CN1770513A - 含锰的多元金属氧化物、锂离子二次电池的正极材料及其制备方法 - Google Patents
含锰的多元金属氧化物、锂离子二次电池的正极材料及其制备方法 Download PDFInfo
- Publication number
- CN1770513A CN1770513A CNA2004100812231A CN200410081223A CN1770513A CN 1770513 A CN1770513 A CN 1770513A CN A2004100812231 A CNA2004100812231 A CN A2004100812231A CN 200410081223 A CN200410081223 A CN 200410081223A CN 1770513 A CN1770513 A CN 1770513A
- Authority
- CN
- China
- Prior art keywords
- metal oxide
- salt
- manganese
- grinding
- drying
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 19
- 229910044991 metal oxide Inorganic materials 0.000 title claims description 46
- 150000004706 metal oxides Chemical class 0.000 title claims description 44
- 229910001416 lithium ion Inorganic materials 0.000 title claims description 21
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 title claims description 20
- 239000010405 anode material Substances 0.000 title description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 29
- 238000000227 grinding Methods 0.000 claims abstract description 28
- 238000001035 drying Methods 0.000 claims abstract description 27
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 22
- 229910018060 Ni-Co-Mn Inorganic materials 0.000 claims abstract description 20
- 229910018209 Ni—Co—Mn Inorganic materials 0.000 claims abstract description 20
- 239000002904 solvent Substances 0.000 claims abstract description 18
- 239000000203 mixture Substances 0.000 claims abstract description 17
- 229920000642 polymer Polymers 0.000 claims abstract description 15
- 239000002184 metal Substances 0.000 claims abstract description 14
- 229910052751 metal Inorganic materials 0.000 claims abstract description 12
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 11
- 150000001868 cobalt Chemical class 0.000 claims abstract description 10
- 230000008569 process Effects 0.000 claims abstract description 10
- 150000002815 nickel Chemical class 0.000 claims abstract description 9
- -1 compound hydrogen Chemical class 0.000 claims abstract description 4
- 150000003839 salts Chemical class 0.000 claims abstract description 3
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 claims description 72
- 239000011572 manganese Substances 0.000 claims description 42
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 33
- 239000002131 composite material Substances 0.000 claims description 27
- 238000000576 coating method Methods 0.000 claims description 23
- 238000010438 heat treatment Methods 0.000 claims description 23
- 238000002156 mixing Methods 0.000 claims description 23
- 239000011248 coating agent Substances 0.000 claims description 22
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 21
- 239000007774 positive electrode material Substances 0.000 claims description 20
- 229910052744 lithium Inorganic materials 0.000 claims description 18
- 238000003756 stirring Methods 0.000 claims description 18
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 17
- 229910052748 manganese Inorganic materials 0.000 claims description 17
- 238000005406 washing Methods 0.000 claims description 17
- 239000002243 precursor Substances 0.000 claims description 16
- 238000002360 preparation method Methods 0.000 claims description 14
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 13
- 239000011777 magnesium Substances 0.000 claims description 13
- 239000003513 alkali Substances 0.000 claims description 12
- 239000000243 solution Substances 0.000 claims description 12
- 238000006243 chemical reaction Methods 0.000 claims description 11
- 239000010936 titanium Substances 0.000 claims description 11
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 10
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 10
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 9
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 9
- 239000011261 inert gas Substances 0.000 claims description 9
- 229910052782 aluminium Inorganic materials 0.000 claims description 8
- 229910052796 boron Inorganic materials 0.000 claims description 8
- 229910052749 magnesium Inorganic materials 0.000 claims description 8
- 150000002696 manganese Chemical class 0.000 claims description 8
- 239000011259 mixed solution Substances 0.000 claims description 8
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 8
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 8
- 229910052710 silicon Inorganic materials 0.000 claims description 8
- 229910052719 titanium Inorganic materials 0.000 claims description 8
- 229910014915 LiaNi1-x-yCox Inorganic materials 0.000 claims description 7
- 238000000975 co-precipitation Methods 0.000 claims description 7
- 238000012986 modification Methods 0.000 claims description 7
- 230000004048 modification Effects 0.000 claims description 7
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 7
- 229910015460 Ni1-x-yCoxMnyO2 Inorganic materials 0.000 claims description 5
- 229910015456 Ni1-x−yCoxMnyO2 Inorganic materials 0.000 claims description 5
- 229910015266 Ni1−x−yCoxMnyO2 Inorganic materials 0.000 claims description 5
- 229910052720 vanadium Inorganic materials 0.000 claims description 5
- 239000002174 Styrene-butadiene Substances 0.000 claims description 4
- 239000000839 emulsion Substances 0.000 claims description 4
- 229920002401 polyacrylamide Polymers 0.000 claims description 4
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 239000010703 silicon Substances 0.000 claims description 3
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 2
- 229910002651 NO3 Inorganic materials 0.000 claims description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 2
- 150000002739 metals Chemical class 0.000 claims description 2
- 239000012266 salt solution Substances 0.000 claims description 2
- 238000012545 processing Methods 0.000 abstract description 10
- GLXDVVHUTZTUQK-UHFFFAOYSA-M lithium;hydroxide;hydrate Chemical compound [Li+].O.[OH-] GLXDVVHUTZTUQK-UHFFFAOYSA-M 0.000 abstract description 8
- 230000003647 oxidation Effects 0.000 abstract 3
- 238000007254 oxidation reaction Methods 0.000 abstract 3
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 238000000151 deposition Methods 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000000047 product Substances 0.000 description 37
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 26
- 239000007864 aqueous solution Substances 0.000 description 22
- 239000000463 material Substances 0.000 description 21
- 230000002441 reversible effect Effects 0.000 description 21
- 230000014759 maintenance of location Effects 0.000 description 15
- 238000007873 sieving Methods 0.000 description 12
- 239000002245 particle Substances 0.000 description 11
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 10
- 229910052759 nickel Inorganic materials 0.000 description 10
- 229910013716 LiNi Inorganic materials 0.000 description 9
- 239000012298 atmosphere Substances 0.000 description 8
- 229910017052 cobalt Inorganic materials 0.000 description 8
- 239000010941 cobalt Substances 0.000 description 8
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 8
- 238000001816 cooling Methods 0.000 description 8
- 238000005245 sintering Methods 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- 150000001242 acetic acid derivatives Chemical class 0.000 description 7
- PQVSTLUFSYVLTO-UHFFFAOYSA-N ethyl n-ethoxycarbonylcarbamate Chemical compound CCOC(=O)NC(=O)OCC PQVSTLUFSYVLTO-UHFFFAOYSA-N 0.000 description 7
- 238000002474 experimental method Methods 0.000 description 7
- 229940040692 lithium hydroxide monohydrate Drugs 0.000 description 7
- 239000002244 precipitate Substances 0.000 description 7
- 238000000926 separation method Methods 0.000 description 7
- 229910001228 Li[Ni1/3Co1/3Mn1/3]O2 (NCM 111) Inorganic materials 0.000 description 6
- 239000000084 colloidal system Substances 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- QHGJSLXSVXVKHZ-UHFFFAOYSA-N dilithium;dioxido(dioxo)manganese Chemical compound [Li+].[Li+].[O-][Mn]([O-])(=O)=O QHGJSLXSVXVKHZ-UHFFFAOYSA-N 0.000 description 6
- 239000012153 distilled water Substances 0.000 description 6
- 239000012299 nitrogen atmosphere Substances 0.000 description 6
- 238000001514 detection method Methods 0.000 description 5
- 239000012300 argon atmosphere Substances 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 4
- 239000003792 electrolyte Substances 0.000 description 4
- 229920002994 synthetic fiber Polymers 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 3
- 238000001704 evaporation Methods 0.000 description 3
- 150000004679 hydroxides Chemical class 0.000 description 3
- 238000005303 weighing Methods 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 229910011328 LiNi0.6Co0.2Mn0.2O2 Inorganic materials 0.000 description 2
- 229910011669 LiNi0.7Co0.2Mn0.1O2 Inorganic materials 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 239000006182 cathode active material Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 2
- 239000000347 magnesium hydroxide Substances 0.000 description 2
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 2
- 229910052596 spinel Inorganic materials 0.000 description 2
- 239000011029 spinel Substances 0.000 description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
- 238000001291 vacuum drying Methods 0.000 description 2
- 206010067484 Adverse reaction Diseases 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910032387 LiCoO2 Inorganic materials 0.000 description 1
- 229910015645 LiMn Inorganic materials 0.000 description 1
- 229910015872 LiNi0.8Co0.1Mn0.1O2 Inorganic materials 0.000 description 1
- 229910006025 NiCoMn Inorganic materials 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 239000006230 acetylene black Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000006838 adverse reaction Effects 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000006183 anode active material Substances 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229910000361 cobalt sulfate Inorganic materials 0.000 description 1
- 229940044175 cobalt sulfate Drugs 0.000 description 1
- KTVIXTQDYHMGHF-UHFFFAOYSA-L cobalt(2+) sulfate Chemical compound [Co+2].[O-]S([O-])(=O)=O KTVIXTQDYHMGHF-UHFFFAOYSA-L 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910052909 inorganic silicate Inorganic materials 0.000 description 1
- IPJKJLXEVHOKSE-UHFFFAOYSA-L manganese dihydroxide Chemical compound [OH-].[OH-].[Mn+2] IPJKJLXEVHOKSE-UHFFFAOYSA-L 0.000 description 1
- 229940099596 manganese sulfate Drugs 0.000 description 1
- 239000011702 manganese sulphate Substances 0.000 description 1
- 235000007079 manganese sulphate Nutrition 0.000 description 1
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 1
- 229940053662 nickel sulfate Drugs 0.000 description 1
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000001878 scanning electron micrograph Methods 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000010183 spectrum analysis Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920005609 vinylidenefluoride/hexafluoropropylene copolymer Polymers 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
- H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G45/00—Compounds of manganese
- C01G45/12—Manganates manganites or permanganates
- C01G45/1221—Manganates or manganites with a manganese oxidation state of Mn(III), Mn(IV) or mixtures thereof
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G51/00—Compounds of cobalt
- C01G51/40—Cobaltates
- C01G51/42—Cobaltates containing alkali metals, e.g. LiCoO2
- C01G51/44—Cobaltates containing alkali metals, e.g. LiCoO2 containing manganese
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
- C01G53/40—Nickelates
- C01G53/42—Nickelates containing alkali metals, e.g. LiNiO2
- C01G53/44—Nickelates containing alkali metals, e.g. LiNiO2 containing manganese
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/50—Solid solutions
- C01P2002/52—Solid solutions containing elements as dopants
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/40—Electric properties
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
- H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
Description
Claims (11)
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2004100812231A CN100413122C (zh) | 2004-11-03 | 2004-11-03 | 含锰的多元金属氧化物、锂离子二次电池的正极材料及其制备方法 |
HK06110753.0A HK1088720A1 (en) | 2004-11-03 | 2006-09-27 | Manganic multi-metal oxides, anode material of li-ion rechargeable battery and its preparation method |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2004100812231A CN100413122C (zh) | 2004-11-03 | 2004-11-03 | 含锰的多元金属氧化物、锂离子二次电池的正极材料及其制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1770513A true CN1770513A (zh) | 2006-05-10 |
CN100413122C CN100413122C (zh) | 2008-08-20 |
Family
ID=36751624
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB2004100812231A Active CN100413122C (zh) | 2004-11-03 | 2004-11-03 | 含锰的多元金属氧化物、锂离子二次电池的正极材料及其制备方法 |
Country Status (2)
Country | Link |
---|---|
CN (1) | CN100413122C (zh) |
HK (1) | HK1088720A1 (zh) |
Cited By (36)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101777643A (zh) * | 2010-01-14 | 2010-07-14 | 镇江科捷锂电池有限公司 | Al2O3包覆锰基层状晶体锂电池正极材料的制备方法 |
CN102195034A (zh) * | 2010-03-09 | 2011-09-21 | 深圳市比克电池有限公司 | 锂离子电池正极材料制备方法及制得的电池 |
CN102447097A (zh) * | 2010-10-09 | 2012-05-09 | 青海佛照锂电正极材料有限公司 | 一种锂离子正极材料镍锰钴的制备方法 |
CN102449817A (zh) * | 2009-06-08 | 2012-05-09 | 住友化学株式会社 | 电极合剂、电极合剂糊状物、电极及非水电解质二次电池 |
CN103325996A (zh) * | 2013-06-06 | 2013-09-25 | 南通瑞翔新材料有限公司 | 锂离子电池正极材料包覆铝钛的制备方法 |
CN103490058A (zh) * | 2013-10-02 | 2014-01-01 | 山东润峰集团新能源科技有限公司 | 一种掺杂层状锰酸锂的制备方法 |
CN103560236A (zh) * | 2013-10-23 | 2014-02-05 | 合肥国轩高科动力能源股份公司 | 氧化铝包覆Li(NixCoyMn1-x-y)O2锂离子电池正极材料的制备方法 |
CN104393286A (zh) * | 2014-11-26 | 2015-03-04 | 南通瑞翔新材料有限公司 | 一种高电压钴酸锂正极材料的水系包覆方法 |
CN105161693A (zh) * | 2015-10-27 | 2015-12-16 | 湖南桑顿新能源有限公司 | 一种高循环锂电多元正极材料ncm及其制备方法 |
CN105244492A (zh) * | 2014-07-11 | 2016-01-13 | 北京当升材料科技股份有限公司 | 一种含硼锂离子电池正极材料及其制备方法 |
CN103456942B (zh) * | 2013-08-20 | 2016-01-20 | 中信大锰矿业有限责任公司大新锰矿分公司 | 一种锰酸锂液相包覆工艺 |
CN105304890A (zh) * | 2014-07-11 | 2016-02-03 | 北京当升材料科技股份有限公司 | 一种含硅锂离子电池正极材料及其制备方法 |
CN105355842A (zh) * | 2015-11-14 | 2016-02-24 | 合肥国轩高科动力能源有限公司 | 一种改良的锂离子电池正极材料制备方法 |
CN105428643A (zh) * | 2015-12-30 | 2016-03-23 | 山东精工电子科技有限公司 | 一种粒度可控的球型正极材料及其合成方法 |
CN105932261A (zh) * | 2016-06-30 | 2016-09-07 | 湖南桑顿新能源有限公司 | 一种锰酸锂正极材料及其制备方法 |
CN105934846A (zh) * | 2014-01-24 | 2016-09-07 | 日产自动车株式会社 | 电器件 |
CN105977466A (zh) * | 2016-06-30 | 2016-09-28 | 湖南桑顿新能源有限公司 | 一种导电性氧化物包覆的锂离子电池三元正极材料及其制备方法 |
CN106159244A (zh) * | 2016-09-27 | 2016-11-23 | 宁德时代新能源科技股份有限公司 | 一种锂电池正极材料其制备方法及动力用锂离子电池 |
CN107742711A (zh) * | 2017-10-19 | 2018-02-27 | 陕西省石油化工研究设计院 | 一种三元正极材料包覆三氧化二硼的制备方法 |
CN107910612A (zh) * | 2017-12-06 | 2018-04-13 | 贵州红星电子材料有限公司 | 一种从废旧锂电池中回收钴镍的方法 |
CN108199021A (zh) * | 2017-12-29 | 2018-06-22 | 青海泰丰先行锂能科技有限公司 | 一种锂离子电池大晶粒体三元正极材料及其制备方法 |
CN108520952A (zh) * | 2018-04-16 | 2018-09-11 | 广东迈纳科技有限公司 | 一种高镍与无机纳米粉体复合的电极材料及其制备方法 |
CN108598447A (zh) * | 2018-06-26 | 2018-09-28 | 浙江天能能源科技股份有限公司 | 一种双氧化合物包覆的多元高镍正极材料及其制备方法 |
CN108878827A (zh) * | 2018-06-26 | 2018-11-23 | 浙江天能能源科技股份有限公司 | 一种双氧化合物包覆的高镍三元正极材料及其制备方法 |
CN108899531A (zh) * | 2018-08-10 | 2018-11-27 | 合肥工业大学 | 一种磷酸盐包覆镍钴铝三元正极材料的制备方法 |
CN108963218A (zh) * | 2018-07-09 | 2018-12-07 | 王丹亮 | 一种低钴高镍三元锂的制备方法与应用 |
CN109037602A (zh) * | 2018-05-30 | 2018-12-18 | 浙江天能能源科技股份有限公司 | 一种双氧化物包覆三元正极材料及其制备方法 |
US10290855B2 (en) | 2012-11-22 | 2019-05-14 | Nissan Motor Co., Ltd. | Negative electrode for electrical device, and electrical device using the same |
US10476101B2 (en) | 2014-01-24 | 2019-11-12 | Nissan Motor Co., Ltd. | Electrical device |
CN110492061A (zh) * | 2018-05-15 | 2019-11-22 | 湖南师范大学 | 一种水溶性添加剂辅助正极材料界面生长硼铝氧化物薄层的包覆方法 |
CN111276691A (zh) * | 2020-03-24 | 2020-06-12 | 江门市科恒实业股份有限公司 | 一种高电压单晶低钴三元正极材料及其制备方法 |
CN111640928A (zh) * | 2020-06-30 | 2020-09-08 | 蜂巢能源科技有限公司 | Ncma四元系材料及其制备方法、锂电池正极材料及锂电池 |
CN112599779A (zh) * | 2020-12-15 | 2021-04-02 | 上海华谊(集团)公司 | 双层包覆的锂离子电池正极材料及其制备方法 |
CN113677630A (zh) * | 2019-04-12 | 2021-11-19 | 住友化学株式会社 | 锂金属复合氧化物粉末、锂二次电池用正极活性物质、正极以及锂二次电池 |
CN114644369A (zh) * | 2022-01-22 | 2022-06-21 | 温州大学新材料与产业技术研究院 | 一种lnmc622@lrnmc复合材料的制备方法及应用 |
CN114772655A (zh) * | 2022-01-22 | 2022-07-22 | 温州大学新材料与产业技术研究院 | 一种lnm@lrnmc复合材料的制备方法及应用 |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102623706A (zh) * | 2012-04-09 | 2012-08-01 | 中国科学院新疆理化技术研究所 | 一种改善三元素锂离子电池正极材料低温性能的方法 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SG82599A1 (en) * | 1998-02-10 | 2001-08-21 | Samsung Display Devices Co Ltd | Active material for positive electrode used in lithium secondary battery and method of manufacturing same |
JP4592931B2 (ja) * | 2000-11-30 | 2010-12-08 | Jx日鉱日石金属株式会社 | リチウム二次電池用正極材料及び及びその製造方法 |
CN1208866C (zh) * | 2001-11-02 | 2005-06-29 | 中国科学院物理研究所 | 以纳米表面包覆复合材料为正极活性物质的锂二次电池 |
CN1501529A (zh) * | 2002-11-16 | 2004-06-02 | 中国科学院青海盐湖研究所 | 表面修饰改性锂离子电池正极材料及其制备方法 |
CN1595689A (zh) * | 2003-09-08 | 2005-03-16 | 中国科学院物理研究所 | 锰系正极材料及其制备与用途 |
CN1627550A (zh) * | 2003-12-11 | 2005-06-15 | 比亚迪股份有限公司 | 锂离子电池正极材料及其制备方法 |
-
2004
- 2004-11-03 CN CNB2004100812231A patent/CN100413122C/zh active Active
-
2006
- 2006-09-27 HK HK06110753.0A patent/HK1088720A1/xx unknown
Cited By (48)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102449817A (zh) * | 2009-06-08 | 2012-05-09 | 住友化学株式会社 | 电极合剂、电极合剂糊状物、电极及非水电解质二次电池 |
CN102449817B (zh) * | 2009-06-08 | 2014-11-19 | 住友化学株式会社 | 电极合剂、电极合剂糊状物、电极及非水电解质二次电池 |
CN101777643A (zh) * | 2010-01-14 | 2010-07-14 | 镇江科捷锂电池有限公司 | Al2O3包覆锰基层状晶体锂电池正极材料的制备方法 |
CN102195034A (zh) * | 2010-03-09 | 2011-09-21 | 深圳市比克电池有限公司 | 锂离子电池正极材料制备方法及制得的电池 |
CN102447097A (zh) * | 2010-10-09 | 2012-05-09 | 青海佛照锂电正极材料有限公司 | 一种锂离子正极材料镍锰钴的制备方法 |
US10290855B2 (en) | 2012-11-22 | 2019-05-14 | Nissan Motor Co., Ltd. | Negative electrode for electrical device, and electrical device using the same |
CN103325996A (zh) * | 2013-06-06 | 2013-09-25 | 南通瑞翔新材料有限公司 | 锂离子电池正极材料包覆铝钛的制备方法 |
CN103456942B (zh) * | 2013-08-20 | 2016-01-20 | 中信大锰矿业有限责任公司大新锰矿分公司 | 一种锰酸锂液相包覆工艺 |
CN103490058A (zh) * | 2013-10-02 | 2014-01-01 | 山东润峰集团新能源科技有限公司 | 一种掺杂层状锰酸锂的制备方法 |
CN103490058B (zh) * | 2013-10-02 | 2015-08-19 | 山东润峰集团新能源科技有限公司 | 一种掺杂层状锰酸锂的制备方法 |
CN103560236A (zh) * | 2013-10-23 | 2014-02-05 | 合肥国轩高科动力能源股份公司 | 氧化铝包覆Li(NixCoyMn1-x-y)O2锂离子电池正极材料的制备方法 |
CN103560236B (zh) * | 2013-10-23 | 2016-05-11 | 合肥国轩高科动力能源有限公司 | 氧化铝包覆Li(NixCoyMn1-x-y)O2锂离子电池正极材料的制备方法 |
US10476101B2 (en) | 2014-01-24 | 2019-11-12 | Nissan Motor Co., Ltd. | Electrical device |
US10535870B2 (en) | 2014-01-24 | 2020-01-14 | Nissan Motor Co., Ltd. | Electrical device |
CN105934846A (zh) * | 2014-01-24 | 2016-09-07 | 日产自动车株式会社 | 电器件 |
CN105304890A (zh) * | 2014-07-11 | 2016-02-03 | 北京当升材料科技股份有限公司 | 一种含硅锂离子电池正极材料及其制备方法 |
CN105244492A (zh) * | 2014-07-11 | 2016-01-13 | 北京当升材料科技股份有限公司 | 一种含硼锂离子电池正极材料及其制备方法 |
CN104393286A (zh) * | 2014-11-26 | 2015-03-04 | 南通瑞翔新材料有限公司 | 一种高电压钴酸锂正极材料的水系包覆方法 |
CN105161693A (zh) * | 2015-10-27 | 2015-12-16 | 湖南桑顿新能源有限公司 | 一种高循环锂电多元正极材料ncm及其制备方法 |
CN105355842A (zh) * | 2015-11-14 | 2016-02-24 | 合肥国轩高科动力能源有限公司 | 一种改良的锂离子电池正极材料制备方法 |
CN105428643B (zh) * | 2015-12-30 | 2018-05-15 | 山东精工电子科技有限公司 | 一种粒度可控的球型正极材料及其合成方法 |
CN105428643A (zh) * | 2015-12-30 | 2016-03-23 | 山东精工电子科技有限公司 | 一种粒度可控的球型正极材料及其合成方法 |
CN105977466A (zh) * | 2016-06-30 | 2016-09-28 | 湖南桑顿新能源有限公司 | 一种导电性氧化物包覆的锂离子电池三元正极材料及其制备方法 |
CN105932261A (zh) * | 2016-06-30 | 2016-09-07 | 湖南桑顿新能源有限公司 | 一种锰酸锂正极材料及其制备方法 |
CN106159244A (zh) * | 2016-09-27 | 2016-11-23 | 宁德时代新能源科技股份有限公司 | 一种锂电池正极材料其制备方法及动力用锂离子电池 |
US10290865B2 (en) | 2016-09-27 | 2019-05-14 | Contemporary Amperex Technology Co., Limited | Positive electrode material for Li-ion battery, method for preparing the same, and Li-ion power battery containing the same |
CN107742711A (zh) * | 2017-10-19 | 2018-02-27 | 陕西省石油化工研究设计院 | 一种三元正极材料包覆三氧化二硼的制备方法 |
CN107910612B (zh) * | 2017-12-06 | 2020-04-14 | 贵州红星电子材料有限公司 | 一种从废旧锂电池中回收钴镍的方法 |
CN107910612A (zh) * | 2017-12-06 | 2018-04-13 | 贵州红星电子材料有限公司 | 一种从废旧锂电池中回收钴镍的方法 |
CN108199021A (zh) * | 2017-12-29 | 2018-06-22 | 青海泰丰先行锂能科技有限公司 | 一种锂离子电池大晶粒体三元正极材料及其制备方法 |
CN108520952A (zh) * | 2018-04-16 | 2018-09-11 | 广东迈纳科技有限公司 | 一种高镍与无机纳米粉体复合的电极材料及其制备方法 |
CN110492061A (zh) * | 2018-05-15 | 2019-11-22 | 湖南师范大学 | 一种水溶性添加剂辅助正极材料界面生长硼铝氧化物薄层的包覆方法 |
CN110492061B (zh) * | 2018-05-15 | 2022-09-27 | 湖南师范大学 | 一种水溶性添加剂辅助正极材料界面生长硼铝氧化物薄层的包覆方法 |
CN109037602A (zh) * | 2018-05-30 | 2018-12-18 | 浙江天能能源科技股份有限公司 | 一种双氧化物包覆三元正极材料及其制备方法 |
CN108878827A (zh) * | 2018-06-26 | 2018-11-23 | 浙江天能能源科技股份有限公司 | 一种双氧化合物包覆的高镍三元正极材料及其制备方法 |
CN108598447A (zh) * | 2018-06-26 | 2018-09-28 | 浙江天能能源科技股份有限公司 | 一种双氧化合物包覆的多元高镍正极材料及其制备方法 |
CN108963218A (zh) * | 2018-07-09 | 2018-12-07 | 王丹亮 | 一种低钴高镍三元锂的制备方法与应用 |
CN108899531A (zh) * | 2018-08-10 | 2018-11-27 | 合肥工业大学 | 一种磷酸盐包覆镍钴铝三元正极材料的制备方法 |
CN108899531B (zh) * | 2018-08-10 | 2020-10-20 | 合肥工业大学 | 一种磷酸盐包覆镍钴铝三元正极材料的制备方法 |
CN113677630B (zh) * | 2019-04-12 | 2023-08-22 | 住友化学株式会社 | 锂金属复合氧化物粉末、锂二次电池用正极活性物质、正极以及锂二次电池 |
CN113677630A (zh) * | 2019-04-12 | 2021-11-19 | 住友化学株式会社 | 锂金属复合氧化物粉末、锂二次电池用正极活性物质、正极以及锂二次电池 |
CN111276691A (zh) * | 2020-03-24 | 2020-06-12 | 江门市科恒实业股份有限公司 | 一种高电压单晶低钴三元正极材料及其制备方法 |
CN111640928A (zh) * | 2020-06-30 | 2020-09-08 | 蜂巢能源科技有限公司 | Ncma四元系材料及其制备方法、锂电池正极材料及锂电池 |
CN112599779A (zh) * | 2020-12-15 | 2021-04-02 | 上海华谊(集团)公司 | 双层包覆的锂离子电池正极材料及其制备方法 |
CN114772655A (zh) * | 2022-01-22 | 2022-07-22 | 温州大学新材料与产业技术研究院 | 一种lnm@lrnmc复合材料的制备方法及应用 |
CN114644369A (zh) * | 2022-01-22 | 2022-06-21 | 温州大学新材料与产业技术研究院 | 一种lnmc622@lrnmc复合材料的制备方法及应用 |
CN114644369B (zh) * | 2022-01-22 | 2024-06-04 | 温州大学新材料与产业技术研究院 | 一种lnmc622@lrnmc复合材料的制备方法及应用 |
CN114772655B (zh) * | 2022-01-22 | 2024-06-04 | 温州大学新材料与产业技术研究院 | 一种lnm@lrnmc复合材料的制备方法及应用 |
Also Published As
Publication number | Publication date |
---|---|
HK1088720A1 (en) | 2006-11-10 |
CN100413122C (zh) | 2008-08-20 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN1770513A (zh) | 含锰的多元金属氧化物、锂离子二次电池的正极材料及其制备方法 | |
CN108807931B (zh) | 一种表面包覆硅酸铝锂和表层掺杂氟的高镍材料及制备方法 | |
CN107706390B (zh) | 一种快离子导体和导电聚合物双重修饰的锂离子电池三元正极材料的制备方法 | |
JP5879761B2 (ja) | リチウム複合化合物粒子粉末及びその製造方法、並びに非水電解質二次電池 | |
JP7392132B2 (ja) | コバルトフリー正極材料およびその調製方法 | |
CN1493522A (zh) | 一种锂过渡金属氧化物的制备方法 | |
JP2022553638A (ja) | 勾配ドープされたコバルトフリー正極材料、その調製方法、リチウムイオン電池の正極およびリチウム電池 | |
US20230307631A1 (en) | Positive electrode material, battery, and electronic device | |
JP6020204B2 (ja) | 非水電解質二次電池 | |
CN116093271A (zh) | 一种正极材料及包括该正极材料的正极片和电池 | |
CN110931763A (zh) | 锂离子电池正极材料及其制备方法与应用 | |
CN112864363B (zh) | 正极材料、电化学装置和电子设备 | |
CN110931733B (zh) | 一种表面锰掺杂及Li-Mn-PO4包覆高镍正极材料及其制备方法和应用 | |
JP2014216127A (ja) | 非水電解質二次電池 | |
CN1770511A (zh) | 含镍钴的多元金属氧化物的制备方法及对其进行表面包覆修饰的方法 | |
US11621419B2 (en) | Composite positive electrode active material for lithium secondary battery, method of preparing the same, positive electrode for lithium secondary battery including the same, and lithium secondary battery including the positive electrode | |
CN111793856B (zh) | 一种Cu-Br掺杂钛酸锂纳米纤维材料及其制备方法与应用 | |
CN115072799A (zh) | 制造用于锂二次电池的正极活性物质的方法 | |
KR20150080149A (ko) | 고출력 장수명을 나타내는 혼합 양극활물질 | |
JP2015022901A (ja) | 非水電解質二次電池 | |
CN114695875A (zh) | 一种高容量单晶三元正极材料及其制备方法 | |
CN112694132A (zh) | 一种ZnMn2O4负极材料、其制备方法及用途 | |
CN111172510B (zh) | 一种高镍三元正极材料Al2O3/Al复合改性层的化学气相沉积制备方法 | |
JP6045194B2 (ja) | リチウム・マンガン複合酸化物の製造方法、その製造方法によって得られるリチウム・マンガン複合酸化物、それを含む二次電池用正極活物質およびそれを正極活物質として用いるリチウムイオン二次電池 | |
CN116779847B (zh) | 正极极片及其制备方法、储能装置和用电装置 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
REG | Reference to a national code |
Ref country code: HK Ref legal event code: DE Ref document number: 1088720 Country of ref document: HK |
|
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
REG | Reference to a national code |
Ref country code: HK Ref legal event code: GR Ref document number: 1088720 Country of ref document: HK |
|
ASS | Succession or assignment of patent right |
Owner name: TIANJIN HUAXIA HONGYUAN INDUSTRIAL CO.,LTD. Free format text: FORMER OWNER: BIKE CELL CO., LTD., SHENZHEN Effective date: 20131205 |
|
C41 | Transfer of patent application or patent right or utility model | ||
COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 518119 SHENZHEN, GUANGDONG PROVINCE TO: 300000 BAODI, TIANJIN |
|
TR01 | Transfer of patent right |
Effective date of registration: 20131205 Address after: 300000 Tianjin Industrial Park, Baodi District, No. nine road, No. 9 Patentee after: Tianjin Huaxia Hongyuan Industrial Co., Ltd. Address before: 518119, 6 floor, Beek Industrial Park, Kwai Chung Town, Longgang District, Guangdong, Shenzhen, 3 Patentee before: Shenzhen Bak Battery Co., Ltd. |
|
C56 | Change in the name or address of the patentee | ||
CP03 | Change of name, title or address |
Address after: 300182 Tianjin Industrial Park, Baodi District, No. nine road, No. 9 Patentee after: Tianjin Guoan mengguli new materials Polytron Technologies Inc Address before: 300000 Tianjin Industrial Park, Baodi District, No. nine road, No. 9 Patentee before: Tianjin Huaxia Hongyuan Industrial Co., Ltd. |