CN102947220B - 取代的锂锰金属磷酸盐 - Google Patents
取代的锂锰金属磷酸盐 Download PDFInfo
- Publication number
- CN102947220B CN102947220B CN201180007839.2A CN201180007839A CN102947220B CN 102947220 B CN102947220 B CN 102947220B CN 201180007839 A CN201180007839 A CN 201180007839A CN 102947220 B CN102947220 B CN 102947220B
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- CN
- China
- Prior art keywords
- lithium manganese
- manganese metal
- metal phosphate
- lithium
- carbon
- Prior art date
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Links
- 229910001463 metal phosphate Inorganic materials 0.000 title claims abstract description 37
- KLARSDUHONHPRF-UHFFFAOYSA-N [Li].[Mn] Chemical compound [Li].[Mn] KLARSDUHONHPRF-UHFFFAOYSA-N 0.000 title claims abstract description 35
- 229910052744 lithium Inorganic materials 0.000 claims abstract description 17
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 12
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical group [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 9
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 9
- 229910052751 metal Inorganic materials 0.000 claims abstract description 8
- 239000002184 metal Substances 0.000 claims abstract description 8
- 238000002360 preparation method Methods 0.000 claims abstract description 7
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 4
- 229910052788 barium Inorganic materials 0.000 claims abstract description 3
- 229910052793 cadmium Inorganic materials 0.000 claims abstract description 3
- 229910052745 lead Inorganic materials 0.000 claims abstract description 3
- 229910052712 strontium Inorganic materials 0.000 claims abstract description 3
- 229910052718 tin Inorganic materials 0.000 claims abstract description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 55
- 229910052799 carbon Inorganic materials 0.000 claims description 45
- 150000001875 compounds Chemical class 0.000 claims description 33
- 239000002245 particle Substances 0.000 claims description 33
- 239000011572 manganese Substances 0.000 claims description 28
- 238000000034 method Methods 0.000 claims description 26
- 239000000203 mixture Substances 0.000 claims description 16
- 238000002156 mixing Methods 0.000 claims description 12
- -1 Li 2o Chemical compound 0.000 claims description 11
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 11
- 229910052748 manganese Inorganic materials 0.000 claims description 11
- 150000003839 salts Chemical class 0.000 claims description 7
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 claims description 6
- 229910019142 PO4 Inorganic materials 0.000 claims description 6
- 235000021317 phosphate Nutrition 0.000 claims description 6
- 239000011159 matrix material Substances 0.000 claims description 5
- 239000010452 phosphate Substances 0.000 claims description 4
- 150000003016 phosphoric acids Chemical class 0.000 claims description 4
- 229910012851 LiCoO 2 Inorganic materials 0.000 claims description 3
- 229910013290 LiNiO 2 Inorganic materials 0.000 claims description 2
- 239000006258 conductive agent Substances 0.000 claims description 2
- YNQRWVCLAIUHHI-UHFFFAOYSA-L dilithium;oxalate Chemical compound [Li+].[Li+].[O-]C(=O)C([O-])=O YNQRWVCLAIUHHI-UHFFFAOYSA-L 0.000 claims description 2
- XIXADJRWDQXREU-UHFFFAOYSA-M lithium acetate Chemical compound [Li+].CC([O-])=O XIXADJRWDQXREU-UHFFFAOYSA-M 0.000 claims description 2
- UOGMEBQRZBEZQT-UHFFFAOYSA-L manganese(2+);diacetate Chemical compound [Mn+2].CC([O-])=O.CC([O-])=O UOGMEBQRZBEZQT-UHFFFAOYSA-L 0.000 claims description 2
- HDJUVFZHZGPHCQ-UHFFFAOYSA-L manganese(2+);oxalate;dihydrate Chemical compound O.O.[Mn+2].[O-]C(=O)C([O-])=O HDJUVFZHZGPHCQ-UHFFFAOYSA-L 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims 3
- 229910021386 carbon form Inorganic materials 0.000 claims 2
- 229910010707 LiFePO 4 Inorganic materials 0.000 claims 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims 1
- 150000002696 manganese Chemical class 0.000 claims 1
- 239000010406 cathode material Substances 0.000 abstract description 5
- 239000000463 material Substances 0.000 description 40
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 37
- 229910015645 LiMn Inorganic materials 0.000 description 22
- 239000011777 magnesium Substances 0.000 description 12
- 229910052742 iron Inorganic materials 0.000 description 11
- 230000015572 biosynthetic process Effects 0.000 description 9
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 8
- 238000003786 synthesis reaction Methods 0.000 description 8
- 239000011701 zinc Substances 0.000 description 8
- 239000011575 calcium Substances 0.000 description 7
- 238000009826 distribution Methods 0.000 description 6
- 238000005259 measurement Methods 0.000 description 6
- 229910000616 Ferromanganese Inorganic materials 0.000 description 5
- 239000011149 active material Substances 0.000 description 5
- 239000010439 graphite Substances 0.000 description 5
- 229910002804 graphite Inorganic materials 0.000 description 5
- GELKBWJHTRAYNV-UHFFFAOYSA-K lithium iron phosphate Chemical compound [Li+].[Fe+2].[O-]P([O-])([O-])=O GELKBWJHTRAYNV-UHFFFAOYSA-K 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 description 4
- 239000003575 carbonaceous material Substances 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 239000008101 lactose Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 3
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 3
- 239000006230 acetylene black Substances 0.000 description 3
- 230000032683 aging Effects 0.000 description 3
- 238000000149 argon plasma sintering Methods 0.000 description 3
- 239000007833 carbon precursor Substances 0.000 description 3
- 238000007599 discharging Methods 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000007772 electrode material Substances 0.000 description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 3
- ILXAVRFGLBYNEJ-UHFFFAOYSA-K lithium;manganese(2+);phosphate Chemical compound [Li+].[Mn+2].[O-]P([O-])([O-])=O ILXAVRFGLBYNEJ-UHFFFAOYSA-K 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
- 230000010287 polarization Effects 0.000 description 3
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 3
- 238000000197 pyrolysis Methods 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical group [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 2
- 229910010710 LiFePO Inorganic materials 0.000 description 2
- 229910015581 LiMn0.56Fe0.33Mg0.10PO4 Inorganic materials 0.000 description 2
- 229910015833 LiMn0.66Fe0.33PO4 Inorganic materials 0.000 description 2
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 2
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 150000001722 carbon compounds Chemical class 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-M dihydrogenphosphate Chemical compound OP(O)([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-M 0.000 description 2
- 230000005518 electrochemistry Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- 239000003273 ketjen black Substances 0.000 description 2
- 238000011068 loading method Methods 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- GUBGYTABKSRVRQ-XLOQQCSPSA-N Alpha-Lactose Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@H](O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-XLOQQCSPSA-N 0.000 description 1
- WSVLPVUVIUVCRA-KPKNDVKVSA-N Alpha-lactose monohydrate Chemical compound O.O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@H](O)[C@H](O)[C@H]1O WSVLPVUVIUVCRA-KPKNDVKVSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
- 229930091371 Fructose Natural products 0.000 description 1
- 239000005715 Fructose Substances 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 1
- 229910005323 Li(Fe, Mn)PO4 Inorganic materials 0.000 description 1
- 229910003528 Li(Ni,Co,Al)O2 Inorganic materials 0.000 description 1
- 229910003000 Li(Ni,Mn,Co)O2 Inorganic materials 0.000 description 1
- 229910016099 LiMn0.56Fe0.33Zn0.10PO4 Inorganic materials 0.000 description 1
- 229910015895 LiMn0.80Fe0.10Mg0.10PO4 Inorganic materials 0.000 description 1
- 229910015883 LiMn0.80Fe0.20PO4 Inorganic materials 0.000 description 1
- 229910012258 LiPO Inorganic materials 0.000 description 1
- 101100513612 Microdochium nivale MnCO gene Proteins 0.000 description 1
- SOXJQKKNADFEOW-UHFFFAOYSA-L S(=O)(=O)([O-])[O-].[Fe+2].[Li+] Chemical compound S(=O)(=O)([O-])[O-].[Fe+2].[Li+] SOXJQKKNADFEOW-UHFFFAOYSA-L 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- QSNQXZYQEIKDPU-UHFFFAOYSA-N [Li].[Fe] Chemical compound [Li].[Fe] QSNQXZYQEIKDPU-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- WQZGKKKJIJFFOK-PQMKYFCFSA-N alpha-D-mannose Chemical compound OC[C@H]1O[C@H](O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-PQMKYFCFSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000004320 controlled atmosphere Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000001186 cumulative effect Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000009831 deintercalation Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- DALUDRGQOYMVLD-UHFFFAOYSA-N iron manganese Chemical compound [Mn].[Fe] DALUDRGQOYMVLD-UHFFFAOYSA-N 0.000 description 1
- LDHBWEYLDHLIBQ-UHFFFAOYSA-M iron(3+);oxygen(2-);hydroxide;hydrate Chemical compound O.[OH-].[O-2].[Fe+3] LDHBWEYLDHLIBQ-UHFFFAOYSA-M 0.000 description 1
- LNOZJRCUHSPCDZ-UHFFFAOYSA-L iron(ii) acetate Chemical compound [Fe+2].CC([O-])=O.CC([O-])=O LNOZJRCUHSPCDZ-UHFFFAOYSA-L 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- 229910000625 lithium cobalt oxide Inorganic materials 0.000 description 1
- 150000002642 lithium compounds Chemical class 0.000 description 1
- 229910002102 lithium manganese oxide Inorganic materials 0.000 description 1
- LRVBJNJRKRPPCI-UHFFFAOYSA-K lithium;nickel(2+);phosphate Chemical compound [Li+].[Ni+2].[O-]P([O-])([O-])=O LRVBJNJRKRPPCI-UHFFFAOYSA-K 0.000 description 1
- BFZPBUKRYWOWDV-UHFFFAOYSA-N lithium;oxido(oxo)cobalt Chemical compound [Li+].[O-][Co]=O BFZPBUKRYWOWDV-UHFFFAOYSA-N 0.000 description 1
- VLXXBCXTUVRROQ-UHFFFAOYSA-N lithium;oxido-oxo-(oxomanganiooxy)manganese Chemical compound [Li+].[O-][Mn](=O)O[Mn]=O VLXXBCXTUVRROQ-UHFFFAOYSA-N 0.000 description 1
- URIIGZKXFBNRAU-UHFFFAOYSA-N lithium;oxonickel Chemical compound [Li].[Ni]=O URIIGZKXFBNRAU-UHFFFAOYSA-N 0.000 description 1
- 238000004643 material aging Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 238000000634 powder X-ray diffraction Methods 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000001507 sample dispersion Methods 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229910052596 spinel Inorganic materials 0.000 description 1
- 239000011029 spinel Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 238000001291 vacuum drying Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000001238 wet grinding Methods 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/26—Phosphates
- C01B25/45—Phosphates containing plural metal, or metal and ammonium
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/362—Composites
- H01M4/366—Composites as layered products
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/624—Electric conductive fillers
- H01M4/625—Carbon or graphite
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Composite Materials (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
Description
Claims (24)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102010006083.6 | 2010-01-28 | ||
DE102010006083.6A DE102010006083B4 (de) | 2010-01-28 | 2010-01-28 | Substituiertes Lithium-Mangan-Metallphosphat |
PCT/EP2011/051189 WO2011092275A1 (de) | 2010-01-28 | 2011-01-28 | Substituiertes lithium-mangan-metallphosphat |
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EP (1) | EP2528862B1 (zh) |
JP (2) | JP5992335B2 (zh) |
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CN (1) | CN102947220B (zh) |
CA (1) | CA2788042A1 (zh) |
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Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102010006077B4 (de) | 2010-01-28 | 2014-12-11 | Süd-Chemie Ip Gmbh & Co. Kg | Substituiertes Lithium-Mangan-Metallphosphat |
CN102569802A (zh) * | 2012-02-29 | 2012-07-11 | 恒正科技(苏州)有限公司 | 一种电化学活性材料的制备方法 |
WO2014004789A2 (en) * | 2012-06-27 | 2014-01-03 | Precursor Energetics, Inc. | Molecular precursors for synthesis of lithium-iron-containing cathode materials |
US10236512B2 (en) | 2013-05-08 | 2019-03-19 | Advanced Lithium Electrochemistry Co., Ltd. | Preparation method of battery composite material and precursor thereof |
JP6385665B2 (ja) * | 2013-10-04 | 2018-09-05 | 株式会社東芝 | 非水電解質二次電池用正極活物質、非水電解質二次電池、電池パック及び車 |
CN105514357B (zh) * | 2014-09-24 | 2018-05-29 | 比亚迪股份有限公司 | 一种锂电池正极材料LiM1-xNxPO4/C及其制备方法 |
JP5820522B1 (ja) * | 2014-09-29 | 2015-11-24 | 太平洋セメント株式会社 | リチウム二次電池用正極活物質及びその製造方法 |
JP5836461B1 (ja) * | 2014-09-29 | 2015-12-24 | 太平洋セメント株式会社 | リチウム二次電池用正極材料 |
US9692054B2 (en) * | 2014-12-26 | 2017-06-27 | Sumitomo Osaka Cement Co., Ltd. | Electrode material for lithium ion secondary battery, electrode for lithium ion secondary battery, and lithium ion secondary battery |
CN107210438B (zh) * | 2015-09-14 | 2020-12-08 | 株式会社东芝 | 非水电解质电池及电池包 |
JP5999240B1 (ja) * | 2015-09-30 | 2016-09-28 | 住友大阪セメント株式会社 | リチウムイオン二次電池用電極材料およびその製造方法 |
JP5928648B1 (ja) * | 2015-09-30 | 2016-06-01 | 住友大阪セメント株式会社 | リチウムイオン二次電池用電極材料 |
US11522191B2 (en) | 2016-03-16 | 2022-12-06 | Kabushiki Kaisha Toshiba | Nonaqueous electrolyte battery, battery pack and vehicle |
JP6629110B2 (ja) * | 2016-03-16 | 2020-01-15 | 株式会社東芝 | 非水電解質電池、電池パックおよび車両 |
CN106129365B (zh) * | 2016-08-19 | 2017-05-17 | 骆驼集团新能源电池有限公司 | 一种高安全性磷酸锰铁锂电池 |
TWI739098B (zh) * | 2018-06-25 | 2021-09-11 | 國立清華大學 | 用於鋰離子電池之二價金屬磷酸鹽粉末和鋰金屬磷酸鹽粉末及其製備方法 |
CN109678127B (zh) * | 2018-12-06 | 2022-09-16 | 绵阳洁源达环保科技有限公司 | 一种磷酸钛锰铁及其制备方法 |
CN115385385A (zh) * | 2022-09-26 | 2022-11-25 | 江苏沙英喜实业有限公司 | 一种锂电池用锂锰铁复合盐及其生产工艺和应用 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1322023A (zh) * | 2000-04-25 | 2001-11-14 | 索尼株式会社 | 正极活性材料和非水电解质电池 |
CN101207197A (zh) * | 2006-12-22 | 2008-06-25 | 比亚迪股份有限公司 | 锂离子电池正极材料和含有该材料的正极和锂离子电池 |
Family Cites Families (41)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6514640B1 (en) * | 1996-04-23 | 2003-02-04 | Board Of Regents, The University Of Texas System | Cathode materials for secondary (rechargeable) lithium batteries |
US5910382A (en) | 1996-04-23 | 1999-06-08 | Board Of Regents, University Of Texas Systems | Cathode materials for secondary (rechargeable) lithium batteries |
JP2002516371A (ja) | 1998-05-29 | 2002-06-04 | ソリユテイア・インコーポレイテツド | 次亜燐酸塩の存在下でのポリアミドの核形成 |
US7001690B2 (en) * | 2000-01-18 | 2006-02-21 | Valence Technology, Inc. | Lithium-based active materials and preparation thereof |
US6528033B1 (en) * | 2000-01-18 | 2003-03-04 | Valence Technology, Inc. | Method of making lithium-containing materials |
JP4461566B2 (ja) * | 2000-04-25 | 2010-05-12 | ソニー株式会社 | 正極活物質及び非水電解質電池 |
JP4432203B2 (ja) * | 2000-04-25 | 2010-03-17 | ソニー株式会社 | 正極活物質及び非水電解質電池 |
JP4495336B2 (ja) | 2000-11-10 | 2010-07-07 | 株式会社Kri | 鉄リン酸リチウムの製造方法。 |
DE10117904B4 (de) * | 2001-04-10 | 2012-11-15 | Zentrum für Sonnenenergie- und Wasserstoff-Forschung Baden-Württemberg Gemeinnützige Stiftung | Binäre, ternäre und quaternäre Lithiumeisenphosphate, Verfahren zu ihrer Herstellung und ihre Verwendung |
JP2004063422A (ja) * | 2002-07-31 | 2004-02-26 | Sony Corp | 正極活物質、並びに非水電解質電池 |
JP4260572B2 (ja) * | 2003-07-29 | 2009-04-30 | 日本化学工業株式会社 | Mn原子を含有するリチウム鉄リン系複合酸化物炭素複合体の製造方法 |
JP4225859B2 (ja) * | 2003-07-29 | 2009-02-18 | 日本化学工業株式会社 | Mn原子を含有するリチウム鉄リン系複合酸化物炭素複合体の製造方法 |
DE10353266B4 (de) | 2003-11-14 | 2013-02-21 | Süd-Chemie Ip Gmbh & Co. Kg | Lithiumeisenphosphat, Verfahren zu seiner Herstellung und seine Verwendung als Elektrodenmaterial |
US7008726B2 (en) * | 2004-01-22 | 2006-03-07 | Valence Technology, Inc. | Secondary battery electrode active materials and methods for making the same |
JP2006073259A (ja) * | 2004-08-31 | 2006-03-16 | Toyota Central Res & Dev Lab Inc | 正極活物質及び水系リチウム二次電池 |
JP4959145B2 (ja) * | 2005-03-30 | 2012-06-20 | 日本碍子株式会社 | 非水電解質二次電池用正極及び非水電解質二次電池 |
JP2007035358A (ja) * | 2005-07-25 | 2007-02-08 | Toyota Central Res & Dev Lab Inc | 正極活物質及びその製造方法、並びにリチウムイオン二次電池 |
WO2007034823A1 (ja) * | 2005-09-21 | 2007-03-29 | Kanto Denka Kogyo Co., Ltd. | 正極活物質の製造方法およびそれを用いた非水電解質電池 |
JP5344452B2 (ja) * | 2005-09-21 | 2013-11-20 | 関東電化工業株式会社 | 正極活物質及びその製造方法並びに正極活物質を含む正極を有する非水電解質電池 |
JP2007103298A (ja) * | 2005-10-07 | 2007-04-19 | Toyota Central Res & Dev Lab Inc | 正極活物質及びその製造方法、並びに水系リチウム二次電池 |
WO2008018633A1 (fr) * | 2006-08-09 | 2008-02-14 | Kanto Denka Kogyo Co., Ltd. | Composé ayant une structure d'olivine, procédé de fabrication de celui-ci, matière active d'électrode positive utilisant le composé ayant une structure d'olivine et batterie à électrolyte non-acqueux |
CA2566906A1 (en) * | 2006-10-30 | 2008-04-30 | Nathalie Ravet | Carbon-coated lifepo4 storage and handling |
JP5003117B2 (ja) * | 2006-11-22 | 2012-08-15 | ソニー株式会社 | 電池および電池ユニット |
JP5479106B2 (ja) * | 2006-12-22 | 2014-04-23 | ユミコア ソシエテ アノニム | 結晶性ナノLiFeMPO4の合成 |
JP5558349B2 (ja) | 2007-07-12 | 2014-07-23 | エー123 システムズ, インコーポレイテッド | リチウムイオンバッテリー用の多機能合金オリビン |
JP5314258B2 (ja) * | 2007-07-27 | 2013-10-16 | 関東電化工業株式会社 | オリビン型リン酸鉄リチウム化合物及びその製造方法、並びにオリビン型リン酸鉄リチウム化合物を使用する正極活物質及び非水電解質電池 |
CN100499225C (zh) * | 2007-08-27 | 2009-06-10 | 北京中润恒动电池有限公司 | 锂电池磷酸铁锂复合正极材料的制备方法 |
JP2009295566A (ja) * | 2007-11-12 | 2009-12-17 | Gs Yuasa Corporation | 電極材料製造装置、電極材料の製造方法及びリチウム二次電池の製造方法 |
JP5272756B2 (ja) * | 2008-02-12 | 2013-08-28 | 株式会社Gsユアサ | リチウム二次電池用正極活物質、リチウム二次電池用正極及びリチウム二次電池、並びに、その製造方法 |
JP5244966B2 (ja) * | 2008-03-26 | 2013-07-24 | ビーワイディー カンパニー リミテッド | リチウム電池用正極材料 |
WO2009127901A1 (en) * | 2008-04-14 | 2009-10-22 | High Power Lithium S.A. | Lithium metal phosphate/carbon nanocomposites as cathode active materials for secondary lithium batteries |
JP2010086657A (ja) * | 2008-09-29 | 2010-04-15 | Fdk Corp | 非水電解液二次電池 |
JP5159681B2 (ja) * | 2009-03-25 | 2013-03-06 | 株式会社東芝 | 非水電解質電池 |
DE102009020832A1 (de) * | 2009-05-11 | 2010-11-25 | Süd-Chemie AG | Verbundmaterial enthaltend ein gemischtes Lithium-Metalloxid |
JP5600904B2 (ja) * | 2009-08-12 | 2014-10-08 | ソニー株式会社 | 非水電解質電池用の正極活物質及び非水電解質電池 |
JP5287593B2 (ja) * | 2009-08-12 | 2013-09-11 | ソニー株式会社 | 正極活物質の製造方法。 |
JP2011076820A (ja) * | 2009-09-30 | 2011-04-14 | Hitachi Vehicle Energy Ltd | リチウム二次電池及びリチウム二次電池用正極 |
JP5446017B2 (ja) * | 2009-10-06 | 2014-03-19 | 国立大学法人長岡技術科学大学 | リチウムイオン二次電池用正極材料およびその製造方法 |
JP2011086584A (ja) * | 2009-10-19 | 2011-04-28 | Nippon Electric Glass Co Ltd | リチウムイオン二次電池用正極材料 |
JP2011113783A (ja) * | 2009-11-26 | 2011-06-09 | Sony Corp | 非水電解質電池用正極活物質、非水電解質電池、高出力電子機器および自動車 |
DE102010006077B4 (de) * | 2010-01-28 | 2014-12-11 | Süd-Chemie Ip Gmbh & Co. Kg | Substituiertes Lithium-Mangan-Metallphosphat |
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Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1322023A (zh) * | 2000-04-25 | 2001-11-14 | 索尼株式会社 | 正极活性材料和非水电解质电池 |
CN101207197A (zh) * | 2006-12-22 | 2008-06-25 | 比亚迪股份有限公司 | 锂离子电池正极材料和含有该材料的正极和锂离子电池 |
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CA2788042A1 (en) | 2011-08-04 |
EP2528862A1 (de) | 2012-12-05 |
KR101532943B1 (ko) | 2015-07-02 |
WO2011092275A1 (de) | 2011-08-04 |
TW201132580A (en) | 2011-10-01 |
US20130140496A1 (en) | 2013-06-06 |
DE102010006083B4 (de) | 2014-12-11 |
EP2528862B1 (de) | 2018-03-07 |
JP6789688B2 (ja) | 2020-11-25 |
DE102010006083A1 (de) | 2011-08-18 |
JP2013518023A (ja) | 2013-05-20 |
JP5992335B2 (ja) | 2016-09-14 |
KR20120120352A (ko) | 2012-11-01 |
CN102947220A (zh) | 2013-02-27 |
JP2016190787A (ja) | 2016-11-10 |
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