WO1999063820A1 - Compositions bactericides utilisees en agriculture et horticulture et contenant de l'acide silicique et/ou du silicate de potassium - Google Patents

Compositions bactericides utilisees en agriculture et horticulture et contenant de l'acide silicique et/ou du silicate de potassium Download PDF

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Publication number
WO1999063820A1
WO1999063820A1 PCT/JP1999/003063 JP9903063W WO9963820A1 WO 1999063820 A1 WO1999063820 A1 WO 1999063820A1 JP 9903063 W JP9903063 W JP 9903063W WO 9963820 A1 WO9963820 A1 WO 9963820A1
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WO
WIPO (PCT)
Prior art keywords
agricultural
horticultural
active compound
fungicide composition
acid
Prior art date
Application number
PCT/JP1999/003063
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English (en)
Japanese (ja)
Inventor
Ryuichi Kume
Akihisa Uesugi
Riichi Hasegawa
Original Assignee
Shionogi & Co., Ltd.
Nissan Chemical Industries, Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shionogi & Co., Ltd., Nissan Chemical Industries, Ltd. filed Critical Shionogi & Co., Ltd.
Priority to AU40608/99A priority Critical patent/AU4060899A/en
Publication of WO1999063820A1 publication Critical patent/WO1999063820A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
    • A01N37/50—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids the nitrogen atom being doubly bound to the carbon skeleton
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines

Definitions

  • the present invention relates to a fungicide composition for agricultural and horticultural use. More specifically, the present invention relates to a fungicide composition for agricultural and horticultural use containing a stomatovirulic fungicidal active compound, and caic acid and potassium or potassium silicate, which can reduce phytotoxicity.
  • a stoma virulin compound has an antibacterial activity against yeast and several kinds of fungi (for example, Plant Protection, Vol. 7, No. 7, pp. 268-290 (1994)). Some of them are known to have insecticidal or herbicidal activity.
  • stoichiometric bilulin compounds are used as fungicides, insecticides, herbicides, etc. (for example, Patent No. 2555801, European Patent Publication No. See Japanese Patent Publication No. 3822375, Japanese Patent Application Laid-Open No. HEI 4-182649, and Japanese Patent Application Laid-Open No. H4-288045).
  • Patent No. 2555801 European Patent Publication No. See Japanese Patent Publication No. 3822375, Japanese Patent Application Laid-Open No. HEI 4-182649, and Japanese Patent Application Laid-Open No. H4-288045.
  • these stoline virulin compounds are used, for example, as agricultural and horticultural fungicides, excellent disease control effects can be obtained, but there is a problem that phytotoxicity often occurs.
  • An object of the present invention is to provide a fungicide composition for agricultural and horticultural use that exhibits an excellent disease control effect and hardly causes phytotoxicity.
  • the present inventors have conducted intensive studies on the above-mentioned problems, and as a result, by adding caic acid and potassium or silicate to the virulin-based bactericidal active compound, the phytotoxicity caused by the virulin-based bactericidal active compound is significantly reduced. And completed this invention.
  • the present invention relates to an agricultural and horticultural fungicide composition
  • an agricultural and horticultural fungicide composition comprising (1) at least one kind of stoline viruline fungicidally active compound, and caiiic acid and Z or potassium gayate; (2) at least one kind of strobilurin
  • the present invention relates to a fungicidal composition for agricultural and horticultural use containing a bactericidal active compound and potassium silicate, and (3) a fungicidal composition for agricultural and horticultural use containing metominostrobin and rhodium silicate.
  • the strobilurin bactericidal active compound is selected from the group consisting of methinostrobin, azoxystrobin and kresoximmethyl.
  • the strobilurin fungicidally active compound is methominostrobin.
  • the above citric acid and Z or potassium gayate are contained in a ratio of 0.1 to 20 parts by weight with respect to 1 part by weight of the above-mentioned stomatovirulic fungicidally active compound.
  • the agricultural / horticultural fungicide composition further contains a water absorbing agent.
  • the water absorbing agent is anhydrous sodium sulfate.
  • the present invention also relates to a method of using the agricultural and horticultural fungicide composition, which comprises a step of applying the composition to a plant, a plant seed, or soil or water for growing the plant.
  • BEST MODE FOR CARRYING OUT THE INVENTION "Kiic acid” used in the agricultural and horticultural fungicide composition of the present invention refers to a silicon oxide, preferably a natural kaic acid, more preferably diatomaceous earth (tripolite). , Or dia tomite). It should be noted that hydrated kaic acid is excluded.
  • the content of the citric acid and / or potassium silicate in the agricultural and horticultural fungicide composition of the present invention is preferably 0.1 to 20 parts by weight based on 1 part by weight of the stomatal bilulin-based fungicidally active compound described below. , More preferably 0.1 to 10 parts by weight, most preferably 0.1 to 4 parts by weight.
  • any known strobilurin fungicidal active compound can be used.
  • the stoline virulin bactericidal active compound is disclosed in Japanese Patent No. 2558001, European Patent Publication No. 2532-13, European Patent Publication No. 382375, Japanese Patent Publication No. 4-182461, Japanese Patent Publication No. It is described in 4-2-188045 and the like.
  • a typical structure of a strobilurin fungicidal compound is shown below.
  • 13 ⁇ 4 & Oyobi 1 15 are each independently hydrogen, lower alkyl, lower alkoxy, halogenated lower alkyl, lower alkyl silyl, halogen or two Bok port;
  • A represents a substituent selected from the group consisting of: R z O ⁇
  • R 5 A-7 wherein RR 2 and R 3 are each independently a lower alkyl group, R 4 is a lower alkyl group or a lower alkyloxy group, and R 5 is a lower alkyloxy group or a lower alkyloxy group.
  • B represents a substituent selected from the group consisting of:
  • R 6 is a lower alkyl group or a lower alkylthio group
  • R 7 is a lower alkyl group, a phenyl group or a substituted phenyl group
  • R 8 is a lower alkyl group, a phenyl group, a substituted phenyl group or a lower alkoxy group.
  • a carbonyl group R 9 is a lower alkyl group
  • R 1 D is a hydrogen atom or a lower alkyl group
  • E is a phenyl group, a substituted phenyl group or a substituted heterocyclic group
  • G is an aralkyl group. Or a substituted aralkyl group.
  • substituted in various groups refers to, for example, lower alkyl, lower alkoxy, lower alkyl halide, lower alkylated silyl, halogen, nitro or cyano.
  • substituent A in various groups indicates that the group has, for example, 8 or less, preferably 6 or less, more preferably 4 or less carbon atoms.
  • substituent A include the following groups:
  • the combination of a strobilurin-based fungicidally active compound and a keic acid and / or a gay acid power rim may be a combination of metominostrobin with a keic acid and / or Z or a potassium acid strength rim.
  • Preferred is a combination of metominost vial and potassium silicate.
  • the agricultural / horticultural fungicide composition of the present invention can be used in various preparation forms.
  • formulations include solutions, emulsions, suspensions, powders, granules (including tablets), wettable powders, pastes, Formulations with aerosols, microcapsules, seed coatings, combustion devices (eg smoke and fume cartridges, cans, and coils); LV (ultra low volume or mu lation); ) [Cold mist] or [warm mist], and a control liquid for spraying.
  • these preparations contain various additives (for example, liquid diluents, liquefied gas diluents, solid diluents, solid carriers, emulsifiers, foam formers, dispersants, fixing agents, colorants, disintegrants) ⁇ Spreading agents).
  • additives for example, liquid diluents, liquefied gas diluents, solid diluents, solid carriers, emulsifiers, foam formers, dispersants, fixing agents, colorants, disintegrants.
  • liquid diluents examples include ethers (eg, benzyl ether), esters (eg, octyl adipate, butyl stearate, butyl laurate, soybean oil, castor oil) , Olive oil, rapeseed oil), aromatic hydrocarbons [eg, 1-phenyl-1-xylylethane (Hisol SAS-296; Nippon Petrochemical Co., Ltd.), Solvesso ⁇ 00, Solvesso # 1 50, Solvesso # 200 (Exxon Chemical Co., Ltd.), xylene, toluene, getylbenzene, triethylbenzene, cumene, alkylnaphthylene (eg, methylnaphthylene)], chlorinated aromatic or chlorinated fat Aliphatic hydrocarbons (eg, chlorobenzene, ethylene chloride, methylene chloride,
  • the liquefied gas diluents that can be used in the aerosol include compounds that are in a gaseous state at room temperature and pressure, for example, aerosol injections such as butane, propane, nitrogen gas, carbon dioxide, and halogenated hydrocarbons. Agents, etc.
  • solid diluents that can be used in the above powders include soil natural minerals (for example, power ore, clay (for example, Keiwa Fine Powder Clay; Keiwa Furnace Inc.)), talc, chalk, quartz, agar palgitite, Montmorillonite, calcium carbonate, potassium chloride, Gypsum, bentonite (for example, Kunigel VI; Kunimine Industries), soil synthetic minerals except for caicic acid and potassium silicate (for example, alumina, olivine, pyroxene, amphibolite, mica, quartz) And the like.
  • soil natural minerals for example, power ore, clay (for example, Keiwa Fine Powder Clay; Keiwa Furnace Inc.)
  • talc chalk, quartz, agar palgitite, Montmorillonite, calcium carbonate, potassium chloride, Gypsum
  • bentonite for example, Kunigel VI; Kunimine Industries
  • soil synthetic minerals for example, alumina, olivine,
  • solid carriers examples include crushed and fractionated rocks (eg, calcite, marble, pumice, sepiolite, dolomite), and synthetic particles of inorganic and organic powders (eg, hydrated calcium acid ( Carplex; Shionogi Pharmaceutical Co., Ltd.), a synthetic product of smectite and zeolite), and fine particles of plant substances (for example, sawdust, coconut, corn cob, tobacco leaf), etc. Is mentioned.
  • crushed and fractionated rocks eg, calcite, marble, pumice, sepiolite, dolomite
  • synthetic particles of inorganic and organic powders eg, hydrated calcium acid ( Carplex; Shionogi Pharmaceutical Co., Ltd.), a synthetic product of smectite and zeolite
  • fine particles of plant substances for example, sawdust, coconut, corn cob, tobacco leaf
  • a water absorbing agent As the water absorbing agent, anhydrous sodium sulfate is preferable.
  • the water-absorbing agent can act as a component for dehydrating the agricultural / horticultural fungicide composition and promoting solidification, powdering, or granulation.
  • the content of anhydrous sodium sulfate in the powder or granules is preferably 1% to 80% by weight, more preferably 5% to 60% by weight, most preferably 10% to 4% by weight. 0% by weight.
  • emulsifier and / or foam-forming agent examples include nonionic and anionic emulsifiers usually used in the field of agricultural chemicals (for example, polyoxyethylene fatty acid ester, and alkylaryl polyglycol ether, alkyl sulfonate, Alkyl sulfates, polyoxyethylene fatty acid alcohol ethers such as aryl sulfonates), and albumin hydrolysis products.
  • nonionic and anionic emulsifiers usually used in the field of agricultural chemicals (for example, polyoxyethylene fatty acid ester, and alkylaryl polyglycol ether, alkyl sulfonate, Alkyl sulfates, polyoxyethylene fatty acid alcohol ethers such as aryl sulfonates), and albumin hydrolysis products.
  • Solpol 3880H a mixture of P0E styrylphenyl, P0E styrylphenyl ether polymer and alkylarylsulfonate; Toho Chemical Industry
  • Solbol 355L a mixture of P0E styrylphenyl and alkylsulfonate; Toho Chemical Industry
  • New Cargen TG-74 P0A mixture of arylphenyl ether sulfate NII 4 and alkylbenzenesulfonic acid Na Product: Takemoto oils and fats
  • Newcalgen P-150 is preferable.
  • Dispersants that can be used in the above emulsions and suspensions include lignin sulphite solution and methyl cellulose.
  • Fixatives that can be used in the above powders and granules include carboxymethyl cellulose, natural and synthetic polymers (eg, gum arabic, polyvinyl alcohol, polyvinyl acetate) and the like.
  • Colorants that can be used in any of the above formulations include inorganic pigments (eg, iron oxide, titanium oxide, Brussian blue, iron pigments, manganese pigments, boron pigments, copper pigments, trace element pigments), organic dyes (eg, , Alizarin dyes, metal phthalocyanine dyes).
  • inorganic pigments eg, iron oxide, titanium oxide, Brussian blue, iron pigments, manganese pigments, boron pigments, copper pigments, trace element pigments
  • organic dyes eg, Alizarin dyes, metal phthalocyanine dyes.
  • disintegrating and spreading agents used in the above emulsions and suspensions include polycarboxylic acid surfactants such as toxanone (GR-31A; Sanyo Chemical Industries) and Newcalgen-I TG33 (Takemoto Yushi). Mixtures of polycarboxylic acid and naphthalene sulfonic acid surfactants such as Newcalgen TG250 (Takemoto Oil & Fat), polyacrylic acid surfactants such as BOYS 530 (Kao), Solbol 5060 (Toho Chemical Industry), etc. Sulfonate type Z phosphates may be mentioned.
  • polycarboxylic acid surfactants such as toxanone (GR-31A; Sanyo Chemical Industries) and Newcalgen-I TG33 (Takemoto Yushi). Mixtures of polycarboxylic acid and naphthalene sulfonic acid surfactants such as Newcalgen TG250 (Takemoto Oil & Fat), polyacrylic acid surfactants such as BOYS 530 (Kao), Solbol
  • the fungicide composition for agricultural and horticultural use of the present invention further comprises other fungicides, pesticides, herbicides, acaricides, nematicides, bird repellents, growth regulators, fertilizers, soil improvers, etc. It may contain one or more active ingredients.
  • active ingredients exemplified below are general names unless otherwise indicated.
  • Fungicides include, for example, isoprothiolane, iprodione, oxine copper, captan, diclocymet, diclomedine, thifluzamide, tricyclazole, fenarimol, flametopil, furaside, flutranil, proquilon, probenazole, pentocyclone, C And so on.
  • insecticides for example, acetoamipyride, acephate, amitraz, Midacloprid, etofenprox, cartap, carbosurphan, clofuentezin, fenbutin oxide, diazinon, thiodicarb, bifentrin, pimetrozin, pyridaben, fipronil, fenisopromorate, bupu fenadine, propabos , Benfracarb, NAC (also known as force ruvalil) and the like.
  • insecticides for example, acetoamipyride, acephate, amitraz, Midacloprid, etofenprox, cartap, carbosurphan, clofuentezin, fenbutin oxide, diazinon, thiodicarb, bifentrin, pimetrozin, pyridaben, fipronil, fenisopromorate, bupu fenadine
  • herbicides include ACN (compound name 2-amino-3-chloro-1,4-naphthoquinone), azimusulfuron, atrazine, anilofos, ametrine, amaminofos, imazosulfuron, esprocalp, ethoxysulfuron, ethoxybenzamide, evoxaprodan , cafentrol, Quizarophopethyl, Glufosinate, Chromethoxinil, Cyclosulfamuron, Dichyl pill, Sihahopbutyl, Sinosulfuron, Simazine, Dimethamethrin, Symmethillin, Swep, Sulfamuron, Daimlon, Teniclor, Triflururalin , Bifenox, birazosulfronethyl, pyrazolate, pyributicarb, pyriminobac-methyl, pyrethirachlor, bushimi , Prodamine,
  • the agricultural and horticultural fungicide composition of the present invention can be formulated into the above-mentioned various formulation forms by a method known in the art.
  • solutions, emulsions, and suspensions are prepared by adding the stoichiovirin biocidally active compound and a suitable acid diluent to the addition of a silicic acid and Z- or potassium-acid lysate, and optionally adding a surfactant (ie, a surfactant).
  • a surfactant ie, a surfactant
  • Dusts and granules are composed of stoline virulin fungicidally active compound and Can be formulated by mixing potassium silicate with a solid diluent and a solid carrier, respectively.
  • the strobilurin-based fungicidally active compound is pulverized if necessary, mixed with various additives, and then kneaded by adding a solvent and Z or an appropriate amount of water as required. After that, molding by extrusion granulation, drying, and granulation may be mentioned.
  • the fungicide composition for agricultural and horticultural use of the present invention can be produced by a conventional method, for example, spraying a liquid, dipping, spraying, fumigation, smoke, irrigation, suspension formation, application, dusting, dusting, dressing, wet clothes, water surface. It can be applied to plants, plant seeds, soil around the plants, seed seeding soil, paddy fields, hydroponic water, etc. by application, wet coating, pasty coating, or feather coating.
  • the application amount of the agricultural and horticultural fungicide composition of the present invention may vary depending on the formulation form, application method, application target, and the like.
  • the concentration of the stomatovirin fungicide is generally from 0.001 to 1% by weight, preferably from 0.001 to 0.5% by weight.
  • the composition When applied to seeds, the composition is generally prepared such that the stoline virulin fungicide is present in an amount of 0.001 to 50 g, preferably 0.01 to 10 g per kg of seed. use.
  • the composition is generally used in such a manner that the amount of the stoline pyrulin fungicide per hectare of soil is from 1 g to 5.0 kg, preferably from 10 g to 0 kg.
  • the fungicide composition for agricultural and horticultural use of the present invention, phytotoxicity can be reduced while maintaining an excellent disease control effect against diseases such as imochi disease.
  • the keic acid and the Z- or potassium acid lime contained in the composition of the present invention have an advantage of functioning as a fertilizer.
  • it can prevent rice from lodging and increase resistance and salt tolerance to rice pests such as imochi disease, sesame hagare disease, and two-strength beetle, and increase rice yield.
  • Example 1 3 kg of paddy soil (clay loam) was placed in each of three Wagner pots with a surface area of 1 / 100,000, and flooded. After 3 days of tillage and shaving, the 2.2 leaf stage Three rice seedlings (Koshihikari) were transplanted to the center of each pot. Twenty-eight days after rice transplantation, the granular drug prepared in Example 1 was applied to each pot in an amount of 1 kg or 2 kg per 10 ares.
  • paddy rice was transplanted to three Wagner bots, and the granular drug prepared in Comparative Example 1 was applied to each pot.
  • the phytotoxicity index was determined according to the following criteria. The results are shown in Tables 1 and 2, respectively.
  • the phytotoxicity index for each leaf position indicates the average value of the phytotoxicity indexes of each paddy in three bots, that is, a total of nine rice varieties.
  • the symbol L indicates the leaf position, for example, 11 L indicates the first to first leaves from the bottom.
  • the criteria for the phytotoxicity index are as follows:
  • the paddy rice to which the granular drug obtained in the examples of the present invention was applied had a greater degree of spotting than the rice to which the granular drug obtained in the comparative example was applied. It was low.
  • a granular drug is obtained in the same manner as in Example 1, except that caiic acid is used in place of potassium silicate. (Example 3)
  • Example 3 3 kg of paddy soil (clay loam) was placed in a Wagner pot (corresponding to an area of 1 / 5,000 areal) and flooded.
  • Rice (Koshihikari) seedlings (plant height 18 cm, number of roots 7 and root length 6 cm) were transplanted to the center of the pot.
  • 49 days after transplantation of rice the granular drug prepared in Example 3_1 was applied to the pot at the equivalent of 1 kg per 10 ares at the 10th leaf stage of the leaf age of rice, the height of the plant was 86 cm, and the number of stems was 11 stems. Applied.
  • the use of normal disinfectants may cause user anxiety due to the occurrence of drug spots.
  • the use of the agricultural / horticultural fungicide composition of the present invention can reduce such phytotoxicity.
  • this fungicide composition may also be effective as a fertilizer with gay acid and Z or potassium silicate.

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

L'invention porte sur des compositions bactéricides utilisées en agriculture et en horticulture et contenant au moins un composé de strobilurine ayant une activité bactéricide, et de l'acide silicique et/ou du silicate de potassium. Il est possible de remédier aux dégâts chimiques à l'aide de ces compositions et de conserver un excellent effet permettant de lutter contre des maladies provoquées par des accidents du souffle, par exemple.
PCT/JP1999/003063 1998-06-11 1999-06-08 Compositions bactericides utilisees en agriculture et horticulture et contenant de l'acide silicique et/ou du silicate de potassium WO1999063820A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU40608/99A AU4060899A (en) 1998-06-11 1999-06-08 Agricultural/horticultural bactericide compositions containing silicic acid and/or potassium silicate

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP16401498 1998-06-11
JP10/164014 1998-06-11

Publications (1)

Publication Number Publication Date
WO1999063820A1 true WO1999063820A1 (fr) 1999-12-16

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000074484A1 (fr) * 1999-06-04 2000-12-14 Shionogi & Co., Ltd. Composition fongicide a base de strobilurine a dommage chimique reduit
KR20200060653A (ko) * 2018-11-22 2020-06-01 동의대학교 산학협력단 스마트팜의 천연 추출물 및 혼합 분무 장치

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6323852A (ja) * 1986-07-16 1988-02-01 バスフ　アクチェンゲゼルシャフト オキシムエーテル及び該化合物を含有する農園芸用殺菌剤
JPH0211586A (ja) * 1988-05-06 1990-01-16 Basf Ag 新規なストロビルリン誘導体、その製法及び使用
JPH02264765A (ja) * 1989-02-10 1990-10-29 Imperial Chem Ind Plc <Ici> 殺菌性化合物、その製造法及びそれを含有する殺菌剤組成物
JPH03246268A (ja) * 1989-05-17 1991-11-01 Shionogi & Co Ltd アルコキシイミノ酢酸アミド化合物および農業用殺菌剤
JPH0769812A (ja) * 1993-07-02 1995-03-14 Ciba Geigy Ag 殺微生物剤

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6323852A (ja) * 1986-07-16 1988-02-01 バスフ　アクチェンゲゼルシャフト オキシムエーテル及び該化合物を含有する農園芸用殺菌剤
JPH0211586A (ja) * 1988-05-06 1990-01-16 Basf Ag 新規なストロビルリン誘導体、その製法及び使用
JPH02264765A (ja) * 1989-02-10 1990-10-29 Imperial Chem Ind Plc <Ici> 殺菌性化合物、その製造法及びそれを含有する殺菌剤組成物
JPH03246268A (ja) * 1989-05-17 1991-11-01 Shionogi & Co Ltd アルコキシイミノ酢酸アミド化合物および農業用殺菌剤
JPH0769812A (ja) * 1993-07-02 1995-03-14 Ciba Geigy Ag 殺微生物剤

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000074484A1 (fr) * 1999-06-04 2000-12-14 Shionogi & Co., Ltd. Composition fongicide a base de strobilurine a dommage chimique reduit
KR20200060653A (ko) * 2018-11-22 2020-06-01 동의대학교 산학협력단 스마트팜의 천연 추출물 및 혼합 분무 장치
KR102189418B1 (ko) 2018-11-22 2020-12-14 동의대학교 산학협력단 스마트팜의 천연 추출물 및 혼합 분무 장치

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