CN1867702B - 用于生产金属的热和电化学方法 - Google Patents
用于生产金属的热和电化学方法 Download PDFInfo
- Publication number
- CN1867702B CN1867702B CN200480030645.4A CN200480030645A CN1867702B CN 1867702 B CN1867702 B CN 1867702B CN 200480030645 A CN200480030645 A CN 200480030645A CN 1867702 B CN1867702 B CN 1867702B
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- China
- Prior art keywords
- titanium
- anode
- carbon
- electrolyte
- cathode
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B34/00—Obtaining refractory metals
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/32—Electrolytic production, recovery or refining of metals by electrolysis of melts of chromium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B34/00—Obtaining refractory metals
- C22B34/10—Obtaining titanium, zirconium or hafnium
- C22B34/12—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B34/00—Obtaining refractory metals
- C22B34/10—Obtaining titanium, zirconium or hafnium
- C22B34/12—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08
- C22B34/1263—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08 obtaining metallic titanium from titanium compounds, e.g. by reduction
- C22B34/1281—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08 obtaining metallic titanium from titanium compounds, e.g. by reduction using carbon containing agents, e.g. C, CO, carbides
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B34/00—Obtaining refractory metals
- C22B34/10—Obtaining titanium, zirconium or hafnium
- C22B34/12—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08
- C22B34/129—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08 obtaining metallic titanium from titanium compounds by dissociation, e.g. thermic dissociation of titanium tetraiodide, or by electrolysis or with the use of an electric arc
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B34/00—Obtaining refractory metals
- C22B34/10—Obtaining titanium, zirconium or hafnium
- C22B34/12—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08
- C22B34/1295—Refining, melting, remelting, working up of titanium
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/26—Electrolytic production, recovery or refining of metals by electrolysis of melts of titanium, zirconium, hafnium, tantalum or vanadium
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/26—Electrolytic production, recovery or refining of metals by electrolysis of melts of titanium, zirconium, hafnium, tantalum or vanadium
- C25C3/28—Electrolytic production, recovery or refining of metals by electrolysis of melts of titanium, zirconium, hafnium, tantalum or vanadium of titanium
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/34—Electrolytic production, recovery or refining of metals by electrolysis of melts of metals not provided for in groups C25C3/02 - C25C3/32
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/36—Alloys obtained by cathodic reduction of all their ions
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C5/00—Electrolytic production, recovery or refining of metal powders or porous metal masses
- C25C5/04—Electrolytic production, recovery or refining of metal powders or porous metal masses from melts
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Electrochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Electrolytic Production Of Metals (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510236748.6A CN104831318B (zh) | 2003-08-20 | 2004-08-18 | 用于生产金属的热和电化学方法 |
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US49698103P | 2003-08-20 | 2003-08-20 | |
| US60/496,981 | 2003-08-20 | ||
| US10/828,641 US7410562B2 (en) | 2003-08-20 | 2004-04-21 | Thermal and electrochemical process for metal production |
| US10/828,641 | 2004-04-21 | ||
| PCT/US2004/026660 WO2005019501A2 (en) | 2003-08-20 | 2004-08-18 | Thermal and electrochemical process for metal production |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510236748.6A Division CN104831318B (zh) | 2003-08-20 | 2004-08-18 | 用于生产金属的热和电化学方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1867702A CN1867702A (zh) | 2006-11-22 |
| CN1867702B true CN1867702B (zh) | 2015-11-25 |
Family
ID=34221433
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200480030645.4A Expired - Fee Related CN1867702B (zh) | 2003-08-20 | 2004-08-18 | 用于生产金属的热和电化学方法 |
| CN201510236748.6A Expired - Fee Related CN104831318B (zh) | 2003-08-20 | 2004-08-18 | 用于生产金属的热和电化学方法 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510236748.6A Expired - Fee Related CN104831318B (zh) | 2003-08-20 | 2004-08-18 | 用于生产金属的热和电化学方法 |
Country Status (8)
| Country | Link |
|---|---|
| US (3) | US7410562B2 (enExample) |
| EP (2) | EP1656472B1 (enExample) |
| JP (1) | JP5011468B2 (enExample) |
| KR (1) | KR101136586B1 (enExample) |
| CN (2) | CN1867702B (enExample) |
| AU (1) | AU2004267452B2 (enExample) |
| CA (3) | CA2535978C (enExample) |
| WO (1) | WO2005019501A2 (enExample) |
Families Citing this family (100)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7410562B2 (en) * | 2003-08-20 | 2008-08-12 | Materials & Electrochemical Research Corp. | Thermal and electrochemical process for metal production |
| US7794580B2 (en) * | 2004-04-21 | 2010-09-14 | Materials & Electrochemical Research Corp. | Thermal and electrochemical process for metal production |
| GB0422129D0 (en) * | 2004-10-06 | 2004-11-03 | Qinetiq Ltd | Electro-reduction process |
| CN100415940C (zh) * | 2005-05-08 | 2008-09-03 | 北京科技大学 | 一氧化钛/碳化钛可溶性固溶体阳极电解生产纯钛的方法 |
| DE102005026267A1 (de) * | 2005-06-08 | 2006-12-21 | Deutsches Zentrum für Luft- und Raumfahrt e.V. | Herstellung eines Verbundwerkstoffs |
| US20070125659A1 (en) * | 2005-11-14 | 2007-06-07 | Hecker Cartes Christian H D | Process for optimizing the process of copper electro-winning and electro-refining by superimposing a sinussoidal current over a continuous current |
| EP1982006A2 (en) * | 2006-02-06 | 2008-10-22 | E.I. Du Pont De Nemours And Company | Method for electrolytic production of titanium and other metal powders |
| US20080023321A1 (en) * | 2006-07-31 | 2008-01-31 | Donald Sadoway | Apparatus for electrolysis of molten oxides |
| WO2008091806A1 (en) * | 2007-01-22 | 2008-07-31 | Materials & Electrochemical Research Corp. | Metallothermic reduction of in-situ generated titanium chloride |
| CN102268559A (zh) | 2007-05-21 | 2011-12-07 | 奥贝特勘探Vspa有限公司 | 从铝土矿石中提取铝的工艺 |
| JP2010013668A (ja) * | 2008-06-30 | 2010-01-21 | Toshiba Corp | 金属ジルコニウムの製造方法 |
| CN101343755B (zh) * | 2008-08-20 | 2010-08-25 | 攀钢集团研究院有限公司 | 生产金属钒的方法 |
| US20110253544A1 (en) * | 2008-12-08 | 2011-10-20 | University Of South Australia | Formation Of Nanoporous Materials |
| US8960185B2 (en) * | 2009-05-08 | 2015-02-24 | Arthur Ashkin | Compound collector system for solar energy concentration |
| GB0913736D0 (en) | 2009-08-06 | 2009-09-16 | Chinuka Ltd | Treatment of titanium ores |
| CN101649471B (zh) * | 2009-09-23 | 2013-06-12 | 攀钢集团研究院有限公司 | 生产高纯金属钒的方法 |
| CN101914788B (zh) * | 2010-07-26 | 2012-10-03 | 攀钢集团有限公司 | 一种制备金属钛的方法 |
| CN101947652A (zh) * | 2010-09-21 | 2011-01-19 | 攀钢集团有限公司 | 一种微波加热制备碳氧钛复合阳极的方法 |
| CN101949038B (zh) * | 2010-09-21 | 2011-12-14 | 攀钢集团钢铁钒钛股份有限公司 | 一种电解法制备碳氧钛复合阳极的方法 |
| US9562296B2 (en) * | 2010-11-02 | 2017-02-07 | I'msep Co., Ltd. | Production method for silicon nanoparticles |
| EP2469969A1 (en) | 2010-12-24 | 2012-06-27 | Philip Morris Products S.A. | Reduced ceramic heating element |
| CA2829049C (en) | 2011-03-18 | 2014-12-02 | Orbite Aluminae Inc. | Processes for recovering rare earth elements from aluminum-bearing materials |
| JP2014515792A (ja) * | 2011-04-27 | 2014-07-03 | マテリアルズ アンド エレクトロケミカル リサーチ コーポレイション | 球状チタンおよび球状チタン合金粉末を生成する低コスト処理法 |
| WO2012149642A1 (en) | 2011-05-04 | 2012-11-08 | Orbite Aluminae Inc. | Processes for recovering rare earth elements from various ores |
| EP2714594A4 (en) | 2011-06-03 | 2015-05-20 | Orbite Aluminae Inc | PROCESS FOR PRODUCING HEMATITE |
| WO2013022020A1 (ja) | 2011-08-10 | 2013-02-14 | 住友電気工業株式会社 | 元素回収方法および元素回収装置 |
| IN2014DN03007A (enExample) | 2011-09-16 | 2015-05-08 | Orbite Aluminae Inc | |
| CN103031577B (zh) | 2011-09-30 | 2015-07-08 | 攀钢集团攀枝花钢铁研究院有限公司 | 一种金属钛的制备方法及由该方法得到的金属钛 |
| WO2013050772A2 (en) * | 2011-10-04 | 2013-04-11 | Metalysis Limited | Electrolytic production of powder |
| WO2013065511A1 (ja) * | 2011-11-04 | 2013-05-10 | 住友電気工業株式会社 | 溶融塩電解による金属の製造方法及びその製造方法に使用する装置 |
| CN102502806A (zh) * | 2011-11-22 | 2012-06-20 | 中国铝业股份有限公司 | 一种制备一氧化钛粉体材料的方法 |
| EP2794943B8 (en) | 2011-12-22 | 2019-07-10 | Universal Achemetal Titanium, LLC | A method for extraction and refining of titanium |
| WO2013104059A1 (en) | 2012-01-10 | 2013-07-18 | Orbite Aluminae Inc. | Processes for treating red mud |
| EP2838848B1 (en) | 2012-03-29 | 2019-05-08 | Orbite Technologies Inc. | Processes for treating fly ashes |
| BR112015000626A2 (pt) | 2012-07-12 | 2017-06-27 | Orbite Aluminae Inc | processos para preparação de óxido de titânio e outros produtos variados |
| CN102744415B (zh) * | 2012-07-18 | 2014-03-19 | 江西智诚新材料科技有限公司 | 用钽铌电容器废料制取冶金级粉末的方法及碳化氢化装置 |
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| CN102925930B (zh) * | 2012-10-25 | 2015-11-25 | 攀钢集团攀枝花钢铁研究院有限公司 | 一种用含钛物料生产金属钛的方法 |
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| CN103014793B (zh) * | 2012-12-11 | 2015-02-11 | 广东电网公司电力科学研究院 | 脉冲电沉积制备碳化钛涂层的方法 |
| KR101385528B1 (ko) | 2013-05-07 | 2014-04-15 | 충북대학교 산학협력단 | 혼합금속산화물로부터 고온 용융염 전해환원에 의한 니켈네오디뮴 합금 제조방법 |
| CN103290433B (zh) * | 2013-06-26 | 2016-01-20 | 石嘴山市天和铁合金有限公司 | 一种双电解槽熔盐电解制备纯钛的装置及其工艺 |
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| CN106544701B (zh) * | 2016-10-11 | 2018-08-24 | 北京工业大学 | 用氟化物电解回收碳化钨废料中的金属的方法 |
| CN106435648A (zh) * | 2016-10-13 | 2017-02-22 | 北京科技大学 | 一种高温电解熔融钼精矿制备金属钼的方法 |
| EP3315634B1 (en) * | 2016-10-28 | 2020-02-19 | Sintef TTO AS | A method of electrochemical production of rare earth alloys and metals comprising a composite anode |
| CN106757167A (zh) * | 2016-12-26 | 2017-05-31 | 宝纳资源控股(集团)有限公司 | 一种熔盐脉冲电流电解制备钛的方法及装置 |
| CA3049769C (en) | 2017-01-13 | 2023-11-21 | Universal Achemetal Titanium, Llc | Titanium master alloy for titanium-aluminum based alloys |
| CN110366609B (zh) * | 2017-03-01 | 2022-01-14 | 国立大学法人京都大学 | 钛箔或钛板的制造方法及阴极电极 |
| CN106865602B (zh) * | 2017-03-02 | 2019-04-23 | 攀枝花学院 | 石墨-钛低价氧化物复合材料的制备方法 |
| KR101878652B1 (ko) * | 2017-07-12 | 2018-07-16 | 충남대학교산학협력단 | 전해환원 및 전해정련 일관공정에 의한 금속 정련 방법 |
| CN107385474B (zh) * | 2017-08-04 | 2018-10-12 | 中南大学 | 一种氯化钙熔盐电解制钙用电解质及使用该电解质的电解方法 |
| US10872705B2 (en) | 2018-02-01 | 2020-12-22 | Battelle Energy Alliance, Llc | Electrochemical cells for direct oxide reduction, and related methods |
| CN108315768A (zh) * | 2018-02-06 | 2018-07-24 | 北京科技大学 | 一种电场条件下的铝热还原制备Al-Ti合金的方法 |
| US12116684B2 (en) | 2018-04-24 | 2024-10-15 | Battelle Energy Alliance, Llc | Methods of forming alloys by reducing metal oxides |
| CN108441892B (zh) * | 2018-05-24 | 2021-02-02 | 郑州大学 | 基于络合离子的亚稳态高温熔盐电解精炼高纯钛的方法 |
| CN108774738B (zh) * | 2018-07-02 | 2020-09-01 | 重庆大学 | 一种氢气还原TiO2联合熔盐电解Ti4O7制备金属钛的方法 |
| CN112941567B (zh) * | 2018-07-10 | 2024-02-23 | 东北大学 | 潮湿气氛的高温熔盐电解的电化学方法和装置 |
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| CN109055995B (zh) * | 2018-10-26 | 2020-09-25 | 攀钢集团攀枝花钢铁研究院有限公司 | 用于电解提钛的碳氧化物阳极的制备方法 |
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| EP2322693B1 (en) | 2017-10-04 |
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| CN104831318A (zh) | 2015-08-12 |
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| CN104831318B (zh) | 2018-02-02 |
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| EP1656472A2 (en) | 2006-05-17 |
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| CA2535978A1 (en) | 2005-03-03 |
| AU2004267452B2 (en) | 2009-10-29 |
| CA2860451A1 (en) | 2005-03-03 |
| CN1867702A (zh) | 2006-11-22 |
| CA2782837A1 (en) | 2005-03-03 |
| WO2005019501A2 (en) | 2005-03-03 |
| EP2322693A1 (en) | 2011-05-18 |
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