CN102516030B - 异丁烯和叔丁醇的制造方法 - Google Patents

异丁烯和叔丁醇的制造方法 Download PDF

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Publication number
CN102516030B
CN102516030B CN201110301139.6A CN201110301139A CN102516030B CN 102516030 B CN102516030 B CN 102516030B CN 201110301139 A CN201110301139 A CN 201110301139A CN 102516030 B CN102516030 B CN 102516030B
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catalyst
reaction
aforementioned
tba
butanol
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CN102516030A (zh
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山口辰男
野田弘之
渡部彻
桐野俊也
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Asahi Kasei Corp
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Asahi Kasei Chemicals Corp
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18—Stationary reactors having moving elements inside
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/009—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping in combination with chemical reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0053—Details of the reactor
    • B01J19/0066—Stirrers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
    • B01J23/04—Alkali metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/08—Alkenes with four carbon atoms
    • C07C11/09—Isobutene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/03—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2
    • C07C29/04—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2 by hydration of carbon-to-carbon double bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/18—Details relating to the spatial orientation of the reactor
    • B01J2219/185—Details relating to the spatial orientation of the reactor vertical
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C07C2523/04—Alkali metals
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
CN201110301139.6A 2005-11-01 2006-10-25 异丁烯和叔丁醇的制造方法 Active CN102516030B (zh)

Applications Claiming Priority (5)

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JP2005317904 2005-11-01
JP317904/2005 2005-11-01
JP2005373789 2005-12-27
JP373789/2005 2005-12-27
CN2006800408194A CN101300211B (zh) 2005-11-01 2006-10-25 异丁烯和叔丁醇的制造方法

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CN102516030B true CN102516030B (zh) 2016-05-04

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US (3) US8637716B2 (enExample)
EP (2) EP2266939B1 (enExample)
JP (2) JP5240988B2 (enExample)
KR (1) KR100969616B1 (enExample)
CN (2) CN101300211B (enExample)
SG (1) SG158189A1 (enExample)
TW (3) TWI483922B (enExample)
WO (1) WO2007052505A1 (enExample)

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JP5410052B2 (ja) * 2008-09-03 2014-02-05 東ソー株式会社 硫酸鉄の生成抑制方法
CN102300626B (zh) * 2009-02-03 2014-10-15 株式会社日本触媒 过滤器的再生方法
DE102009026585A1 (de) * 2009-05-29 2010-12-02 Evonik Oxeno Gmbh Herstellung von 3-Methylbut-1-en durch Dehydratisierung von 3-Methylbutan-1-ol
US8912373B2 (en) 2009-07-29 2014-12-16 The United States Of America As Represented By The Secretary Of The Navy Process for the dehydration of aqueous bio-derived terminal alcohols to terminal alkenes
US9242226B2 (en) 2009-07-29 2016-01-26 The Government Of The United States Of America As Represented By The Secretary Of The Navy Process for the dehydration of aqueous bio-derived terminal alcohols to terminal alkenes
US9649626B2 (en) 2009-07-29 2017-05-16 The United States Of America As Represented By The Secretary Of The Navy Process for the dehydration of aqueous bio-derived terminal alcohols to terminal alkenes
US8969636B2 (en) 2009-07-29 2015-03-03 The United States Of America As Represented By The Secretary Of The Navy Homogeneous metallocene ziegler-natta catalysts for the oligomerization of olefins in aliphatic-hydrocarbon solvents
US8785702B2 (en) 2009-07-29 2014-07-22 The United States Of America As Represented By The Secretary Of The Navy Turbine and diesel fuels and methods for making the same
US9266792B2 (en) 2009-07-29 2016-02-23 The United States Of America As Represented By The Secretary Of The Navy Process and apparatus for the selective dimerization of terpenes and alpha-olefin oligomers with a single-stage reactor and a single-stage fractionation system
MX2012004857A (es) * 2009-11-03 2012-09-07 Basf Se Proceso para el manejo de soluciones acuosas de acido metanosulfonico.
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WO2014092849A1 (en) * 2012-12-14 2014-06-19 Washington State University Process and catalyst for conversion of acetic acid to isobutene
WO2014204509A1 (en) * 2013-06-18 2014-12-24 Washington State University Process and catalyst for conversion of acetic acid to isobutene and propylene
CN106458786B (zh) 2014-05-07 2020-05-08 三菱化学株式会社 由异丁醇制造异丁烯的方法
SG11201704201VA (en) 2014-12-03 2017-06-29 China Petroleum & Chem Corp Catalyst and preparation method thereof, and method for preparing isobutylene by applying the same
KR20170035621A (ko) * 2015-09-23 2017-03-31 롯데케미칼 주식회사 터트-부탄올로부터 이소부틸렌의 제조 방법
CN105732326A (zh) * 2016-03-18 2016-07-06 安徽三联泵业股份有限公司 一种利用树脂处理正丁醇生产废液的方法
KR102080381B1 (ko) * 2018-01-09 2020-02-21 한화토탈 주식회사 알루미늄과 코발트를 중심원소로 하는 헤테로폴리산 촉매, 그 제조방법 및 상기 촉매를 이용하여 n-부텐의 수화반응으로부터 2-부탄올을 제조하는 방법
JP7020623B2 (ja) * 2018-03-27 2022-02-16 株式会社クラレ イソブテンの製造方法
FR3084267B1 (fr) 2018-07-25 2021-10-08 Axens Alumine a acidite et structure de porosite optimales
CN109096026B (zh) * 2018-08-28 2021-07-06 宁波昊德化学工业股份有限公司 一种异丁烯的生产方法
CN114456024A (zh) * 2022-02-15 2022-05-10 凯瑞环保科技股份有限公司 一种制备高纯度异丁烯的工艺装置及方法

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US4236034A (en) * 1978-06-08 1980-11-25 Asahi Kasei Kogyo Kabushiki Kaisha Process for producing tert-butanol from mixed butylenes
US5716895A (en) * 1993-04-01 1998-02-10 Nippon Kayaku Kabushiki Kaisha Process for regeneration of catalysts

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EP1944282A1 (en) 2008-07-16
US9919283B2 (en) 2018-03-20
WO2007052505A1 (ja) 2007-05-10
SG158189A1 (en) 2010-01-29
US20150360198A1 (en) 2015-12-17
KR100969616B1 (ko) 2010-07-14
TWI537240B (zh) 2016-06-11
US8637716B2 (en) 2014-01-28
CN102516030A (zh) 2012-06-27
TWI322797B (enExample) 2010-04-01
JP5582621B2 (ja) 2014-09-03
US20090124835A1 (en) 2009-05-14
EP1944282A4 (en) 2009-05-06
JPWO2007052505A1 (ja) 2009-04-30
TW201514139A (zh) 2015-04-16
EP1944282B1 (en) 2016-06-29
US20140107387A1 (en) 2014-04-17
JP5240988B2 (ja) 2013-07-17
CN101300211B (zh) 2012-10-17
TW200940486A (en) 2009-10-01
US9145342B2 (en) 2015-09-29
KR20080046735A (ko) 2008-05-27
TWI483922B (zh) 2015-05-11
EP2266939A1 (en) 2010-12-29
TW200728249A (en) 2007-08-01
JP2013006864A (ja) 2013-01-10
CN101300211A (zh) 2008-11-05
EP2266939B1 (en) 2016-09-28

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