DE3784999D1 - - Google Patents

Info

Publication number
DE3784999D1
DE3784999D1 DE87309925T DE3784999T DE3784999D1 DE 3784999 D1 DE3784999 D1 DE 3784999D1 DE 87309925 T DE87309925 T DE 87309925T DE 3784999 T DE3784999 T DE 3784999T DE 3784999 D1 DE3784999 D1 DE 3784999D1
Authority
DE
Germany
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE87309925T
Other languages
German (de)
Other versions
DE3784999T2 (de
Inventor
Satoru Kumazawa
Susumu Shimizu
Hiroyuki Enari
Atsushi Iwaki-Shi Fukushima-Ken Jp Ito
Susumu Naka-Gun Kanagawa-Ken Jp Ikeda
Nobuo Sato
Toshihide Iwaki-Shi Fukushima-Ken Jp Saishoji
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kureha Corp
Original Assignee
Kureha Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kureha Corp filed Critical Kureha Corp
Publication of DE3784999D1 publication Critical patent/DE3784999D1/de
Application granted granted Critical
Publication of DE3784999T2 publication Critical patent/DE3784999T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/12—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
    • A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/28—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C25/00—Compounds containing at least one halogen atom bound to a six-membered aromatic ring
    • C07C25/18—Polycyclic aromatic halogenated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/673—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by change of size of the carbon skeleton
    • C07C45/676—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by change of size of the carbon skeleton by elimination of carboxyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
    • C07C49/657—Unsaturated compounds containing a keto groups being part of a ring containing six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
    • C07C49/687—Unsaturated compounds containing a keto groups being part of a ring containing halogen
    • C07C49/697—Unsaturated compounds containing a keto groups being part of a ring containing halogen containing six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
    • C07D233/56—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
    • C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
    • C07D249/08—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/08—Compounds containing oxirane rings with hydrocarbon radicals, substituted by halogen atoms, nitro radicals or nitroso radicals

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Environmental Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Plant Pathology (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Epoxy Compounds (AREA)
DE8787309925T 1986-11-10 1987-11-10 Azol-derivate verwendbar zur kontrolle von pflanzenkrankheiten und regulierung von pflanzenwachstum. Expired - Lifetime DE3784999T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP26555986 1986-11-10
JP16112687 1987-06-30
JP62271277A JPH0625140B2 (ja) 1986-11-10 1987-10-27 新規アゾール誘導体、その製造方法及び該誘導体の農園芸用薬剤

Publications (2)

Publication Number Publication Date
DE3784999D1 true DE3784999D1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 1993-04-29
DE3784999T2 DE3784999T2 (de) 1993-07-01

Family

ID=27321802

Family Applications (1)

Application Number Title Priority Date Filing Date
DE8787309925T Expired - Lifetime DE3784999T2 (de) 1986-11-10 1987-11-10 Azol-derivate verwendbar zur kontrolle von pflanzenkrankheiten und regulierung von pflanzenwachstum.

Country Status (9)

Country Link
US (3) US4938792A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
EP (1) EP0267778B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
JP (1) JPH0625140B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
AU (1) AU584530B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
BR (1) BR8706104A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
CA (1) CA1331006C (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
DE (1) DE3784999T2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
DK (1) DK171542B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
ES (1) ES2053564T3 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)

Families Citing this family (121)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0819108B2 (ja) * 1986-12-22 1996-02-28 呉羽化学工業株式会社 新規アゾ−ル誘導体、その製造法及び該誘導体を活性成分として含有する農園芸用殺菌剤
JPH0696530B2 (ja) * 1987-06-05 1994-11-30 呉羽化学工業株式会社 アゾール抗真菌剤
US5240955A (en) * 1987-06-05 1993-08-31 Kureha Kagaku Kogyo Kabushiki Kaisha Azole derivative and azole mycocide
JPH0739396B2 (ja) * 1988-01-14 1995-05-01 呉羽化学工業株式会社 新規アゾール置換シクロアルカノール誘導体、その製造法及び該誘導体の農園芸用殺菌剤としての利用
JPH0762001B2 (ja) * 1988-02-16 1995-07-05 呉羽化学工業株式会社 アゾリルメチルシクロアルカノール誘導体の製造法
US5292764A (en) * 1988-05-10 1994-03-08 Kureha Kagaku Kogyo K.K. Azole derivatives for protecting industrial materials from bacteria
GB2225006B (en) 1988-08-31 1992-02-12 Shell Int Research Process for the preparation of cyclopentane derivatives
CA1339611C (en) * 1988-08-31 1997-12-30 Paul Howard Briner Cyclopentane derivatives
US5262543A (en) * 1988-08-31 1993-11-16 Kureha Kagaku Kogyu Kabushiki Kaisha Process for the preparation of cyclopentane derivatives
GB8820603D0 (en) * 1988-08-31 1988-09-28 Shell Int Research Cyclopentane derivatives
FR2649101B1 (fr) * 1989-06-30 1994-10-28 Rhone Poulenc Agrochimie Azolylmethylcyclohexane benzilidene et utilisation comme fongicide
FR2641277B1 (fr) * 1988-12-29 1994-08-26 Rhone Poulenc Agrochimie Azolylmethylcyclopentane ou cyclopentene benzolidene et utilisation comme fongicide
US5256683A (en) * 1988-12-29 1993-10-26 Rhone-Poulenc Agrochimie Fungicidal compositions containing (benzylidene)-azolylmethylcycloalkane
MA21706A1 (fr) * 1988-12-29 1990-07-01 Rhone Poulenc Agrochimie Benzolidene azolylmethylcycloalcane et utilisation comme fongicide.
FR2649700B2 (fr) * 1988-12-29 1994-10-14 Rhone Poulenc Agrochimie Azolylmethylcyclopentane benzilidene et utilisation comme fongicide
JP2637824B2 (ja) * 1989-08-15 1997-08-06 呉羽化学工業株式会社 新規アゾール置換シクロアルカノール誘導体、その製造法及び該誘導体の農園芸用殺菌剤
US5264450A (en) * 1989-08-15 1993-11-23 Kureha Kagaku Kogyo Kabushiki Kaisha Imidazole substituted cycloalkanol derivatives and fungicidal compositions containing same
JPH03197464A (ja) * 1989-12-16 1991-08-28 Basf Ag 置換アゾリルメチルシクロアルカノール及びこれを含有する殺菌剤
FR2662911B1 (fr) * 1990-06-12 1996-12-13 Rhone Poulenc Agrochimie Procede pour proteger les produits de multiplication des vegetaux et les vegetaux en resultant au moyen d'un triazolyl cyclopentanol.
FR2663196A1 (fr) * 1990-06-13 1991-12-20 Rhone Poulenc Agrochimie Composition fongicide a base d'un triazole et d'une autre matiere active pour le traitement des semences.
FR2663195A1 (fr) * 1990-06-13 1991-12-20 Rhone Poulenc Agrochimie Procede de traitement fongicide foliaire au moyen d'un triazole et composition fongicide pour mettre en óoeuvre le procede.
GB9019191D0 (en) * 1990-09-03 1990-10-17 Shell Int Research Cyclopentanol derivatives
TW221288B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * 1990-09-03 1994-02-21 Shell Int Research
US5200535A (en) * 1990-09-03 1993-04-06 Shell Research Limited Cyclohexanone derivatives
JPH04202190A (ja) * 1990-11-30 1992-07-22 Kureha Chem Ind Co Ltd 光学活性トリアゾール誘導体及び殺菌剤
DE69124482T2 (de) * 1990-11-30 1997-05-15 Kureha Chemical Ind Co Ltd Azolylmethyloxabicyclohexane Derivate, ihre Zwischenprodukte und fungizide Zusammensetzungen
JP2938223B2 (ja) * 1991-06-07 1999-08-23 呉羽化学工業株式会社 切花の鮮度保持剤及び鮮度保持方法
GB9116557D0 (en) * 1991-07-31 1991-09-11 Shell Int Research Fungicidal compositions
JPH0826012B2 (ja) * 1991-08-23 1996-03-13 呉羽化学工業株式会社 新規な１，３，２−ジオキサチオランｓ酸化物誘導体、その製造方法及びその用途
JPH0784413B2 (ja) * 1991-09-18 1995-09-13 呉羽化学工業株式会社 ３−（無置換または置換ベンジル）−１−アルキル−２−オキソシクロペンタンカルボン酸アルキルエステル誘導体、その製造方法、殺菌剤及び中間体としての利用
JP2700595B2 (ja) * 1992-05-21 1998-01-21 呉羽化学工業株式会社 アゾール誘導体を含有する抗アロマターゼ剤
JP2719679B2 (ja) * 1992-06-06 1998-02-25 呉羽化学工業株式会社 新規アゾール誘導体、その製造方法並びに該誘導体を含有する抗真菌剤及び抗アロマターゼ剤
JPH06100542A (ja) * 1992-09-24 1994-04-12 Kureha Chem Ind Co Ltd （アゾリルメチル）（ビフェニルメチル）シクロペンタノール誘導体の製造方法
FR2704388B1 (fr) * 1993-04-27 1995-06-09 Rhone Poulenc Agrochimie Procede pour ameliorer la vigueur et ou la sante des vegetaux tels que les cereales par action d'un derive de type triazole.
JPH0782219A (ja) * 1993-09-14 1995-03-28 Kureha Chem Ind Co Ltd ３−（無置換または置換ベンジリデン）−１−アルキル−２−オキソシクロペンタンカルボン酸アルキルエステル誘導体、その製造方法、殺菌剤及び中間体としての利用
JPH07112973A (ja) * 1993-10-13 1995-05-02 Kureha Chem Ind Co Ltd アゾリルメチルシクロペンタノール誘導体の精製法
JPH07138234A (ja) * 1993-11-11 1995-05-30 Kureha Chem Ind Co Ltd アゾリルメチルシクロアルカノール誘導体の製造方法
JPH07138160A (ja) * 1993-11-18 1995-05-30 Kureha Chem Ind Co Ltd アゾール誘導体を含有する抗アロマターゼ剤
TW286264B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 1994-05-20 1996-09-21 Ciba Geigy Ag
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DE4425948A1 (de) * 1994-07-21 1996-01-25 Bayer Ag Azolylmethyl-substituierte Cycloalkanole oder Mikrobzide
DE4425949A1 (de) * 1994-07-21 1996-01-25 Bayer Ag Azolylmethylcyclopentanol-Derivate als Mikrobizide
JPH08245517A (ja) * 1995-03-10 1996-09-24 Kureha Chem Ind Co Ltd アルキルシクロペンタノン誘導体の製造方法
DE19520098A1 (de) * 1995-06-01 1996-12-05 Bayer Ag Triazolylmethyl-cyclopentanole
DE19617282A1 (de) * 1996-04-30 1997-11-06 Bayer Ag Triazolyl-mercaptide
DE19617461A1 (de) 1996-05-02 1997-11-06 Bayer Ag Acylmercapto-triazolyl-Derivate
DE19619544A1 (de) * 1996-05-15 1997-11-20 Bayer Ag Triazolyl-Disulfide
DE19620408A1 (de) * 1996-05-21 1997-11-27 Bayer Ag Mercapto-imidazolyl-Derivate
DE19620407A1 (de) * 1996-05-21 1997-11-27 Bayer Ag Thiocyano-triazolyl-Derivate
DE19620590A1 (de) * 1996-05-22 1997-11-27 Bayer Ag Sulfonyl-mercapto-triazolyl-Derivate
US6096769A (en) * 1998-04-20 2000-08-01 American Cyanamid Company Fungicidal co-formulation
US5968964A (en) * 1998-07-01 1999-10-19 American Cyanamid Company Fungicidal liquid formulation
TW591012B (en) * 1999-08-13 2004-06-11 Kureha Chemical Ind Co Ltd Process for producing 5-[(4-chlorophenyl)methyl]-2,2-dimethylcyclopentanone
US6872736B1 (en) 2000-01-26 2005-03-29 Basf Aktiengesellschaft Non-aqueous emulsifiable concentrate formulation
US6344580B1 (en) * 2000-06-12 2002-02-05 Basf Aktiengesellschaft Process for the preparation of 2,2-dimethyl-5-(4-chlorobenzyl) cyclopentanone and an intermediate useful therefore
CZ303562B6 (cs) * 2000-08-11 2012-12-12 Kureha Corporation Zpusob výroby 5-[(4-chlorfenyl)methyl]-2,2-dimethylcyklopentanonu
PL219689B1 (pl) * 2002-03-07 2015-06-30 Basf Ag Mieszanina grzybobójcza zawierająca protiokonazol oraz tritikonazol, sposób zwalczania szkodliwych grzybów i środek grzybobójczy
BR0308830A (pt) * 2002-04-05 2005-01-25 Basf Ag Mistura fungicida, processo para combater nocivos, e, agente fungicida
PL209421B1 (pl) * 2002-07-10 2011-08-31 Basf Ag Mieszanina grzybobójcza na bazie ditianonu, środek grzybobójczy, sposób zwalczania szkodliwych grzybów i zastosowanie
DE10248335A1 (de) 2002-10-17 2004-05-06 Bayer Ag Fungizide Wirkstoffkombinationen
CA2472806A1 (en) 2004-05-18 2005-11-18 Petro-Canada Compositions and methods for treating turf insect pests and diseases such as fungal infestations
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US9357768B2 (en) 2006-10-05 2016-06-07 Suncor Energy Inc. Herbicidal composition with increased herbicidal efficacy
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AU2009261903B2 (en) 2008-06-26 2013-12-05 Nutrien Ag Solutions (Canada) Inc. Improved turfgrass fungicide formulation with pigment
JP5530428B2 (ja) 2008-07-04 2014-06-25 ビーエーエスエフ ソシエタス・ヨーロピア 置換１−メチルピラゾール−４−イルカルボキシアニリドを含んでいる殺菌剤混合物
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JP5365158B2 (ja) * 2008-11-25 2013-12-11 住友化学株式会社 植物病害防除用組成物及び植物病害の防除方法
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WO2010122169A1 (en) * 2009-04-24 2010-10-28 Basf Se 5-mercapto- [1,2, 4] triazole compounds and their agricultural and pharmaceutical uses
US20120077676A1 (en) 2009-06-12 2012-03-29 Basf Se Antifungal 1,2,4-Triazolyl Derivatives Having a 5-Sulfur Substituent
US20120088664A1 (en) 2009-06-18 2012-04-12 Basf Se Antifungal 1,2,4-triazolyl derivatives having a 5-sulfur subtituent
JP2012530109A (ja) 2009-06-18 2012-11-29 ビーエーエスエフ ソシエタス・ヨーロピア 抗菌性１，２，４−トリアゾリル誘導体
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DE3784999T2 (de) 1993-07-01
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DK171542B1 (da) 1996-12-30
US5028254A (en) 1991-07-02
US5159118A (en) 1992-10-27
EP0267778B1 (en) 1993-03-24
US4938792A (en) 1990-07-03
ES2053564T3 (es) 1994-08-01
CA1331006C (en) 1994-07-26
DK588687A (da) 1988-05-11
JPH0193574A (ja) 1989-04-12
DK588687D0 (da) 1987-11-10
BR8706104A (pt) 1988-06-14
EP0267778A2 (en) 1988-05-18
AU584530B2 (en) 1989-05-25

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