DE3032611C2 - Organische Seltenerdsalzleuchtstoffe - Google Patents
Organische SeltenerdsalzleuchtstoffeInfo
- Publication number
- DE3032611C2 DE3032611C2 DE3032611A DE3032611A DE3032611C2 DE 3032611 C2 DE3032611 C2 DE 3032611C2 DE 3032611 A DE3032611 A DE 3032611A DE 3032611 A DE3032611 A DE 3032611A DE 3032611 C2 DE3032611 C2 DE 3032611C2
- Authority
- DE
- Germany
- Prior art keywords
- acid
- salt
- europium
- doped
- rare earth
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910052761 rare earth metal Inorganic materials 0.000 title claims description 63
- -1 rare earth salt Chemical class 0.000 title claims description 51
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 32
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 22
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 13
- 125000000962 organic group Chemical group 0.000 claims description 11
- 150000002909 rare earth metal compounds Chemical class 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 description 139
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 84
- WBYWAXJHAXSJNI-VOTSOKGWSA-M .beta-Phenylacrylic acid Natural products [O-]C(=O)\C=C\C1=CC=CC=C1 WBYWAXJHAXSJNI-VOTSOKGWSA-M 0.000 description 83
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 description 75
- 229910052693 Europium Inorganic materials 0.000 description 74
- 238000004020 luminiscence type Methods 0.000 description 58
- 239000000243 solution Substances 0.000 description 51
- 230000000052 comparative effect Effects 0.000 description 47
- 239000000843 powder Substances 0.000 description 47
- 238000010586 diagram Methods 0.000 description 45
- 235000013985 cinnamic acid Nutrition 0.000 description 43
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 description 43
- WBYWAXJHAXSJNI-SREVYHEPSA-N Cinnamic acid Chemical compound OC(=O)\C=C/C1=CC=CC=C1 WBYWAXJHAXSJNI-SREVYHEPSA-N 0.000 description 42
- 229930016911 cinnamic acid Natural products 0.000 description 42
- 229940114081 cinnamate Drugs 0.000 description 39
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 33
- 230000021615 conjugation Effects 0.000 description 32
- LPNBBFKOUUSUDB-UHFFFAOYSA-N p-toluic acid Chemical compound CC1=CC=C(C(O)=O)C=C1 LPNBBFKOUUSUDB-UHFFFAOYSA-N 0.000 description 32
- 239000008213 purified water Substances 0.000 description 29
- NNMXSTWQJRPBJZ-UHFFFAOYSA-K europium(iii) chloride Chemical compound Cl[Eu](Cl)Cl NNMXSTWQJRPBJZ-UHFFFAOYSA-K 0.000 description 28
- 229910052751 metal Inorganic materials 0.000 description 28
- 150000002910 rare earth metals Chemical class 0.000 description 27
- 239000000463 material Substances 0.000 description 26
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 25
- 238000000034 method Methods 0.000 description 24
- 238000012360 testing method Methods 0.000 description 23
- 230000005284 excitation Effects 0.000 description 22
- 239000002184 metal Substances 0.000 description 22
- 229910052771 Terbium Inorganic materials 0.000 description 20
- 239000007864 aqueous solution Substances 0.000 description 20
- 238000006243 chemical reaction Methods 0.000 description 20
- 239000000203 mixture Substances 0.000 description 20
- GZCRRIHWUXGPOV-UHFFFAOYSA-N terbium atom Chemical compound [Tb] GZCRRIHWUXGPOV-UHFFFAOYSA-N 0.000 description 20
- 238000003756 stirring Methods 0.000 description 18
- ICAKDTKJOYSXGC-UHFFFAOYSA-K lanthanum(iii) chloride Chemical compound Cl[La](Cl)Cl ICAKDTKJOYSXGC-UHFFFAOYSA-K 0.000 description 17
- 229910052727 yttrium Inorganic materials 0.000 description 16
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 16
- 150000001735 carboxylic acids Chemical class 0.000 description 15
- 239000000047 product Substances 0.000 description 15
- DXIHILNWDOYYCH-UHDJGPCESA-M sodium;(e)-3-phenylprop-2-enoate Chemical compound [Na+].[O-]C(=O)\C=C\C1=CC=CC=C1 DXIHILNWDOYYCH-UHDJGPCESA-M 0.000 description 15
- 229910052688 Gadolinium Inorganic materials 0.000 description 14
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 14
- 150000001875 compounds Chemical class 0.000 description 14
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 14
- UIWYJDYFSGRHKR-UHFFFAOYSA-N gadolinium atom Chemical compound [Gd] UIWYJDYFSGRHKR-UHFFFAOYSA-N 0.000 description 13
- 229910052746 lanthanum Inorganic materials 0.000 description 13
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 13
- GPSDUZXPYCFOSQ-UHFFFAOYSA-N m-toluic acid Chemical compound CC1=CC=CC(C(O)=O)=C1 GPSDUZXPYCFOSQ-UHFFFAOYSA-N 0.000 description 13
- SIOXPEMLGUPBBT-UHFFFAOYSA-N picolinic acid Chemical compound OC(=O)C1=CC=CC=N1 SIOXPEMLGUPBBT-UHFFFAOYSA-N 0.000 description 12
- 238000002474 experimental method Methods 0.000 description 11
- 239000006069 physical mixture Substances 0.000 description 11
- 239000011521 glass Substances 0.000 description 10
- 238000004519 manufacturing process Methods 0.000 description 10
- 229910052712 strontium Inorganic materials 0.000 description 10
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 10
- 239000000126 substance Substances 0.000 description 10
- VLSRUFWCGBMYDJ-ONEGZZNKSA-N (e)-3-(3,5-dimethoxyphenyl)prop-2-enoic acid Chemical compound COC1=CC(OC)=CC(\C=C\C(O)=O)=C1 VLSRUFWCGBMYDJ-ONEGZZNKSA-N 0.000 description 9
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 9
- 229910052791 calcium Inorganic materials 0.000 description 9
- 239000011575 calcium Substances 0.000 description 9
- 238000002329 infrared spectrum Methods 0.000 description 9
- 229910052788 barium Inorganic materials 0.000 description 8
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 8
- 230000008569 process Effects 0.000 description 8
- GFISHBQNVWAVFU-UHFFFAOYSA-K terbium(iii) chloride Chemical compound Cl[Tb](Cl)Cl GFISHBQNVWAVFU-UHFFFAOYSA-K 0.000 description 8
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 7
- OBOSXEWFRARQPU-UHFFFAOYSA-N 2-n,2-n-dimethylpyridine-2,5-diamine Chemical compound CN(C)C1=CC=C(N)C=N1 OBOSXEWFRARQPU-UHFFFAOYSA-N 0.000 description 7
- WMXICQUIACARNL-UHFFFAOYSA-K 4-methylbenzoate terbium(3+) Chemical compound C1(=CC=C(C=C1)C(=O)[O-])C.[Tb+3].C1(=CC=C(C=C1)C(=O)[O-])C.C1(=CC=C(C=C1)C(=O)[O-])C WMXICQUIACARNL-UHFFFAOYSA-K 0.000 description 7
- 239000013078 crystal Substances 0.000 description 6
- MEANOSLIBWSCIT-UHFFFAOYSA-K gadolinium trichloride Chemical compound Cl[Gd](Cl)Cl MEANOSLIBWSCIT-UHFFFAOYSA-K 0.000 description 6
- 238000005259 measurement Methods 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 230000009102 absorption Effects 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 239000000919 ceramic Substances 0.000 description 5
- 239000013522 chelant Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 238000011835 investigation Methods 0.000 description 5
- CKMXAIVXVKGGFM-UHFFFAOYSA-N p-cumic acid Chemical compound CC(C)C1=CC=C(C(O)=O)C=C1 CKMXAIVXVKGGFM-UHFFFAOYSA-N 0.000 description 5
- 238000006467 substitution reaction Methods 0.000 description 5
- 230000002195 synergetic effect Effects 0.000 description 5
- XHQZJYCNDZAGLW-UHFFFAOYSA-N 3-methoxybenzoic acid Chemical compound COC1=CC=CC(C(O)=O)=C1 XHQZJYCNDZAGLW-UHFFFAOYSA-N 0.000 description 4
- ZQVKTHRQIXSMGY-UHFFFAOYSA-N 4-Ethylbenzoic acid Chemical compound CCC1=CC=C(C(O)=O)C=C1 ZQVKTHRQIXSMGY-UHFFFAOYSA-N 0.000 description 4
- SHSGDXCJYVZFTP-UHFFFAOYSA-N 4-ethoxybenzoic acid Chemical compound CCOC1=CC=C(C(O)=O)C=C1 SHSGDXCJYVZFTP-UHFFFAOYSA-N 0.000 description 4
- 229910052779 Neodymium Inorganic materials 0.000 description 4
- CIUQDSCDWFSTQR-UHFFFAOYSA-N [C]1=CC=CC=C1 Chemical compound [C]1=CC=CC=C1 CIUQDSCDWFSTQR-UHFFFAOYSA-N 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 150000004687 hexahydrates Chemical class 0.000 description 4
- 238000005342 ion exchange Methods 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 150000002894 organic compounds Chemical class 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 238000006862 quantum yield reaction Methods 0.000 description 4
- 125000001424 substituent group Chemical group 0.000 description 4
- QERYCTSHXKAMIS-UHFFFAOYSA-N thiophene-2-carboxylic acid Chemical compound OC(=O)C1=CC=CS1 QERYCTSHXKAMIS-UHFFFAOYSA-N 0.000 description 4
- OBETXYAYXDNJHR-SSDOTTSWSA-M (2r)-2-ethylhexanoate Chemical compound CCCC[C@@H](CC)C([O-])=O OBETXYAYXDNJHR-SSDOTTSWSA-M 0.000 description 3
- NRQHBNNTBIDSRK-YRNVUSSQSA-N (4e)-4-[(4-methoxyphenyl)methylidene]-2-methyl-1,3-oxazol-5-one Chemical compound C1=CC(OC)=CC=C1\C=C\1C(=O)OC(C)=N/1 NRQHBNNTBIDSRK-YRNVUSSQSA-N 0.000 description 3
- WBJWXIQDBDZMAW-UHFFFAOYSA-N 2-hydroxynaphthalene-1-carbonyl chloride Chemical compound C1=CC=CC2=C(C(Cl)=O)C(O)=CC=C21 WBJWXIQDBDZMAW-UHFFFAOYSA-N 0.000 description 3
- RURHILYUWQEGOS-VOTSOKGWSA-N 4-Methylcinnamic acid Chemical compound CC1=CC=C(\C=C\C(O)=O)C=C1 RURHILYUWQEGOS-VOTSOKGWSA-N 0.000 description 3
- ZEYHEAKUIGZSGI-UHFFFAOYSA-N 4-methoxybenzoic acid Chemical compound COC1=CC=C(C(O)=O)C=C1 ZEYHEAKUIGZSGI-UHFFFAOYSA-N 0.000 description 3
- 229910052692 Dysprosium Inorganic materials 0.000 description 3
- 229910052772 Samarium Inorganic materials 0.000 description 3
- 238000002441 X-ray diffraction Methods 0.000 description 3
- 229910052769 Ytterbium Inorganic materials 0.000 description 3
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 3
- PYHXGXCGESYPCW-UHFFFAOYSA-N alpha-phenylbenzeneacetic acid Natural products C=1C=CC=CC=1C(C(=O)O)C1=CC=CC=C1 PYHXGXCGESYPCW-UHFFFAOYSA-N 0.000 description 3
- 230000006399 behavior Effects 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- KBQHZAAAGSGFKK-UHFFFAOYSA-N dysprosium atom Chemical compound [Dy] KBQHZAAAGSGFKK-UHFFFAOYSA-N 0.000 description 3
- 238000010894 electron beam technology Methods 0.000 description 3
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 3
- IXCSERBJSXMMFS-UHFFFAOYSA-N hcl hcl Chemical compound Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 3
- GPSDUZXPYCFOSQ-UHFFFAOYSA-M m-toluate Chemical compound CC1=CC=CC(C([O-])=O)=C1 GPSDUZXPYCFOSQ-UHFFFAOYSA-M 0.000 description 3
- 239000004570 mortar (masonry) Substances 0.000 description 3
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000000123 paper Substances 0.000 description 3
- AZQWKYJCGOJGHM-UHFFFAOYSA-N para-benzoquinone Natural products O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 3
- 229940081066 picolinic acid Drugs 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- 239000010453 quartz Substances 0.000 description 3
- 230000005855 radiation Effects 0.000 description 3
- 239000011833 salt mixture Substances 0.000 description 3
- KZUNJOHGWZRPMI-UHFFFAOYSA-N samarium atom Chemical compound [Sm] KZUNJOHGWZRPMI-UHFFFAOYSA-N 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 235000010199 sorbic acid Nutrition 0.000 description 3
- 239000004334 sorbic acid Substances 0.000 description 3
- 229940075582 sorbic acid Drugs 0.000 description 3
- 238000004611 spectroscopical analysis Methods 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- QGOSWKYGLZGCBH-UHFFFAOYSA-H terbium(3+);terephthalate Chemical compound [Tb+3].[Tb+3].[O-]C(=O)C1=CC=C(C([O-])=O)C=C1.[O-]C(=O)C1=CC=C(C([O-])=O)C=C1.[O-]C(=O)C1=CC=C(C([O-])=O)C=C1 QGOSWKYGLZGCBH-UHFFFAOYSA-H 0.000 description 3
- YEMUSDCFQUBPAL-SNAWJCMRSA-N (e)-3-(3-bromophenyl)prop-2-enoic acid Chemical compound OC(=O)\C=C\C1=CC=CC(Br)=C1 YEMUSDCFQUBPAL-SNAWJCMRSA-N 0.000 description 2
- GVNVAWHJIKLAGL-UHFFFAOYSA-N 2-(cyclohexen-1-yl)cyclohexan-1-one Chemical compound O=C1CCCCC1C1=CCCCC1 GVNVAWHJIKLAGL-UHFFFAOYSA-N 0.000 description 2
- VLSRUFWCGBMYDJ-UHFFFAOYSA-N 3-(3,5-dimethoxyphenyl)prop-2-enoic acid Chemical compound COC1=CC(OC)=CC(C=CC(O)=O)=C1 VLSRUFWCGBMYDJ-UHFFFAOYSA-N 0.000 description 2
- LULAYUGMBFYYEX-UHFFFAOYSA-N 3-chlorobenzoic acid Chemical compound OC(=O)C1=CC=CC(Cl)=C1 LULAYUGMBFYYEX-UHFFFAOYSA-N 0.000 description 2
- MCGBIXXDQFWVDW-UHFFFAOYSA-N 4,5-dihydro-1h-pyrazole Chemical compound C1CC=NN1 MCGBIXXDQFWVDW-UHFFFAOYSA-N 0.000 description 2
- CMSGUKVDXXTJDQ-UHFFFAOYSA-N 4-(2-naphthalen-1-ylethylamino)-4-oxobutanoic acid Chemical compound C1=CC=C2C(CCNC(=O)CCC(=O)O)=CC=CC2=C1 CMSGUKVDXXTJDQ-UHFFFAOYSA-N 0.000 description 2
- GXLIFJYFGMHYDY-ZZXKWVIFSA-N 4-chlorocinnamic acid Chemical compound OC(=O)\C=C\C1=CC=C(Cl)C=C1 GXLIFJYFGMHYDY-ZZXKWVIFSA-N 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- GNHLCRAUMFTBIE-UHFFFAOYSA-K C(C=CC=CC)(=O)[O-].[Eu+3].C(C=CC=CC)(=O)[O-].C(C=CC=CC)(=O)[O-] Chemical compound C(C=CC=CC)(=O)[O-].[Eu+3].C(C=CC=CC)(=O)[O-].C(C=CC=CC)(=O)[O-] GNHLCRAUMFTBIE-UHFFFAOYSA-K 0.000 description 2
- SEMZLCAKCHGRQF-UHFFFAOYSA-L C1(=CC=C(C=C1)C(=O)[O-])C.[Sr+2].C1(=CC=C(C=C1)C(=O)[O-])C Chemical compound C1(=CC=C(C=C1)C(=O)[O-])C.[Sr+2].C1(=CC=C(C=C1)C(=O)[O-])C SEMZLCAKCHGRQF-UHFFFAOYSA-L 0.000 description 2
- 229910052684 Cerium Inorganic materials 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- 101150065749 Churc1 gene Proteins 0.000 description 2
- 229910052691 Erbium Inorganic materials 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 150000000918 Europium Chemical class 0.000 description 2
- 229910052689 Holmium Inorganic materials 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 229910052765 Lutetium Inorganic materials 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- PVNIIMVLHYAWGP-UHFFFAOYSA-N Niacin Chemical compound OC(=O)C1=CC=CN=C1 PVNIIMVLHYAWGP-UHFFFAOYSA-N 0.000 description 2
- 229910052777 Praseodymium Inorganic materials 0.000 description 2
- 102100038239 Protein Churchill Human genes 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- 150000001217 Terbium Chemical class 0.000 description 2
- 229910052775 Thulium Inorganic materials 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 230000003213 activating effect Effects 0.000 description 2
- 239000012190 activator Substances 0.000 description 2
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 2
- 150000001447 alkali salts Chemical class 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- WDIHJSXYQDMJHN-UHFFFAOYSA-L barium chloride Chemical compound [Cl-].[Cl-].[Ba+2] WDIHJSXYQDMJHN-UHFFFAOYSA-L 0.000 description 2
- 229910001626 barium chloride Inorganic materials 0.000 description 2
- MUTGRVRJCJPFCN-UHFFFAOYSA-H benzene-1,3-dicarboxylate;terbium(3+) Chemical compound [Tb+3].[Tb+3].[O-]C(=O)C1=CC=CC(C([O-])=O)=C1.[O-]C(=O)C1=CC=CC(C([O-])=O)=C1.[O-]C(=O)C1=CC=CC(C([O-])=O)=C1 MUTGRVRJCJPFCN-UHFFFAOYSA-H 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- QAIPRVGONGVQAS-UHFFFAOYSA-N cis-caffeic acid Natural products OC(=O)C=CC1=CC=C(O)C(O)=C1 QAIPRVGONGVQAS-UHFFFAOYSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 230000001268 conjugating effect Effects 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- UYAHIZSMUZPPFV-UHFFFAOYSA-N erbium Chemical compound [Er] UYAHIZSMUZPPFV-UHFFFAOYSA-N 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- KPBQWHNHYYZJOJ-UHFFFAOYSA-K gadolinium(3+) 4-methylbenzoate Chemical compound C1(=CC=C(C=C1)C(=O)[O-])C.[Gd+3].C1(=CC=C(C=C1)C(=O)[O-])C.C1(=CC=C(C=C1)C(=O)[O-])C KPBQWHNHYYZJOJ-UHFFFAOYSA-K 0.000 description 2
- 125000005843 halogen group Chemical group 0.000 description 2
- 125000005842 heteroatom Chemical group 0.000 description 2
- 125000000623 heterocyclic group Chemical group 0.000 description 2
- KJZYNXUDTRRSPN-UHFFFAOYSA-N holmium atom Chemical compound [Ho] KJZYNXUDTRRSPN-UHFFFAOYSA-N 0.000 description 2
- 239000008240 homogeneous mixture Substances 0.000 description 2
- 150000002484 inorganic compounds Chemical class 0.000 description 2
- 229910010272 inorganic material Inorganic materials 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- OHSVLFRHMCKCQY-UHFFFAOYSA-N lutetium atom Chemical compound [Lu] OHSVLFRHMCKCQY-UHFFFAOYSA-N 0.000 description 2
- 239000011259 mixed solution Substances 0.000 description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 2
- 230000005693 optoelectronics Effects 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- XNERWVPQCYSMLC-UHFFFAOYSA-N phenylpropiolic acid Chemical compound OC(=O)C#CC1=CC=CC=C1 XNERWVPQCYSMLC-UHFFFAOYSA-N 0.000 description 2
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 230000001235 sensitizing effect Effects 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 229910001631 strontium chloride Inorganic materials 0.000 description 2
- AHBGXTDRMVNFER-UHFFFAOYSA-L strontium dichloride Chemical compound [Cl-].[Cl-].[Sr+2] AHBGXTDRMVNFER-UHFFFAOYSA-L 0.000 description 2
- 125000004434 sulfur atom Chemical group 0.000 description 2
- JRDLRVRPRUODON-UHFFFAOYSA-H terephthalate;yttrium(3+) Chemical compound [Y+3].[Y+3].[O-]C(=O)C1=CC=C(C([O-])=O)C=C1.[O-]C(=O)C1=CC=C(C([O-])=O)C=C1.[O-]C(=O)C1=CC=C(C([O-])=O)C=C1 JRDLRVRPRUODON-UHFFFAOYSA-H 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 2
- NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 description 2
- VOLGAXAGEUPBDM-UHFFFAOYSA-N $l^{1}-oxidanylethane Chemical compound CC[O] VOLGAXAGEUPBDM-UHFFFAOYSA-N 0.000 description 1
- SFYSWUFJCMYFPE-UHFFFAOYSA-N (2,2,2-trifluoroacetyl) thiophene-2-carboxylate Chemical compound FC(F)(F)C(=O)OC(=O)C1=CC=CS1 SFYSWUFJCMYFPE-UHFFFAOYSA-N 0.000 description 1
- IAAPVNQZSBLWKH-ICDJNDDTSA-N (2e,4e,6e)-octa-2,4,6-trienoic acid Chemical compound C\C=C\C=C\C=C\C(O)=O IAAPVNQZSBLWKH-ICDJNDDTSA-N 0.000 description 1
- PLVPPLCLBIEYEA-AATRIKPKSA-N (E)-3-(indol-3-yl)acrylic acid Chemical compound C1=CC=C2C(/C=C/C(=O)O)=CNC2=C1 PLVPPLCLBIEYEA-AATRIKPKSA-N 0.000 description 1
- FFKGOJWPSXRALK-SNAWJCMRSA-N (e)-3-(3-chlorophenyl)prop-2-enoic acid Chemical compound OC(=O)\C=C\C1=CC=CC(Cl)=C1 FFKGOJWPSXRALK-SNAWJCMRSA-N 0.000 description 1
- PYHXGXCGESYPCW-UHFFFAOYSA-M 2,2-diphenylacetate Chemical compound C=1C=CC=CC=1C(C(=O)[O-])C1=CC=CC=C1 PYHXGXCGESYPCW-UHFFFAOYSA-M 0.000 description 1
- QAOJBHRZQQDFHA-UHFFFAOYSA-N 2,3-dichlorobenzoic acid Chemical compound OC(=O)C1=CC=CC(Cl)=C1Cl QAOJBHRZQQDFHA-UHFFFAOYSA-N 0.000 description 1
- XNTIGDVFBDJLTQ-UHFFFAOYSA-N 2-chloro-6-fluorobenzoic acid Chemical compound OC(=O)C1=C(F)C=CC=C1Cl XNTIGDVFBDJLTQ-UHFFFAOYSA-N 0.000 description 1
- OXXYGNFXACOVNH-UHFFFAOYSA-K 2-ethylhexanoate;europium(3+) Chemical compound [Eu+3].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O OXXYGNFXACOVNH-UHFFFAOYSA-K 0.000 description 1
- YTRMTPPVNRALON-UHFFFAOYSA-N 2-phenyl-4-quinolinecarboxylic acid Chemical compound N=1C2=CC=CC=C2C(C(=O)O)=CC=1C1=CC=CC=C1 YTRMTPPVNRALON-UHFFFAOYSA-N 0.000 description 1
- CBEPDLCICDYPMR-UHFFFAOYSA-N 2-pyridin-3-ylprop-2-enoic acid Chemical compound OC(=O)C(=C)C1=CC=CN=C1 CBEPDLCICDYPMR-UHFFFAOYSA-N 0.000 description 1
- ARGCLRFUGIDKBB-UHFFFAOYSA-K 3-(3,5-dimethoxyphenyl)prop-2-enoate europium(3+) Chemical compound COC=1C=C(C=CC(=O)[O-])C=C(C1)OC.[Eu+3].COC=1C=C(C=CC(=O)[O-])C=C(C1)OC.COC=1C=C(C=CC(=O)[O-])C=C(C1)OC ARGCLRFUGIDKBB-UHFFFAOYSA-K 0.000 description 1
- XHQZJYCNDZAGLW-UHFFFAOYSA-M 3-methoxybenzoate Chemical compound COC1=CC=CC(C([O-])=O)=C1 XHQZJYCNDZAGLW-UHFFFAOYSA-M 0.000 description 1
- AFPHTEQTJZKQAQ-UHFFFAOYSA-N 3-nitrobenzoic acid Chemical compound OC(=O)C1=CC=CC([N+]([O-])=O)=C1 AFPHTEQTJZKQAQ-UHFFFAOYSA-N 0.000 description 1
- 125000003349 3-pyridyl group Chemical group N1=C([H])C([*])=C([H])C([H])=C1[H] 0.000 description 1
- KKMZQOIASVGJQE-UHFFFAOYSA-N 3-thiophen-2-ylprop-2-enoic acid Chemical compound OC(=O)C=CC1=CC=CS1 KKMZQOIASVGJQE-UHFFFAOYSA-N 0.000 description 1
- IFQUPKAISSPFTE-UHFFFAOYSA-N 4-benzoylbenzoic acid Chemical compound C1=CC(C(=O)O)=CC=C1C(=O)C1=CC=CC=C1 IFQUPKAISSPFTE-UHFFFAOYSA-N 0.000 description 1
- TUXYZHVUPGXXQG-UHFFFAOYSA-N 4-bromobenzoic acid Chemical compound OC(=O)C1=CC=C(Br)C=C1 TUXYZHVUPGXXQG-UHFFFAOYSA-N 0.000 description 1
- NNJMFJSKMRYHSR-UHFFFAOYSA-N 4-phenylbenzoic acid Chemical compound C1=CC(C(=O)O)=CC=C1C1=CC=CC=C1 NNJMFJSKMRYHSR-UHFFFAOYSA-N 0.000 description 1
- KDVYCTOWXSLNNI-UHFFFAOYSA-N 4-t-Butylbenzoic acid Chemical compound CC(C)(C)C1=CC=C(C(O)=O)C=C1 KDVYCTOWXSLNNI-UHFFFAOYSA-N 0.000 description 1
- POPBYCBXVLHSKO-UHFFFAOYSA-N 9,10-dioxoanthracene-1-carboxylic acid Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2C(=O)O POPBYCBXVLHSKO-UHFFFAOYSA-N 0.000 description 1
- XGWFJBFNAQHLEF-UHFFFAOYSA-N 9-anthroic acid Chemical compound C1=CC=C2C(C(=O)O)=C(C=CC=C3)C3=CC2=C1 XGWFJBFNAQHLEF-UHFFFAOYSA-N 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- RAFGELQLHMBRHD-VFYVRILKSA-N Bixin Natural products COC(=O)C=CC(=C/C=C/C(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/C(=O)O)/C)C RAFGELQLHMBRHD-VFYVRILKSA-N 0.000 description 1
- KYSJBCJXFZJNJT-UHFFFAOYSA-K C1(=CC(=CC=C1)C(=O)[O-])C.[Eu+3].C1(=CC(=CC=C1)C(=O)[O-])C.C1(=CC(=CC=C1)C(=O)[O-])C Chemical compound C1(=CC(=CC=C1)C(=O)[O-])C.[Eu+3].C1(=CC(=CC=C1)C(=O)[O-])C.C1(=CC(=CC=C1)C(=O)[O-])C KYSJBCJXFZJNJT-UHFFFAOYSA-K 0.000 description 1
- 229910004762 CaSiO Inorganic materials 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 241000723347 Cinnamomum Species 0.000 description 1
- PANKHBYNKQNAHN-JTBLXSOISA-N Crocetin Natural products OC(=O)C(\C)=C/C=C/C(/C)=C\C=C\C=C(\C)/C=C/C=C(/C)C(O)=O PANKHBYNKQNAHN-JTBLXSOISA-N 0.000 description 1
- 101100496858 Mus musculus Colec12 gene Proteins 0.000 description 1
- 125000000066 S-methyl group Chemical group [H]C([H])([H])S* 0.000 description 1
- 206010070834 Sensitisation Diseases 0.000 description 1
- 229910004283 SiO 4 Inorganic materials 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical class [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- WGCOBXJJERIKEL-UHFFFAOYSA-L [Cl-].[Cl-].[Y+2] Chemical compound [Cl-].[Cl-].[Y+2] WGCOBXJJERIKEL-UHFFFAOYSA-L 0.000 description 1
- GEVSMKYDOIVVKW-UHFFFAOYSA-H [Cl-].[La+3].[Eu+3].[Cl-].[Cl-].[Cl-].[Cl-].[Cl-] Chemical compound [Cl-].[La+3].[Eu+3].[Cl-].[Cl-].[Cl-].[Cl-].[Cl-] GEVSMKYDOIVVKW-UHFFFAOYSA-H 0.000 description 1
- BNZDSZFHGLFGPJ-UHFFFAOYSA-K [Tb+3].[O-]C(=O)c1ccccn1.[O-]C(=O)c1ccccn1.[O-]C(=O)c1ccccn1 Chemical compound [Tb+3].[O-]C(=O)c1ccccn1.[O-]C(=O)c1ccccn1.[O-]C(=O)c1ccccn1 BNZDSZFHGLFGPJ-UHFFFAOYSA-K 0.000 description 1
- SKQWEERDYRHPFP-UHFFFAOYSA-N [Y].S=O Chemical compound [Y].S=O SKQWEERDYRHPFP-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- RAFGELQLHMBRHD-UHFFFAOYSA-N alpha-Fuc-(1-2)-beta-Gal-(1-3)-(beta-GlcNAc-(1-6))-GalNAc-ol Natural products COC(=O)C=CC(C)=CC=CC(C)=CC=CC=C(C)C=CC=C(C)C=CC(O)=O RAFGELQLHMBRHD-UHFFFAOYSA-N 0.000 description 1
- 239000001670 anatto Substances 0.000 description 1
- 235000012665 annatto Nutrition 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical group 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- WHDJXHPCQRJPKH-UHFFFAOYSA-H benzene-1,3-dicarboxylate;yttrium(3+) Chemical compound [Y+3].[Y+3].[O-]C(=O)C1=CC=CC(C([O-])=O)=C1.[O-]C(=O)C1=CC=CC(C([O-])=O)=C1.[O-]C(=O)C1=CC=CC(C([O-])=O)=C1 WHDJXHPCQRJPKH-UHFFFAOYSA-H 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- RAFGELQLHMBRHD-SLEZCNMESA-N bixin Chemical compound COC(=O)\C=C\C(\C)=C/C=C/C(/C)=C/C=C/C=C(\C)/C=C/C=C(\C)/C=C/C(O)=O RAFGELQLHMBRHD-SLEZCNMESA-N 0.000 description 1
- 239000007853 buffer solution Substances 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- PANKHBYNKQNAHN-JUMCEFIXSA-N carotenoid dicarboxylic acid Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C(=O)O)C=CC=C(/C)C(=O)O PANKHBYNKQNAHN-JUMCEFIXSA-N 0.000 description 1
- 238000002144 chemical decomposition reaction Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- MUYSADWCWFFZKR-UHFFFAOYSA-N cinchomeronic acid Chemical compound OC(=O)C1=CC=NC=C1C(O)=O MUYSADWCWFFZKR-UHFFFAOYSA-N 0.000 description 1
- 235000017803 cinnamon Nutrition 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001672 corrected emission spectrum Methods 0.000 description 1
- PANKHBYNKQNAHN-MQQNZMFNSA-N crocetin Chemical compound OC(=O)C(/C)=C/C=C/C(/C)=C/C=C/C=C(\C)/C=C/C=C(\C)C(O)=O PANKHBYNKQNAHN-MQQNZMFNSA-N 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 150000001923 cyclic compounds Chemical class 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 239000012769 display material Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000000295 emission spectrum Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003623 enhancer Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- QUPDWYMUPZLYJZ-UHFFFAOYSA-N ethyl Chemical compound C[CH2] QUPDWYMUPZLYJZ-UHFFFAOYSA-N 0.000 description 1
- MDFCXYVJUZMYCJ-UHFFFAOYSA-N europium gadolinium Chemical compound [Eu][Gd] MDFCXYVJUZMYCJ-UHFFFAOYSA-N 0.000 description 1
- CUZYJNBUPITPEI-UHFFFAOYSA-N europium lanthanum Chemical compound [La][Eu] CUZYJNBUPITPEI-UHFFFAOYSA-N 0.000 description 1
- UVJXTGHHRXRPRO-UHFFFAOYSA-K europium(3+) 4-methylbenzoate Chemical compound C1(=CC=C(C=C1)C(=O)[O-])C.[Eu+3].C1(=CC=C(C=C1)C(=O)[O-])C.C1(=CC=C(C=C1)C(=O)[O-])C UVJXTGHHRXRPRO-UHFFFAOYSA-K 0.000 description 1
- KDFCPSPTDPVENZ-UHFFFAOYSA-K europium(3+) thiophene-3-carboxylate Chemical compound S1C=C(C=C1)C(=O)[O-].[Eu+3].S1C=C(C=C1)C(=O)[O-].S1C=C(C=C1)C(=O)[O-] KDFCPSPTDPVENZ-UHFFFAOYSA-K 0.000 description 1
- DSPCOFQXGVSEHZ-UHFFFAOYSA-K europium(3+);thiophene-2-carboxylate Chemical compound [Eu+3].[O-]C(=O)C1=CC=CS1.[O-]C(=O)C1=CC=CS1.[O-]C(=O)C1=CC=CS1 DSPCOFQXGVSEHZ-UHFFFAOYSA-K 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- HQWUQSSKOBTIHZ-UHFFFAOYSA-N gadolinium terbium Chemical compound [Gd][Tb] HQWUQSSKOBTIHZ-UHFFFAOYSA-N 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- IENZCGNHSIMFJE-UHFFFAOYSA-N indole-5-carboxylic acid Chemical compound OC(=O)C1=CC=C2NC=CC2=C1 IENZCGNHSIMFJE-UHFFFAOYSA-N 0.000 description 1
- PLVPPLCLBIEYEA-UHFFFAOYSA-N indoleacrylic acid Natural products C1=CC=C2C(C=CC(=O)O)=CNC2=C1 PLVPPLCLBIEYEA-UHFFFAOYSA-N 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- QQVIHTHCMHWDBS-UHFFFAOYSA-L isophthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC(C([O-])=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-L 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 239000008204 material by function Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- WCYWZMWISLQXQU-UHFFFAOYSA-N methyl Chemical compound [CH3] WCYWZMWISLQXQU-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- GRVDJDISBSALJP-UHFFFAOYSA-N methyloxidanyl Chemical compound [O]C GRVDJDISBSALJP-UHFFFAOYSA-N 0.000 description 1
- 229960003512 nicotinic acid Drugs 0.000 description 1
- 235000001968 nicotinic acid Nutrition 0.000 description 1
- 239000011664 nicotinic acid Substances 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- ZWLPBLYKEWSWPD-UHFFFAOYSA-N o-toluic acid Chemical compound CC1=CC=CC=C1C(O)=O ZWLPBLYKEWSWPD-UHFFFAOYSA-N 0.000 description 1
- IAAPVNQZSBLWKH-UHFFFAOYSA-N octatrienoic acid Natural products CC=CC=CC=CC(O)=O IAAPVNQZSBLWKH-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 230000010355 oscillation Effects 0.000 description 1
- GFKJCVBFQRKZCJ-UHFFFAOYSA-N oxygen(2-);yttrium(3+);trisulfide Chemical compound [O-2].[O-2].[O-2].[S-2].[S-2].[S-2].[Y+3].[Y+3].[Y+3].[Y+3] GFKJCVBFQRKZCJ-UHFFFAOYSA-N 0.000 description 1
- LPNBBFKOUUSUDB-UHFFFAOYSA-M p-toluate Chemical compound CC1=CC=C(C([O-])=O)C=C1 LPNBBFKOUUSUDB-UHFFFAOYSA-M 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 238000005424 photoluminescence Methods 0.000 description 1
- WOSVAFWHYVSWCA-UHFFFAOYSA-H phthalate terbium(3+) Chemical compound [Tb+3].[Tb+3].[O-]C(=O)c1ccccc1C([O-])=O.[O-]C(=O)c1ccccc1C([O-])=O.[O-]C(=O)c1ccccc1C([O-])=O WOSVAFWHYVSWCA-UHFFFAOYSA-H 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 125000003367 polycyclic group Chemical group 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- VVNLENFYCXOLPC-UHFFFAOYSA-N pyridin-3-yl prop-2-enoate Chemical compound C=CC(=O)OC1=CC=CN=C1 VVNLENFYCXOLPC-UHFFFAOYSA-N 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- LOAUVZALPPNFOQ-UHFFFAOYSA-N quinaldic acid Chemical compound C1=CC=CC2=NC(C(=O)O)=CC=C21 LOAUVZALPPNFOQ-UHFFFAOYSA-N 0.000 description 1
- 238000005395 radioluminescence Methods 0.000 description 1
- 230000009103 reabsorption Effects 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 238000002310 reflectometry Methods 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 229910052706 scandium Inorganic materials 0.000 description 1
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 description 1
- 230000008313 sensitization Effects 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- QDRKDTQENPPHOJ-UHFFFAOYSA-N sodium ethoxide Chemical compound [Na+].CC[O-] QDRKDTQENPPHOJ-UHFFFAOYSA-N 0.000 description 1
- GNCGTEQGBYYYBX-UHFFFAOYSA-M sodium;4-methylbenzoate Chemical compound [Na+].CC1=CC=C(C([O-])=O)C=C1 GNCGTEQGBYYYBX-UHFFFAOYSA-M 0.000 description 1
- LKYIPGJOXSVWPX-UHFFFAOYSA-M sodium;thiophene-2-carboxylate Chemical compound [Na+].[O-]C(=O)C1=CC=CS1 LKYIPGJOXSVWPX-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- TXBBUSUXYMIVOS-UHFFFAOYSA-N thenoyltrifluoroacetone Chemical compound FC(F)(F)C(=O)CC(=O)C1=CC=CS1 TXBBUSUXYMIVOS-UHFFFAOYSA-N 0.000 description 1
- LOIYMIARKYCTBW-OWOJBTEDSA-N trans-urocanic acid Chemical compound OC(=O)\C=C\C1=CNC=N1 LOIYMIARKYCTBW-OWOJBTEDSA-N 0.000 description 1
- LOIYMIARKYCTBW-UHFFFAOYSA-N trans-urocanic acid Natural products OC(=O)C=CC1=CNC=N1 LOIYMIARKYCTBW-UHFFFAOYSA-N 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/06—Luminescent, e.g. electroluminescent, chemiluminescent materials containing organic luminescent materials
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Luminescent Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11035779A JPS5634782A (en) | 1979-08-31 | 1979-08-31 | Novel energy converting substance and illuminant |
| JP9221480A JPS5718779A (en) | 1980-07-08 | 1980-07-08 | Novel luminous substance |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE3032611A1 DE3032611A1 (de) | 1981-03-26 |
| DE3032611C2 true DE3032611C2 (de) | 1983-12-08 |
Family
ID=26433681
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE3032611A Expired DE3032611C2 (de) | 1979-08-31 | 1980-08-29 | Organische Seltenerdsalzleuchtstoffe |
| DE19803050703 Expired DE3050703C2 (de) | 1979-08-31 | 1980-08-29 | Organische Seltenerdsalzleuchtstoffe |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19803050703 Expired DE3050703C2 (de) | 1979-08-31 | 1980-08-29 | Organische Seltenerdsalzleuchtstoffe |
Country Status (5)
| Country | Link |
|---|---|
| US (2) | US4443380A (enExample) |
| DE (2) | DE3032611C2 (enExample) |
| FR (2) | FR2464292A1 (enExample) |
| GB (2) | GB2061918B (enExample) |
| NL (2) | NL8004876A (enExample) |
Families Citing this family (91)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2061918B (en) * | 1979-08-31 | 1984-05-31 | Asahi Dow Ltd | Organic rare-earth salt phosphors |
| US4957939A (en) * | 1981-07-24 | 1990-09-18 | Schering Aktiengesellschaft | Sterile pharmaceutical compositions of gadolinium chelates useful enhancing NMR imaging |
| DE3525994A1 (de) * | 1985-07-20 | 1987-01-29 | Philips Patentverwaltung | Elektronenstrahl-aufzeichnungstraeger |
| US4752424A (en) * | 1986-01-30 | 1988-06-21 | Kabushiki Kaisha Toshiba | Method of manufacturing a rare earth oxysulfide ceramic |
| GB8602304D0 (en) * | 1986-01-30 | 1986-03-05 | Dakubu S | Dihydropyridine condensation products |
| US5132045A (en) * | 1988-03-16 | 1992-07-21 | Mitsubishi Rayon Co., Ltd. | Acrylic phosphor paste compositions and phosphor coatings obtained therefrom |
| US5154764A (en) * | 1990-04-10 | 1992-10-13 | Mooney Chemicals, Inc. | Neodymium carboxylates as driers in high-solids coating compositions |
| US5095099A (en) * | 1990-12-10 | 1992-03-10 | E. I. Du Pont De Nemours And Company | Fluorescent compounds for absorption and re-emission of radiation |
| US5415151A (en) * | 1993-09-20 | 1995-05-16 | Jcf Research Associates, Inc. | Phosphor-containing projectile and launcher therefor |
| DE69513350T2 (de) | 1994-03-17 | 2000-07-27 | Hitachi Maxell, Ltd. | PHOSPHOR, PHOSPHORZUSAMMENSETZUNG und FLUORESZENTER MARK-TRÄGER |
| US5693693A (en) * | 1994-12-01 | 1997-12-02 | Pitney Bowes, Inc. | Bar code printing and scanning using wax based invisible fluorescent inks |
| US5502304A (en) * | 1994-12-01 | 1996-03-26 | Pitney Bowes Inc. | Bar code scanner for reading a visible ink and a luminescent invisible ink |
| US5525798A (en) * | 1994-12-01 | 1996-06-11 | Pitney Bowes Inc. | Bar code scanner for reading a lower layer luminescent invisible ink that is printed below a upper layer luminescent invisible ink |
| US5542971A (en) * | 1994-12-01 | 1996-08-06 | Pitney Bowes | Bar codes using luminescent invisible inks |
| US6203725B1 (en) * | 1996-07-24 | 2001-03-20 | Mitsui Chemicals, Inc. | Luminescent compound for controlling traveling and method for controlling traveling using the same |
| US5876960A (en) * | 1997-08-11 | 1999-03-02 | The United States Of America As Represented By The Secretary Of The Army | Bacterial spore detection and quantification methods |
| CA2393794A1 (en) * | 1999-12-07 | 2001-06-14 | Robert H. Miller | Long persistent phosphor incorporated within a fabric material |
| FR2814737B1 (fr) * | 2000-10-03 | 2003-08-29 | Rhodia Terres Rares | Compose anhydre a base d'un halogenure de terre rare ou de gallium, son procede de preparation et son utilisation comme catalyseur |
| GB0109758D0 (en) * | 2001-04-20 | 2001-06-13 | Elam T Ltd | Mixed metal organic complexes |
| DE20119574U1 (de) * | 2001-12-03 | 2002-10-02 | Kynast, Ulrich, Prof. Dr., 48565 Steinfurt | Darstellung von Polyurethanen mit Komplexen der Seltenen Erden zur Erzeugung von Lumineszenzeffekten |
| DE10163295B4 (de) | 2001-12-21 | 2004-03-25 | Honeywell Specialty Chemicals Seelze Gmbh | Seltenerdmetall-Verbindungen und Gemische von diesen, Verfahren zu deren Herstellung sowie deren Verwendung |
| US7343973B2 (en) * | 2002-01-08 | 2008-03-18 | Halliburton Energy Services, Inc. | Methods of stabilizing surfaces of subterranean formations |
| US6962200B2 (en) * | 2002-01-08 | 2005-11-08 | Halliburton Energy Services, Inc. | Methods and compositions for consolidating proppant in subterranean fractures |
| US7267171B2 (en) * | 2002-01-08 | 2007-09-11 | Halliburton Energy Services, Inc. | Methods and compositions for stabilizing the surface of a subterranean formation |
| US7216711B2 (en) * | 2002-01-08 | 2007-05-15 | Halliburton Eenrgy Services, Inc. | Methods of coating resin and blending resin-coated proppant |
| US6691780B2 (en) * | 2002-04-18 | 2004-02-17 | Halliburton Energy Services, Inc. | Tracking of particulate flowback in subterranean wells |
| GB0219253D0 (en) * | 2002-08-19 | 2002-09-25 | Elam T Ltd | Electroluminescent materials and device |
| US6705400B1 (en) * | 2002-08-28 | 2004-03-16 | Halliburton Energy Services, Inc. | Methods and compositions for forming subterranean fractures containing resilient proppant packs |
| JP2006512755A (ja) * | 2002-12-24 | 2006-04-13 | エラム−ティー リミテッド | エレクトロルミネッセンス物質および装置 |
| US20040211561A1 (en) * | 2003-03-06 | 2004-10-28 | Nguyen Philip D. | Methods and compositions for consolidating proppant in fractures |
| US7114570B2 (en) * | 2003-04-07 | 2006-10-03 | Halliburton Energy Services, Inc. | Methods and compositions for stabilizing unconsolidated subterranean formations |
| US6978836B2 (en) * | 2003-05-23 | 2005-12-27 | Halliburton Energy Services, Inc. | Methods for controlling water and particulate production |
| US7114560B2 (en) * | 2003-06-23 | 2006-10-03 | Halliburton Energy Services, Inc. | Methods for enhancing treatment fluid placement in a subterranean formation |
| US7413010B2 (en) * | 2003-06-23 | 2008-08-19 | Halliburton Energy Services, Inc. | Remediation of subterranean formations using vibrational waves and consolidating agents |
| US7013976B2 (en) | 2003-06-25 | 2006-03-21 | Halliburton Energy Services, Inc. | Compositions and methods for consolidating unconsolidated subterranean formations |
| US7021379B2 (en) * | 2003-07-07 | 2006-04-04 | Halliburton Energy Services, Inc. | Methods and compositions for enhancing consolidation strength of proppant in subterranean fractures |
| US7066258B2 (en) * | 2003-07-08 | 2006-06-27 | Halliburton Energy Services, Inc. | Reduced-density proppants and methods of using reduced-density proppants to enhance their transport in well bores and fractures |
| US7104325B2 (en) * | 2003-07-09 | 2006-09-12 | Halliburton Energy Services, Inc. | Methods of consolidating subterranean zones and compositions therefor |
| US7017665B2 (en) * | 2003-08-26 | 2006-03-28 | Halliburton Energy Services, Inc. | Strengthening near well bore subterranean formations |
| US7237609B2 (en) * | 2003-08-26 | 2007-07-03 | Halliburton Energy Services, Inc. | Methods for producing fluids from acidized and consolidated portions of subterranean formations |
| US7059406B2 (en) * | 2003-08-26 | 2006-06-13 | Halliburton Energy Services, Inc. | Production-enhancing completion methods |
| US7156194B2 (en) * | 2003-08-26 | 2007-01-02 | Halliburton Energy Services, Inc. | Methods of drilling and consolidating subterranean formation particulate |
| US7032667B2 (en) * | 2003-09-10 | 2006-04-25 | Halliburtonn Energy Services, Inc. | Methods for enhancing the consolidation strength of resin coated particulates |
| US7345011B2 (en) * | 2003-10-14 | 2008-03-18 | Halliburton Energy Services, Inc. | Methods for mitigating the production of water from subterranean formations |
| US7063150B2 (en) * | 2003-11-25 | 2006-06-20 | Halliburton Energy Services, Inc. | Methods for preparing slurries of coated particulates |
| US20050145385A1 (en) * | 2004-01-05 | 2005-07-07 | Nguyen Philip D. | Methods of well stimulation and completion |
| US20070007009A1 (en) * | 2004-01-05 | 2007-01-11 | Halliburton Energy Services, Inc. | Methods of well stimulation and completion |
| US7131493B2 (en) * | 2004-01-16 | 2006-11-07 | Halliburton Energy Services, Inc. | Methods of using sealants in multilateral junctions |
| US20050173116A1 (en) * | 2004-02-10 | 2005-08-11 | Nguyen Philip D. | Resin compositions and methods of using resin compositions to control proppant flow-back |
| US7211547B2 (en) * | 2004-03-03 | 2007-05-01 | Halliburton Energy Services, Inc. | Resin compositions and methods of using such resin compositions in subterranean applications |
| US7063151B2 (en) * | 2004-03-05 | 2006-06-20 | Halliburton Energy Services, Inc. | Methods of preparing and using coated particulates |
| US20050194142A1 (en) * | 2004-03-05 | 2005-09-08 | Nguyen Philip D. | Compositions and methods for controlling unconsolidated particulates |
| US20050263283A1 (en) * | 2004-05-25 | 2005-12-01 | Nguyen Philip D | Methods for stabilizing and stimulating wells in unconsolidated subterranean formations |
| US7541318B2 (en) * | 2004-05-26 | 2009-06-02 | Halliburton Energy Services, Inc. | On-the-fly preparation of proppant and its use in subterranean operations |
| US7299875B2 (en) * | 2004-06-08 | 2007-11-27 | Halliburton Energy Services, Inc. | Methods for controlling particulate migration |
| US7073581B2 (en) * | 2004-06-15 | 2006-07-11 | Halliburton Energy Services, Inc. | Electroconductive proppant compositions and related methods |
| US7281580B2 (en) * | 2004-09-09 | 2007-10-16 | Halliburton Energy Services, Inc. | High porosity fractures and methods of creating high porosity fractures |
| US7255169B2 (en) | 2004-09-09 | 2007-08-14 | Halliburton Energy Services, Inc. | Methods of creating high porosity propped fractures |
| US7757768B2 (en) | 2004-10-08 | 2010-07-20 | Halliburton Energy Services, Inc. | Method and composition for enhancing coverage and displacement of treatment fluids into subterranean formations |
| US7281581B2 (en) * | 2004-12-01 | 2007-10-16 | Halliburton Energy Services, Inc. | Methods of hydraulic fracturing and of propping fractures in subterranean formations |
| US7273099B2 (en) * | 2004-12-03 | 2007-09-25 | Halliburton Energy Services, Inc. | Methods of stimulating a subterranean formation comprising multiple production intervals |
| US7398825B2 (en) * | 2004-12-03 | 2008-07-15 | Halliburton Energy Services, Inc. | Methods of controlling sand and water production in subterranean zones |
| US7883740B2 (en) * | 2004-12-12 | 2011-02-08 | Halliburton Energy Services, Inc. | Low-quality particulates and methods of making and using improved low-quality particulates |
| US7334635B2 (en) * | 2005-01-14 | 2008-02-26 | Halliburton Energy Services, Inc. | Methods for fracturing subterranean wells |
| US7334636B2 (en) * | 2005-02-08 | 2008-02-26 | Halliburton Energy Services, Inc. | Methods of creating high-porosity propped fractures using reticulated foam |
| US7318473B2 (en) * | 2005-03-07 | 2008-01-15 | Halliburton Energy Services, Inc. | Methods relating to maintaining the structural integrity of deviated well bores |
| US7673686B2 (en) * | 2005-03-29 | 2010-03-09 | Halliburton Energy Services, Inc. | Method of stabilizing unconsolidated formation for sand control |
| US7448451B2 (en) * | 2005-03-29 | 2008-11-11 | Halliburton Energy Services, Inc. | Methods for controlling migration of particulates in a subterranean formation |
| US20060240995A1 (en) * | 2005-04-23 | 2006-10-26 | Halliburton Energy Services, Inc. | Methods of using resins in subterranean formations |
| US7318474B2 (en) | 2005-07-11 | 2008-01-15 | Halliburton Energy Services, Inc. | Methods and compositions for controlling formation fines and reducing proppant flow-back |
| US20070114032A1 (en) * | 2005-11-22 | 2007-05-24 | Stegent Neil A | Methods of consolidating unconsolidated particulates in subterranean formations |
| EP1793261B1 (en) * | 2005-12-01 | 2009-08-12 | C.R.F. Societa Consortile per Azioni | Transparent display based on photoluminescent material |
| US7926591B2 (en) | 2006-02-10 | 2011-04-19 | Halliburton Energy Services, Inc. | Aqueous-based emulsified consolidating agents suitable for use in drill-in applications |
| US20080006405A1 (en) * | 2006-07-06 | 2008-01-10 | Halliburton Energy Services, Inc. | Methods and compositions for enhancing proppant pack conductivity and strength |
| US7819192B2 (en) * | 2006-02-10 | 2010-10-26 | Halliburton Energy Services, Inc. | Consolidating agent emulsions and associated methods |
| US8613320B2 (en) | 2006-02-10 | 2013-12-24 | Halliburton Energy Services, Inc. | Compositions and applications of resins in treating subterranean formations |
| US7665517B2 (en) * | 2006-02-15 | 2010-02-23 | Halliburton Energy Services, Inc. | Methods of cleaning sand control screens and gravel packs |
| US7407010B2 (en) * | 2006-03-16 | 2008-08-05 | Halliburton Energy Services, Inc. | Methods of coating particulates |
| US7500521B2 (en) * | 2006-07-06 | 2009-03-10 | Halliburton Energy Services, Inc. | Methods of enhancing uniform placement of a resin in a subterranean formation |
| US20080115692A1 (en) * | 2006-11-17 | 2008-05-22 | Halliburton Energy Services, Inc. | Foamed resin compositions and methods of using foamed resin compositions in subterranean applications |
| US7934557B2 (en) * | 2007-02-15 | 2011-05-03 | Halliburton Energy Services, Inc. | Methods of completing wells for controlling water and particulate production |
| CN101067079B (zh) * | 2007-05-25 | 2010-05-19 | 上海师范大学 | 核-壳结构杂化纳米荧光粉体及其制备方法 |
| FR2917226B1 (fr) * | 2007-06-06 | 2009-09-11 | Inst Nat Sciences Appliq | Procede de marquage de materiaux a base de matrices organiques polymeriques thermoplastiques ou thermodurcissables |
| RU2373211C2 (ru) * | 2007-10-05 | 2009-11-20 | Самсунг Электроникс Ко., Лтд | Соединение ди(нитрато)ацетилацетонатобис (1,10-фенантролин) лантаноид (iii), пригодное для использования в качестве люминесцентной добавки в чернила, и чернила для скрытой маркировки ценных материальных объектов |
| DE102008058177A1 (de) * | 2008-11-20 | 2010-06-24 | Eos Gmbh Electro Optical Systems | Verfahren zur Identifizierung von Lasersinterpulvern |
| US7762329B1 (en) | 2009-01-27 | 2010-07-27 | Halliburton Energy Services, Inc. | Methods for servicing well bores with hardenable resin compositions |
| CN102766356B (zh) * | 2012-07-31 | 2013-12-04 | 武汉大学 | 一种紫外线复合吸收材料及其制备方法 |
| EP3090032A1 (en) * | 2013-12-04 | 2016-11-09 | Merck Patent GmbH | Eu2 -activated phosphors |
| CN104193770B (zh) * | 2014-08-01 | 2016-09-28 | 浙江大学 | 一种用于生理温度探测的双稀土有机框架材料及其制备方法 |
| KR101735405B1 (ko) * | 2014-08-22 | 2017-05-15 | 나노씨엠에스(주) | 발광 희토류 화합물 및 이를 포함하는 이색성 형광체 조성물 |
| RU2643966C1 (ru) * | 2017-05-29 | 2018-02-06 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Кубанский государственный университет" (ФГБОУ ВО "КубГУ") | Способ получения ацетилсалицилата тербия(iii) |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR898263A (fr) * | 1942-09-25 | 1945-04-18 | Auergesellschaft Ag | Agent d'enrobage pour couleurs luminescentes |
| US2901496A (en) * | 1949-09-09 | 1959-08-25 | George A Cowan | Salicylate process for thorium separation from rare earths |
| FR1522465A (fr) * | 1967-03-15 | 1968-04-26 | Centre Nat Rech Scient | Compositions de revêtement invisibles à la lumière ordinaire et visibles dans l'ultra-violet |
| DE1717194A1 (de) * | 1968-01-03 | 1971-07-29 | Georg Dr Kallistratos | Leuchtschirm,insbesondere fuer Elektronenstrahlroehren zur Wiedergabe von Farbbildern |
| GB2061918B (en) * | 1979-08-31 | 1984-05-31 | Asahi Dow Ltd | Organic rare-earth salt phosphors |
| JPS5780476A (en) * | 1980-11-07 | 1982-05-20 | Asahi Chem Ind Co Ltd | Radiation calorescent material |
| JPS5783580A (en) * | 1980-11-12 | 1982-05-25 | Asahi Chem Ind Co Ltd | Temperature-light transducing material |
| JPS57108189A (en) * | 1980-12-25 | 1982-07-06 | Asahi Chem Ind Co Ltd | Temperature-light transducer |
-
1980
- 1980-08-22 GB GB8027344A patent/GB2061918B/en not_active Expired
- 1980-08-22 US US06/180,324 patent/US4443380A/en not_active Expired - Lifetime
- 1980-08-28 NL NL8004876A patent/NL8004876A/nl not_active Application Discontinuation
- 1980-08-28 FR FR8018692A patent/FR2464292A1/fr active Granted
- 1980-08-29 DE DE3032611A patent/DE3032611C2/de not_active Expired
- 1980-08-29 DE DE19803050703 patent/DE3050703C2/de not_active Expired
-
1982
- 1982-05-14 FR FR8208445A patent/FR2509319B1/fr not_active Expired
- 1982-06-30 US US06/393,678 patent/US4572803A/en not_active Expired - Fee Related
-
1983
- 1983-04-13 NL NL8301295A patent/NL8301295A/nl not_active Application Discontinuation
- 1983-04-28 GB GB08311562A patent/GB2128985B/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| NL8004876A (nl) | 1981-03-03 |
| FR2464292B1 (enExample) | 1984-04-20 |
| DE3050703C2 (de) | 1983-12-01 |
| FR2464292A1 (fr) | 1981-03-06 |
| DE3032611A1 (de) | 1981-03-26 |
| GB2061918A (en) | 1981-05-20 |
| FR2509319B1 (fr) | 1985-06-07 |
| GB2128985B (en) | 1984-11-14 |
| GB2128985A (en) | 1984-05-10 |
| NL8301295A (nl) | 1983-09-01 |
| GB2061918B (en) | 1984-05-31 |
| GB8311562D0 (en) | 1983-06-02 |
| FR2509319A1 (fr) | 1983-01-14 |
| US4572803A (en) | 1986-02-25 |
| US4443380A (en) | 1984-04-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE3032611C2 (de) | Organische Seltenerdsalzleuchtstoffe | |
| DE69521198T2 (de) | Elektrolumineszentesdünnschichtelement | |
| DE2353943C2 (de) | Leuchtstoff, Verfahren zu dessen Herstellung und dessen Verwendung | |
| DE19521119C5 (de) | Langsam abklingende phosphoreszierende Stoffe | |
| DE2654387C3 (de) | Erdalkalifluorhalogenid-Leuchtstoff | |
| DE1792502A1 (de) | Leuchtstoff auf Chalcogenidbasis mit einem Lanthanidenelement als Aktivator | |
| DE10163295B4 (de) | Seltenerdmetall-Verbindungen und Gemische von diesen, Verfahren zu deren Herstellung sowie deren Verwendung | |
| DE69909751T2 (de) | Verfahren zur herstellung rotstrahlenden phosphors von keinen partikeln mit hoher helligkeit und der phosphor | |
| DE2903073B2 (de) | Mit Nd und Yb coaktivierter Leuchtstoff | |
| DE102004010250A1 (de) | Fluoreszierendes Material aus Terbium-aluminium-Granat und Verfahren zu seiner Herstellung | |
| DE2201271C3 (de) | Verfahren zur Herstellung von Oxychalcogenid-Leuchtstoffen | |
| DE2209872A1 (enExample) | ||
| DE112008000505T5 (de) | Verfahren zur Darstellung von grün emittierenden Borat-Leuchtstoffen | |
| DE2704649C3 (de) | Durch Europium aktivierte Erdalkalisiliciumfluoride | |
| Amami et al. | Crystal structure and spectroscopic studies of NaGd (PO3) 4 | |
| DE2213898A1 (de) | Europium-aktivierte Erdalkali-Calcium-Alumini umfluorid-Leuchtstoffe | |
| DE2820889C2 (de) | Lumineszierende Substanz | |
| DE2628346A1 (de) | Leuchtstoffzusammensetzung und verfahren zu ihrer herstellung | |
| DE2625217C3 (de) | Zimtsäureester und diese enthaltende nematische Flüssigkristallmassen | |
| DE3404055A1 (de) | 2,5-disubstituierte pyridine, verfahren zu ihrer herstellung, fluessigkristallines material und elektrooptische vorrichtung | |
| DE2541748B2 (de) | Verfahren zur herstellung eines mit zweiwertigem europium aktivierten erdalkalifluorhalogenidleuchtstoffs | |
| DE1180474B (de) | Mischoxydhaltige Leuchtstoffzubereitungen | |
| DE2925740A1 (de) | Mit niederenergetischen elektronen erregte fluoreszenz-anzeigevorrichtung | |
| EP3728515B1 (de) | Erdalkalimetallsilikat-leuchtstoff und verfahren zum verbessern der langzeitstabilität eines erdalkalimetallsilikat-leuchtstoffes | |
| DE1800671C (de) | Leuchtstoff auf der Basis von Oxychalcogeniden seltener Erden |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OP8 | Request for examination as to paragraph 44 patent law | ||
| 8172 | Supplementary division/partition in: |
Ref country code: DE Ref document number: 3050703 Format of ref document f/p: P |
|
| Q171 | Divided out to: |
Ref country code: DE Ref document number: 3050703 |
|
| AH | Division in |
Ref country code: DE Ref document number: 3050703 Format of ref document f/p: P |
|
| D2 | Grant after examination | ||
| 8327 | Change in the person/name/address of the patent owner |
Owner name: ASAHI KASEI KOGYO K.K., OSAKA, JP |
|
| 8328 | Change in the person/name/address of the agent |
Free format text: SCHOENWALD, K., DR.-ING. FUES, J., DIPL.-CHEM. DR.RER.NAT. VON KREISLER, A., DIPL.-CHEM. KELLER, J., DIPL.-CHEM. SELTING, G., DIPL.-ING. WERNER, H., DIPL.-CHEM. DR.RER.NAT., PAT.-ANW., 5000 KOELN |
|
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |