CN102245333B - 金属纳米粒子及其制备方法和用途 - Google Patents
金属纳米粒子及其制备方法和用途 Download PDFInfo
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- CN102245333B CN102245333B CN2009801499743A CN200980149974A CN102245333B CN 102245333 B CN102245333 B CN 102245333B CN 2009801499743 A CN2009801499743 A CN 2009801499743A CN 200980149974 A CN200980149974 A CN 200980149974A CN 102245333 B CN102245333 B CN 102245333B
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- functionalized
- metal
- metal nanoparticle
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- polymerization stabilizer
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
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Families Citing this family (75)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8894760B2 (en) * | 2009-11-20 | 2014-11-25 | Rohm And Haas Electronic Materials Llc | Group 3a ink and methods of making and using same |
| DE102010033924A1 (de) * | 2010-08-03 | 2012-02-09 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Verfahren zur Herstellung von Nanopartikeln aus einem Edelmetall und die Verwendung der so hergestellten Nanopartikel |
| TW201219470A (en) * | 2010-11-12 | 2012-05-16 | Univ Nat Taiwan | Oil dispersible composite of metallic nanoparticle and method for synthesizing the same |
| US8308842B2 (en) * | 2010-12-08 | 2012-11-13 | Xerox Corporation | Pyrophoric iron nanoparticles and continuous processes for production thereof |
| CN102179525B (zh) * | 2011-04-15 | 2013-05-08 | 北京航空航天大学 | 一种室温条件制备镍铂双层纳米碗的可控合成方法 |
| US10071174B2 (en) | 2011-06-06 | 2018-09-11 | Portland State University | Bismuth particle X-ray contrast agents |
| JP5140187B1 (ja) * | 2011-09-27 | 2013-02-06 | 田中貴金属工業株式会社 | 導電粒子及び金属ペースト並びに電極 |
| CN102528070B (zh) * | 2012-01-09 | 2014-01-01 | 苏州银瑞光电材料科技有限公司 | 利用高速射流生产纳米银粉的方法和装置 |
| CN102554219B (zh) * | 2012-01-31 | 2014-03-26 | 云南云天化股份有限公司 | 铜锡核壳结构的纳米粒子及其制备方法 |
| CN102649035A (zh) * | 2012-02-06 | 2012-08-29 | 京东方科技集团股份有限公司 | 一种电泳粒子及其制作方法、电泳微胶囊 |
| KR101279459B1 (ko) * | 2012-04-19 | 2013-06-26 | 서울과학기술대학교 산학협력단 | 화학적 환원 합성법을 이용한 주석계 솔더 페이스트 제조 방법 |
| CN103624265A (zh) * | 2012-08-21 | 2014-03-12 | 国家纳米科学中心 | 一种纳米金颗粒及其制备方法 |
| CN103658672B (zh) * | 2012-09-11 | 2015-10-21 | 中国科学院大连化学物理研究所 | 一种金属纳米粒子的水相制备方法 |
| EP2900409B1 (en) | 2012-09-27 | 2019-05-22 | Rhodia Operations | Process for making silver nanostructures and copolymer useful in such process |
| FR2997101B1 (fr) * | 2012-10-18 | 2015-01-02 | Holding Textile Hermes | Procede de fabrication d'un textile a effet de coloration variable contenant de l'or ou au moins un alliage contenant de l'or sous forme de particules et textile a effet de coloration variable. |
| KR20240095365A (ko) * | 2012-10-29 | 2024-06-25 | 알파 어셈블리 솔루션스 인크. | 소결 분말 |
| CN103056388B (zh) * | 2013-01-22 | 2015-07-22 | 西南科技大学 | 液相化学还原法制备包覆有分散稳定剂的铝纳米粒子的方法 |
| CN103970375A (zh) * | 2013-01-29 | 2014-08-06 | 华为终端有限公司 | 指甲油、指甲装饰物及触控屏幕的操作方法 |
| CN103157808B (zh) * | 2013-02-01 | 2015-04-01 | 天津商业大学 | 一种金铂钌合金纳米粒子及其胶体分散体系的制备方法 |
| CN103149194B (zh) * | 2013-02-28 | 2015-08-26 | 西安交通大学 | 一种表面增强拉曼散射基体的制备方法 |
| EP2781562B1 (en) * | 2013-03-20 | 2016-01-20 | Agfa-Gevaert | A method to prepare a metallic nanoparticle dispersion |
| WO2014196786A1 (ko) * | 2013-06-07 | 2014-12-11 | 주식회사 엘지화학 | 금속 나노입자의 제조방법 |
| PT3016149T (pt) * | 2013-08-01 | 2021-05-06 | Lg Chemical Ltd | Precursor em fase de agregado para produzir uma camada de absorção de luz de uma célula solar e respetivo método de produção |
| CN103433044B (zh) * | 2013-08-27 | 2015-05-13 | 安徽大学 | 一种钴-镍双金属氢氧化物纳米复合物的制备方法 |
| CN105899313A (zh) * | 2013-11-01 | 2016-08-24 | 科学与工业研究理事会 | 一种制备金属纳米粒子的方法 |
| CN103752846A (zh) * | 2014-01-17 | 2014-04-30 | 昆明理工大学 | 一种微通道连续快速制备纳米铜的方法 |
| WO2015183034A1 (ko) * | 2014-05-30 | 2015-12-03 | 한국화학연구원 | 금속 나노입자 및 이의 제조방법 |
| CN103990810A (zh) * | 2014-05-30 | 2014-08-20 | 洛阳理工学院 | 一种纳米铟粉的制备工艺 |
| CN104130629B (zh) * | 2014-07-30 | 2016-01-20 | 深圳市宇顺电子股份有限公司 | 导电墨水及其制备方法 |
| CN104128616B (zh) * | 2014-08-12 | 2016-03-23 | 苏州思美特表面材料科技有限公司 | 一种金属粉末的制备方法 |
| CZ307129B6 (cs) * | 2014-09-24 | 2017-12-27 | Univerzita Pardubice | Způsob přípravy bimodální směsi nanočástic a mikročástic mědi s polymerní ochrannou vrstvou |
| CN104475751A (zh) * | 2014-12-05 | 2015-04-01 | 山东理工大学 | 一种制备两亲性纳米银粒子的新方法 |
| CN105732918A (zh) * | 2014-12-12 | 2016-07-06 | 中国石油天然气股份有限公司 | 一种有机硅改性的丙烯酸酯/银纳米复合材料及其制备方法 |
| CN105798320B (zh) * | 2014-12-31 | 2018-05-04 | 中国科学院化学研究所 | 一种低温制备纳米铜粉的方法 |
| CN104624204B (zh) * | 2015-02-06 | 2017-02-01 | 中国科学院上海高等研究院 | 用于co选择性加氢的催化剂及其制法和应用 |
| CN104841932A (zh) * | 2015-06-04 | 2015-08-19 | 山东理工大学 | 制备核壳型聚苯乙烯包覆纳米银复合粒子的新方法 |
| CN105080603B (zh) * | 2015-08-20 | 2017-05-17 | 郑州大学 | 一种硝基苯选择性加氢制苯胺用催化剂及其制备方法、使用方法 |
| CN105056997B (zh) * | 2015-08-20 | 2017-08-11 | 郑州大学 | 一种对苯二甲酸选择性加氢制1,4‑环己烷二甲酸用催化剂及其制备方法、使用方法 |
| CN105056996B (zh) * | 2015-08-20 | 2017-05-17 | 郑州大学 | 对苯二甲酸二甲酯选择性加氢制1,4‑环己烷二甲酸二甲酯用催化剂及其制备方法、使用方法 |
| CN105149609A (zh) * | 2015-09-07 | 2015-12-16 | 昆明仁旺科技有限公司 | 一种制备贵金属粉体的方法 |
| CN105127413B (zh) * | 2015-09-18 | 2017-07-21 | 温州大学 | 贵金属纳米环及其制备方法 |
| CN105153401B (zh) * | 2015-10-13 | 2017-11-17 | 厦门大学 | 荧光金纳米团簇及其水性聚氨酯模板法制备方法 |
| DE102015221529A1 (de) | 2015-11-03 | 2017-05-04 | Cht R. Beitlich Gmbh | Kontinuierliches Verfahren für Reaktionen mit feinteiligen Alkalimetall-Dispersionen |
| CN106807952B (zh) * | 2015-12-01 | 2019-05-07 | 中国科学院大连化学物理研究所 | 一种合成Au25纳米球的方法及Au25纳米球 |
| WO2017108610A1 (en) * | 2015-12-21 | 2017-06-29 | Sandvik Intellectual Property Ab | Cutting tool |
| CL2015003794A1 (es) * | 2015-12-30 | 2016-07-29 | Univ Chile | Método de obtención de nano partículas de cobre y uso de dichas partículas |
| JP6255635B1 (ja) * | 2016-04-22 | 2018-01-10 | Dic株式会社 | 金属ナノ粒子水分散液 |
| CN105834450B (zh) * | 2016-05-13 | 2019-03-19 | 浙江光达电子科技有限公司 | 银粉的制备方法 |
| CN107520459A (zh) * | 2016-06-21 | 2017-12-29 | 张家港市山牧新材料技术开发有限公司 | 铜纳米颗粒的制备方法和抗菌塑料 |
| EP3519510A4 (en) | 2016-09-30 | 2019-09-11 | Nanyang Technological University | INK COMPOSITION, METHOD FOR PRODUCING A CONDUCTIVE ELEMENT AND CONDUCTIVE ELEMENT |
| JP6849374B2 (ja) * | 2016-10-06 | 2021-03-24 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーＥ．Ｉ．Ｄｕ Ｐｏｎｔ Ｄｅ Ｎｅｍｏｕｒｓ Ａｎｄ Ｃｏｍｐａｎｙ | 接合用の導電性ペースト |
| US9975110B1 (en) | 2016-11-23 | 2018-05-22 | Honda Motor Co., Ltd. | Method for producing metal catalyst nanoparticles |
| KR101874623B1 (ko) * | 2016-11-29 | 2018-08-02 | 주식회사 나노뉴텍 | 우수한 항균 효과를 갖는 고급 함침재 및 이를 구비한 화장품 |
| CN108161020A (zh) * | 2016-12-13 | 2018-06-15 | 中国科学院光电技术研究所 | 一种金纳米八面体的制备方法 |
| JP7132695B2 (ja) * | 2016-12-20 | 2022-09-07 | Ｔｏｍａｔｅｃ株式会社 | 金属微粒子、金属微粒子含有分散液及びその製造方法 |
| CN106984804A (zh) * | 2017-05-10 | 2017-07-28 | 哈尔滨工程大学 | 一种纳米铝粉包覆方法 |
| EP3678804B1 (en) * | 2017-09-06 | 2022-06-15 | Council of Scientific and Industrial Research | Continuous flow production of metal nanowires |
| KR102067819B1 (ko) * | 2017-10-31 | 2020-02-11 | 영남대학교 산학협력단 | 나노 구조체의 안정화 방법 |
| CN108284232B (zh) * | 2018-01-26 | 2021-07-20 | 上海应用技术大学 | 一种银纳米粒子的制备方法 |
| EP3656826B1 (en) | 2018-11-22 | 2021-05-19 | Société BIC | Process for preparing aqueous gel inks with fixed color, and aqueous gel inks thereof |
| EP3656825B1 (en) | 2018-11-22 | 2021-04-28 | Société BIC | Process for preparing aqueous gel inks with variable color, and aqueous gel inks thereof |
| CN109746457A (zh) * | 2018-11-28 | 2019-05-14 | 石河子大学 | 一种纳米金的制备方法 |
| CN109848438B (zh) * | 2019-03-25 | 2022-02-25 | 珠海纳金科技有限公司 | 一种双模粒径纳米银颗粒及其制备方法 |
| CN114450357B (zh) * | 2019-08-29 | 2023-09-19 | 法国比克公司 | 制备包括银纳米颗粒的具有可变颜色的水性凝胶油墨的方法 |
| CN110480004B (zh) * | 2019-08-29 | 2021-11-09 | 南京理工大学 | 水热法制备碳包覆纳米铝粉的方法 |
| WO2021038066A1 (en) | 2019-08-29 | 2021-03-04 | Societe Bic | Process for preparing an aqueous gel ink with fixed color comprising silver or gold nanoparticles |
| EP4021988B1 (en) | 2019-08-29 | 2023-08-09 | Société BIC | Process of preparation of an aqueous gel ink with fixed color comprising gold nanoparticles |
| KR20220053592A (ko) | 2019-08-29 | 2022-04-29 | 소시에떼 빅 | 은 나노입자를 포함하는 가변 색을 갖는 수성 겔 잉크의 제조 방법 |
| CN111592788B (zh) * | 2020-05-29 | 2022-09-16 | 合肥福纳科技有限公司 | 量子点发光二极管、量子点墨水及其制作方法 |
| CN111975011B (zh) * | 2020-07-20 | 2022-01-18 | 华南理工大学 | 一种芯片无压烧结互连用纳米铜浆及其制备方法与应用 |
| CN114316666A (zh) * | 2022-01-06 | 2022-04-12 | 渭南市瑞梦印务有限责任公司 | 一种专色油墨配方及其加工工艺 |
| JP7779771B2 (ja) * | 2022-03-08 | 2025-12-03 | トヨタ自動車株式会社 | 金属ナノ粒子の製造方法 |
| CN114833334B (zh) * | 2022-04-02 | 2023-08-15 | 有研工程技术研究院有限公司 | 可连续制备微米级球形金粉的方法 |
| DE102023101927A1 (de) * | 2023-01-26 | 2024-08-01 | Karlsruher Institut für Technologie, Körperschaft des öffentlichen Rechts | Verfahren zur kontinuierlichen Cluster- und Nanopartikelsynthese |
| CN116786833B (zh) * | 2023-06-20 | 2025-08-15 | 宁夏中色新材料有限公司 | 一种钯亚微米类球形银粉及其制备方法 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101020242A (zh) * | 2006-02-15 | 2007-08-22 | 三星电机株式会社 | 生产金属纳米颗粒的方法 |
| CN101128550A (zh) * | 2005-01-10 | 2008-02-20 | 耶路撒冷希伯来大学伊萨姆研发公司 | 金属纳米颗粒的水基分散液 |
| EP1952918A1 (en) * | 2005-10-14 | 2008-08-06 | Toyo Ink Mfg. Co., Ltd | Method for producing metal particle dispersion, conductive ink using metal particle dispersion produced by such method, and conductive coating film |
Family Cites Families (47)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3465599D1 (en) | 1984-01-27 | 1987-10-01 | Byk Chemie Gmbh | Addition compounds suited as dispersing agents, process for their preparation, their use and solid materials coated with them |
| DE3641581C3 (de) | 1986-12-05 | 1996-08-01 | Byk Chemie Gmbh | Verfahren zur Herstellung von Dispergiermitteln und deren Salzen und ihre Verwendung |
| US4942213A (en) | 1987-12-04 | 1990-07-17 | Byk-Chemie Gmbh | Addition compounds useful as dispersing agents and dispersion stabilizers, process for producing them, their use and solids coated therewith |
| DE3930687A1 (de) | 1989-09-14 | 1991-04-11 | Byk Chemie Gmbh | Phosphorsaeureester, verfahren zu deren herstellung und deren verwendung als dispergiermittel |
| DE19721728C2 (de) | 1997-05-24 | 2001-07-12 | Byk Chemie Gmbh | Dispergiermittel für Pigmente oder Füllstoffe auf der Basis von Acrylsäurealkylester-Polymeren, Verwendung und Verfahren zur Herstellung |
| JP3594803B2 (ja) * | 1997-07-17 | 2004-12-02 | 日本ペイント株式会社 | 貴金属又は銅のコロイド溶液及びその製造方法並びに塗料組成物及び樹脂成型物 |
| DE19732251B4 (de) | 1997-07-26 | 2004-07-29 | Byk-Chemie Gmbh | Versalzungsprodukte von Polyaminen und deren Einsatz als Dispergiermittel für Pigmente und Füllstoffe |
| DE19745904A1 (de) * | 1997-10-17 | 1999-04-22 | Hoechst Ag | Polymerstabilisierte Metallkolloid-Lösungen, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren für Brennstoffzellen |
| ATE366932T1 (de) * | 1998-11-30 | 2007-08-15 | Nanosphere Inc | Nanopartikel mit polymerschalen |
| DE19941031A1 (de) | 1999-08-28 | 2001-03-01 | Byk Chemie Gmbh | Verzweigte, Imidazolgruppen enthaltende Polymere, sowie deren Herstellung und Verwendung |
| JP2002285207A (ja) * | 2001-03-23 | 2002-10-03 | Nippon Paint Co Ltd | 白金コロイド水溶液、その製造方法及び白金の担持方法 |
| WO2002087749A1 (en) | 2001-04-30 | 2002-11-07 | Postech Foundation | Colloid solution of metal nanoparticles, metal-polymer nanocomposites and methods for preparation thereof |
| JP4094277B2 (ja) | 2001-11-09 | 2008-06-04 | 独立行政法人科学技術振興機構 | シェル架橋型ミセルを鋳型とする金属ナノ粒子の調製 |
| US7138468B2 (en) | 2002-03-27 | 2006-11-21 | University Of Southern Mississippi | Preparation of transition metal nanoparticles and surfaces modified with (CO)polymers synthesized by RAFT |
| JP2004033901A (ja) * | 2002-07-03 | 2004-02-05 | Nippon Paint Co Ltd | 金属コロイド溶液の製造方法 |
| DE10236133A1 (de) | 2002-08-07 | 2004-02-26 | Byk-Chemie Gmbh | Verwendung von Gradientencopolymeren als Dispergiermittel zur Behandlung von Pigmenten und Feststoffen |
| JP4448962B2 (ja) * | 2003-01-14 | 2010-04-14 | Ｄｏｗａエレクトロニクス株式会社 | ニッケル被覆微粒子銅粉の製法 |
| WO2004081111A1 (en) * | 2003-03-11 | 2004-09-23 | Dow Global Technologies Inc. | High dielectric constant composites |
| US6992039B2 (en) | 2003-03-13 | 2006-01-31 | General Motors Corporation | Method for making monodispersed noble metal nanoparticles supported on oxide substrates |
| DE10326147A1 (de) | 2003-06-06 | 2005-03-03 | Byk-Chemie Gmbh | Epoxid-Addukte und deren Salze als Dispergiermittel |
| US20060266157A1 (en) | 2003-09-05 | 2006-11-30 | Dai Nippon Toryo Co., Ltd. | Metal fine particles, composition containing the same, and production method for producing metal fine particles |
| ATE492888T1 (de) | 2004-03-10 | 2011-01-15 | Asahi Glass Co Ltd | Metallhaltiger feinpartikel, flüssigdispersion eines metallhaltigen feinpartikels und leitfähiges metallhaltiges material |
| DE102004016479B4 (de) | 2004-03-31 | 2007-03-15 | Byk-Chemie Gmbh | Verwendung von Polyestern als Dispergiermittel und Polyester enthaltende Masterbatches |
| DE102004022753B3 (de) | 2004-05-07 | 2006-02-16 | Byk-Chemie Gmbh | Als Dispergiermittel und Dispersionsstabilisatoren geeignete Additionsverbindungen |
| US7718094B2 (en) * | 2004-06-18 | 2010-05-18 | The Research Foundation Of State University Of New York | Preparation of metallic nanoparticles |
| GB2416316A (en) | 2004-07-20 | 2006-01-25 | Protensive Ltd | Spinning disc reactor with spiral passageway for heat transfer fluid |
| US8361553B2 (en) * | 2004-07-30 | 2013-01-29 | Kimberly-Clark Worldwide, Inc. | Methods and compositions for metal nanoparticle treated surfaces |
| GB2417215B (en) | 2004-08-18 | 2009-06-10 | Protensive Ltd | Spinning disc reactor with enhanced spreader plate features |
| DE102004044879A1 (de) | 2004-09-14 | 2006-03-30 | Byk-Chemie Gmbh | Copolymerisate, deren Herstellung und Verwendung als Netz- und Dispergiermittel |
| GB2419100A (en) | 2004-10-15 | 2006-04-19 | Protensive Ltd | Spinning disc reactor with cross-flow filtration or solvation |
| DE102004050955A1 (de) | 2004-10-20 | 2006-04-27 | Byk-Chemie Gmbh | Alkoxylierte Epoxyd-Amin-Addukte und deren Verwendung |
| US20060090597A1 (en) | 2004-10-29 | 2006-05-04 | Goia Dan V | Polyol-based method for producing ultra-fine metal powders |
| WO2006050251A2 (en) * | 2004-10-29 | 2006-05-11 | Nanodynamics, Inc. | Polyol-based method for producing ultra-fine metal powders |
| WO2006053225A2 (en) | 2004-11-12 | 2006-05-18 | Board Of Regents, The University Of Texas System | Protein-noble metal nanoparticles |
| WO2006076611A2 (en) | 2005-01-14 | 2006-07-20 | Cabot Corporation | Production of metal nanoparticles |
| US7824466B2 (en) * | 2005-01-14 | 2010-11-02 | Cabot Corporation | Production of metal nanoparticles |
| DE102005006870A1 (de) | 2005-02-14 | 2006-08-24 | Byk-Chemie Gmbh | Oberflächenmodifizierte Nanopartikel, Verfahren zu ihrer Herstellung und ihre Verwendung |
| JP2006252976A (ja) * | 2005-03-11 | 2006-09-21 | Nippon Paint Co Ltd | 金属ナノ粒子ペーストおよびその製造方法 |
| US7291292B2 (en) * | 2005-08-26 | 2007-11-06 | E.I. Du Pont De Nemours And Company | Preparation of silver particles using thermomorphic polymers |
| WO2007032144A1 (ja) | 2005-09-16 | 2007-03-22 | Fujifilm Corporation | 着色組成物及び感光性転写材料 |
| JP2007301461A (ja) * | 2006-05-10 | 2007-11-22 | Nippon Paint Co Ltd | 金属コロイド溶液の製造方法及び金属コロイド溶液 |
| KR100790948B1 (ko) * | 2006-05-25 | 2008-01-03 | 삼성전기주식회사 | 금속 나노입자의 제조방법 및 이에 의해 제조되는 금속나노입자 |
| TW200806408A (en) * | 2006-06-27 | 2008-02-01 | Ishihara Sangyo Kaisha | Nickel fine particles, method for preparing the same and fluid composition comprising the same |
| GB0621050D0 (en) * | 2006-10-23 | 2006-11-29 | Univ Strathclyde | Functionalised polymers for labelling metal surfaces |
| DE102006055218A1 (de) | 2006-11-21 | 2008-05-29 | Bayer Technology Services Gmbh | Kontinuierliches Verfahren zur Synthese von nanoskaligen metallhaltigen Nanopartikel und Nanopartikeldispersion |
| US20080272344A1 (en) * | 2007-03-23 | 2008-11-06 | Georgia Tech Research Corporation | Conductive polymer composites |
| JP5026303B2 (ja) * | 2007-03-30 | 2012-09-12 | Ｄｏｗａエレクトロニクス株式会社 | 銀粉の製造方法 |
-
2009
- 2009-03-28 DE DE102009015470A patent/DE102009015470A1/de not_active Withdrawn
- 2009-11-20 WO PCT/EP2009/008289 patent/WO2010066335A1/de not_active Ceased
- 2009-11-20 JP JP2011539917A patent/JP5833447B2/ja not_active Expired - Fee Related
- 2009-11-20 KR KR1020117016016A patent/KR101278939B1/ko not_active Expired - Fee Related
- 2009-11-20 EP EP09760108A patent/EP2358489A1/de not_active Withdrawn
- 2009-11-20 BR BRPI0923509A patent/BRPI0923509A2/pt not_active IP Right Cessation
- 2009-11-20 US US13/139,366 patent/US8870998B2/en not_active Expired - Fee Related
- 2009-11-20 CN CN2009801499743A patent/CN102245333B/zh not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101128550A (zh) * | 2005-01-10 | 2008-02-20 | 耶路撒冷希伯来大学伊萨姆研发公司 | 金属纳米颗粒的水基分散液 |
| EP1952918A1 (en) * | 2005-10-14 | 2008-08-06 | Toyo Ink Mfg. Co., Ltd | Method for producing metal particle dispersion, conductive ink using metal particle dispersion produced by such method, and conductive coating film |
| CN101020242A (zh) * | 2006-02-15 | 2007-08-22 | 三星电机株式会社 | 生产金属纳米颗粒的方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| US20120037041A1 (en) | 2012-02-16 |
| WO2010066335A1 (de) | 2010-06-17 |
| KR20110099731A (ko) | 2011-09-08 |
| US8870998B2 (en) | 2014-10-28 |
| JP2012511627A (ja) | 2012-05-24 |
| CN102245333A (zh) | 2011-11-16 |
| JP5833447B2 (ja) | 2015-12-16 |
| BRPI0923509A2 (pt) | 2019-09-24 |
| KR101278939B1 (ko) | 2013-06-28 |
| DE102009015470A1 (de) | 2010-06-17 |
| EP2358489A1 (de) | 2011-08-24 |
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