DD291997A5 - Verfahren zur herstellung von propensaeurederivaten - Google Patents
Verfahren zur herstellung von propensaeurederivaten Download PDFInfo
- Publication number
- DD291997A5 DD291997A5 DD90337681A DD33768190A DD291997A5 DD 291997 A5 DD291997 A5 DD 291997A5 DD 90337681 A DD90337681 A DD 90337681A DD 33768190 A DD33768190 A DD 33768190A DD 291997 A5 DD291997 A5 DD 291997A5
- Authority
- DD
- German Democratic Republic
- Prior art keywords
- compound
- cyano
- formula
- ppm
- compounds
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
- C07D401/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
- C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
- C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
- C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
- C07D239/46—Two or more oxygen, sulphur or nitrogen atoms
- C07D239/52—Two oxygen atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D413/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
- C07D413/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings
- C07D413/12—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D417/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00
- C07D417/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings
- C07D417/12—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings linked by a chain containing hetero atoms as chain links
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Agronomy & Crop Science (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Plural Heterocyclic Compounds (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
- Nitrogen- Or Sulfur-Containing Heterocyclic Ring Compounds With Rings Of Six Or More Members (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB898903019A GB8903019D0 (en) | 1989-02-10 | 1989-02-10 | Fungicides |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DD291997A5 true DD291997A5 (de) | 1991-07-18 |
Family
ID=10651469
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DD90337681A DD291997A5 (de) | 1989-02-10 | 1990-02-08 | Verfahren zur herstellung von propensaeurederivaten |
Country Status (34)
| Country | Link |
|---|---|
| EP (1) | EP0382375B1 (nl) |
| JP (1) | JPH0672140B2 (nl) |
| KR (1) | KR0120741B1 (nl) |
| CN (1) | CN1023600C (nl) |
| AP (1) | AP126A (nl) |
| AT (1) | ATE103278T1 (nl) |
| AU (1) | AU625501B2 (nl) |
| BG (1) | BG61668B2 (nl) |
| BR (1) | BR9000591A (nl) |
| CA (1) | CA2008701C (nl) |
| CZ (1) | CZ282265B6 (nl) |
| DD (1) | DD291997A5 (nl) |
| DE (3) | DE122006000030I2 (nl) |
| DK (1) | DK0382375T3 (nl) |
| EG (1) | EG19307A (nl) |
| ES (1) | ES2063253T3 (nl) |
| GB (2) | GB8903019D0 (nl) |
| HK (1) | HK1005453A1 (nl) |
| HU (1) | HU204798B (nl) |
| IE (1) | IE66312B1 (nl) |
| IL (1) | IL93199A (nl) |
| LT (2) | LTIP868A (nl) |
| LU (1) | LU91197I2 (nl) |
| LV (1) | LV10018B (nl) |
| MD (1) | MD1006C2 (nl) |
| MY (1) | MY105613A (nl) |
| NL (3) | NL971016I2 (nl) |
| NZ (1) | NZ232275A (nl) |
| PL (2) | PL161278B1 (nl) |
| PT (1) | PT93089B (nl) |
| RU (2) | RU2019543C1 (nl) |
| SK (1) | SK279185B6 (nl) |
| TR (1) | TR27525A (nl) |
| ZA (1) | ZA90687B (nl) |
Families Citing this family (105)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8908875D0 (en) * | 1989-04-19 | 1989-06-07 | Ici Plc | Fungicides |
| GB9016783D0 (en) * | 1989-09-01 | 1990-09-12 | Ici Plc | Agrochemical compositions |
| IE74711B1 (en) | 1990-07-27 | 1997-07-30 | Ici Plc | Fungicides |
| GB9016584D0 (en) * | 1990-07-27 | 1990-09-12 | Ici Plc | Fungicides |
| GB9122430D0 (en) * | 1990-11-16 | 1991-12-04 | Ici Plc | Chemical process |
| TR25727A (tr) * | 1990-11-16 | 1993-09-01 | Ici Plc | Fenoksipirimidin bilesiklerini hazirlamaya mahsus yöntem. |
| US5760250A (en) * | 1991-11-05 | 1998-06-02 | Zeneca Limited | Process for the preparation of 3-(α-methoxy)methylenebenzofuranones and intermediates therefor |
| US6235887B1 (en) | 1991-11-26 | 2001-05-22 | Isis Pharmaceuticals, Inc. | Enhanced triple-helix and double-helix formation directed by oligonucleotides containing modified pyrimidines |
| GB9210830D0 (en) * | 1992-05-21 | 1992-07-08 | Ici Plc | Fungicidial composition |
| IL106324A (en) * | 1992-07-17 | 1998-09-24 | Shell Int Research | Transformed pyrimidine compounds, their preparation and use as pesticides |
| GB9305039D0 (en) * | 1993-03-11 | 1993-04-28 | Zeneca Ltd | Herbicidal composition |
| GB9307247D0 (en) * | 1993-04-07 | 1993-06-02 | Zeneca Ltd | Fungicidal compounds |
| US5436248A (en) * | 1993-07-02 | 1995-07-25 | Ciba-Geigy Corporation | Microbicides |
| EP0648417B1 (de) * | 1993-09-24 | 1996-12-04 | BASF Aktiengesellschaft | Fungizide Mischungen |
| JP3307026B2 (ja) * | 1993-11-04 | 2002-07-24 | 住友化学工業株式会社 | 農園芸用殺菌組成物 |
| DE4340181A1 (de) * | 1993-11-25 | 1995-06-01 | Bayer Ag | 3-Methoxy-2-phenyl-acrylsäuremethylester |
| GB9404375D0 (en) * | 1994-03-07 | 1994-04-20 | Zeneca Ltd | Fungicides |
| DE4426753A1 (de) * | 1994-07-28 | 1996-02-01 | Bayer Ag | Mittel zur Bekämpfung von Pflanzenschädlingen |
| DE4444911A1 (de) * | 1994-12-16 | 1996-06-27 | Basf Ag | Fungizide Mischung |
| DE19522712A1 (de) * | 1995-06-22 | 1997-01-02 | Basf Ag | Lagerstabile, wäßrige Fungizid-Formulierung |
| TW318777B (nl) * | 1995-06-29 | 1997-11-01 | Novartis Ag | |
| AU6788196A (en) * | 1995-08-17 | 1997-03-12 | Basf Aktiengesellschaft | Fungicidal mixtures |
| TW384208B (en) | 1995-09-22 | 2000-03-11 | Basf Ag | Compositions and methods for controlling harmful fungi |
| TW401275B (en) | 1995-09-25 | 2000-08-11 | Basf Ag | Compositions and methods of controlling harmful fungi |
| DE19623061A1 (de) * | 1996-06-10 | 1997-12-11 | Bayer Ag | Aryloxyacrylsäureester |
| GB9622345D0 (en) * | 1996-10-28 | 1997-01-08 | Zeneca Ltd | Chemical process |
| DE19710609A1 (de) * | 1997-03-14 | 1998-09-17 | Bayer Ag | Substituierte Aminosalicylsäureamide |
| PL337157A1 (en) | 1997-06-04 | 2000-07-31 | Basf Ag | Fungicidal mixtures |
| EP0897664A1 (fr) * | 1997-08-22 | 1999-02-24 | Chimac-Agriphar S.A. | Composition fongicide |
| US5849910A (en) * | 1997-09-05 | 1998-12-15 | American Cyanamid Company | Process for the preparation of unsymmetrical 4,6-bis aryloxy-pyrimidine compounds |
| WO1999063820A1 (fr) * | 1998-06-11 | 1999-12-16 | Shionogi & Co., Ltd. | Compositions bactericides utilisees en agriculture et horticulture et contenant de l'acide silicique et/ou du silicate de potassium |
| WO2000015637A1 (en) * | 1998-09-16 | 2000-03-23 | Dow Agrosciences Llc | 2-methoxyimino -2-(pyridinyloxymethyl) phenyl acetamides with 5 membered heterocyclic rings on the pyridine ring as fungicides |
| EP0986965A1 (en) * | 1998-09-18 | 2000-03-22 | Janssen Pharmaceutica N.V. | Antifungal food coatings |
| AU3154601A (en) | 1999-11-18 | 2001-05-30 | Basf Aktiengesellschaft | Non-aqueous concentrated spreading oil composition |
| GB0010198D0 (en) * | 2000-04-26 | 2000-06-14 | Novartis Ag | Organic compounds |
| IT1318599B1 (it) * | 2000-06-28 | 2003-08-27 | Alfredo Martini | Impiego di azossistrobina come conservante di prodotti alimentari. |
| JP4581102B2 (ja) * | 2000-12-05 | 2010-11-17 | クミアイ化学工業株式会社 | ストロビルリン系殺菌剤の効力増強剤及びその方法。 |
| US7687434B2 (en) | 2000-12-22 | 2010-03-30 | Monsanto Technology, Llc | Method of improving yield and vigor of plants |
| DE10140269A1 (de) | 2001-08-16 | 2003-02-27 | Degussa | Verfahren zur Herstellung von 4,6-Dihydroxypyrimidin |
| WO2004043150A1 (de) | 2002-11-12 | 2004-05-27 | Basf Aktiengesellschaft | Verfahren zur ertragssteigerung bei glyphosate resistenten leguminosen |
| DE10347090A1 (de) | 2003-10-10 | 2005-05-04 | Bayer Cropscience Ag | Synergistische fungizide Wirkstoffkombinationen |
| DE10349501A1 (de) | 2003-10-23 | 2005-05-25 | Bayer Cropscience Ag | Synergistische fungizide Wirkstoffkombinationen |
| UA85690C2 (ru) | 2003-11-07 | 2009-02-25 | Басф Акциенгезелльшафт | Смесь для применения в сельском хозяйстве, содержащая стробилурин и модулятор этилена, способ обработки и борьбы с инфекциями в бобовых культурах |
| EA011813B1 (ru) | 2004-04-30 | 2009-06-30 | Басф Акциенгезельшафт | Фунгицидные смеси |
| AR049400A1 (es) * | 2004-06-17 | 2006-07-26 | Basf Ag | Uso de (e)-5-(4-clorobenciliden)-2, 2-dimetil -1-(1h-1, 2, 4-triazol-1-il-metil)-ciclop entanol para combatir la infestacion de plantas de soja por accion de la roya |
| DE102004049761A1 (de) | 2004-10-12 | 2006-04-13 | Bayer Cropscience Ag | Fungizide Wirkstoffkombinationen |
| DE102005015850A1 (de) | 2005-04-07 | 2006-10-12 | Bayer Cropscience Ag | Synergistische fungizide Wirkstoffkombinationen |
| BRPI0612022B1 (pt) | 2005-06-09 | 2016-12-06 | Bayer Cropscience Ag | combinações de substâncias ativas, seus usos, processos para combater fungos fitopatogênicos indesejáveis, processo para preparar composições fungicidas, revestimento de semente, e processos para revestir semente e semente transgênica |
| DE102005026482A1 (de) | 2005-06-09 | 2006-12-14 | Bayer Cropscience Ag | Wirkstoffkombinationen |
| CN100443463C (zh) * | 2005-06-28 | 2008-12-17 | 沈阳化工研究院 | 取代的对三氟甲基苯醚类化合物及其制备与应用 |
| DE102005035300A1 (de) | 2005-07-28 | 2007-02-01 | Bayer Cropscience Ag | Synergistische fungizide Wirkstoffkombinationen |
| ITMI20051558A1 (it) | 2005-08-09 | 2007-02-10 | Isagro Spa | Miscele e-o composizioni sinergiche cin elevata attivita'fungicida |
| US8273686B2 (en) | 2006-03-24 | 2012-09-25 | Basf Se | Method for combating phytopathogenic fungi |
| DE102006022758A1 (de) | 2006-05-16 | 2007-11-29 | Bayer Cropscience Ag | Fungizide Wirkstoffkombinationen |
| DE102006023263A1 (de) | 2006-05-18 | 2007-11-22 | Bayer Cropscience Ag | Synergistische Wirkstoffkombinationen |
| EA026766B1 (ru) | 2006-09-18 | 2017-05-31 | Басф Се | Антраниламидсульфамоильное соединение и его применение в сельском хозяйстве |
| IL180134A0 (en) * | 2006-12-17 | 2007-07-04 | David Ovadia | Process for the preparation of substituted cyanophenoxy-pyrimidinyloxy -phenyl acrylate derivatives |
| IL181125A0 (en) | 2007-02-01 | 2007-07-04 | Maktheshim Chemical Works Ltd | Polymorphs of 3-(e)-2-{2-[6-(2- |
| EP2679096A1 (en) | 2007-02-06 | 2014-01-01 | Basf Se | Pesticidal mixtures |
| CN101668860B (zh) | 2007-04-23 | 2014-02-12 | 巴斯夫欧洲公司 | 组合化学剂和转基因修饰增强植物生产力 |
| EP2000030A1 (de) | 2007-06-06 | 2008-12-10 | Bayer CropScience AG | Fungizide Wirkstoffkombinationen |
| JP2010540495A (ja) | 2007-09-26 | 2010-12-24 | ビーエーエスエフ ソシエタス・ヨーロピア | ボスカリド及びクロロタロニルを含む三成分殺菌組成物 |
| DE102007045920B4 (de) | 2007-09-26 | 2018-07-05 | Bayer Intellectual Property Gmbh | Synergistische Wirkstoffkombinationen |
| KR20100135711A (ko) | 2007-12-20 | 2010-12-27 | 엔비보 파마슈티칼즈, 인코퍼레이티드 | 사중치환된 벤젠 |
| RU2352114C1 (ru) * | 2008-01-10 | 2009-04-20 | Закрытое акционерное общество "Щелково Агрохим" | Фунгицидная композиция в виде микроэмульсии |
| LT2300013T (lt) | 2008-05-21 | 2017-12-27 | Ariad Pharmaceuticals, Inc. | Fosforo dariniai kaip kinazių inhibitoriai |
| US9273077B2 (en) | 2008-05-21 | 2016-03-01 | Ariad Pharmaceuticals, Inc. | Phosphorus derivatives as kinase inhibitors |
| KR101647703B1 (ko) | 2009-03-25 | 2016-08-11 | 바이엘 인텔렉쳐 프로퍼티 게엠베하 | 상승적 활성 성분 배합물 |
| JP5690514B2 (ja) * | 2009-06-30 | 2015-03-25 | 株式会社堀場製作所 | アゾキシストロビン誘導体、アゾキシストロビンに対する抗体またはそのフラグメント、ならびにそれらの抗体またはフラグメントを用いた測定キットおよび測定方法 |
| JP5642786B2 (ja) | 2009-07-16 | 2014-12-17 | バイエル・クロップサイエンス・アーゲーＢａｙｅｒ Ｃｒｏｐｓｃｉｅｎｃｅ Ａｇ | フェニルトリアゾール類を含む相乗的活性化合物組み合わせ |
| WO2011012458A1 (en) | 2009-07-28 | 2011-02-03 | Basf Se | A method for increasing the level of free amino acids in storage tissues of perennial plants |
| WO2011026796A1 (en) | 2009-09-01 | 2011-03-10 | Basf Se | Synergistic fungicidal mixtures comprising lactylates and method for combating phytopathogenic fungi |
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| BRPI1003373A2 (pt) | 2010-09-29 | 2013-01-29 | Fmc Quimica Do Brasil Ltda | combinaÇÕes sinÉrgicas de triazàis, estrobirulinas e benzimidazàis, usos, formulaÇÕes, processos de produÇço e aplicaÇÕes utilizando a mesma |
| PT105407B (pt) | 2010-11-26 | 2016-09-30 | Sapec Agro S A | Mistura fungicida |
| WO2012084670A1 (en) | 2010-12-20 | 2012-06-28 | Basf Se | Pesticidal active mixtures comprising pyrazole compounds |
| EP2481284A3 (en) | 2011-01-27 | 2012-10-17 | Basf Se | Pesticidal mixtures |
| WO2012121120A1 (ja) * | 2011-03-09 | 2012-09-13 | 住友化学株式会社 | 有害生物防除組成物及び有害生物の防除方法 |
| ES2660555T3 (es) | 2011-03-23 | 2018-03-22 | Basf Se | Composiciones que contienen compuestos iónicos, poliméricos que comprenden grupos imidazolio |
| CN103501612B (zh) | 2011-05-04 | 2017-03-29 | 阿里亚德医药股份有限公司 | 抑制表皮生长因子受体导致的癌症中细胞增殖的化合物 |
| CN102217642A (zh) * | 2011-05-06 | 2011-10-19 | 浙江泰达作物科技有限公司 | 一种氟硅唑和嘧菌酯复配的杀菌剂悬浮剂及其制备方法 |
| JP5997931B2 (ja) | 2011-05-25 | 2016-09-28 | 石原産業株式会社 | 農園芸用殺菌剤組成物及び植物病害の防除方法 |
| MX2014001866A (es) | 2011-09-02 | 2015-04-16 | Basf Se | Mezclas agricolas que comprenden compuestos de arilquinazolinona. |
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| CN103385252B (zh) * | 2012-05-12 | 2017-02-15 | 青岛金尔农化研制开发有限公司 | 一种含嘧螨酯的农药组合物 |
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| WO2015036059A1 (en) | 2013-09-16 | 2015-03-19 | Basf Se | Fungicidal pyrimidine compounds |
| CN105722833A (zh) | 2013-09-16 | 2016-06-29 | 巴斯夫欧洲公司 | 杀真菌的嘧啶化合物 |
| CN104430366A (zh) * | 2013-09-24 | 2015-03-25 | 中国中化股份有限公司 | 取代芳醚类化合物作为抗植物病毒剂的应用 |
| CN104725321B (zh) * | 2013-12-20 | 2017-11-21 | 上海泰禾国际贸易有限公司 | 一种嘧菌酯中间体的制备方法 |
| EP2979549A1 (en) | 2014-07-31 | 2016-02-03 | Basf Se | Method for improving the health of a plant |
| RU2707051C2 (ru) | 2014-10-24 | 2019-11-21 | Басф Се | Неамфолитные, кватернизируемые и водорастворимые полимеры для модифицирования поверхностного заряда твердых частиц |
| EP2910126A1 (en) | 2015-05-05 | 2015-08-26 | Bayer CropScience AG | Active compound combinations having insecticidal properties |
| ES2873388T3 (es) | 2015-07-02 | 2021-11-03 | Basf Agro Bv | Composiciones plaguicidas que comprenden un compuesto de triazol |
| CN108689950B (zh) * | 2018-05-15 | 2021-06-11 | 河南省科学院高新技术研究中心 | [(6-取代-嘧啶-4-基氧)苯基]-3-甲氧基丙烯酸甲酯 |
| WO2020136130A1 (de) | 2018-12-28 | 2020-07-02 | Saltigo Gmbh | Verbessertes verfahren zur herstellung von 4,6-dihydroxypyrimidin |
| BR112021020906A2 (pt) * | 2019-04-18 | 2022-04-19 | Upl Ltd | Processo para a preparação de azoxistrobina e intermediários da mesma |
| BR112021020912A2 (pt) * | 2019-04-18 | 2022-06-07 | Upl Ltd | Processo para o preparo de compostos de estrobilurina ativos como fungicidas, e intermediários dos mesmos |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS608203A (ja) * | 1983-06-29 | 1985-01-17 | Mitsui Toatsu Chem Inc | ピリミジン誘導体を有効成分とする農園芸用殺菌剤 |
| NZ213630A (en) * | 1984-10-19 | 1990-02-26 | Ici Plc | Acrylic acid derivatives and fungicidal compositions |
| EP0242070A3 (en) * | 1986-04-17 | 1988-12-28 | Imperial Chemical Industries Plc | Phenyl-acrylic acid ester derivatives, process for their preparation and their use as fungicides |
| EP0391451A1 (en) * | 1986-04-17 | 1990-10-10 | Imperial Chemical Industries Plc | Fungicides |
| GB8620251D0 (en) * | 1986-08-20 | 1986-10-01 | Ici Plc | Fungicides |
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1989
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1990
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1992
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1993
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2006
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