen - Google Patents
Röntgenundurchlässige dentalmaterialien mit nano-teilchen Download PDFInfo
- Publication number
- DE60011122T2 DE60011122T2 DE60011122T DE60011122T DE60011122T2 DE 60011122 T2 DE60011122 T2 DE 60011122T2 DE 60011122 T DE60011122 T DE 60011122T DE 60011122 T DE60011122 T DE 60011122T DE 60011122 T2 DE60011122 T2 DE 60011122T2
- Authority
- DE
- Germany
- Prior art keywords
- particles
- heavy metal
- dental
- metal oxide
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 239000005548 dental material Substances 0.000 title claims description 144
- 239000002105 nanoparticle Substances 0.000 title 1
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- 238000004519 manufacturing process Methods 0.000 claims description 9
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 186
- 239000000203 mixture Substances 0.000 description 79
- 239000000523 sample Substances 0.000 description 69
- -1 zirconium carboxylates Chemical class 0.000 description 68
- 238000000034 method Methods 0.000 description 66
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- DUFCMRCMPHIFTR-UHFFFAOYSA-N 5-(dimethylsulfamoyl)-2-methylfuran-3-carboxylic acid Chemical compound CN(C)S(=O)(=O)C1=CC(C(O)=O)=C(C)O1 DUFCMRCMPHIFTR-UHFFFAOYSA-N 0.000 description 7
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- KUBDPQJOLOUJRM-UHFFFAOYSA-N 2-(chloromethyl)oxirane;4-[2-(4-hydroxyphenyl)propan-2-yl]phenol Chemical compound ClCC1CO1.C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 KUBDPQJOLOUJRM-UHFFFAOYSA-N 0.000 description 5
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- OZLBDYMWFAHSOQ-UHFFFAOYSA-N diphenyliodanium Chemical class C=1C=CC=CC=1[I+]C1=CC=CC=C1 OZLBDYMWFAHSOQ-UHFFFAOYSA-N 0.000 description 5
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- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 5
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- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 5
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- 125000005373 siloxane group Chemical group [SiH2](O*)* 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 238000003980 solgel method Methods 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 229940014800 succinic anhydride Drugs 0.000 description 1
- 150000003455 sulfinic acids Chemical class 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium Chemical compound [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical compound FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- QEMXHQIAXOOASZ-UHFFFAOYSA-N tetramethylammonium Chemical compound C[N+](C)(C)C QEMXHQIAXOOASZ-UHFFFAOYSA-N 0.000 description 1
- 238000001029 thermal curing Methods 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000001016 thiazine dye Substances 0.000 description 1
- 239000001017 thiazole dye Substances 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 150000003585 thioureas Chemical class 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- YXFVVABEGXRONW-UHFFFAOYSA-N toluene Substances CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- DQFBYFPFKXHELB-VAWYXSNFSA-N trans-chalcone Chemical compound C=1C=CC=CC=1C(=O)\C=C\C1=CC=CC=C1 DQFBYFPFKXHELB-VAWYXSNFSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000004627 transmission electron microscopy Methods 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- HVYVMSPIJIWUNA-UHFFFAOYSA-N triphenylstibine Chemical compound C1=CC=CC=C1[Sb](C=1C=CC=CC=1)C1=CC=CC=C1 HVYVMSPIJIWUNA-UHFFFAOYSA-N 0.000 description 1
- WLOQLWBIJZDHET-UHFFFAOYSA-N triphenylsulfonium Chemical compound C1=CC=CC=C1[S+](C=1C=CC=CC=1)C1=CC=CC=C1 WLOQLWBIJZDHET-UHFFFAOYSA-N 0.000 description 1
- 239000012953 triphenylsulfonium Substances 0.000 description 1
- XREXPQGDOPQPAH-QKUPJAQQSA-K trisodium;[(z)-18-[1,3-bis[[(z)-12-sulfonatooxyoctadec-9-enoyl]oxy]propan-2-yloxy]-18-oxooctadec-9-en-7-yl] sulfate Chemical compound [Na+].[Na+].[Na+].CCCCCCC(OS([O-])(=O)=O)C\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CC(CCCCCC)OS([O-])(=O)=O)COC(=O)CCCCCCC\C=C/CC(CCCCCC)OS([O-])(=O)=O XREXPQGDOPQPAH-QKUPJAQQSA-K 0.000 description 1
- 238000000108 ultra-filtration Methods 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- XKGLSKVNOSHTAD-UHFFFAOYSA-N valerophenone Chemical compound CCCCC(=O)C1=CC=CC=C1 XKGLSKVNOSHTAD-UHFFFAOYSA-N 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 239000012991 xanthate Substances 0.000 description 1
- 239000001018 xanthene dye Substances 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 1
- XJUNLJFOHNHSAR-UHFFFAOYSA-J zirconium(4+);dicarbonate Chemical class [Zr+4].[O-]C([O-])=O.[O-]C([O-])=O XJUNLJFOHNHSAR-UHFFFAOYSA-J 0.000 description 1
- SXPUVBFQXJHYNS-UHFFFAOYSA-N α-furil Chemical compound C=1C=COC=1C(=O)C(=O)C1=CC=CO1 SXPUVBFQXJHYNS-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/20—Protective coatings for natural or artificial teeth, e.g. sealings, dye coatings or varnish
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/30—Compositions for temporarily or permanently fixing teeth or palates, e.g. primers for dental adhesives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/70—Preparations for dentistry comprising inorganic additives
- A61K6/71—Fillers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
- A61K6/884—Preparations for artificial teeth, for filling teeth or for capping teeth comprising natural or synthetic resins
- A61K6/887—Compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
- A61K6/884—Preparations for artificial teeth, for filling teeth or for capping teeth comprising natural or synthetic resins
- A61K6/891—Compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S522/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S522/908—Dental utility
Landscapes
- Health & Medical Sciences (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Epidemiology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Plastic & Reconstructive Surgery (AREA)
- Nanotechnology (AREA)
- Physics & Mathematics (AREA)
- Inorganic Chemistry (AREA)
- Composite Materials (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Dental Preparations (AREA)
- Dental Prosthetics (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/429,185 US6387981B1 (en) | 1999-10-28 | 1999-10-28 | Radiopaque dental materials with nano-sized particles |
| US429185 | 1999-10-28 | ||
| PCT/US2000/004566 WO2001030305A1 (en) | 1999-10-28 | 2000-02-22 | Radiopaque dental materials with nano-sized particles |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE60011122D1 DE60011122D1 (de) | 2004-07-01 |
| DE60011122T2 true DE60011122T2 (de) | 2005-01-05 |
Family
ID=23702168
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE60011122T Expired - Lifetime DE60011122T2 (de) | 1999-10-28 | 2000-02-22 | Röntgenundurchlässige dentalmaterialien mit nano-teilchen |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US6387981B1 (enExample) |
| EP (1) | EP1225867B1 (enExample) |
| JP (2) | JP2003512405A (enExample) |
| AU (1) | AU3241500A (enExample) |
| CA (1) | CA2387474C (enExample) |
| DE (1) | DE60011122T2 (enExample) |
| WO (1) | WO2001030305A1 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102005019600A1 (de) * | 2005-04-27 | 2006-11-09 | Ivoclar Vivadent Ag | Oberflächenmodifizierte Füllstoffe |
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| US6933331B2 (en) * | 1998-05-22 | 2005-08-23 | Nanoproducts Corporation | Nanotechnology for drug delivery, contrast agents and biomedical implants |
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| US7476889B2 (en) * | 1998-12-07 | 2009-01-13 | Meridian Research And Development | Radiation detectable and protective articles |
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| DE60022667T2 (de) * | 1999-10-28 | 2006-06-14 | 3M Innovative Properties Co | Dentalmaterialien mit siliciumdioxid-nanoteilchen |
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| US8129443B2 (en) * | 2000-08-11 | 2012-03-06 | Sun Medical Co., Ltd. | Polymerizable composition, cured object obtained therefrom, and composite material |
| DE10042050A1 (de) * | 2000-08-26 | 2002-03-14 | Degussa | Dentalkomposite aufweisend Hybridfüllstoffe und Verfahren zur Herstellung |
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| US7241856B2 (en) * | 2003-06-02 | 2007-07-10 | Pentron Clinical Technologies Llc | Dental resins, dental composite materials, and method of manufacture thereof |
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| US6787629B2 (en) | 2001-11-02 | 2004-09-07 | Pentron Clinical Technologies, Llc | Dental resin materials, method of manufacture, and uses thereof |
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| ITTO20011191A1 (it) * | 2001-12-18 | 2003-06-18 | Itw Ind Components Srl | Dispositivo di servizio per un frigorifero e frigorifero provvisto ditale dispositivo. |
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| TWI236374B (en) * | 2003-02-13 | 2005-07-21 | Univ Nat Taiwan | Light curable epoxy nano composite for dental restorative material |
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| DE60305025T2 (de) | 2003-07-14 | 2006-10-12 | 3M Espe Ag | Klebstoffzusammensetzung mit verringerter Polarität nach der Polymerisation |
| FR2857668B1 (fr) * | 2003-07-16 | 2006-01-13 | Commissariat Energie Atomique | Composition photopolymerisable a base d'une resine expoxyvinylester et d'une resine urethane acrylate et utilisation de ladite composition pour realiser des preformes et/ou des maquettes de protheses dentaires. |
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| EP1706086A1 (en) * | 2004-01-21 | 2006-10-04 | 3M Innovative Properties Company | Dental compositions and kits containing bitterness inhibitors, and related methods |
| DE102005002845A1 (de) * | 2004-02-18 | 2005-09-15 | Heraeus Kulzer Gmbh | Dispersionen nanoskaliger, nicht-agglomerierter Teilchen zum Einsatz in Dentalmaterialien |
| DE102004017124B4 (de) * | 2004-04-07 | 2008-07-10 | Ivoclar Vivadent Ag | Härtbare Dentalmaterialien mit einer einstellbaren Transluzenz und hohen Opaleszenz |
| PL1737415T3 (pl) * | 2004-04-15 | 2008-10-31 | Dentofit As | Ultradźwiękowe utwardzanie stomatologicznych materiałów wypełniających |
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| US7825167B2 (en) * | 2004-07-14 | 2010-11-02 | 3M Espe Ag | Dental composition containing unsaturated halogenated aryl alkyl ether components |
| ATE447924T1 (de) * | 2004-07-14 | 2009-11-15 | 3M Innovative Properties Co | Dentalzusammensetzungen mit carbosilan-monomeren |
| CN101060827A (zh) * | 2004-07-14 | 2007-10-24 | 3M埃斯佩股份公司 | 包括环氧基官能的碳硅烷化合物的牙科组合物 |
| US7458384B1 (en) * | 2004-07-15 | 2008-12-02 | University Of Central Florida Research Foundation, Inc. | Surfactant incorporated nanostructure for pressure drop reduction in oil and gas lines |
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| US20060204452A1 (en) * | 2005-03-10 | 2006-09-14 | Velamakanni Bhaskar V | Antimicrobial film-forming dental compositions and methods |
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| ES2412379T3 (es) | 2005-04-25 | 2013-07-11 | G&G Biotechnology Ltd. | Dispositivo protésico implantable ligero. |
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| EP4067381A1 (en) | 2021-04-01 | 2022-10-05 | Julius-Maximilians-Universität Würzburg | Novel tnfr2 binding molecules |
| EP4444809A1 (en) | 2021-12-06 | 2024-10-16 | 3M Innovative Properties Company | Adhesives comprising cyclic imide addition-fragmentation and adhesion agents |
| JP7660768B2 (ja) | 2021-12-06 | 2025-04-11 | ソルベンタム インテレクチュアル プロパティズ カンパニー | 歯科用組成物 |
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-
1999
- 1999-10-28 US US09/429,185 patent/US6387981B1/en not_active Expired - Lifetime
-
2000
- 2000-02-22 CA CA2387474A patent/CA2387474C/en not_active Expired - Fee Related
- 2000-02-22 JP JP2001532725A patent/JP2003512405A/ja not_active Withdrawn
- 2000-02-22 DE DE60011122T patent/DE60011122T2/de not_active Expired - Lifetime
- 2000-02-22 WO PCT/US2000/004566 patent/WO2001030305A1/en not_active Ceased
- 2000-02-22 AU AU32415/00A patent/AU3241500A/en not_active Abandoned
- 2000-02-22 EP EP00910298A patent/EP1225867B1/en not_active Expired - Lifetime
-
2011
- 2011-05-11 JP JP2011106466A patent/JP5563520B2/ja not_active Expired - Lifetime
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102005019600A1 (de) * | 2005-04-27 | 2006-11-09 | Ivoclar Vivadent Ag | Oberflächenmodifizierte Füllstoffe |
| US8367748B2 (en) | 2005-04-27 | 2013-02-05 | Ivoclar Vivadent Ag | Surface-modified fillers |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2003512405A (ja) | 2003-04-02 |
| CA2387474C (en) | 2011-01-04 |
| AU3241500A (en) | 2001-05-08 |
| JP2011207890A (ja) | 2011-10-20 |
| JP5563520B2 (ja) | 2014-07-30 |
| US6387981B1 (en) | 2002-05-14 |
| DE60011122D1 (de) | 2004-07-01 |
| WO2001030305A1 (en) | 2001-05-03 |
| CA2387474A1 (en) | 2001-05-03 |
| EP1225867A1 (en) | 2002-07-31 |
| EP1225867B1 (en) | 2004-05-26 |
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