CN1561406A - 金属氧化物和/或金属氢氧化物涂敷的金属材料及其生产方法 - Google Patents
金属氧化物和/或金属氢氧化物涂敷的金属材料及其生产方法 Download PDFInfo
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- CN1561406A CN1561406A CNA028193601A CN02819360A CN1561406A CN 1561406 A CN1561406 A CN 1561406A CN A028193601 A CNA028193601 A CN A028193601A CN 02819360 A CN02819360 A CN 02819360A CN 1561406 A CN1561406 A CN 1561406A
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- 239000007769 metal material Substances 0.000 title claims abstract description 103
- 229910044991 metal oxide Inorganic materials 0.000 title claims abstract description 87
- 150000004706 metal oxides Chemical class 0.000 title claims abstract description 83
- 229910000000 metal hydroxide Inorganic materials 0.000 title claims abstract description 80
- 150000004692 metal hydroxides Chemical class 0.000 title claims abstract description 80
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 33
- 239000011248 coating agent Substances 0.000 claims abstract description 113
- 238000000576 coating method Methods 0.000 claims abstract description 113
- 239000000463 material Substances 0.000 claims abstract description 76
- 238000000034 method Methods 0.000 claims abstract description 61
- 239000000243 solution Substances 0.000 claims abstract description 59
- 239000007864 aqueous solution Substances 0.000 claims abstract description 53
- 229910021645 metal ion Inorganic materials 0.000 claims abstract description 53
- 229910052751 metal Inorganic materials 0.000 claims abstract description 48
- 239000002184 metal Substances 0.000 claims abstract description 48
- 239000011737 fluorine Substances 0.000 claims abstract description 25
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 25
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims abstract 7
- 229910052782 aluminium Inorganic materials 0.000 claims description 88
- 239000004411 aluminium Substances 0.000 claims description 87
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 87
- 239000004020 conductor Substances 0.000 claims description 61
- 239000010935 stainless steel Substances 0.000 claims description 46
- 229910001220 stainless steel Inorganic materials 0.000 claims description 46
- 229910000831 Steel Inorganic materials 0.000 claims description 40
- 239000010959 steel Substances 0.000 claims description 40
- 150000001875 compounds Chemical class 0.000 claims description 24
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 12
- 230000008569 process Effects 0.000 claims description 12
- 229910052725 zinc Inorganic materials 0.000 claims description 12
- 239000011701 zinc Substances 0.000 claims description 12
- 238000005868 electrolysis reaction Methods 0.000 claims description 9
- 238000010924 continuous production Methods 0.000 claims description 4
- 150000002500 ions Chemical class 0.000 abstract description 14
- 230000015572 biosynthetic process Effects 0.000 abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract description 5
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 abstract 1
- 230000001747 exhibiting effect Effects 0.000 abstract 1
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 136
- NMGYKLMMQCTUGI-UHFFFAOYSA-J diazanium;titanium(4+);hexafluoride Chemical compound [NH4+].[NH4+].[F-].[F-].[F-].[F-].[F-].[F-].[Ti+4] NMGYKLMMQCTUGI-UHFFFAOYSA-J 0.000 description 102
- 229910052697 platinum Inorganic materials 0.000 description 68
- LXPCOISGJFXEJE-UHFFFAOYSA-N oxifentorex Chemical compound C=1C=CC=CC=1C[N+](C)([O-])C(C)CC1=CC=CC=C1 LXPCOISGJFXEJE-UHFFFAOYSA-N 0.000 description 63
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 39
- 238000002474 experimental method Methods 0.000 description 38
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 36
- 230000000052 comparative effect Effects 0.000 description 36
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 35
- 230000008021 deposition Effects 0.000 description 33
- 238000011010 flushing procedure Methods 0.000 description 32
- 238000006243 chemical reaction Methods 0.000 description 31
- 229910001335 Galvanized steel Inorganic materials 0.000 description 30
- 239000008397 galvanized steel Substances 0.000 description 30
- MIMUSZHMZBJBPO-UHFFFAOYSA-N 6-methoxy-8-nitroquinoline Chemical compound N1=CC=CC2=CC(OC)=CC([N+]([O-])=O)=C21 MIMUSZHMZBJBPO-UHFFFAOYSA-N 0.000 description 28
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 28
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 28
- 239000010936 titanium Substances 0.000 description 25
- 239000000758 substrate Substances 0.000 description 22
- 229910052742 iron Inorganic materials 0.000 description 20
- 239000007772 electrode material Substances 0.000 description 18
- 239000001257 hydrogen Substances 0.000 description 18
- 229910052739 hydrogen Inorganic materials 0.000 description 18
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 17
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 16
- OMOVVBIIQSXZSZ-UHFFFAOYSA-N [6-(4-acetyloxy-5,9a-dimethyl-2,7-dioxo-4,5a,6,9-tetrahydro-3h-pyrano[3,4-b]oxepin-5-yl)-5-formyloxy-3-(furan-3-yl)-3a-methyl-7-methylidene-1a,2,3,4,5,6-hexahydroindeno[1,7a-b]oxiren-4-yl] 2-hydroxy-3-methylpentanoate Chemical compound CC12C(OC(=O)C(O)C(C)CC)C(OC=O)C(C3(C)C(CC(=O)OC4(C)COC(=O)CC43)OC(C)=O)C(=C)C32OC3CC1C=1C=COC=1 OMOVVBIIQSXZSZ-UHFFFAOYSA-N 0.000 description 12
- 235000011114 ammonium hydroxide Nutrition 0.000 description 12
- 238000012545 processing Methods 0.000 description 12
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 10
- FJMNNXLGOUYVHO-UHFFFAOYSA-N aluminum zinc Chemical compound [Al].[Zn] FJMNNXLGOUYVHO-UHFFFAOYSA-N 0.000 description 10
- 229910052804 chromium Inorganic materials 0.000 description 10
- 239000011651 chromium Substances 0.000 description 10
- BJZIJOLEWHWTJO-UHFFFAOYSA-H dipotassium;hexafluorozirconium(2-) Chemical compound [F-].[F-].[F-].[F-].[F-].[F-].[K+].[K+].[Zr+4] BJZIJOLEWHWTJO-UHFFFAOYSA-H 0.000 description 10
- 238000007747 plating Methods 0.000 description 10
- 238000006722 reduction reaction Methods 0.000 description 10
- 239000005028 tinplate Substances 0.000 description 10
- 239000006185 dispersion Substances 0.000 description 9
- 238000005755 formation reaction Methods 0.000 description 9
- 241001163841 Albugo ipomoeae-panduratae Species 0.000 description 8
- 238000010828 elution Methods 0.000 description 8
- 150000003839 salts Chemical class 0.000 description 8
- 238000012546 transfer Methods 0.000 description 8
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 8
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 7
- 230000003628 erosive effect Effects 0.000 description 7
- 238000007598 dipping method Methods 0.000 description 6
- PWBYYTXZCUZPRD-UHFFFAOYSA-N iron platinum Chemical compound [Fe][Pt][Pt] PWBYYTXZCUZPRD-UHFFFAOYSA-N 0.000 description 6
- KFZAUHNPPZCSCR-UHFFFAOYSA-N iron zinc Chemical compound [Fe].[Zn] KFZAUHNPPZCSCR-UHFFFAOYSA-N 0.000 description 6
- 238000004062 sedimentation Methods 0.000 description 6
- RPAJSBKBKSSMLJ-DFWYDOINSA-N (2s)-2-aminopentanedioic acid;hydrochloride Chemical compound Cl.OC(=O)[C@@H](N)CCC(O)=O RPAJSBKBKSSMLJ-DFWYDOINSA-N 0.000 description 5
- 239000008151 electrolyte solution Substances 0.000 description 5
- 238000011156 evaluation Methods 0.000 description 5
- 239000007791 liquid phase Substances 0.000 description 5
- 229910052684 Cerium Inorganic materials 0.000 description 4
- 229910003803 Gold(III) chloride Inorganic materials 0.000 description 4
- 208000037656 Respiratory Sounds Diseases 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- LCKIEQZJEYYRIY-UHFFFAOYSA-N Titanium ion Chemical compound [Ti+4] LCKIEQZJEYYRIY-UHFFFAOYSA-N 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 4
- 230000005611 electricity Effects 0.000 description 4
- 239000011888 foil Substances 0.000 description 4
- RJHLTVSLYWWTEF-UHFFFAOYSA-K gold trichloride Chemical compound Cl[Au](Cl)Cl RJHLTVSLYWWTEF-UHFFFAOYSA-K 0.000 description 4
- 229940076131 gold trichloride Drugs 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- PIBWKRNGBLPSSY-UHFFFAOYSA-L palladium(II) chloride Chemical compound Cl[Pd]Cl PIBWKRNGBLPSSY-UHFFFAOYSA-L 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 235000005074 zinc chloride Nutrition 0.000 description 4
- 239000011592 zinc chloride Substances 0.000 description 4
- -1 Boron ion Chemical class 0.000 description 3
- 229910045601 alloy Inorganic materials 0.000 description 3
- 239000000956 alloy Substances 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 239000004922 lacquer Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- QGHDLJAZIIFENW-UHFFFAOYSA-N 4-[1,1,1,3,3,3-hexafluoro-2-(4-hydroxy-3-prop-2-enylphenyl)propan-2-yl]-2-prop-2-enylphenol Chemical group C1=C(CC=C)C(O)=CC=C1C(C(F)(F)F)(C(F)(F)F)C1=CC=C(O)C(CC=C)=C1 QGHDLJAZIIFENW-UHFFFAOYSA-N 0.000 description 2
- 229920000877 Melamine resin Polymers 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 239000002390 adhesive tape Substances 0.000 description 2
- 229920000180 alkyd Polymers 0.000 description 2
- 238000003287 bathing Methods 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 125000001153 fluoro group Chemical group F* 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 239000002198 insoluble material Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 2
- 230000001699 photocatalysis Effects 0.000 description 2
- 238000007146 photocatalysis Methods 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 238000003980 solgel method Methods 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000007669 thermal treatment Methods 0.000 description 2
- MEYZYGMYMLNUHJ-UHFFFAOYSA-N tunicamycin Natural products CC(C)CCCCCCCCCC=CC(=O)NC1C(O)C(O)C(CC(O)C2OC(C(O)C2O)N3C=CC(=O)NC3=O)OC1OC4OC(CO)C(O)C(O)C4NC(=O)C MEYZYGMYMLNUHJ-UHFFFAOYSA-N 0.000 description 2
- 239000012808 vapor phase Substances 0.000 description 2
- 239000002966 varnish Substances 0.000 description 2
- YGYGASJNJTYNOL-CQSZACIVSA-N 3-[(4r)-2,2-dimethyl-1,1-dioxothian-4-yl]-5-(4-fluorophenyl)-1h-indole-7-carboxamide Chemical compound C1CS(=O)(=O)C(C)(C)C[C@@H]1C1=CNC2=C(C(N)=O)C=C(C=3C=CC(F)=CC=3)C=C12 YGYGASJNJTYNOL-CQSZACIVSA-N 0.000 description 1
- 229910052779 Neodymium Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical compound [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 238000010349 cathodic reaction Methods 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 229910021518 metal oxyhydroxide Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/34—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/68—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous solutions with pH between 6 and 8
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D9/00—Electrolytic coating other than with metals
- C25D9/04—Electrolytic coating other than with metals with inorganic materials
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- Chemical & Material Sciences (AREA)
- Metallurgy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Electrochemistry (AREA)
- Chemical Treatment Of Metals (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Chemically Coating (AREA)
Abstract
Description
实验号 | 金属材料 | 处理溶液 | 时间 | 结果 | 注 | ||||
A(基材) | B | 处理溶液类型 | 溶液温度 | pH | 沉积状况 | 表面情况 | |||
1 | 铝 | - | 0.1M氯化钛+0.05M氟化氢铵(Ti∶F(摩尔比)=1∶1) | 室温 | 3 | 5分钟 | × | × | 对比实施例 |
2 | 铝 | - | 0.1M氯化钛+0.1M氟化氢铵(Ti∶F(摩尔比)=1∶2) | 室温 | 3 | 5分钟 | × | × | 对比实施例 |
3 | 铝 | - | 0.1M氯化钛+0.15M氟化氢铵(Ti∶F(摩尔比)=1∶3) | 室温 | 3 | 5分钟 | × | × | 对比实施例 |
4 | 铝 | - | 0.1M氯化钛+0.2M氟化氢铵(Ti∶F(摩尔比)=1∶4) | 室温 | 3 | 5分钟 | ○ | ○ | 实施例 |
5 | 铝 | - | 0.1M氯化钛+0.25M氟化氢铵(Ti∶F(摩尔比)=1∶5) | 室温 | 3 | 5分钟 | ○ | ○ | 实施例 |
6 | 铝 | - | 0.1M氯化钛+0.3M氟化氢铵Ti∶F(摩尔比)=1∶6) | 室温 | 3 | 5分钟 | ○ | ○ | 实施例 |
7 | 铝 | - | 0.1M六氟钛酸铵 | 室温 | 1 | 5分钟 | × | × | 对比实施例 |
8 | 铝 | - | 0.1M六氟钛酸铵 | 室温 | 3 | 5分钟 | ○ | ○ | 实施例 |
9 | 铝 | - | 0.1M六氟钛酸铵 | 50℃ | 3 | 5分钟 | ○ | ○ | 实施例 |
10 | 铝 | - | 0.1M六氟钛酸铵 | 80℃ | 3 | 5分钟 | ○ | ○ | 实施例 |
11 | 铝 | - | 0.1M六氟钛酸铵 | 室温 | 5 | 5分钟 | ○ | ○ | 实施例 |
12 | 铝 | - | 0.1M六氟钛酸铵 | 室温 | 7 | 5分钟 | ○ | ○ | 实施例 |
13 | 铝 | - | 0.1M六氟钛酸铵 | 室温 | 9 | 5分钟 | × | × | 对比实施例 |
14 | 铝 | - | 0.1M六氟锆酸钾 | 室温 | 1 | 5分钟 | × | × | 对比实施例 |
15 | 铝 | - | 0.1M六氟锆酸钾 | 室温 | 3 | 5分钟 | ○ | ○ | 实施例 |
16 | 铝 | - | 0.1M六氟锆酸钾 | 室温 | 5 | 5分钟 | ○ | ○ | 实施例 |
17 | 铝 | - | 0.1M六氟锆酸钾 | 室温 | 7 | 5分钟 | ○ | ○ | 实施例 |
实验号 | 金属材料 | 处理溶液 | 时间 | 结果 | 注 | ||||
A(基材) | B | 处理溶液类型 | 溶液温度 | pH | 沉积状况 | 表面情况 | |||
18 | 铝 | - | 0.1M六氟锆酸钾 | 室温 | 9 | 5分钟 | × | × | 对比实施例 |
19 | 不锈钢(SUS 304) | 铝 | 0.1M氯化钛+0.05M氟化氢铵(Ti∶F(摩尔比)=1∶1) | 室温 | 3 | 5分钟 | × | × | 对比实施例 |
20 | 不锈钢(SUS 304) | 铝 | 0.1M氯化钛+0.1M氟化氢铵(Ti∶F(摩尔比)=1∶2) | 室温 | 3 | 5分钟 | × | × | 对比实施例 |
○ | 不锈钢(SUS 304) | 铝 | 0.1M氯化钛+0.15M氟化氢铵(Ti∶F(摩尔比)=1∶3) | 室温 | 3 | 5分钟 | × | × | 对比实施例 |
22 | 不锈钢(SUS 304) | 铝 | 0.1M氯化钛+0.2M氟化氢铵(Ti∶F(摩尔比)=1∶4) | 室温 | 3 | 5分钟 | ○ | ○ | 实施例 |
23 | 不锈钢(SUS 304) | 铝 | 0.1M氯化钛+0.25M氟化氢铵(Ti∶F(摩尔比)=1∶5) | 室温 | 3 | 5分钟 | ○ | ○ | 实施例 |
24 | 不锈钢(SUS 304) | 铝 | 0.1M氯化钛+0.3M氟化氢铵(Ti∶F(摩尔比)=1∶6) | 室温 | 3 | 5分钟 | ○ | ○ | 实施例 |
25 | 不锈钢(SUS 304) | 铝 | 0.1M六氟钛酸铵 | 室温 | 1 | 5分钟 | × | × | 对比实施例 |
26 | 不锈钢(SUS 304) | 铝 | 0.1M六氟钛酸铵 | 室温 | 3 | 5分钟 | ○ | ◎ | 实施例 |
27 | 不锈钢(SUS 304) | 铝 | 0.1M六氟钛酸铵 | 室温 | 5 | 5分钟 | ○ | ○ | 实施例 |
28 | 不锈钢(SUS 304) | 铝 | 0.1M六氟钛酸铵 | 室温 | 7 | 5分钟 | ○ | ○ | 实施例 |
29 | 不锈钢(SUS 304) | 铝 | 0.1M六氟钛酸铵 | 室温 | 9 | 5分钟 | × | × | 对比实施例 |
30 | 不锈钢(SUS 304) | 铝 | 0.1M六氟硅酸铵 | 室温 | 1 | 5分钟 | × | × | 对比实施例 |
31 | 不锈钢(SUS 304) | 铝 | 0.1M六氟硅酸铵 | 室温 | 3 | 5分钟 | ○ | ◎ | 实施例 |
32 | 不锈钢(SUS 304) | 铝 | 0.1M六氟硅酸铵 | 室温 | 5 | 5分钟 | ○ | ○ | 实施例 |
33 | 不锈钢(SUS 304) | 铝 | 0.1M六氟硅酸铵 | 室温 | 7 | 5分钟 | ○ | ○ | 实施例 |
34 | 不锈钢(SUS 304) | 铝 | 0.1M六氟硅酸铵 | 室温 | 9 | 5分钟 | × | × | 对比实施例 |
金属材料 | 处理溶液 | 时间 | 结果 | 注 | |||||||
A(基材) | B | 处理溶液类型 | 溶液温度 | pH | 添加剂 | 沉积状况 | 表面情况 | 沉积结构 | |||
35 | 铁 | 锌 | 层1:0.1M六氟钛酸铵层2:0.1M六氟硅酸铵 | 室温室温 | 33 | 无无 | 2.5分钟2.5分钟 | ○ | ○ | 双层结构 | 实施例 |
36 | 铁 | 锌 | 层1:0.1M六氟钛酸铵层2:0.08M六氟钛酸铵+0.02M六氟硅酸铵层3:0.06M六氟钛酸铵+0.04M六氟硅酸铵层4:0.04M六氟钛酸铵+0.06M六氟硅酸铵层5:0.02M六氟钛酸铵+0.08M六氟硅酸铵 | 室温室温室温室温室温 | 33333 | 无无无无无 | 1分钟1分钟1分钟1分钟1分钟 | ○ | ○ | 层状结构 | 实施例 |
37 | 铁 | 锌 | 0.1M六氟钛酸铵 | 室温 | 3 | 1%氯化锌 | 1分钟 | ○ | ○ | 精细分散结构 | 实施例 |
38 | 铁 | 锌 | 0.1M六氟钛酸铵 | 室温 | 3 | 1%氯化金 | 5分钟 | ○ | ○ | 精细分散结构 | 实施例 |
39 | 铁 | 锌 | 0.1M六氟钛酸铵 | 室温 | 3 | 1%氯化钯 | 5分钟 | ○ | ○ | 精细分散结构 | 实施例 |
40 | 铁 | 锌 | 0.1M六氟钛酸铵 | 室温 | 3 | EDTA-铈 | 5分钟 | ○ | ○ | 精细分散结构 | 实施例 |
实验号 | 金属材料 | 处理溶液 | 处理条件 | 结果 | 注 | ||||||
基材 | 电极材料 | 处理溶液类型 | 溶液温度 | pH | 电位 | 时间 | 沉积状况 | 表面情况 | 沉积量 | ||
101 | 导电橡胶 | 铂 | 0.1M氯化钛+0.05M氟化氢铵(Ti∶F(摩尔比)=1∶1) | 室温 | 3 | 50mV | 5分钟 | × | × | - | 对比实施例 |
102 | 导电橡胶 | 铂 | 0.1M氯化钛+0.1M氟化氢铵(Ti∶F(摩尔比)=1∶2) | 室温 | 3 | 50mV | 5分钟 | × | × | - | 对比实施例 |
103 | 导电橡胶 | 铂 | 0.1M氯化钛+0.15M氟化氢铵(Ti∶F(摩尔比)=1∶3) | 室温 | 3 | 50mV | 5分钟 | × | × | - | 对比实施例 |
104 | 导电橡胶 | 铂 | 0.1M氯化钛+0.2M氟化氢铵(Ti∶F(摩尔比)=1∶4) | 室温 | 3 | 50mV | 5分钟 | ○ | ○ | 约1μg/cm2 | 实施例 |
105 | 导电橡胶 | 铂 | 0.1M氯化钛+0.25M氟化氢铵(Ti∶F(摩尔比)=1∶5) | 室温 | 3 | 50mV | 5分钟 | ○ | ○ | 约1μg/cm2 | 实施例 |
106 | 导电橡胶 | 铂 | 0.1M氯化钛+0.3M氟化氢铵(Ti∶F(摩尔比)=1∶6) | 室温 | 3 | 50mV | 5分钟 | ○ | ○ | 约1μg/cm2 | 实施例 |
107 | 导电橡胶 | 铂 | 0.1M六氟钛酸铵 | 室温 | 1 | 50mV | 5分钟 | × | × | - | 对比实施例 |
108 | 导电橡胶 | 铂 | 0.1M六氟钛酸铵 | 室温 | 3 | 50mV | 5分钟 | ○ | ○ | 约1μg/cm2 | 实施例 |
109 | 导电橡胶 | 铂 | 0.1M六氟钛酸铵 | 50℃ | 3 | 50mV | 5分钟 | ○ | ○ | 约25μg/cm2 | 实施例 |
110 | 导电橡胶 | 铂 | 0.1M六氟钛酸铵 | 80℃ | 3 | 50mV | 5分钟 | ○ | ○ | 约50μg/cm2 | 实施例 |
111 | 导电橡胶 | 铂 | 0.1M六氟钛酸铵 | 室温 | 5 | 50mV | 5分钟 | ○ | ○ | 约1μg/cm2 | 实施例 |
112 | 导电橡胶 | 铂 | 0.1M六氟钛酸铵 | 室温 | 7 | 50mV | 5分钟 | ○ | ○ | 约1μg/cm2 | 实施例 |
113 | 导电橡胶 | 铂 | 0.1M六氟钛酸铵 | 室温 | 9 | 50mV | 5分钟 | × | × | - | 对比实施例 |
114 | 导电橡胶 | 铂 | 0.1M六氟锆酸钾 | 室温 | 1 | 50mV | 5分钟 | × | × | - | 对比实施例 |
115 | 导电橡胶 | 铂 | 0.1M六氟锆酸钾 | 室温 | 3 | 50mV | 5分钟 | ○ | ○ | 约1μg/cm2 | 实施例 |
116 | 导电橡胶 | 铂 | 0.1M六氟锆酸钾 | 室温 | 5 | 50mV | 5分钟 | ○ | ○ | 约1μg/cm2 | 实施例 |
117 | 导电橡胶 | 铂 | 0.1M六氟锆酸钾 | 室温 | 7 | 50mV | 5分钟 | ○ | ○ | 约1μg/cm2 | 实施例 |
118 | 导电橡胶 | 铂 | 0.1M六氟锆酸钾 | 室温 | 9 | 50mV | 5分钟 | × | × | - | 对比实施例 |
实验号 | 金属材料 | 处理溶液 | 处理条件 | 结果 | 注 | ||||||
基材 | 电极材料 | 处理溶液类型 | 溶液温度 | pH | 电位 | 时间 | 沉积状况 | 表面情况 | 沉积量 | ||
119 | SUS304 | 铂 | 0.1M氯化钛+0.05M氟化氢铵(Ti∶F(摩尔比)=1∶1) | 室温 | 3 | 50mV | 5分钟 | × | × | - | 对比实施例 |
120 | SUS304 | 铂 | 0.1M氯化钛+0.1M氟化氢铵(Ti∶F(摩尔比)=1∶2) | 室温 | 3 | 50mV | 5分钟 | × | × | - | 对比实施例 |
121 | SUS304 | 铂 | 0.1M氯化钛+0.15M氟化氢铵(Ti∶F(摩尔比)=1∶3) | 室温 | 3 | 50mV | 5分钟 | × | × | - | 对比实施例 |
122 | SUS304 | 铂 | 0.1M氯化钛+0.2M氟化氢铵(Ti∶F(摩尔比)=1∶4) | 室温 | 3 | 50mV | 5分钟 | ○ | ○ | 约1μg/cm2 | 实施例 |
123 | SUS304 | 铂 | 0.1M氯化钛+0.25M氟化氢铵(Ti∶F(摩尔比)=1∶5) | 室温 | 3 | 50mV | 5分钟 | ○ | ○ | 约1μg/cm2 | 实施例 |
124 | SUS304 | 铂 | 0.1M氯化钛+0.3M氟化氢铵(Ti∶F(摩尔比)=1∶6) | 室温 | 3 | 50mV | 5分钟 | ○ | ○ | 约1μg/cm2 | 实施例 |
125 | SUS304 | 铂 | 0.1M六氟钛酸铵 | 室温 | 1 | 50mV | 5分钟 | × | × | - | 对比实施例 |
126 | SUS304 | 铂 | 0.1M六氟钛酸铵 | 室温 | 3 | 50mV | 5分钟 | ○ | ◎ | 约1μg/cm2 | 实施例 |
127 | SUS304 | 铂 | 0.1M六氟钛酸铵 | 室温 | 5 | 50mV | 5分钟 | ○ | ○ | 约1μg/cm2 | 实施例 |
128 | SUS304 | 铂 | 0.1M六氟钛酸铵 | 室温 | 7 | 50mV | 5分钟 | ○ | ○ | 约1μg/cm2 | 实施例 |
129 | SUS304 | 铂 | 0.1M六氟钛酸铵 | 室温 | 9 | 50mV | 5分钟 | × | × | - | 对比实施例 |
130 | SUS304 | 铂 | 0.1M六氟硅酸铵 | 室温 | 1 | 50mV | 5分钟 | × | × | - | 对比实施例 |
131 | SUS304 | 铂 | 0.1M六氟硅酸铵 | 室温 | 3 | 50mV | 5分钟 | ○ | ◎ | 约1μg/cm2 | 实施例 |
132 | SUS304 | 铂 | 0.1M六氟硅酸铵 | 室温 | 5 | 50mV | 5分钟 | ○ | ○ | 约1μg/cm2 | 实施例 |
133 | SUS304 | 铂 | 0.1M六氟硅酸铵 | 室温 | 7 | 50mV | 5分钟 | ○ | ○ | 约1μg/cm2 | 实施例 |
134 | SUS304 | 铂 | 0.1M六氟硅酸铵 | 室温 | 9 | 50mV | 5分钟 | × | × | - | 对比实施例 |
实验号 | 金属材料 | 处理溶液 | 处理条件 | 结果 | 注 | ||||||||
基材 | 电极材料 | 处理溶液类型 | 溶液温度 | pH | 添加剂 | 电位 | 时间 | 沉积状况 | 表面情况 | 沉积量 | 沉积结构 | ||
135 | 铁 | 铂 | 层1:0.1M六氟钛酸铵层2:0.1M六氟硅酸铵 | 室温室温 | 33 | 无无 | 50mV50mV | 2.5分钟2.5分钟 | ○ | ○ | 约1μg/cm2 | 双层结构 | 实施例 |
136 | 铁 | 铂 | 层1:0.1M六氟钛酸铵层2:0.08M六氟钛酸铵+0.02M六氟硅酸铵层3:0.06M六氟钛酸铵+0.04M六氟硅酸铵层4:0.04M六氟钛酸铵+0.06M六氟硅酸铵层5:0.02M六氟钛酸铵+0.08M六氟硅酸铵 | 室温室温室温室温室温 | 33333 | 无无无无无 | 50mV50mV50mV50mV50mV | 1分钟1分钟1分钟1分钟1分钟 | ○ | ○ | 约1μg/cm2 | 层状结构 | 实施例 |
137 | 铁 | 铂 | 0.1M六氟钛酸铵 | 室温 | 3 | 1%氯化锌 | 50mV | 5分钟 | ○ | ○ | 约1μg/cm2 | 精细分散结构 | 实施例 |
138 | 铁 | 铂 | 0.1M六氟钛酸铵 | 室温 | 3 | 1%氯化金 | 50mV | 5分钟 | ○ | ○ | 约1μg/cm2 | 精细分散结构 | 实施例 |
139 | 铁 | 铂 | 0.1M六氟钛酸铵 | 室温 | 3 | 1%氯化钯 | 50mV | 5分钟 | ○ | ○ | 约1μg/cm2 | 精细分散结构 | 实施例 |
140 | 玻璃 | - | 0.1M六氟钛酸铵 | 室温 | 3 | 无 | - | 5小时 | - | ○ | 约1μg/cm2 | 对比实施例 | |
141 | 铁 | 铂 | 0.1M六氟钛酸铵 | 室温 | 3 | EDTA-铈 | 50mV | 5分钟 | ○ | ○ | 约1μg/cm2 | 精细分散结构 | 实施例 |
实验号 | 电极材料 | 处理溶液 | 耐腐蚀性 | 漆粘合力 | ||||||
基材 | 处理溶液类型 | 溶液温度 | pH | 时间(min) | 板 | 加工区 | 第一道 | 第二道 | ||
201 | 电镀锌钢 | 0.1M六氟硅酸铵 | 室温 | 3 | 10 | ○ | ○ | ○ | ○ | 实施例 |
202 | 电镀锌钢 | 0.1M六氟钛酸铵 | 室温 | 3 | 10 | ○ | ○ | ○ | ○ | 实施例 |
203 | 电镀锌钢 | 0.1M六氟锆酸铵 | 室温 | 3 | 10 | ○ | ○ | ○ | ○ | 实施例 |
204 | 电镀锌钢 | 未处理 | × | × | × | × | 对比实施例 | |||
205 | 热浸镀锌钢板 | 0.1M六氟硅酸铵 | 室温 | 3 | 10 | ○ | ○ | ○ | ○ | 实施例 |
206 | 热浸镀锌钢板 | 0.1M六氟钛酸铵 | 室温 | 3 | 10 | ○ | ○ | ○ | ○ | 实施例 |
207 | 热浸镀锌钢板 | 0.1M六氟锆酸铵 | 室温 | 3 | 10 | ○ | ○ | ○ | ○ | 实施例 |
208 | 热浸镀锌钢板 | 未处理 | × | × | × | × | 对比实施例 | |||
209 | 热浸镀铝钢板 | 0.1M六氟硅酸铵 | 室温 | 3 | 10 | ○ | ○ | ○ | ○ | 实施例 |
210 | 热浸镀铝钢板 | 0.1M六氟钛酸铵 | 室温 | 3 | 10 | ○ | ○ | ○ | ○ | 实施例 |
211 | 热浸镀铝钢板 | 0.1M六氟锆酸铵 | 室温 | 3 | 10 | ○ | ○ | ○ | ○ | 实施例 |
212 | 热浸镀铝钢板 | 未处理 | × | × | × | × | 对比实施例 | |||
213 | 热浸镀锌钢板 | 0.1M六氟硅酸铵 | 室温 | 3 | 10 | ○ | ○ | ○ | ○ | 实施例 |
214 | 热浸镀锌钢板 | 0.1M六氟钛酸铵 | 室温 | 3 | 10 | ○ | ○ | ○ | ○ | 实施例 |
215 | 热浸镀锌钢板 | 0.1M六氟锆酸铵 | 室温 | 3 | 10 | ○ | ○ | ○ | ○ | 实施例 |
216 | 热浸镀锌钢板 | 未处理 | × | × | × | × | 对比实施例 | |||
217 | 热浸镀锌铝钢板 | 0.1M六氟硅酸铵 | 室温 | 3 | 10 | ○ | ○ | ○ | ○ | 实施例 |
218 | 热浸镀锌铝钢板 | 0.1M六氟钛酸铵 | 室温 | 3 | 10 | ○ | ○ | ○ | ○ | 实施例 |
219 | 热浸镀锌铝钢板 | 0.1M六氟锆酸铵 | 室温 | 3 | 10 | ○ | ○ | ○ | ○ | 实施例 |
220 | 热浸镀锌铝钢板 | 未处理 | × | × | × | × | 对比实施例 | |||
221 | 镀锡钢板 | 0.1M六氟硅酸铵 | 室温 | 3 | 10 | ○ | ○ | ○ | ○ | 实施例 |
222 | 镀锡钢板 | 0.1M六氟钛酸铵 | 室温 | 3 | 10 | ○ | ○ | ○ | ○ | 实施例 |
223 | 镀锡钢板 | 0.1M六氟锆酸铵 | 室温 | 3 | 10 | ○ | ○ | ○ | ○ | 实施例 |
224 | 镀锡钢板 | 未处理 | Δ | Δ | Δ | Δ | 对比实施例 | |||
225 | 镀铬钢板 | 0.1M六氟硅酸铵 | 室温 | 3 | 10 | ○ | ○ | ○ | ○ | 实施例 |
226 | 镀铬钢板 | 0.1M六氟钛酸铵 | 室温 | 3 | 10 | ○ | ○ | ○ | ○ | 实施例 |
227 | 镀铬钢板 | 0.1M六氟锆酸铵 | 室温 | 3 | 10 | ○ | ○ | ○ | ○ | 实施例 |
228 | 镀铬钢板 | 未处理 | Δ | Δ | Δ | Δ | 对比实施例 |
实验号 | 电极材料 | 处理溶液 | 处理条件 | 耐腐蚀性 | 漆粘合力 | |||||||
基材 | 不溶性材料 | 处理溶液类型 | 溶液温度 | pH | 电流 | 时间(分钟) | 板 | 加工区 | 第一道 | 第二道 | ||
301 | 电镀锌钢 | 铂 | 0.1M六氟硅酸铵 | 室温 | 3 | 100mA/cm2 | 5 | ○ | ○ | ○ | ○ | 实施例 |
302 | 电镀锌钢 | 铂 | 0.1M六氟钛酸铵 | 室温 | 3 | 100mA/cm2 | 5 | ○ | ○ | ○ | ○ | 实施例 |
303 | 电镀锌钢 | 铂 | 0.1M六氟锆酸铵 | 室温 | 3 | 100mA/cm2 | 5 | ○ | ○ | ○ | ○ | 实施例 |
304 | 热浸镀锌钢板 | 铂 | 0.1M六氟硅酸铵 | 室温 | 3 | 100mA/cm2 | 5 | ○ | ○ | ○ | ○ | 实施例 |
305 | 热浸镀锌钢板 | 铂 | 0.1M六氟钛酸铵 | 室温 | 3 | 100mA/cm2 | 5 | ○ | ○ | ○ | ○ | 实施例 |
306 | 热浸镀锌钢板 | 铂 | 0.1M六氟锆酸铵 | 室温 | 3 | 100mA/cm2 | 5 | ○ | ○ | ○ | ○ | 实施例 |
307 | 热浸镀铝钢板 | 铂 | 0.1M六氟硅酸铵 | 室温 | 3 | 100mA/cm2 | 5 | ○ | ○ | ○ | ○ | 实施例 |
308 | 热浸镀铝钢板 | 铂 | 0.1M六氟钛酸铵 | 室温 | 3 | 100mA/cm2 | 5 | ○ | ○ | ○ | ○ | 实施例 |
309 | 热浸镀铝钢板 | 铂 | 0.1M六氟锆酸铵 | 室温 | 3 | 100mA/cm2 | 5 | ○ | ○ | ○ | ○ | 实施例 |
310 | 热浸镀锌钢板 | 铂 | 0.1M六氟硅酸铵 | 室温 | 3 | 100mA/cm2 | 5 | ○ | ○ | ○ | ○ | 实施例 |
311 | 热浸镀锌钢板 | 铂 | 0.1M六氟钛酸铵 | 室温 | 3 | 100mA/cm2 | 5 | ○ | ○ | ○ | ○ | 实施例 |
312 | 热浸镀锌钢板 | 铂 | 0.1M六氟锆酸铵 | 室温 | 3 | 100mA/cm2 | 5 | ○ | ○ | ○ | ○ | 实施例 |
313 | 热浸镀锌铝钢板 | 铂 | 0.1M六氟硅酸铵 | 室温 | 3 | 100mA/cm2 | 5 | ○ | ○ | ○ | ○ | 实施例 |
314 | 热浸镀锌铝钢板 | 铂 | 0.1M六氟钛酸铵 | 室温 | 3 | 100mA/cm2 | 5 | ○ | ○ | ○ | ○ | 实施例 |
315 | 热浸镀锌铝钢板 | 铂 | 0.1M六氟锆酸铵 | 室温 | 3 | 100mA/cm2 | 5 | ○ | ○ | ○ | ○ | 实施例 |
316 | 镀锡钢板 | 铂 | 0.1M六氟硅酸铵 | 室温 | 3 | 100mA/cm2 | 5 | ○ | ○ | ○ | ○ | 实施例 |
317 | 镀锡钢板 | 铂 | 0.1M六氟钛酸铵 | 室温 | 3 | 100mA/cm2 | 5 | ○ | ○ | ○ | ○ | 实施例 |
318 | 镀锡钢板 | 铂 | 0.1M六氟锆酸铵 | 室温 | 3 | 100mA/cm2 | 5 | ○ | ○ | ○ | ○ | 实施例 |
319 | 镀铬钢板 | 铂 | 0.1M六氟硅酸铵 | 室温 | 3 | 100mA/cm2 | 5 | ○ | ○ | ○ | ○ | 实施例 |
320 | 镀铬钢板 | 铂 | 0.1M六氟钛酸铵 | 室温 | 3 | 100mA/cm2 | 5 | ○ | ○ | ○ | ○ | 实施例 |
321 | 镀铬钢板 | 铂 | 0.1M六氟锆酸铵 | 室温 | 3 | 100mA/cm2 | 5 | ○ | ○ | ○ | ○ | 实施例 |
实验号 | 电极材料 | 处理溶液 | 处理条件 | 耐腐蚀性 | 漆粘合力 | |||||||
基材 | 不溶性材料 | 处理溶液类型 | 溶液温度 | pH | 电流 | 时间(分钟) | 板 | 加工区 | 第一道 | 第二道 | ||
401 | 电镀锌钢 | 铝 | 0.1M六氟硅酸铵 | 室温 | 3 | 100mA/cm2 | 5 | ○ | ○ | ○ | ○ | 实施例 |
402 | 电镀锌钢 | 铝 | 0.1M六氟钛酸铵 | 室温 | 3 | 100mA/cm2 | 5 | ○ | ○ | ○ | ○ | 实施例 |
403 | 电镀锌钢 | 铝 | 0.1M六氟锆酸铵 | 室温 | 3 | 100mA/cm2 | 5 | ○ | ○ | ○ | ○ | 实施例 |
404 | 热浸镀锌钢板 | 铝 | 0.1M六氟硅酸铵 | 室温 | 3 | 100mA/cm2 | 5 | ○ | ○ | ○ | ○ | 实施例 |
405 | 热浸镀锌钢板 | 铝 | 0.1M六氟钛酸铵 | 室温 | 3 | 100mA/cm2 | 5 | ○ | ○ | ○ | ○ | 实施例 |
406 | 热浸镀锌钢板 | 铝 | 0.1M六氟锆酸铵 | 室温 | 3 | 100mA/cm2 | 5 | ○ | ○ | ○ | ○ | 实施例 |
407 | 热浸镀铝钢板 | 铝 | 0.1M六氟硅酸铵 | 室温 | 3 | 100mA/cm2 | 5 | ○ | ○ | ○ | ○ | 实施例 |
408 | 热浸镀铝钢板 | 铝 | 0.1M六氟钛酸铵 | 室温 | 3 | 100mA/cm2 | 5 | ○ | ○ | ○ | ○ | 实施例 |
409 | 热浸镀铝钢板 | 铝 | 0.1M六氟锆酸铵 | 室温 | 3 | 100mA/cm2 | 5 | ○ | ○ | ○ | ○ | 实施例 |
410 | 热浸镀锌钢板 | 铝 | 0.1M六氟硅酸铵 | 室温 | 3 | 100mA/cm2 | 5 | ○ | ○ | ○ | ○ | 实施例 |
411 | 热浸镀锌钢板 | 铝 | 0.1M六氟钛酸铵 | 室温 | 3 | 100mA/cm2 | 5 | ○ | ○ | ○ | ○ | 实施例 |
412 | 热浸镀锌钢板 | 铝 | 0.1M六氟锆酸铵 | 室温 | 3 | 100mA/cm2 | 5 | ○ | ○ | ○ | ○ | 实施例 |
413 | 热浸镀锌铝钢板 | 铝 | 0.1M六氟硅酸铵 | 室温 | 3 | 100mA/cm2 | 5 | ○ | ○ | ○ | ○ | 实施例 |
414 | 热浸镀锌铝钢板 | 铝 | 0.1M六氟钛酸铵 | 室温 | 3 | 100mA/cm2 | 5 | ○ | ○ | ○ | ○ | 实施例 |
415 | 热浸镀锌铝钢板 | 铝 | 0.1M六氟锆酸铵 | 室温 | 3 | 100mA/cm2 | 5 | ○ | ○ | ○ | ○ | 实施例 |
416 | 镀锡钢板 | 铝 | 0.1M六氟硅酸铵 | 室温 | 3 | 100mA/cm2 | 5 | ○ | ○ | ○ | ○ | 实施例 |
417 | 镀锡钢板 | 铝 | 0.1M六氟钛酸铵 | 室温 | 3 | 100mA/cm2 | 5 | ○ | ○ | ○ | ○ | 实施例 |
418 | 镀锡钢板 | 铝 | 0.1M六氟锆酸铵 | 室温 | 3 | 100mA/cm2 | 5 | ○ | ○ | ○ | ○ | 实施例 |
419 | 镀铬钢板 | 铝 | 0.1M六氟硅酸铵 | 室温 | 3 | 100mA/cm2 | 5 | ○ | ○ | ○ | ○ | 实施例 |
420 | 镀铬钢板 | 铝 | 0.1M六氟钛酸铵 | 室温 | 3 | 100mA/cm2 | 5 | ○ | ○ | ○ | ○ | 实施例 |
421 | 镀铬钢板 | 铝 | 0.1M六氟锆酸铵 | 室温 | 3 | 100mA/cm2 | 5 | ○ | ○ | ○ | ○ | 实施例 |
实验号 | 基材 | 反电极类型 | 处理面 | 电解溶液 | 电流 | 输送速度 | 结果 | 所用设备 | 注 | |||||
类型 | 板厚 | 类型 | pH | 温度 | 循环 | 沉积状况 | 表面情况 | |||||||
501 | 不锈钢板 | 10μm | 铝 | 一面 | 0.1M六氟钛酸铵 | 3 | 50℃ | + | 10A/dm2 | 1mpm | ○ | ○ | 图1 | 实施例 |
502 | 不锈钢板 | 10μm | 铝 | 两面 | 0.1M六氟钛酸铵 | 3 | 50℃ | + | 10A/dm2 | 1mpm | ○ | ○ | 图2 | 实施例 |
503 | 不锈钢板 | 10μm | 铝 | 一面 | 0.1M六氟钛酸铵 | 3 | 50℃ | - | 1A/dm2 | 1mpm | ○ | ○ | 图1 | 实施例 |
504 | 不锈钢板 | 10μm | 铝 | 两面 | 0.1M六氟钛酸铵 | 3 | 50℃ | - | 1A/dm2 | 1mpm | ○ | ○ | 图2 | 实施例 |
505 | 不锈钢板 | 10μm | 铝 | 一面 | 0.1M六氟钛酸铵 | 3 | 50℃ | + | 基材和电极短路 | 1mpm | ○ | ○ | 图1中的电极短路 | 实施例 |
506 | 不锈钢板 | 10μm | 铝 | 两面 | 0.1M六氟钛酸铵 | 3 | 50℃ | + | 基材和电极短路 | 1mpm | ○ | ○ | 图2中的电极短路 | 实施例 |
507 | 不锈钢板 | 10μm | 铝 | 一面 | 0.1M六氟钛酸铵 | 3 | 50℃ | + | 10A/dm2 | 1mpm | ○ | ○ | 图3 | 实施例 |
508 | 不锈钢板 | 10μm | 铝 | 两面 | 0.1M六氟钛酸铵 | 3 | 50℃ | + | 10A/dm2 | 1mpm | ○ | ○ | 图4 | 实施例 |
509 | 不锈钢板 | 100μm | 铝 | 一面 | 0.1M六氟硅酸铵 | 3 | 50℃ | + | 10A/dm2 | 1mpm | ○ | ○ | 图1 | 实施例 |
510 | 不锈钢板 | 100μm | 铝 | 两面 | 0.1M六氟硅酸铵 | 3 | 50℃ | + | 10A/dm2 | 1mpm | ○ | ○ | 图2 | 实施例 |
511 | 不锈钢板 | 100μm | 铝 | 一面 | 0.1M六氟硅酸铵 | 3 | 50℃ | + | 基材和电极短路 | 1mpm | ○ | ○ | 图1中的电极短路 | 实施例 |
512 | 不锈钢板 | 100μm | 铝 | 两面 | 0.1M六氟硅酸铵 | 3 | 50℃ | + | 基材和电极短路 | 1mpm | ○ | ○ | 图2中的电极短路 | 实施例 |
513 | 不锈钢板 | 100μm | 铝 | 一面 | 0.1M六氟硅酸铵 | 3 | 50℃ | + | 10A/dm2 | 1mpm | ○ | ○ | 图3 | 实施例 |
514 | 不锈钢板 | 100μm | 铝 | 两面 | 0.1M六氟硅酸铵 | 3 | 50℃ | + | 10A/dm2 | 1mpm | ○ | ○ | 图4 | 实施例 |
515 | 铁 | 200μm | 铝 | 一面 | 0.1M六氟锆酸铵 | 3 | 50℃ | + | 10A/dm2 | 10mpm | ○ | ○ | 图1 | 实施例 |
516 | 铁 | 200μm | 铝 | 两面 | 0.1M六氟锆酸铵 | 3 | 50℃ | + | 10A/dm2 | 10mpm | ○ | ○ | 图2 | 实施例 |
517 | 铁 | 200μm | 铝 | 一面 | 0.1M六氟锆酸铵 | 3 | 50℃ | + | 基材和电极短路 | 10mpm | ○ | ○ | 图1中的电极短路 | 实施例 |
518 | 铁 | 200μm | 铝 | 两面 | 0.1M六氟锆酸铵 | 3 | 50℃ | + | 基材和电极短路 | 10mpm | ○ | ○ | 图2中的电极短路 | 实施例 |
519 | 铁 | 200μm | 铝 | 一面 | 0.1M六氟锆酸铵 | 3 | 50℃ | + | 10A/dm2 | 10mpm | ○ | ○ | 图3 | 实施例 |
520 | 铁 | 200μm | 铝 | 两面 | 0.1M六氟锆酸铵 | 3 | 50℃ | + | 10A/dm2 | 10mpm | ○ | ○ | 图4 | 实施例 |
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-
2002
- 2002-12-03 JP JP2003549591A patent/JPWO2003048416A1/ja active Pending
- 2002-12-03 US US10/497,616 patent/US7883616B2/en not_active Expired - Fee Related
- 2002-12-03 KR KR1020047007984A patent/KR100697354B1/ko active IP Right Grant
- 2002-12-03 WO PCT/JP2002/012682 patent/WO2003048416A1/ja active Application Filing
- 2002-12-03 CN CNB028193601A patent/CN1306064C/zh not_active Expired - Fee Related
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2008
- 2008-04-21 JP JP2008110760A patent/JP4757893B2/ja not_active Expired - Fee Related
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105102681A (zh) * | 2013-02-27 | 2015-11-25 | 东洋钢钣株式会社 | 表面处理钢板的制造方法 |
CN105102681B (zh) * | 2013-02-27 | 2018-05-29 | 东洋钢钣株式会社 | 表面处理钢板的制造方法 |
US10156021B2 (en) | 2013-02-27 | 2018-12-18 | Toyo Kohan Co., Ltd. | Method of producing surface-treated steel sheet |
CN113235143A (zh) * | 2021-05-08 | 2021-08-10 | 重庆大学 | 移动式原位薄层电解法在电极上连续合成金属氧化物或金属沉积物微/纳米结构的方法 |
Also Published As
Publication number | Publication date |
---|---|
KR100697354B1 (ko) | 2007-03-20 |
TWI280988B (en) | 2007-05-11 |
KR20050044602A (ko) | 2005-05-12 |
JP2008214758A (ja) | 2008-09-18 |
US7883616B2 (en) | 2011-02-08 |
TW200300803A (en) | 2003-06-16 |
JP4757893B2 (ja) | 2011-08-24 |
WO2003048416A1 (fr) | 2003-06-12 |
US20050067056A1 (en) | 2005-03-31 |
JPWO2003048416A1 (ja) | 2005-04-14 |
JP2010121218A (ja) | 2010-06-03 |
CN1306064C (zh) | 2007-03-21 |
EP1455001A1 (en) | 2004-09-08 |
EP1455001A4 (en) | 2005-05-18 |
JP4673903B2 (ja) | 2011-04-20 |
EP1455001B1 (en) | 2013-09-25 |
JP5171865B2 (ja) | 2013-03-27 |
JP2008208464A (ja) | 2008-09-11 |
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