CN1322625C - 钙钛矿基的燃料电池电极以及薄膜 - Google Patents

钙钛矿基的燃料电池电极以及薄膜 Download PDF

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CN1322625C
CN1322625C CNB038184885A CN03818488A CN1322625C CN 1322625 C CN1322625 C CN 1322625C CN B038184885 A CNB038184885 A CN B038184885A CN 03818488 A CN03818488 A CN 03818488A CN 1322625 C CN1322625 C CN 1322625C
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value
perovskite
membrane
fuel cell
positive electrode
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CN1672284A (zh
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J·T·S·欧文
陶善文
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University of St Andrews
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CNB038184885A 2002-08-01 2003-07-31 钙钛矿基的燃料电池电极以及薄膜 Expired - Lifetime CN1322625C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB0217794.7 2002-08-01
GBGB0217794.7A GB0217794D0 (en) 2002-08-01 2002-08-01 Fuel cell electrodes

Publications (2)

Publication Number Publication Date
CN1672284A CN1672284A (zh) 2005-09-21
CN1322625C true CN1322625C (zh) 2007-06-20

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US (1) US7504172B2 (enExample)
EP (1) EP1532710B1 (enExample)
JP (1) JP4961614B2 (enExample)
CN (1) CN1322625C (enExample)
AU (1) AU2003248994B2 (enExample)
CA (1) CA2493029C (enExample)
DK (1) DK1532710T3 (enExample)
ES (1) ES2598356T3 (enExample)
GB (1) GB0217794D0 (enExample)
WO (1) WO2004013925A1 (enExample)

Families Citing this family (59)

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Publication number Priority date Publication date Assignee Title
KR100543979B1 (ko) * 2003-11-21 2006-01-20 한국표준과학연구원 나노 크기의 세공을 갖는 강자기성 망간 산화물 막과 이의제조방법
KR101158947B1 (ko) * 2004-01-23 2012-06-21 베리 스몰 파티클 컴파니 피티와이 리미티드 금속 산화물의 제조 방법
CN1294670C (zh) * 2004-03-03 2007-01-10 哈尔滨工业大学 一种镓酸镧基固体氧化物燃料电池用正极材料的制备方法
KR100909120B1 (ko) 2004-06-10 2009-07-23 테크니칼 유니버시티 오브 덴마크 고체 산화물 연료 전지
EP1844517B1 (en) * 2005-02-02 2010-04-21 Technical University of Denmark A method for producing a reversible solid oxid fuel cell
US20090206297A1 (en) * 2005-06-30 2009-08-20 Maarit Karppinen Oxygen excess type metal oxide, ceramic for oxygen storage and/or an oxygen selective membrane, and methods and apparatuses using said metal oxide
DK1760817T3 (da) 2005-08-31 2013-10-14 Univ Denmark Tech Dtu Reversibel fastoxidbrændselscellestak og fremgangsmåde til fremstilling af samme
JP4788274B2 (ja) * 2005-10-03 2011-10-05 株式会社村田製作所 Ｃｔｒ特性を有する酸化物導電体磁器および抵抗体
GB0602842D0 (en) * 2006-02-14 2006-03-22 Rolls Royce Plc A Solid Oxide Fuel Cell And A Solid Oxide Fuel Cell Module
AT9543U1 (de) 2006-07-07 2007-11-15 Plansee Se Verfahren zur herstellung einer elektrisch leitfähigen schicht
JP5361143B2 (ja) * 2007-05-29 2013-12-04 新光電気工業株式会社 固体酸化物型燃料電池およびその製造方法
US8367273B2 (en) * 2007-05-31 2013-02-05 Elcogen As Method for preparation of the solid oxide fuel cell single cell
RU2424604C1 (ru) * 2007-05-31 2011-07-20 Элкоген Ас Способ изготовления одиночного твердооксидного топливного элемента
US20090017341A1 (en) * 2007-07-09 2009-01-15 Uchicago Argonne, Llc Air electrode composition for intermediate temperature electrochemical devices
US20110127169A1 (en) 2007-08-22 2011-06-02 Stichting Energieonderzoek Centrum Nederland Electrode for fixed oxide reactor and fixed oxide reactor
CN100459250C (zh) * 2007-10-11 2009-02-04 北京科技大学 一种用于固体氧化物燃料电池的缺位掺杂阳极材料
JP5226290B2 (ja) * 2007-12-19 2013-07-03 国立大学法人東京工業大学 固体酸化物型電池
TWI380970B (zh) * 2008-04-03 2013-01-01 沙坎公司 使用二羧酸鎓鹽製備高級陶瓷粉末之方法
GB2456445B (en) * 2008-06-13 2011-09-14 Ceres Ip Co Ltd Method for deposition of ceramic films
KR101213060B1 (ko) 2009-03-12 2012-12-17 한창산업 주식회사 고체산화물 연료전지용 공기극 물질
CN101789501B (zh) * 2010-01-22 2011-12-28 清华大学 用于固体氧化物电解池阴极的钙钛矿粉体材料的制备方法
DE102010027645A1 (de) * 2010-07-19 2012-01-19 Forschungszentrum Jülich GmbH CO2 tolerantes, gemischt leitendes Oxid und dessen Anwendung für die Wasserstoffabtrennung
TWI411154B (zh) 2010-07-23 2013-10-01 Iner Aec Executive Yuan 一種用於固態氧化物燃料電池之雙層陽極-金屬基板結構及其製作方法
TWI416787B (zh) 2010-07-23 2013-11-21 Iner Aec Executive Yuan 固態氧化物燃料電池之多孔金屬基板結構及其之製作方法
JP5204816B2 (ja) * 2010-08-11 2013-06-05 株式会社ノリタケカンパニーリミテド 酸素分離膜エレメント及びその製造方法
JP5737954B2 (ja) * 2011-01-07 2015-06-17 国立大学法人茨城大学 バナデート系複合酸化物の製造方法
JP5717067B2 (ja) * 2011-04-22 2015-05-13 独立行政法人物質・材料研究機構 中低温で動作する固体酸化物燃料電池用複合カソード材料、固体酸化物燃料電池用複合カソード及び固体酸化物燃料電池用電解質−複合カソード構造体の製造方法
US8364236B2 (en) 2011-04-22 2013-01-29 Topera, Inc. Flexible electrode assembly for insertion into body lumen or organ
FR2981508B1 (fr) * 2011-10-12 2013-11-15 Areva Electrode pour cellule electrochimique et procede de fabrication d'une telle electrode
EP2621006B1 (en) 2012-01-26 2016-10-26 Institute of Nuclear Energy Research Atomic Energy Council An anode on a pretreated substrate for improving redox-stablility of solid oxide fuel cell and the fabrication method thereof
JP5746309B2 (ja) * 2012-12-17 2015-07-08 サムソン エレクトロ−メカニックス カンパニーリミテッド． 固体酸化物燃料電池の電極用ペースト、これを用いる固体酸化物燃料電池およびその製造方法
JP5961709B2 (ja) * 2013-01-30 2016-08-02 富士電機株式会社 正極触媒、及び機器
CN103149256A (zh) * 2013-02-27 2013-06-12 上海大学 由SrNiFeO3修饰玻碳电极的电化学传感器及其对H2O2的测定方法
US9809453B2 (en) 2013-03-15 2017-11-07 Lg Fuel Cell Systems, Inc. Catalysts for hydrocarbon reforming
JP5603515B1 (ja) * 2013-08-23 2014-10-08 日本碍子株式会社 空気極材料及び固体酸化物型燃料電池
GB2522522B (en) * 2014-11-27 2018-01-24 Ceres Ip Co Ltd Structure
CN104458859A (zh) * 2014-12-12 2015-03-25 上海大学 La0.88Sr0.12MnO3纳米纤维修饰的碳糊电极及其制备方法和应用
CN104779398A (zh) * 2015-04-27 2015-07-15 上海邦民新能源科技有限公司 固体氧化物燃料电池阳极材料及具有其的阳极
KR101902617B1 (ko) * 2015-05-15 2018-10-01 세종대학교산학협력단 삼중층 페로브스카이트 공기극 촉매를 구비하는 고체 산화물 전기화학소자
CN105449227B (zh) * 2016-01-02 2018-07-06 红河学院 一种层状钙钛矿燃料电池阴极材料及其制备方法
CN106835206B (zh) * 2017-01-03 2018-10-02 北京科技大学 一种铬酸镧基惰性阳极的制备方法及应用
JP6844440B2 (ja) * 2017-06-16 2021-03-17 日本製鉄株式会社 水素の製造方法
CN107293718B (zh) * 2017-06-26 2020-05-26 合肥国轩高科动力能源有限公司 R2-xMxEMnO6改性镍锰酸锂材料及制备、应用
CN107285390B (zh) * 2017-06-29 2018-11-09 宁波吉电鑫新材料科技有限公司 一种电场调控选择结晶合成双钙钛矿锂离子电池负极材料及其制备方法
CN107265502B (zh) * 2017-06-29 2018-10-23 宁波吉电鑫新材料科技有限公司 一种电场调控选择结晶合成双钙钛矿钾离子电池负极材料及其制备方法
CN107352587B (zh) * 2017-06-29 2018-10-23 宁波吉电鑫新材料科技有限公司 一种电场调控选择结晶合成双钙钛矿钠离子电池负极材料及其制备方法
WO2019169244A1 (en) * 2018-03-02 2019-09-06 Northwestern University Cobalt-substituted perovskite compounds for solid oxide electrochemical cells
CN109921043B (zh) * 2019-02-26 2021-10-08 五邑大学 一种b掺杂钙钛矿类氧化物的电催化剂及其制备方法
CN109809486A (zh) * 2019-03-26 2019-05-28 暨南大学 一种向KNbO3钙钛矿中掺杂Ba和Ni离子的方法
CN109913900A (zh) * 2019-04-18 2019-06-21 北京理工大学 一种具有高催化活性的用于co2电解的soec阴极材料
JP7360276B2 (ja) 2019-08-30 2023-10-12 太陽誘電株式会社 固体酸化物型燃料電池およびその製造方法
JP7377051B2 (ja) 2019-10-07 2023-11-09 太陽誘電株式会社 固体酸化物型燃料電池およびその製造方法
CN110668804A (zh) * 2019-10-17 2020-01-10 江苏科技大学 一种固体氧化物燃料电池用陶瓷连接体材料及其制备方法
JP7484048B2 (ja) 2020-03-10 2024-05-16 太陽誘電株式会社 固体酸化物型燃料電池およびその製造方法
GB202016089D0 (en) * 2020-10-09 2020-11-25 Ceres Ip Co Ltd Structure
CN113299960B (zh) * 2021-05-17 2022-12-20 深圳大学 一种乙烯与电能共生型固体氧化物燃料电池及其制备方法
CN113800908A (zh) * 2021-08-26 2021-12-17 桂林理工大学 中介电常数双钙钛矿微波介质陶瓷材料及其制备方法
KR102454622B1 (ko) * 2022-01-20 2022-10-17 주식회사 에코나인 이중 페로브스카이트 또는 삼중 페로브스카이트 구조를 갖는 산화방지제
CN115939472A (zh) * 2022-11-25 2023-04-07 中国科学院宁波材料技术与工程研究所 一种抗积碳固体氧化物燃料电池及其制备方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01200560A (ja) * 1988-02-05 1989-08-11 Mitsubishi Heavy Ind Ltd 電極材料
JPH02236959A (ja) * 1989-03-09 1990-09-19 Mitsubishi Heavy Ind Ltd 電極材料
CN1212788A (zh) * 1996-02-29 1999-03-31 西屋电气公司 用于高温固体氧化物电解质电化学电池的低成本的稳定的空气电极材料

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2810104B2 (ja) * 1989-04-28 1998-10-15 日本碍子株式会社 セラミックス電極及びこれを有する燃料電池
JPH0317959A (ja) * 1989-06-14 1991-01-25 Agency Of Ind Science & Technol 固体電解質型燃料電池用空気極材料および固体電解質型燃料電池
JPH0317958A (ja) * 1989-06-14 1991-01-25 Agency Of Ind Science & Technol 固体電解質型燃料電池用空気極材料および固体電解質型燃料電池
EP0411547A1 (en) 1989-07-31 1991-02-06 Tonen Corporation Lanthanum chromite-based complex oxides and uses thereof
JP2946053B2 (ja) * 1990-06-16 1999-09-06 工業技術院長 円筒型固体電解質燃料電池並びに平板型固体電解質燃料電池
JPH0644991A (ja) * 1992-07-27 1994-02-18 Ngk Insulators Ltd 固体電解質型燃料電池用インターコネクターの製造方法
JPH0927330A (ja) * 1995-07-11 1997-01-28 Tokyo Gas Co Ltd 固体電解質燃料電池の燃料極
JP2001196069A (ja) * 1999-11-01 2001-07-19 Mitsubishi Heavy Ind Ltd 燃料電池
JP4379987B2 (ja) * 1999-11-30 2009-12-09 トヨタ自動車株式会社 燃料電池の制御装置
US6537465B2 (en) * 2000-12-29 2003-03-25 Praxair Technology, Inc. Low pressure steam purged chemical reactor including an oxygen transport membrane
GB0125276D0 (en) * 2001-10-20 2001-12-12 Strathclyde Improvements in fuel cells related devices

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01200560A (ja) * 1988-02-05 1989-08-11 Mitsubishi Heavy Ind Ltd 電極材料
JPH02236959A (ja) * 1989-03-09 1990-09-19 Mitsubishi Heavy Ind Ltd 電極材料
CN1212788A (zh) * 1996-02-29 1999-03-31 西屋电气公司 用于高温固体氧化物电解质电化学电池的低成本的稳定的空气电极材料

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
catalytic and electrochemical properties of doped lanthanumchromites as new anode materials forsolid oxide fuel cells VERNOUX PHILIPPE,J.AM.CERAM.SOC.,Vol.84 No.10 2001 *

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