CN103339245A - 包含上蓝剂和快速水溶性增白剂的洗涤剂组合物 - Google Patents
包含上蓝剂和快速水溶性增白剂的洗涤剂组合物 Download PDFInfo
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- CN103339245A CN103339245A CN2011800509891A CN201180050989A CN103339245A CN 103339245 A CN103339245 A CN 103339245A CN 2011800509891 A CN2011800509891 A CN 2011800509891A CN 201180050989 A CN201180050989 A CN 201180050989A CN 103339245 A CN103339245 A CN 103339245A
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- C09B31/068—Naphthols
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Abstract
本发明公开了一种固体衣物洗涤剂组合物，所述组合物包含：（a）去污表面活性剂；（b）上蓝剂；（c）C.I.荧光增白剂260；和（d）任选的一种或多种附加的衣物洗涤剂成分。
Description
技术领域
本发明涉及包含上蓝剂和快速水溶性增白剂的洗涤剂组合物。本发明的组合物提供优异的清洁性能，尤其是即使在染料存在的情况下由增白剂体现的增白有益性能。
背景技术
希望衣物洗涤剂制造商将调色染料和增白剂掺入到固体衣物洗涤剂组合物中，以例如在更广泛的织物类型范围内以及在多种不同光照条件下提供有益效果。
调色染料沉积在白色织物上，致使消费者产生洁白度增加的感觉，并且抵消织物的褪色和泛黄。
光学增白剂通常吸收不可见光如紫外且能量以光的形式放出。就洗涤剂产品的目的而言，光通常在可见光谱内发射，通常为蓝光或绿光。蓝色和/或绿色光谱范围内的额外发光使得用包含增白剂的洗涤剂洗涤的织物或纺织品在洗涤后人眼看上去显得更亮。市场上有许多包含各种增白剂分子的洗涤剂粉末。
增白剂的一个问题在于，它们趋于表现出低溶解度，并且在冷水中的溶解速率低。当前，消费者因节能和环境有益效果而对在冷水中洗涤感兴趣，但是不情愿因在冷水中洗涤而损害增白剂性能。改进增白剂粒度和/或具体增白剂如C.I.荧光增白剂260的晶形，可致使其溶解速率尤其是冷水中的溶解速率增加。例如，C.I.荧光增白剂260具有3至30微米范围内的重均粒度，其显示出比较大粒度的增白剂更大的溶解速率。此外，α晶形显示出比β晶形更大的溶解速率。
增白剂的另一个问题在于它们一般是针对专门织物的。一些增白剂对棉有效，但是对聚酯无效，反之亦然。需要提供在多种织物上具有良好增白剂性能的洗涤剂组合物，所述织物包括棉和聚酯织物类型。
然而，当将调色染料和增白剂掺入到固体衣物洗涤剂组合物中时，增白剂的性能因调色染料的存在而受到不利的影响。本发明人已发现，通过将特定增白剂与特定调色染料组合，调色染料与增白剂之间的该不利相互作用不仅被削弱，而且观测到提高增白剂性能的协同效应。
本发明人已发现，如本发明定义的特定调色剂（本文称为上蓝剂）与如本发明定义的特定增白剂的组合，致使具有不同织物类型的一系列织物的洁白度提高，并且功效大于独立使用任一方法：特定的上蓝剂使与特定增白剂的协同效应最大化。通过利用特定上蓝剂与特定增白剂的组合，可延长纺织品基底如衣服制品、餐布等的寿命。
发明内容
本发明提供了固体衣物洗涤剂组合物，所述组合物包含：
(a)去污表面活性剂；
(b)上蓝剂，其中所述上蓝剂具有以下结构：
其中：
R1和R2独立地选自：H；烷基；烷氧基；亚烷基氧基；烷基封端的亚烷基氧基；脲；和酰氨基；
R3为取代的芳基；
X为包含磺酰胺部分和任选的烷基和/或芳基部分的取代基，并且其中所述取代基包含至少一个包含至少四个亚烷基氧基部分的亚烷基氧基链；
(c)具有下列结构的C.I.荧光增白剂260：
其中所述C.I.荧光增白剂260或者：
(i)主要为β-晶体形式，并具有3至30微米的重均原生粒度；或者
(ii)主要为α-晶体形式；以及
(d)任选的一种或多种附加的衣物洗涤剂成分。
具体实施方式
固体衣物洗涤剂组合物：通常，所述组合物为全配方衣物洗涤剂组合物，而不是其一部分，如仅形成衣物洗涤剂组合物一部分的喷雾干燥或附聚颗粒。然而，在本发明方法期间，还可使附加漂洗添加剂组合物（例如织物调理剂或增强剂）或主要的洗涤添加剂组合物（例如漂白添加剂）与所述衣物洗涤剂组合物组合使用，这是在本发明范畴内的。然而，本发明方法期间优选无漂白添加剂组合物与所述衣物洗涤剂组合物组合使用。
通常，所述组合物包含多个化学上不同的颗粒，如喷雾干燥的基础洗涤剂颗粒和/或附聚的基础洗涤剂颗粒和/或压制的基础洗涤剂颗粒与一个或多个、通常两个或更多个、或三个或更多个、或四个或更多个、或五个或更多个、或六个或更多个、或甚至十个或更多个颗粒的组合，所述颗粒选自：表面活性剂颗粒，包括表面活性剂附聚物、表面活性剂挤出物、表面活性剂针粒、表面活性剂条粒、表面活性剂薄片；聚合物颗粒如纤维素聚合物颗粒、聚酯颗粒、聚胺颗粒、对苯二甲酸聚合物颗粒、聚乙二醇聚合物颗粒；助洗剂颗粒，如碳酸钠和硅酸钠共助洗剂颗粒、磷酸盐颗粒、沸石颗粒、硅酸盐颗粒、碳酸盐颗粒；填料颗粒，例如硫酸盐颗粒；染料转移抑制剂颗粒；染料固定剂颗粒；漂白剂颗粒，如过碳酸盐颗粒，特别是包被的过碳酸盐颗粒，如碳酸盐、硫酸盐、硅酸盐、硼硅酸盐、过碳酸盐、或它们的任何组合包被的过碳酸盐；过硼酸盐颗粒；漂白催化剂颗粒，如过渡金属漂白催化剂颗粒、或基于过氧亚胺正离子的漂白催化剂颗粒；预生的过酸颗粒，特别是包被的预生的过酸颗粒；和漂白活化剂的共漂白剂颗粒；过氧化氢源和任选的漂白催化剂；漂白活化剂颗粒如氧苯磺酸钠漂白活化剂颗粒和四乙酰基乙二胺漂白活化剂颗粒；螯合剂颗粒例如螯合剂附聚物；调色染料颗粒；增白剂颗粒；酶颗粒如蛋白酶粒、脂肪酶粒、纤维素酶粒、淀粉酶粒、甘露聚糖酶粒、果胶酸裂合酶粒、木葡聚糖酶粒、漂白酶粒、角质酶粒和其中任何酶的共同造粒；粘土颗粒，例如蒙脱石颗粒或粘土和硅酮的颗粒；絮凝剂颗粒如聚环氧乙烷颗粒；蜡颗粒如蜡质附聚物；香料颗粒如香料微胶囊，特别是基于三聚氰胺甲醛的香料微胶囊，淀粉包封的香料谐香剂颗粒，和前香料颗粒如席夫碱反应产物颗粒；美化颗粒如彩色条状或针状或薄片状颗粒，和皂环包括彩色皂环；以及它们的任何组合。
洗涤剂成分：所述组合物通常包含洗涤剂成分。适合的洗涤剂成分包括：上蓝剂；去污表面活性剂，包括阴离子去污表面活性剂、非离子去污表面活性剂、阳离子去污表面活性剂、两性离子去污表面活性剂、两性去污表面活性剂、以及它们的任何组合。聚合物，包括羧酸盐聚合物、聚乙二醇聚合物、去垢聚酯聚合物如对苯二甲酸乙二醇酯聚合物、聚胺、纤维素聚合物、染料转移抑制剂聚合物、染料封闭聚合物如由咪唑和环氧氯丙烷缩合产生的缩合低聚物，任选的比率是1:4:1、1,6-己二胺衍生物聚合物、以及它们的任何组合；助洗剂，包括沸石、磷酸盐、柠檬酸盐、以及它们的任何组合；缓冲剂和碱度来源，包括碳酸盐和/或硅酸盐；填料，包括硫酸盐和生物填料物质；漂白剂，包括漂白活化剂、可用氧来源、预生的过酸、漂白催化剂、还原漂白剂、以及它们的任何组合；螯合剂；光漂白剂；调色剂；增白剂；酶，包括蛋白酶、淀粉酶、纤维素酶、脂肪酶、木葡聚糖酶、果胶酸裂合酶、甘露聚糖酶、漂白酶、角质酶、以及它们的任何组合；织物柔软剂，包括粘土、有机硅、季铵盐织物柔软剂、絮凝剂如聚环氧乙烷；香料，包括淀粉包封的香料谐香剂、香料微胶囊、载有香料的沸石、酮类香料原料和多胺的席夫碱反应产物、盛开的香料、以及它们的任何组合；美化剂，包括皂环、层状美化颗粒、明胶小珠、碳酸盐和/或硫酸盐斑点、有色粘土、以及它们的任何组合；以及它们的任何组合。
上蓝剂：所述组合物包含具有下列结构的上蓝剂：
其中：R1和R2独立地选自：H；烷基；烷氧基；亚烷基氧基；烷基封端的亚烷基氧基；脲；和酰氨基；R3为取代的芳基；X为包含磺酰胺部分和任选的烷基和/或芳基部分的取代基，并且其中所述取代基包含至少一个包含至少四个亚烷基氧基部分的亚烷基氧基链。
适宜的上蓝剂具有以下结构：
C.I.荧光增白剂260.所述组合物包含具有下列结构的C.I.荧光增白剂260：
其中所述C.I.荧光增白剂260或者：（i）主要为α-晶体形式；或者（ii）主要为β-晶体形式，并且具有3至30微米的重均原生粒度。如本文所用，主要通常是指“包含大于50重量%至100重量%，或大于60重量%，或大于70重量%，或大于80重量%，或大于90重量%至100重量%，或甚至占100重量%”。
去污表面活性剂：所述组合物包含去污表面活性剂。适宜的去污表面活性剂包括阴离子去污表面活性剂、非离子去污表面活性剂、阳离子去污表面活性剂、两性离子清洁表面活性剂、两性去污表面活性剂、以及它们的任何组合。
阴离子去污表面活性剂：适宜的阴离子去污表面活性剂包括硫酸盐和磺酸盐去污表面活性剂。
适宜的磺酸盐去污表面活性剂包括烷基苯磺酸盐，如C10-13烷基苯磺酸盐。适宜的烷基苯磺酸盐（LAS）是可获取的，或甚至通过磺化可商购获得的直链烷基苯得到（LAB）；适宜的LAB包括低2-苯基LAB，如由Sasol以商品名
或由Petresa以商品名
提供的那些；其他适宜的LAB包括高2-苯基LAB，如由Sasol以商品名
提供的那些。另一个适宜的阴离子去污表面活性剂是烷基苯磺酸盐，可以通过DETAL催化方法获得，尽管其他合成路线如HF也可以是适宜的。
适宜的硫酸盐去污表面活性剂包括烷基硫酸盐如C8-18烷基硫酸盐，或主要地为C12烷基硫酸盐。烷基硫酸盐可来源于天然来源，如椰油和/或牛油。作为另外一种选择，烷基硫酸盐可来源于合成来源，如C12-15烷基硫酸盐。
另一种适宜的硫酸盐去污表面活性剂是烷基烷氧基化硫酸盐，如烷基乙氧基化硫酸盐，或C8-18烷基烷氧基化硫酸盐，或C8-18烷基乙氧基化硫酸盐。烷基烷氧基化硫酸盐可具有0.5至20，或0.5至10的平均烷氧基化度。烷基烷氧基化硫酸盐可为C8-18烷基乙氧基化硫酸盐，其通常具有0.5至10，或0.5至7，或0.5至5，或0.5至3的平均乙氧基化度。
所述烷基硫酸盐、烷基烷氧基化硫酸盐和烷基苯磺酸盐可为直链或支化的、取代的或未取代的。
阴离子去污表面活性剂可为中链支化的阴离子去污表面活性剂，如中链支化的烷基硫酸盐和/或中链支化的烷基苯磺酸盐。中链支化通常为C1-4烷基，如甲基和/或乙基。
另一种适宜的阴离子去污表面活性剂为烷基乙氧基羧酸盐。
所述阴离子去污表面活性剂通常以它们的盐形式存在，通常与适宜的阳离子复合。适宜的抗衡离子包括Na+和K+、适宜的铵如C1-C6链烷醇铵，如单乙醇胺（MEA）、三乙醇胺（TEA）、二乙醇胺（DEA）、以及它们的任何混合物。
非离子去污表面活性剂：适宜的非离子去污表面活性剂选自：C8-C18烷基乙氧基化物，如得自Shell的
非离子表面活性剂；C6-C12烷基酚烷氧基化物，其中任选地所述烷氧基化物单元为乙烯氧基单元、丙烯氧基单元或它们的混合物；C12-C18醇和C6-C12烷基酚与环氧乙烷/环氧丙烷嵌段聚合物的缩合物，如购自BASF的C14-C22中链支化的醇；C14-C22中链支化的烷基烷氧基化物，通常其具有1至30的平均烷氧基化度；烷基多糖，如烷基多糖苷；多羟基脂肪酸酰胺；醚封端的聚(烷氧基化)醇表面活性剂；以及它们的混合物。
适宜的非离子去污表面活性剂为烷基多葡糖苷和/或烷基烷氧基化醇。
适宜的非离子去污表面活性剂包括烷基烷氧基化醇，如C8-18烷基烷氧基化醇，或C8-18烷基乙氧基化醇。烷基烷氧基化醇可具有0.5至50，或1至30，或1至20，或1至10的平均烷氧基化度。烷基烷氧基化醇可为C8-18烷基乙氧基化醇，其通常具有1至10，或1至7，或1至5，或3至7的平均乙氧基化度。所述烷基烷氧基化醇可以是直链或支化的，并且是取代的或未取代的。
适宜的非离子去污表面活性剂包括基于仲醇的去污表面活性剂，其具有下式：
其中R1=直链或支化的、取代或未取代的、饱和或不饱和的C2-8烷基；
其中R2=直链或支化的、取代或未取代的、饱和或不饱和的C2-8烷基，
其中R1+R2部分中存在的碳原子总数在7至13范围内；
其中EO/PO为烷氧基部分，选自乙氧基、丙氧基、或它们的混合物，所述EO/PO烷氧基部分任选为无规或嵌段构型；
其中n为平均烷氧基化度，并且在4至10范围内。
其它适宜的非离子去污表面活性剂包括EO/PO嵌段共聚物表面活性剂，如购自BASF的系列表面活性剂，和糖衍生的表面活性剂如烷基N-甲基葡萄糖酰胺。
阳离子去污表面活性剂：适宜的阳离子去污表面活性剂包括烷基吡啶
化合物、烷基季铵化合物、烷基季铵
化合物、烷基三元锍化合物、以及它们的混合物。
适宜的阳离子去污表面活性剂为具有以下通式的季铵化合物：
(R)(R1)(R2)(R3)N+X-
其中，R为直链或支化的、取代或未取代的C6-18烷基或烯基部分，R1和R2独立地选自甲基或乙基部分，R3是羟基、羟甲基或羟乙基部分，X是提供电中性的阴离子，适宜的阴离子包括：卤化物，如氯化物；硫酸根；和磺酸根。适宜的阳离子去污表面活性剂为单C6-18烷基单羟乙基二甲基氯化铵。适宜的阳离子去污表面活性剂为单C8-10烷基单羟乙基二甲基氯化铵、单C10-12烷基单羟乙基二甲基氯化铵和单C10烷基单羟乙基二甲基氯化铵。
两性离子和/或两性去污表面活性剂：适宜的两性离子和/或两性去污表面活性剂包括氧化胺如十二烷基二甲基氧化胺、链烷醇胺磺酸甜菜碱、椰油酰胺基丙基甜菜碱、基于HN+-R-CO2 -的表面活性剂，其中R可能是任何桥接基团，如烷基、烷基、芳基或氨基酸。
聚合物：适宜的聚合物包括羧酸盐聚合物、聚乙二醇聚合物、聚酯去垢性聚合物如对苯二甲酸聚合物、胺聚合物、纤维素聚合物、染料转移抑制剂聚合物、染料固定聚合物如通过咪唑和环氧氯丙烷任选的以1:4:1比率缩合生成的缩合低聚物、1,6-己二胺衍生物聚合物、以及它们的任何组合。
羧酸盐聚合物：适宜的羧酸盐聚合物包括马来酸盐/丙烯酸盐的无规共聚物或聚丙烯酸盐均聚物。所述羧酸酯聚合物可为聚丙烯酸酯均聚物，其分子量为4,000Da至9,000Da，或6,000Da至9,000Da。其它适宜的羧酸酯聚合物为马来酸和丙烯酸的共聚物，并且其分子量可以在4,000Da至90,000Da的范围内。
其它适宜的羧酸盐聚合物为共聚物，包含：（i）50至小于98重量%的结构单元，所述结构单元衍生自一种或多种包含羧基的单体；（ii）1至小于49重量%的结构单元，所述结构单元衍生自一种或多种包含磺酸根部分的单体；和（iii）1至49重量%的结构单元，所述结构单元衍生自一种或多种类型的单体，所述单体选自由式（I）和（II）表示的含醚键的单体：
式（I）
其中在式（I）中，R0表示氢原子或CH3基团，R表示CH2基团、CH2CH2基团或单键，X表示数字0-5，当R为单键时X表示数字1-5，并且R1为氢原子或C1-C20有机基团；
式（II）
在式（II）中，R0表示氢原子或CH3基团，R表示CH2基团、CH2CH2基团或单键，X表示数字0-5，并且R1为氢原子或C1-C20有机基团。
聚乙二醇聚合物：适宜的聚乙二醇聚合物包括无规接枝共聚物，其包含：（i）亲水性主链，其包含聚乙二醇；以及（ii）一个或多个疏水性侧链，其选自：C4-C25烷基、聚丙烯、聚丁烯、饱和的C1-C6一元羧酸的乙烯基酯、丙烯酸或甲基丙烯酸的C1-6烷基酯、以及它们的混合物；适宜的聚乙二醇聚合物具有聚乙二醇主链和无规接枝聚醋酸乙烯酯侧链。聚乙二醇主链的平均分子量可在2,000Da至20,000Da，或4,000Da至8,000Da的范围内。聚乙二醇主链与聚醋酸乙烯酯侧链的分子量比可在1:1至1:5，或1:1.2至1:2的范围内。每个环氧乙烷单元的接枝位点平均数可小于1，或小于0.8，每个环氧乙烷单元的接枝位点平均数可在0.5-0.9的范围内，或每个环氧乙烷单元的接枝位点平均数可在0.1-0.5，或0.2-0.4的范围内。适宜的聚乙二醇聚合物为Sokalan HP22。
聚酯去垢性聚合物：适宜的聚酯去垢性聚合物具有如下列结构（I）、（II）、或（III）中的一个定义的结构：
(I)-[(OCHR1-CHR2)a-O-OC-Ar-CO-]d
(II)-[(OCHR3-CHR4)b-O-OC-sAr-CO-]e
(III)-[(OCHR5-CHR6)c-OR7]f
其中：
a、b和c为1至200；
d、e和f为1至50；
Ar为1,4-取代的亚苯基；
sAr为在5位被SO3Me取代的1,3-取代的亚苯基；
Me为H、Na、Li、K、Mg/2、Ca/2、Al/3、铵、单烷基铵、二烷基铵、三烷基铵或四烷基铵，其中所述烷基为C1-C18烷基或C2-C10羟烷基、或它们的任何混合物；
R1、R2、R3、R4、R5和R6独立地选自H或C1-C18正烷基或异烷基；和
R7为直链或支化的C1-C18烷基，或直链或支化的C2-C30烯基，或具有5至9个碳原子的环烷基，或C8-C30芳基，或C6-C30芳烷基。适宜的聚酯去垢性聚合物为具有上式(I)或(II)结构的对苯二甲酸酯聚合物。
适宜的聚酯去垢性聚合物包括Repel-o-tex系列聚合物如Repel-o-texSF2（Rhodia），和/或Texcare系列聚合物如Texcare SRA300（Clariant）。
胺聚合物：适宜的胺聚合物包括聚乙烯亚胺聚合物，如烷氧基化聚亚烷基亚胺，任选地包括聚乙烯和/或聚丙烯氧化物嵌段。
纤维素聚合物：所述组合物可包含纤维素聚合物，如选自烷基纤维素、烷氧基烷基纤维素、羧甲基纤维素、烷基羧甲基、以及它们的任何组合。适宜的纤维素聚合物选自羧甲基纤维素、甲基纤维素、甲基羟乙基纤维素、甲基羧甲基纤维素、以及它们的混合物。羧甲基纤维素可具有0.5至0.9的羧甲基取代度和100,000Da至300,000Da的分子量。另一种适宜的纤维素聚合物为疏水改性的羧甲基纤维素，如Finnfix SH-1（CP Kelco）。
其它适宜的纤维素聚合物可具有0.01至0.99的取代度（DS）和一定的嵌段度（DB），使得DS+DB为至少1.00或者DB+2DS-DS2为至少1.20。取代的纤维素聚合物可具有至少0.55的取代度（DS）。取代的纤维素聚合物可具有至少0.35的嵌段度（DB）。取代的纤维素聚合物可具有1.05至2.00的DS+DB。适宜的取代的纤维素聚合物为羧甲基纤维素。
另一种适宜的纤维素聚合物为阳离子改性的羟乙基纤维素。
染料转移抑制剂聚合物：适宜的染料转移抑制剂（DTI）聚合物包括聚乙烯吡咯烷酮（PVP）、乙烯基吡咯烷酮和咪唑啉共聚物（PVPVI）、聚乙烯-N-氧化物（PVNO）、以及它们的任何混合物。
1,6-己二胺衍生物聚合物：适宜的聚合物包括1,6-己二胺衍生物聚合物，所述1,6-己二胺衍生物聚合物通常具有下式：
R2（CH3）N+（CH2）6N+（CH3）R2.2X-
其中X-为适宜的抗衡离子例如氯离子，并且R为具有20至30平均乙氧基化度的聚(乙二醇)链。所述聚(乙二醇)链优选可独立地被硫酸根和/或磺酸根基团封端，通常具有通过减少X-抗衡离子数目，或（在每分子平均硫酸化度大于二的情况下）引入Y+抗衡离子例如钠阳离子来平衡的电荷。
助洗剂：适宜的助洗剂包括沸石、磷酸盐、柠檬酸盐、以及它们的任何组合。
沸石助剂：所述组合物可基本上不含沸石助洗剂。基本上不含沸石助洗剂通常是指包含0重量%至10重量%的沸石助洗剂，或至8重量%，或至6重量%，或至4重量%，或至3重量%，或至2重量%，或甚至至1重量%的沸石助洗剂。基本上不含沸石助洗剂优选是指“无有意添加的”沸石助洗剂。典型的沸石助洗剂包括沸石A、沸石P、沸石MAP、沸石X和沸石Y。
磷酸盐助洗剂：所述组合物可基本上不含磷酸盐助洗剂。基本上不含磷酸盐助洗剂通常是指包含0重量%至10重量%的磷酸盐助洗剂，或至8重量%，或至6重量%，或至4重量%，或至3重量%，或至2重量%，或甚至至1重量%的磷酸盐助洗剂。基本上不含沸石助洗剂优选是指“无有意添加的”磷酸盐助洗剂。典型的磷酸盐助洗剂为三聚磷酸钠（STPP）。
柠檬酸盐：适宜的柠檬酸盐为柠檬酸钠。然而，也可将柠檬酸掺入到所述组合物中，使其能在洗涤液体中形成柠檬酸盐。
缓冲剂和碱度来源：适宜的缓冲剂和碱度来源包括碳酸盐和/或硅酸盐和/或复盐如碳酸钠矾。
碳酸盐：适宜的碳酸盐是碳酸钠和/或碳酸氢钠。所述组合物可包含碳酸氢盐。所述组合物适于包含低含量的碳酸盐，例如所述组合物适于包含0重量%至10重量%的碳酸盐，或至8重量%，或至6重量%，或至4重量%，或至3重量%，或至2重量%，或甚至至1重量%的碳酸盐。所述组合物可以甚至基本上不含碳酸盐；基本上不含意为“无有意添加的”。
碳酸盐可具有100微米至500微米的重均平均粒度。作为另外一种选择，所述碳酸盐可具有10微米至25微米的重均平均粒度。
硅酸盐：所述组合物可包含0重量%至20重量%的硅酸盐，或至15重量%、或至10重量%、或至5重量%、或至4重量%、或甚至至2重量%的硅酸盐，并且可包含高于0重量%、或0.5重量%、或甚至1重量%的硅酸盐。所述硅酸盐可以是结晶的或无定形的。适宜的结晶硅酸盐包括结晶层状硅酸盐如SKS-6。其它适宜的硅酸盐包括1.6R硅酸盐和/或2.0R硅酸盐。适宜的硅酸盐为硅酸钠。另一种适宜的硅酸盐为偏硅酸钠。
填料：所述组合物可包含0重量%至70%的填料。适宜的填料包括硫酸盐和/或生物填充材料。
硫酸盐：适宜的硫酸盐是硫酸钠。硫酸盐可具有100微米至500微米的重均平均粒度，作为另外一种选择，硫酸盐可具有10微米至45微米的重均平均粒度。
生物填充材料：适宜的生物填充材料为碱和/或漂白剂处理过的农业废料。
漂白剂：所述组合物可包含漂白剂。作为另外一种选择，所述组合物可以基本上不含漂白剂；基本上不含是指“无有意添加的”。适宜的漂白剂包括漂白活性化剂、可用氧来源、预成型的过酸、漂白催化剂、还原漂白剂、以及它们的任何组合。如果存在，则漂白剂或其任何组分例如预生过酸可用例如脲或环糊精涂覆，如包封或包合。
漂白活化剂：适宜的漂白活化剂包含：四乙酰基乙二胺（TAED）；苯酚磺酸盐如壬酰基苯酚磺酸盐（NOBS）、丙烯酰胺壬酰基苯酚磺酸盐(NACA-OBS)、3,5,5-三甲基己酰苯酚磺酸盐(Iso-NOBS)、十二烷基苯酚磺酸盐(LOBS)、以及它们的任何混合物；己内酰胺；五乙酸酯葡萄糖（PAG）；季铵腈；酰亚胺漂白活化剂，如N-壬酰基-N-甲基乙酰胺；以及它们的任何混合物。
可用氧来源：适宜的可用氧来源（AvOx）是指过氧化氢源，如过碳酸盐和/或过硼酸盐，如过碳酸钠。过氧源可被涂层成分如碳酸盐、硫酸盐、硅酸盐、硼硅酸盐、或它们的任何混合物（包括它们的混合盐）至少部分涂覆，或甚至完全涂覆。适宜的过碳酸盐可由流化床方法或由结晶方法制得。适宜的过硼酸盐包括过硼酸钠一水合物（PB1）、过硼酸钠四水合物（PB4）和被称为泡沫过硼酸钠的无水过硼酸钠。其它适宜的AvOx源包括过硫酸盐如过硫酸氢钾。另一种适宜的AvOx源为过氧化氢。
预生的过酸：适宜的预生的过酸是N,N-邻苯二甲氨基己过氧酸（PAP）。
漂白催化剂：适宜的漂白催化剂包括基于过氧亚胺正离子的漂白催化剂、过渡金属漂白催化剂和漂白酶。
基于过氧亚胺正离子的漂白催化剂：适宜的基于过氧亚胺正离子的漂白催化剂具有下式：
其中：R1选自：H、包含3至24个碳的支链烷基、以及包含1至24个碳的直链烷基；R1可为包含6至18个碳的支化的烷基、或包含5至18个碳的直链烷基；R1可选自：2-丙基庚基、2-丁基辛基、2-戊基壬基、2-己基癸基、正己基、正辛基、正癸基、正十二烷基、正十四烷基、正十六烷基、正十八烷基、异壬基、异癸基、异十三烷基和异十五烷基；R2独立地选自：H、包含3至12个碳的支链烷基、以及包含1至12个碳的直链烷基；任选地，R2独立地选自H和甲基；并且n为0至1的整数。
过渡金属漂白催化剂：所述组合物可包含过渡金属漂白催化剂，其通常包含铜、铁、钛、钌、钨、钼和/或锰阳离子。适宜的过渡金属漂白催化剂为基于锰的过渡金属漂白催化剂。
还原漂白剂：所述组合物可包含还原漂白剂。然而，所述组合物可以基本上不含还原漂白剂；基本上不含是指“无有意添加的”。适宜的还原漂白剂包括亚硫酸钠和/或二氧化硫脲(TDO)。
共漂白剂颗粒：所述组合物可包含共漂白剂颗粒。通常，所述共漂白剂颗粒包含漂白活化剂和过氧化物源。在共漂白剂颗粒中，相对于过氧化氢源存在大量的漂白活化剂，是高度适宜的。存在于共漂白剂颗粒状的漂白活化剂与过氧化氢源的重量比可为至少0.3:1，或至少0.6:1，或至少0.7:1，或至少0.8:1，或至少0.9:1，或至少1.0:1.0，或甚至至少1.2:1或更高。
所述共漂白剂颗粒包含：（i）漂白活化剂，如TAED；和（ii）过氧化氢源，如过碳酸钠。所述漂白活化剂可至少部分，或甚至完全包封过氧化氢源。
共漂白剂颗粒可包含粘合剂。适宜的粘合剂为羧酸酯聚合物如聚丙烯酸酯聚合物，和/或表面活性剂，包括非离子去污表面活性剂和/或阴离子去污表面活性剂，如直链C11-C13烷基苯磺酸盐。
所述共漂白剂颗粒可包含漂白催化剂，如基于过氧亚胺正离子的漂白催化剂。
螯合剂：适宜的螯合剂选自：二乙烯三胺五乙酸酯、二乙烯三胺五（甲基膦酸）、乙烯二胺-N’N’-二琥珀酸、乙烯二胺四乙酸酯、乙烯二胺四（亚甲基膦酸）、羟乙烷二（亚甲基膦酸）、以及它们的任何组合。适宜的螯合剂为乙二胺-N’N’-二琥珀酸（EDDS）和/或羟基乙烷二磷酸（HEDP）。所述衣物洗涤剂组合物可包含乙二胺-N’N’-二琥珀酸或其盐。乙二胺-N’N’-二琥珀酸可为S,S对映体形式。所述组合物可包含4,5-二羟基间苯二磺酸二钠盐。适宜的螯合剂还可为钙晶体生长抑制剂。
碳酸钙晶体生长抑制剂：所述组合物可包含碳酸钙晶体生长抑制剂，如所述碳酸钙晶体生长抑制剂选自：1-羟乙基二磷酸（HEDP）及其盐；N,N-二羧甲基-2-氨基戊烷-1,5-二酸及其盐；2-磷酸丁烷-1,2,4-三羧酸及其盐；以及它们的任何组合。
光漂白剂：适宜的光漂白剂是磺化酞菁锌和/或磺化酞菁铝。
调色剂：通常配制调色剂（本文还定义为调色染料）以从洗涤液体中沉积到织物上以改善织物白色感，例如在衣服上产生200°至320°的相对色彩角。所述调色剂通常为蓝色或紫色。调色染料具有550nm至650nm，或570nm至630nm的峰值吸收波长是合适的。所述调色剂可为染料的组合，其共同对人眼具有如同单一染料的视觉效应，所述单一染料在聚酯上具有550nm至650nm，或570nm至630nm的峰值吸收波长。这可通过例如将红色和竹绿色染料混合以产生蓝色或紫色色调来提供。
染料通常为有色有机分子，其可溶于包含表面活性剂的含水介质中。染料可选自碱性染料、酸性染料、疏水性染料、直接染料和聚合物染料、以及染料缀合物类别。适宜的聚合物调色染料是可商购获得的，例如得自Milliken（Spartanburg，South Carolina，USA）。
适宜的染料例如紫DD、直接紫7、直接紫9、直接紫11、直接紫26、直接紫31、直接紫35、直接紫40、直接紫41、直接紫51、直接紫66、直接紫99、酸性紫50、酸性蓝9、酸性紫17、酸性黑1、酸性红17、酸性蓝29、溶剂紫13、分散紫27、分散紫26、分散紫28、分散紫63和分散紫77、碱性蓝16、碱性蓝65、碱性蓝66、碱性蓝67、碱性蓝71、碱性蓝159、碱性紫19、碱性紫35、碱性紫38、碱性紫48；碱性蓝3、碱性蓝75、碱性蓝95、碱性蓝122、碱性蓝124、碱性蓝141、噻唑染料、活性蓝19、活性蓝163、活性蓝182、活性蓝96、
Violet CT（Milliken，Spartanburg，USA）和Azo-CM-Cellulose（Megazyme，Bray，Republic of Ireland）。其它适宜的调色剂为调色染料-光漂白剂缀合物，如磺化酞菁锌与直接紫99的缀合物。尤其适宜的调色剂为酸性红52和酸性蓝80的组合，或直接紫9和溶剂紫13的组合。
增白剂：适宜的增白剂为二苯乙烯，如增白剂49。所述增白剂可为微粉化颗粒形式，具有3微米至30微米，或3微米至20微米，或3微米至10微米范围内的重均粒度。所述增白剂可为α或β晶形。
酶：适宜的酶包括蛋白酶、淀粉酶、纤维素酶、脂肪酶、木葡聚糖酶、果胶酸裂合酶、甘露聚糖酶、漂白酶、角质酶、以及它们的混合物。
就酶而言，括弧中示出的登录号和ID是指数据库Genbank、EMBL和/或Swiss-Prot中的编目流水号。就任何突变而言，将标准的1-字母氨基酸编码与表示缺失的*一起使用。以DSM为前缀的登录号是指保存于Deutsche Sammlung von Mikroorganismen und Zellkulturen GmbH（Mascheroder Weg1b，38124Brunswick（DSMZ））处的微生物体。
蛋白酶：所述组合物可包含蛋白酶。适宜的蛋白酶包括金属蛋白酶和/或丝氨酸蛋白酶，包括中性或碱性微生物丝氨酸蛋白酶，如枯草杆菌蛋白酶（EC3.4.21.62）。适用的蛋白酶包括动物、植物或微生物起源的那些蛋白酶。在一个方面，此类适宜的蛋白酶可源自微生物。适宜的蛋白酶包括化学上或基因上改性的上述适宜蛋白酶的突变体。在一个方面，适宜的蛋白酶可为丝氨酸蛋白酶，如碱性微生物蛋白酶和/或胰蛋白酶型蛋白酶。适宜中性或碱性蛋白酶的例子包括：
(a)枯草杆菌蛋白酶（EC3.4.21.62），包括来源于芽孢杆菌属的那些，如迟缓芽孢杆菌、嗜碱芽孢杆菌（P27963，ELYA_BACAO）、枯草芽孢杆菌、解淀粉芽孢杆菌（P00782，SUBT_BACAM）、短小芽孢杆菌（P07518）和吉氏芽孢杆菌（DSM14391）。
(b)胰蛋白酶型或胰凝乳蛋白酶型蛋白酶，如胰蛋白酶（例如源自猪或牛的胰蛋白酶），包括来源于纤维单胞菌属（A2RQE2）的镰孢属蛋白酶和胰凝乳蛋白酶。
(c)金属蛋白酶，包括来源于解淀粉芽孢杆菌（P06832，NPRE_BACAM）的那些。
适宜的蛋白酶包括来源于吉氏芽孢杆菌或迟缓芽孢杆菌如枯草杆菌蛋白酶309（P29600）和/或DSM5483（P29599）的那些。
适宜的可商购获得的蛋白酶包括：由Novozymes A/S（Denmark）以商品名 
和销售的那些；由Genencor International以商品名
Purafect
和
销售的那些；由Solvay Enzymes以商品名
和
销售的那些；均购自Henkel/Kemira的那些，即BLAP（P29599具有下列突变S99D+S101R+S103A+V104I+G159S）、和它们的变体，包括BLAP R（BLAP加上S3T+V4I+V199M+V205I+L217D）、BLAP X（BLAP加上S3T+V4I+V205I）和BLAP F49（BLAP加上S3T+V4I+A194P+V199M+V205I+L217D）；和得自Kao的KAP（具有突变A230V+S256G+S259N的嗜碱芽孢杆菌枯草杆菌蛋白酶）。
淀粉酶：适宜的淀粉酶为α-淀粉酶，包括源自细菌或真菌的那些。包括化学或基因修饰的突变体（变体）。适宜的碱性α-淀粉酶来源于芽孢杆菌属菌株，如地衣芽孢杆菌、解淀粉芽孢杆菌、嗜热脂肪芽胞杆菌、枯草芽孢杆菌、或其它芽孢杆菌属，如芽孢杆菌属NCIB12289、NCIB12512、NCIB12513、sp707、DSM9375、DSM12368、DSMZ no.12649、KSMAP1378、KSM K36或KSM K38。适宜的淀粉酶包括：
(a)α-淀粉酶，其来源于地衣芽孢杆菌（P06278、AMY_BACLI）及其变体，特别是在下列位点中的一个或多个具有取代的变体：15、23、105、106、124、128、133、154、156、181、188、190、197、202、208、209、243、264、304、305、391、408、和444。
(b)AA560淀粉酶(CBU30457,HD066534)及其变体，尤其是具有下列位点中的一处或多处取代的变体：26、30、33、82、37、106、118、128、133、149、150、160、178、182、186、193、203、214、231、256、257、258、269、270、272、283、295、296、298、299、303、304、305、311、314、315、318、319、339、345、361、378、383、419、421、437、441、444、445、446、447、450、461、471、482、484，任选还包含D183*和G184*缺失的变体。
(c)表现出与来源于芽孢杆菌属SP722（CBU30453、HD066526）中野生型酶具有至少90%的同一性的变体，特别是在183和184位点发生缺失的变体。
适宜的可商购获得的α-淀粉酶为
和
（Novozymes A/S），
及其变体（Biocon India Ltd.），
AT9000（Biozym Ges.m.b.H，Austria），和Purastar（Genencor International Inc.），以及
（KAO，Japan）。适宜的淀粉酶为
和Stainzyme
纤维素酶：所述组合物可包含纤维素酶。适用的纤维素酶包括细菌或真菌来源的那些。包括化学改性的或重组蛋白的突变体。适宜的纤维素酶包括来源于芽孢杆菌属、假单胞菌属、腐质霉属、镰孢属、草根霉菌属、枝顶孢霉属的纤维素酶，例如购自特异腐质霉、嗜热毁丝霉和尖孢镰孢菌的真菌纤维素酶。
可商购获得的纤维素酶包括
和
（Novozymes A/S），和PURADAX（GenencorInternational Inc.），以及
（Kao Corporation）。
所述纤维素酶能包括微生物来源的内葡聚糖酶，具有内切-β-1,4-葡聚糖酶活性(E.C.3.2.1.4），包括一个芽孢杆菌属成员AA349内源的细菌多肽以及它们的混合物。适宜的内切葡聚糖酶以商品名
和
（Novozymes A/S（Bagsvaerd，Denmark））出售。
所述组合物可包含属于糖基水解酶第45族的具有17kDa至30kDa分子量的清洁纤维素酶，例如以商品名
NCD、DCC和DCL（ABEnzymes（Darmstadt，Germany））出售的内葡聚糖酶。
适宜的纤维素酶还可表现出木葡聚糖酶活性，如
脂肪酶：所述组合物可包含脂肪酶。适宜的脂肪酶包括细菌源或真菌源的那些。包括化学改性的或重组蛋白的突变体。有用的脂肪酶例子包括来自腐质霉属（同义词嗜热）、例如来自柔毛腐质霉（疏绵状嗜热丝胞菌）、或来自特异腐质霉脂肪酶；假单胞菌脂肪酶，例如来自产碱假单胞菌或类产碱假单胞菌、洋葱假单胞菌、施氏假单胞菌、荧光假单胞菌、假单胞菌属株系名为SD705的菌种、威斯康辛假单胞菌；芽孢杆菌属脂肪酶，例如枯草芽孢杆菌、嗜热脂肪芽孢杆菌或短小芽孢杆菌。
所述脂肪酶可为“第一循环脂肪酶”，任选地为来源于包含T231R和N233R突变的疏绵状嗜热丝胞菌野生型脂肪酶的变体。野生型序列是Swissprot登录号为Swiss-Prot O59952（来源于疏棉状嗜热丝孢菌（柔毛腐质霉属））的269种氨基酸（氨基酸23-291）。适宜的脂肪酶将包括以商品名
和
由Novozymes（Bagsvaerd，Denmark）出售的那些。
所述组合物可包含与野生型氨基酸具有>90%同一性并且在T231和/或N233处，任选地在T231R和/或N233R处包含一个或多个取代基的疏棉状嗜热丝孢菌（O59952）脂肪酶的变体。
木葡聚糖酶：适宜的木葡聚糖酶可以有对木葡聚糖和无定形纤维素底物的酶活性。所述酶可为选自GH第5、12、44或74家族的糖基水解酶（GH）。选自GH第44家族的糖基水解酶是尤其适宜的。来自GH第44家族的适宜糖基水解酶为来源于多粘类芽胞杆菌（ATCC832）XYG1006糖基水解酶及其变体。
果胶酸裂合酶：适宜的果胶酸裂合酶为野生型的或为来源于芽孢杆菌属果胶裂解酶（CAF05441、AAU25568）的变体，以商品名
和（购自NovozymesA/S、Bagsvaerd、Denmark）销售。
甘露聚糖酶：适宜的甘露聚糖酶以商品名
（购自NovozymesA/S，Bagsvaerd，Denmark）和
（GenencorInternational Inc.，Palo Alto，California）销售。
漂白酶：适宜的漂白酶包括氧化还原酶，例如氧化酶如葡萄糖、胆碱或碳水化合物氧化酶、加氧酶、过氧化氢酶、过氧化物酶如卤代、氯代、溴代、木质素、葡萄糖或锰过氧化物酶、双加氧酶或漆酶（酚氧化酶、多酚氧化酶）。适宜的商业产品由Novozymes以
和
系列商标出售。额外的有机化合物，尤其是芳香族化合物掺入漂白酶一起使用可以是有利的；这些化合物与漂白酶相互作用增强了氧化还原酶的活性（增强子）或有利于氧化酶和污渍间的电子流动（调节子），通常氧化酶和污渍之上有强烈不同的氧化还原电位。
其它适宜的漂白酶包括过水解酶，其催化由酯底物和过氧源形成过酸。适宜的过水解酶包括耻垢分枝杆菌过水解酶变体、俗称CE-7的过水解酶变体、以及具有过水解酶活性的野生型枯草菌溶素变体。
角质酶：适宜的角质酶由E.C.Class3.1.1.73定义，任选地显示与来源于镧素对镰孢菌、门多萨假单胞菌或特异腐质霉中的一个的野生型具有至少90%，或95%，或最任选地至少98%的同一性。
同一性：两种氨基酸序列之间的关系由参数“同一性”描述。就本发明目的而言，通过采用EMBOSS软件包（http://emboss.org）2.8.0版的Needle程序，进行两种氨基酸序列比对测定。实施Needleman，S.B.和Wunsch，C.D.（1970）J.Mol.Biol.（48，443-453）中描述的全序列对准算法。使用的取代矩阵是BLOSUM62，空位开放罚分为10，空位延伸罚分为0.5。
织物软化剂：适宜的织物软化剂包括粘土、有机硅和/或季铵化合物。适宜的粘土包括蒙脱石粘土、锂蒙脱石粘土和/或合成锂皂石粘土。适宜的粘土为蒙脱石粘土。适宜的硅氧烷包括氨基硅氧烷和/或聚二甲基硅氧烷（PDMS）。适宜的织物软化剂为包含粘土和硅氧烷的颗粒，如包含蒙脱石粘土和PDMS的颗粒。
絮凝剂：适宜的絮凝剂包括聚环氧乙烷；例如具有平均分子量300,000Da至900,000Da。
抑泡剂：适宜的抑泡剂包括有机硅和/或脂肪酸如硬脂酸。
香料：适宜的香料包括香料微胶囊、聚合物辅助释放的香料体系，包括席夫碱香料/聚合物复合物、淀粉包封的香料谐香剂、载有香料的沸石、起霜香料谐香剂、以及它们的任何组合。适宜的香料微胶囊是基于三聚氰胺甲醛的，通常包含被包含三聚氰胺甲醛的外壳包封的香料。此类香料微胶囊高度适于在外壳中包含阳离子和/或阳离子前体材料，如聚乙烯基甲酰胺（PVF）和/或阳离子改性的羟乙基纤维素（catHEC）。
美化剂：适宜的美化颗粒包括皂环、层状美化颗粒、明胶小珠、碳酸盐和/或硫酸盐斑粒、有色粘土颗粒、以及它们的任何组合。
织物洗涤方法：所述织物洗涤方法通常包括将组合物与水接触形成洗涤液体，以及将织物在所述洗涤液体中洗涤的步骤，其中洗涤液体的温度通常为0℃以上至90℃、或至60℃、或至40℃、或至30℃、或至20℃、或至10℃、或甚至至8℃。织物可在使衣物洗涤剂组合物与水接触之前、之后或同时与水接触。所述组合物可用于预处理应用中。
通常，通过使洗涤剂与一定量的水接触来形成洗涤液体，使得洗涤液体中衣物洗涤剂组合物的浓度为0g/l以上至5g/l，或1g/l，并且至4.5g/l，或至4.0g/l，或至3.5g/l，或至3.0g/l，或至2.5g/l，或甚至至2.0g/l，或甚至至1.5g/l。
洗涤织物的方法可在顶部加载式或前加载式自动洗衣机中实施，或可用于手洗衣物洗涤应用中。在这些应用中，所形成的洗涤液体以及衣物洗涤剂组合物在所述洗涤液体中的浓度为主洗涤循环中的那些。在任何任选的一个或多个漂洗步骤期间，当确定所述洗涤液体的体积时，不包括任何加入的水。
所述洗涤液体可包含40升或更少的水，或30升或更少，或20升或更少，或10升或更少，或8升或更少，或甚至6升或更少的水。所述洗涤液体可包含0升以上至15升，或2升，并且至12升，或甚至至8升的水。
通常将每升洗涤液体0.01kg至2kg的织物加入到所述洗涤液体中。通常将每升洗涤液体0.01kg，或0.05kg，或0.07kg，或0.10kg，或0.15kg，或0.20kg，或0.25kg织物加入到所述洗涤液体中。
任选使50g或更少，或45g或更少，或40g或更少，或35g或更少，或30g或更少，或25g或更少，或20g或更少，或甚至15g或更少，或甚至10g或更少的组合物接触水以形成洗涤液体。
实例
实例1：适宜的颗粒状衣物洗涤剂组合物：
实例2：上蓝剂与高度可溶的增白剂的组合的有益效果
测试方法
织物洗涤：在Tergotometer设备（Copley800型）中测试每个样本，采用下列典型条件，用下列织物模拟洗涤：厚绒布毛巾、针织棉、未经压紧的棉、聚酯：1.6g于0.8升水中，2000ppm剂量，20℃浴温，1.36mM（3:1Ca2+:Mg2+摩尔比）水硬度，15分钟洗涤时间。将织物漂洗一次，漂洗5分钟，并且在环境条件下避光干燥。
使用具有D65照明、10°观察仪并且无紫外滤光器的Hunter LabScanXE反射光谱光度计，对每个织物测定L*、a*和b*以及CIE WI值（每个洗涤条件进行八次内部平行测定）。“L”为样本中白色或黑色量的量度；较高的“L”表示较浅着色的样本。样本中红色或绿色的量的测定由“a*”值确定。样本中蓝色或黄色的量的测定由“b*”值确定；较低的（更负）b*值表示样本上有更多蓝色。
将每个样本漂洗和干燥后，通过使用具有D65照明、10°观察仪并且无紫外滤光器的Hunter LabScan XE反射光谱光度计测定每个样本的L*、a*和b*值量度，评定样本的调色功效DE*eff。
通过下列转换，可由L*、a*和b*值计算CIEWI：CIEWI=(100*((L*+16)/116)^3) +800*(0.313776034-((94.825*(((a*/500)+ (((100*((L*+a*)/116)^3)/100)^0.3333))^3))/((100*((L*+a*)/116)^3)+(94.825*(((I9/500)+(((100*((L*+a*)/116)^3)/100)^0.3333))^3))+(107.381*(((((100*((L*+a*)/116)^3)/100)^0.3333)-b*/200)^3)))))+1700*((0.330900114-((100*((L*+a*)/)/116)^3)/((100*((L*+a*)/)/116)^3)+(94.825*(((I9/500)+(((100*((L*+a*)/)/116)^3)/100)^0.3333))^3))+(107.381*(((((100*((L*+a*)/)/116)^3)/100)^0.3333)-b*/200)^3))))))
样本衣物洗涤剂
形成下列固体粒状衣物洗涤剂组合物以供测试：
当染料和增白剂存在时，它们分别达到提供10ml水中0.4Au的染料强度，以及洗涤液体中5ppm的增白剂浓度的含量。所述染料为具有如本发明所述结构的上蓝剂或紫罗兰DV9染料（比较例），并且所述增白剂为β晶形的C.I.荧光增白剂260，具有3微米至30微米的重均粒度。
结果
下示结果为所有处理过的织物类型（厚绒布毛巾、针织棉、未经压紧的棉、聚酯）的ΔCIEWI总和。
样本 ΔCIEWI
仅具有增白剂的洗涤剂（比较） +29.9（相对于无染料和无增白剂）
具有DV9 和增白剂的洗涤剂（比较） +27.3（相对于DV9自身）
具有上蓝剂和增白剂的洗涤剂（本发明） +34.0（相对于上蓝剂自身）
结果示出包含染料和/或增白剂的样本相对于无染料和/或无增白剂的参比对CIE WI的影响。所述增白剂将所处理织物的洁白度提高+29.9个CIEWI单位。然而，当与DV9（比较）组合使用时，由增白剂体现的洁白度有益效果被削弱（-2.6个CIE WI单位）至+27.3个CIE WI单位。然而，当与上蓝剂（如本发明所述）组合使用时，由增白剂体现的洁白度有益效果增加（+4.1个CIE WI单位）至+34个CIE WI单位。+2CIE WI单位的差值是人眼可显著注意到的。
本文所公开的量纲和值不旨在被理解为严格地限于所述的精确值。相反，除非另外指明，每个这样的量纲旨在表示所述值以及围绕该值功能上等同的范围。例如，所公开的尺寸“40mm”旨在表示“约40mm”。
除非明确地不包括在内或进行其它限制，本文所引用的每篇文献，包括任何交叉引用的或相关的专利或专利申请，均特此以引用方式全文并入本文。任何文献的引用不是对其作为本文所公开的或受权利要求书保护的任何发明的现有技术，或者其单独地或者与任何其它参考文献的任何组合，或者参考、提出、建议或公开任何此类发明的认可。此外，当本发明中术语的任何含义或定义与以引用方式并入的文件中术语的任何含义或定义矛盾时，应当服从在本发明中赋予该术语的含义或定义。
Claims (9)
1.一种固体衣物洗涤剂组合物，包含：
(a)去污表面活性剂；
(b)上蓝剂，其中所述上蓝剂具有以下结构：
其中：
R1和R2独立地选自：H；烷基；烷氧基；亚烷基氧基；烷基封端的亚烷基氧基；脲；和酰氨基；
R3为取代的芳基；
X为包含磺酰胺部分和任选的烷基和/或芳基部分的取代基，并且其中所述取代基包含至少一个包含至少四个亚烷基氧基部分的亚烷基氧基链；
(c)具有下列结构的C.I.荧光增白剂260：
其中所述C.I.荧光增白剂260或者：
(i)主要为β-晶体形式，并具有3至30微米的重均原生粒度；或者
(ii)主要为α-晶体形式；以及
(d)任选的一种或多种附加的衣物洗涤剂成分。
2.根据权利要求1所述的组合物，其中所述上蓝剂具有以下结构：
其中：
R1和R2独立地选自：H；烷基；烷氧基；亚烷基氧基；烷基封端的亚烷基氧基；脲；和酰氨基；
U为氢、取代或未取代的氨基；
W为包含氨基部分和任选的烷基和/或芳基部分的取代基，并且其中所述取代基包含至少一个包含至少四个亚烷基氧基部分的亚烷基氧基链；
Y为氢或磺酸部分；并且
Z为磺酸部分或被芳基取代的氨基。
3.根据权利要求2所述的组合物，其中R1为烷氧基，并且R2为烷基。
4.根据前述权利要求中任一项所述的组合物，其中所述组合物基本上不含沸石助洗剂和磷酸盐助洗剂。
5.根据前述权利要求中任一项所述的组合物，其中所述去污表面活性剂包含：
(i)烷氧基化烷基硫酸盐阴离子去污表面活性剂，所述表面活性剂具有0.5至5的平均烷氧基化度；和/或
(ii)主要为C12烷基硫酸盐阴离子去污表面活性剂。
6.根据前述权利要求中任一项所述的组合物，其中所述组合物包含粘土和污垢移除/抗再沉积剂，所述粘土和污垢移除/抗再沉积剂选自：
(a)无规接枝共聚物，其包含：
(i)亲水性主链，其包含聚乙二醇；以及
(ii)一个或多个疏水性侧链，其选自：C4-C25烷基、聚丙烯、聚丁烯、饱和的C1-C6一元羧酸的乙烯基酯、丙烯酸或甲基丙烯酸的C1-C6烷基酯、以及它们的混合物；
(b)纤维素聚合物，所述纤维素聚合物具有0.01至0.99的取代度（DS）和一定的嵌段度（DB），使得DS+DB为至少1.00或者DB+2DS-DS2为至少1.20；
(c)共聚物，其包含：
(i)50至小于98重量%的结构单元，所述结构单元衍生自一种或多种包含羧基的单体；
(ii)1至小于49重量%的结构单元，所述结构单元衍生自一种或多种包含磺酸根部分的单体；以及
(iii)1至49重量%的结构单元，所述结构单元衍生自一种或多种类型的单体，所述单体选自由式（I）和（II）表示的包含醚键的单体：
式（I）：
其中在式（I）中，R0表示氢原子或CH3基团，R表示CH2基团、CH2CH2基团或单键，X表示数字0-5，当R为单键时X表示数字1-5，并且R1为氢原子或C1-C20有机基团；
式（II）：
在式（II）中，R0表示氢原子或CH3基团，R表示CH2基团、CH2CH2基团或单键，X表示数字0-5，并且R1为氢原子或C1-C20有机基团；
(d)聚酯去垢性聚合物，所述聚酯去垢性聚合物具有符合下列结构（I）、（II）或（III）之一的结构：
(I)-[(OCHR1-CHR2)a-O-OC-Ar-CO-]d
(II)-[(OCHR3-CHR4)b-O-OC-sAr-CO-]e
(III)-[(OCHR5-CHR6)c-OR7]f
其中：
a、b和c为1至200；
d、e和f为1至50；
Ar为1,4-取代的亚苯基；
sAr为5位被SO3Me取代的1,3-取代的亚苯基；
Me为H、Na、Li、K、Mg/2、Ca/2、Al/3、铵、单烷基铵、二烷基铵、三烷基铵或四烷基铵，其中所述烷基为C1-C18烷基或C2-C10羟烷基、或它们的任何混合物；
R1、R2、R3、R4、R5和R6独立地选自H或C1-C18正烷基或异烷基；并且
R7为直链或支化的C1-C18烷基、或直链或支化的C2-C30烯基、或具有5至9个碳原子的环烷基、或C8-C30芳基、或C6-C30芳烷基；以及
(e)它们的任何组合。
7.根据前述权利要求中任一项所述的组合物，其中所述组合物包含酶，所述酶选自：
(a)绵毛嗜热丝孢菌脂肪酶的变体，所述绵毛嗜热丝孢菌脂肪酶与野生型氨基酸具有>90%的同一性并且在T231和/或N233处包含一个或多个取代基；
(b)属于糖基水解酶第45族的清洁纤维素酶；
(c)芽孢杆菌属DSM12649内源的AA560α-淀粉酶的变体，所述变体具有：
(i)在一个或多个下列位点处的突变：9、26、149、182、186、202、257、295、299、323、339和345；和
(ii)在下列位点处的一个或多个取代和/或缺失：118、183、184、195、320和458；以及
(d)它们的任何组合。
8.根据前述权利要求中任一项所述的组合物，其中所述组合物包含基于过氧亚胺正离子的漂白催化剂，所述漂白催化剂具有下式：
其中：R1选自：H、包含3至24个碳的支链烷基、以及包含1至24个碳的直链烷基；R2独立地选自：H、包含3至12个碳的支链烷基、以及包含1至12个碳的直链烷基；并且n为0至1的整数。
9.根据前述权利要求中任一项所述的组合物，其中所述组合物包含香料微胶囊。
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| CN108603139A (zh) * | 2016-02-17 | 2018-09-28 | 荷兰联合利华有限公司 | 增白组合物 |
| CN108603139B (zh) * | 2016-02-17 | 2020-12-04 | 荷兰联合利华有限公司 | 增白组合物 |
| CN109881500A (zh) * | 2019-03-05 | 2019-06-14 | 游晟纺织科技(深圳)有限公司 | 一种不含荧光增白剂的纺织面料及其制备方法 |
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