CA2721206C - Alkali/transition metal phosphates and related electrode active materials - Google Patents

Alkali/transition metal phosphates and related electrode active materials Download PDF

Info

Publication number
CA2721206C
CA2721206C CA2721206A CA2721206A CA2721206C CA 2721206 C CA2721206 C CA 2721206C CA 2721206 A CA2721206 A CA 2721206A CA 2721206 A CA2721206 A CA 2721206A CA 2721206 C CA2721206 C CA 2721206C
Authority
CA
Canada
Prior art keywords
metal
electrode active
active material
preferred
mixtures
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA2721206A
Other languages
English (en)
French (fr)
Other versions
CA2721206A1 (en
Inventor
Jeremy Barker
M. Yazid Saidi
Jeffrey L. Swoyer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Valence Technology Inc
Original Assignee
Valence Technology Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Valence Technology Inc filed Critical Valence Technology Inc
Publication of CA2721206A1 publication Critical patent/CA2721206A1/en
Application granted granted Critical
Publication of CA2721206C publication Critical patent/CA2721206C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/136—Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00—Phosphorus; Compounds thereof
    • C01B25/16—Oxyacids of phosphorus; Salts thereof
    • C01B25/26—Phosphates
    • C01B25/45—Phosphates containing plural metal, or metal and ammonium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/20—Silicates
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0565—Polymeric materials, e.g. gel-type or solid-type
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0025—Organic electrolyte
    • H01M2300/0028—Organic electrolyte characterised by the solvent
    • H01M2300/0037—Mixture of solvents
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0471—Processes of manufacture in general involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/409—Separators, membranes or diaphragms characterised by the material
    • H01M50/411—Organic material
    • H01M50/414—Synthetic resins, e.g. thermoplastics or thermosetting resins
    • H01M50/426—Fluorocarbon polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00—Primary cells; Manufacture thereof
    • H01M6/40—Printed batteries, e.g. thin film batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)
CA2721206A 2002-03-06 2003-03-05 Alkali/transition metal phosphates and related electrode active materials Expired - Fee Related CA2721206C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US10/092,317 US6815122B2 (en) 2002-03-06 2002-03-06 Alkali transition metal phosphates and related electrode active materials
US10/092,317 2002-03-06
CA002478507A CA2478507A1 (en) 2002-03-06 2003-03-05 Alkali/transition metal phosphates and related electrode active materials

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
CA002478507A Division CA2478507A1 (en) 2002-03-06 2003-03-05 Alkali/transition metal phosphates and related electrode active materials

Publications (2)

Publication Number Publication Date
CA2721206A1 CA2721206A1 (en) 2003-09-18
CA2721206C true CA2721206C (en) 2012-05-22

Family

ID=27787823

Family Applications (2)

Application Number Title Priority Date Filing Date
CA2721206A Expired - Fee Related CA2721206C (en) 2002-03-06 2003-03-05 Alkali/transition metal phosphates and related electrode active materials
CA002478507A Abandoned CA2478507A1 (en) 2002-03-06 2003-03-05 Alkali/transition metal phosphates and related electrode active materials

Family Applications After (1)

Application Number Title Priority Date Filing Date
CA002478507A Abandoned CA2478507A1 (en) 2002-03-06 2003-03-05 Alkali/transition metal phosphates and related electrode active materials

Country Status (8)

Country Link
US (3) US6815122B2 (enExample)
EP (2) EP1490919A4 (enExample)
JP (1) JP2005519451A (enExample)
KR (1) KR20040094762A (enExample)
CN (1) CN100413124C (enExample)
AU (1) AU2003217990A1 (enExample)
CA (2) CA2721206C (enExample)
WO (1) WO2003077335A1 (enExample)

Families Citing this family (128)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2378278C (en) * 2001-03-26 2008-11-18 Kabushiki Kaisha Toshiba Positive electrode active material and nonaqueous electrolyte secondary battery
EP2278643B1 (en) 2001-12-21 2018-03-28 Massachusetts Institute of Technology (MIT) Conductive lithium storage electrode
US20090220838A9 (en) * 2002-04-04 2009-09-03 Jeremy Barker Secondary electrochemical cell
US20110052986A1 (en) * 2002-04-04 2011-03-03 Jeremy Barker Sodium Ion Batteries
US7042615B2 (en) * 2002-05-17 2006-05-09 The Regents Of The University Of California Electrochromic devices based on lithium insertion
CA2776362A1 (en) * 2002-12-19 2004-06-19 Valence Technology, Inc. Batteries with alkali metal phosphate electrodes
US20040202935A1 (en) * 2003-04-08 2004-10-14 Jeremy Barker Cathode active material with increased alkali/metal content and method of making same
US7986124B2 (en) 2003-09-22 2011-07-26 Valence Technology, Inc. Electrical systems, battery assemblies, and battery assembly operational methods
DE10353266B4 (de) * 2003-11-14 2013-02-21 Süd-Chemie Ip Gmbh & Co. Kg Lithiumeisenphosphat, Verfahren zu seiner Herstellung und seine Verwendung als Elektrodenmaterial
FR2864348B1 (fr) * 2003-12-18 2006-03-10 Commissariat Energie Atomique Accumulateur au lithium presentant a la fois un potentiel electrique et une capacite d'insertion du lthium eleves.
US20050170256A1 (en) * 2004-01-30 2005-08-04 John Cummings Electrical power source apparatuses, electrical power source operational methods, and electrochemical device charging methods
US8617745B2 (en) 2004-02-06 2013-12-31 A123 Systems Llc Lithium secondary cell with high charge and discharge rate capability and low impedance growth
US7348101B2 (en) * 2004-02-06 2008-03-25 A123 Systems, Inc. Lithium secondary cell with high charge and discharge rate capability
US7719227B2 (en) * 2004-02-13 2010-05-18 Valence Technology, Inc. Electrical energy supply methods and electrical energy power supplies
KR100651246B1 (ko) * 2004-02-17 2006-11-29 경상대학교산학협력단 액체전해질을 사용한 나트륨/유황 전지
US7960057B2 (en) * 2004-05-17 2011-06-14 Toyota Motor Engineering & Manufacturing North America, Inc. Battery with molten salt electrolyte and phosphorus-containing cathode
WO2005113863A2 (en) * 2004-05-20 2005-12-01 Valence Technology, Inc. Secondary electrochemical cell
US7338647B2 (en) 2004-05-20 2008-03-04 Valence Technology, Inc. Synthesis of cathode active materials
KR100725705B1 (ko) * 2004-07-16 2007-06-07 주식회사 엘지화학 리튬 이차 전지용 전극 활물질
EP1831943B1 (en) * 2004-12-31 2014-12-10 IUCF-HYU (Industry-University Cooperation Foundation Hanyang University) Method for preparing double-layer cathode active materials for lithium secondary batteries
US7842420B2 (en) 2005-02-03 2010-11-30 A123 Systems, Inc. Electrode material with enhanced ionic transport properties
US7205067B2 (en) * 2005-02-08 2007-04-17 Valence Technology, Inc. Method and apparatus for dissipation of heat generated by a secondary electrochemical cell
US7799457B2 (en) * 2005-05-10 2010-09-21 Advanced Lithium Electrochemistry Co., Ltd Ion storage compound of cathode material and method for preparing the same
US20080138710A1 (en) * 2005-05-10 2008-06-12 Ben-Jie Liaw Electrochemical Composition and Associated Technology
TWI254031B (en) * 2005-05-10 2006-05-01 Aquire Energy Co Ltd Manufacturing method of LixMyPO4 compound with olivine structure
US7700236B2 (en) * 2005-09-09 2010-04-20 Aquire Energy Co., Ltd. Cathode material for manufacturing a rechargeable battery
US7887954B2 (en) * 2005-05-10 2011-02-15 Advanced Lithium Electrochemistry Co., Ltd. Electrochemical composition and associated technology
US7824581B2 (en) 2007-06-18 2010-11-02 Advanced Lithium Electrochemistry Co., Ltd. Cocrystalline metallic compounds and electrochemical redox active material employing the same
US7524529B2 (en) * 2005-09-09 2009-04-28 Aquire Energy Co., Ltd. Method for making a lithium mixed metal compound having an olivine structure
WO2007041209A2 (en) * 2005-09-29 2007-04-12 Massachusetts Institute Of Technology Oxides having high energy densities
KR101320788B1 (ko) * 2005-12-02 2013-10-23 에이일이삼 시스템즈 인코포레이티드 비정질 및 부분 비정질의 나노스케일 이온 저장 재료
JP5068459B2 (ja) * 2006-01-25 2012-11-07 Ｎｅｃエナジーデバイス株式会社 リチウム二次電池
CN100390052C (zh) * 2006-02-28 2008-05-28 北大先行科技产业有限公司 一种合成类球形磷酸金属锂盐的方法
US7723958B2 (en) 2006-03-31 2010-05-25 Valence Technology, Inc. Battery charge indication methods, battery charge monitoring devices, rechargeable batteries, and articles of manufacture
CN100563047C (zh) * 2006-04-25 2009-11-25 立凯电能科技股份有限公司 适用于制作二次电池的正极的复合材料及其所制得的电池
CN101479877B (zh) * 2006-05-04 2013-07-31 株式会社Lg化学 锂二次电池及其制造方法
KR20090012262A (ko) * 2006-05-09 2009-02-02 발렌스 테크놀로지, 인코포레이티드 증가된 집전 효율을 갖는 2차 전기화학 전지
TWI319920B (en) * 2006-07-06 2010-01-21 The preparation and application of the lifepo4/li3v2(po4)3 composite cathode materials for lithium ion batteries
EP2067198A2 (en) 2006-09-25 2009-06-10 Board of Regents, The University of Texas System Cation-substituted spinel oxide and oxyfluoride cathodes for lithium ion batteries
EP2266160A4 (en) 2006-10-17 2010-12-29 Valence Technology Inc METHOD AND DEVICE FOR MONITORING AND CONTROLLING AN ELECTROCHEMICAL CELL
WO2008097990A1 (en) * 2007-02-07 2008-08-14 Valence Technology, Inc. Oxynitride-based electrode active materials for secondary electrochemical cells
US8168329B2 (en) * 2007-06-18 2012-05-01 Advanced Lithium Electrochemistry Co., Ltd. Electrochemical composition and associated technology
JP5182626B2 (ja) * 2007-06-29 2013-04-17 株式会社Ｇｓユアサ 正極活物質および非水電解質電池
EP2015382A1 (en) * 2007-07-13 2009-01-14 High Power Lithium S.A. Carbon coated lithium manganese phosphate cathode material
US8288997B2 (en) * 2007-08-24 2012-10-16 Alexander Choi Providing power based on state of charge
TWI466370B (zh) 2008-01-17 2014-12-21 A123 Systems Inc 鋰離子電池的混合式金屬橄欖石電極材料
CN101494302B (zh) * 2008-01-22 2012-10-03 索尼株式会社 电池
JP5370937B2 (ja) * 2008-01-28 2013-12-18 シャープ株式会社 正極活物質、正極及び非水二次電池
EP2274789B1 (en) * 2008-04-07 2016-12-07 Carnegie Mellon University Sodium ion based aqueous electrolyte electrochemical secondary energy storage device
US9782949B2 (en) 2008-05-30 2017-10-10 Corning Incorporated Glass laminated articles and layered articles
US7715082B2 (en) * 2008-06-30 2010-05-11 Soladigm, Inc. Electrochromic devices based on lithium insertion
JP5107213B2 (ja) * 2008-11-18 2012-12-26 シャープ株式会社 正極活物質、正極及び非水二次電池
KR100939647B1 (ko) * 2009-01-22 2010-02-03 한화석유화학 주식회사 전극 활물질인 음이온 부족형 비화학양론 리튬 전이금속 다중산 화합물, 그 제조 방법 및 그를 이용한 전기화학 소자
US8398883B2 (en) * 2009-03-19 2013-03-19 Advanced Lithium Electrochemistry Co., Ltd. Electrochemical composition and associated technology
US8432603B2 (en) 2009-03-31 2013-04-30 View, Inc. Electrochromic devices
DE112010002062B4 (de) * 2009-05-22 2014-02-13 Sharp Kabushiki Kaisha Aktives Material für eine Kathode, Kathode, nichtwässrige Sekundärbatterie, Modul und Energiespeichersystem
JP2011054562A (ja) * 2009-08-04 2011-03-17 Sumitomo Chemical Co Ltd アルカリ金属複合遷移金属酸化物の判別方法
US9178215B2 (en) 2009-08-25 2015-11-03 A123 Systems Llc Mixed metal olivine electrode materials for lithium ion batteries having improved specific capacity and energy density
JP5551019B2 (ja) * 2009-09-02 2014-07-16 シャープ株式会社 正極活物質、正極及び非水二次電池
JP6034191B2 (ja) * 2009-09-18 2016-11-30 エイ１２３・システムズ・リミテッド・ライアビリティ・カンパニーＡ１２３ Ｓｙｓｔｅｍｓ， Ｌｌｃ リン酸第二鉄およびその調製の方法
US9660267B2 (en) 2009-09-18 2017-05-23 A123 Systems, LLC High power electrode materials
US9269955B2 (en) * 2009-09-24 2016-02-23 Valence Technology Inc. Manganese phosphates and related electrode active materials
CA2772255A1 (en) * 2009-09-24 2011-03-31 Valence Technology, Inc. Manganese phosphates and related electrode active materials
JP5489627B2 (ja) 2009-10-02 2014-05-14 トヨタ自動車株式会社 リチウム二次電池
JP5482115B2 (ja) * 2009-11-05 2014-04-23 株式会社豊田中央研究所 非水系二次電池用活物質および非水系二次電池
KR101751422B1 (ko) 2009-12-17 2017-07-11 존슨 맛쎄이 퍼블릭 리미티드 컴파니 알칼리 금속 산소 음이온 전극 재료의 전기화학적 성능 향상 방법 및 이로부터 얻은 알칼리 금속 산소 음이온 전극 재료
KR101698762B1 (ko) 2010-04-30 2017-01-23 삼성에스디아이 주식회사 리튬 전이금속 인산염의 제조방법
JP5463207B2 (ja) * 2010-05-28 2014-04-09 シャープ株式会社 正極活物質、正極及び非水電解質二次電池
JP5463208B2 (ja) * 2010-05-31 2014-04-09 シャープ株式会社 正極活物質、正極及び非水電解質二次電池
JP5548523B2 (ja) * 2010-05-31 2014-07-16 シャープ株式会社 正極活物質、正極及び非水電解質二次電池
WO2011152455A1 (ja) * 2010-06-02 2011-12-08 シャープ株式会社 リチウム含有複合酸化物の製造方法
US20120003139A1 (en) * 2010-06-30 2012-01-05 Semiconductor Energy Laboratory Co., Ltd. Method for manufacturing power storage device
US9373844B2 (en) 2010-07-01 2016-06-21 Sharp Kabushiki Kaisha Positive electrode active substance containing lithium-containing metal oxide
JP5271975B2 (ja) * 2010-07-01 2013-08-21 シャープ株式会社 正極活物質、正極及び非水電解質二次電池
JP5843766B2 (ja) * 2010-07-01 2016-01-13 シャープ株式会社 正極活物質、正極及び非水系二次電池
JP5463222B2 (ja) * 2010-07-08 2014-04-09 シャープ株式会社 正極活物質、正極及び非水電解質二次電池
JP5698929B2 (ja) * 2010-07-09 2015-04-08 シャープ株式会社 正極活物質、正極及び非水二次電池
JP5132727B2 (ja) * 2010-07-12 2013-01-30 シャープ株式会社 正極活物質、正極及び非水電解質二次電池
JP5698951B2 (ja) 2010-10-19 2015-04-08 シャープ株式会社 正極活物質及びその製造方法、正極ならびに非水電解質二次電池
WO2012057340A1 (ja) * 2010-10-29 2012-05-03 旭硝子株式会社 ケイ酸－リン酸化合物、二次電池用正極、二次電池、およびそれらの製造方法
WO2012057341A1 (ja) * 2010-10-29 2012-05-03 旭硝子株式会社 ケイ酸化合物、二次電池用正極、二次電池、およびそれらの製造方法
US9160001B2 (en) 2010-12-23 2015-10-13 Wildcat Discovery Technologies, Inc. Lithium-ion battery materials with improved properties
WO2012148569A2 (en) 2011-03-01 2012-11-01 Aquion Energy Inc. Profile responsive electrode ensemble
US8298701B2 (en) 2011-03-09 2012-10-30 Aquion Energy Inc. Aqueous electrolyte energy storage device
JP5451671B2 (ja) 2011-03-23 2014-03-26 シャープ株式会社 正極活物質、正極及び非水系二次電池
JP5478549B2 (ja) 2011-04-18 2014-04-23 シャープ株式会社 正極活物質の製造方法
JP5451681B2 (ja) * 2011-05-09 2014-03-26 シャープ株式会社 正極活物質、正極及び非水系二次電池
US9236611B2 (en) 2011-07-04 2016-01-12 Shoei Chemical Inc. Cathode material for lithium ion secondary battery, cathode member, lithium ion secondary battery, and production method for said cathode material
US8137830B2 (en) 2011-07-19 2012-03-20 Aquion Energy, Inc. High voltage battery composed of anode limited electrochemical cells
US8945751B2 (en) 2011-07-19 2015-02-03 Aquion Energy, Inc. High voltage battery composed of anode limited electrochemical cells
JP5637102B2 (ja) 2011-09-05 2014-12-10 昭栄化学工業株式会社 リチウムイオン二次電池用正極材料、リチウムイオン二次電池用正極部材、及びリチウムイオン二次電池
JP5760871B2 (ja) 2011-09-05 2015-08-12 昭栄化学工業株式会社 リチウムイオン二次電池用正極材料、リチウムイオン二次電池用正極部材、リチウムイオン二次電池、及びリチウムイオン二次電池用正極材料の製造方法
JP5850058B2 (ja) 2011-09-28 2016-02-03 昭栄化学工業株式会社 リチウムイオン二次電池用正極材料、リチウムイオン二次電池用正極部材、及びリチウムイオン二次電池
CN104011588B (zh) 2011-12-12 2021-06-22 唯景公司 薄膜装置和制造
JP5847204B2 (ja) * 2012-01-17 2016-01-20 シャープ株式会社 正極活物質、正極及び非水系二次電池
US8652672B2 (en) 2012-03-15 2014-02-18 Aquion Energy, Inc. Large format electrochemical energy storage device housing and module
US9090476B2 (en) 2012-03-22 2015-07-28 Chun-Chieh Chang Direct deposition of graphene on substrate material
US9059466B2 (en) 2012-03-22 2015-06-16 Chun-Chieh Chang Direct synthesis of lithium ion battery electrode materials using graphene treated raw materials as the reactant
US9325009B2 (en) 2012-06-06 2016-04-26 Sharp Kabushiki Kaisha Cathodic active material for nonaqueous electrolyte secondary battery, cathode for nonaqueous electrolyte secondary battery, and nonaqueous electrolyte secondary battery
ES2394245B2 (es) 2012-11-28 2013-12-16 Universidad De Granada Composición de melatonina o sus derivados con coenzima q10 y su uso contra el envejecimiento de la piel
US8945756B2 (en) 2012-12-12 2015-02-03 Aquion Energy Inc. Composite anode structure for aqueous electrolyte energy storage and device containing same
JP5932691B2 (ja) * 2013-03-18 2016-06-08 三井造船株式会社 リチウム二次電池用正極材料及びその製造方法
ES2798309T3 (es) 2013-07-09 2020-12-10 Dow Global Technologies Llc Material activo positivo mixto que comprende óxido metálico de litio y fosfato metálico de litio
CN103647077B (zh) * 2013-11-15 2016-01-20 成都兴能新材料有限公司 一种含镁、铝的磷酸铁锂正极材料的制备方法
CN103647076B (zh) * 2013-11-15 2015-12-30 成都兴能新材料有限公司 镁、铝活化磷酸铁锂正极材料
CN103647075B (zh) * 2013-11-15 2015-12-30 成都兴能新材料有限公司 含镁、铝的磷酸铁锂正极材料的制备方法
GB201409154D0 (en) 2014-05-22 2014-07-09 Faradion Ltd Sodium transition metal silicates
KR102228749B1 (ko) * 2014-08-11 2021-03-16 삼성에스디아이 주식회사 리튬 이차 전지용 양극 활물질, 이의 제조 방법 및 이를 포함하는 리튬 이차 전지
WO2016095177A1 (en) 2014-12-18 2016-06-23 Dow Global Technologies Llc Lithium ion battery having improved thermal stability
WO2016164617A1 (en) 2015-04-07 2016-10-13 Brown University Cation energy storage device and methods
KR102557725B1 (ko) 2015-09-25 2023-07-24 삼성에스디아이 주식회사 복합 음극 활물질, 상기 복합 음극 활물질을 포함하는 음극 및 상기 음극을 포함하는 리튬 이차전지
FR3055892B1 (fr) * 2016-09-12 2018-09-28 Commissariat A L'energie Atomique Et Aux Energies Alternatives Materiau silicate de structure olivine
KR20180057976A (ko) * 2016-11-23 2018-05-31 포항공과대학교 산학협력단 전이 금속 화합물 선택 소자를 포함하는 저항 변화형 메모리 소자
US10826145B2 (en) 2017-02-10 2020-11-03 General Electric Company Electrochemical cell for use in high temperature metal-air battery
FR3074160B1 (fr) * 2017-11-30 2019-11-22 Commissariat A L'energie Atomique Et Aux Energies Alternatives Materiau silicate phosphate de structure cristallographique olivine
FR3074159B1 (fr) * 2017-11-30 2019-11-22 Commissariat A L'energie Atomique Et Aux Energies Alternatives Materiau silicate phosphate de structure cristallographique olivine
KR102295733B1 (ko) * 2018-08-09 2021-08-31 한양대학교 에리카산학협력단 광전기화학 구조체 및 그 제조 방법, 그리고 광전기화학 소자.
CN112038572B (zh) * 2019-06-03 2021-11-23 安徽盟维新能源科技有限公司 复合粘结剂、电极极片及其制作方法
US20220393146A1 (en) * 2019-11-13 2022-12-08 HYDRO-QUéBEC Processes for the alkaliation or re-alkaliation of an electrode active material
JP7035281B2 (ja) * 2019-12-27 2022-03-14 昭和電工株式会社 リチウムイオン伝導性酸化物およびその用途
US11066305B1 (en) * 2020-11-13 2021-07-20 ionobell Inc Porous silicon manufactured from fumed silica
US11584653B2 (en) 2020-11-13 2023-02-21 Ionobell, Inc. Silicon material and method of manufacture
US20220380606A1 (en) 2021-05-25 2022-12-01 Ionobell, Inc. Silicon material and method of manufacture
WO2023064395A1 (en) 2021-10-12 2023-04-20 Ionobell, Inc Silicon battery and method for assembly
US11945726B2 (en) 2021-12-13 2024-04-02 Ionobell, Inc. Porous silicon material and method of manufacture
WO2024010903A1 (en) 2022-07-08 2024-01-11 Ionobell, Inc. Electrode slurry and method of manufacture
JP2024086156A (ja) * 2022-12-16 2024-06-27 本田技研工業株式会社 積層型柔軟回路装置、柔軟静電容量型センサ、柔軟アクチュエータ、柔軟バッテリ
JP7718557B1 (ja) * 2024-09-18 2025-08-05 トヨタ自動車株式会社 正極活物質、電池、および、正極活物質の製造方法

Family Cites Families (87)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4042482A (en) 1976-01-22 1977-08-16 E. I. Du Pont De Nemours And Company Substituted lithium orthosilicates and solid electrolytes therefrom
US4009092A (en) 1976-02-27 1977-02-22 E. I. Du Pont De Nemours And Company Substituted lithium phosphates and solid electrolytes therefrom
US4049891A (en) 1976-06-21 1977-09-20 Massachusetts Institute Of Technology Compositions for fast alkali-metal-ion transport
US4194062A (en) 1978-07-27 1980-03-18 Bell Telephone Laboratories, Incorporated Rechargeable dichalcogenide cell
US4166159A (en) 1978-08-02 1979-08-28 Massachusetts Institute Of Technology Process for forming fast sodium-ion transport compositions
US4322485A (en) 1979-06-13 1982-03-30 United Kingdom Atomic Energy Authority Preparation of materials
IT1131478B (it) 1980-05-13 1986-06-25 Consiglio Nazionale Ricerche Pile ricaricabili ad elevata energia specifica con anodo e catodo a intercalazione
DE3123099A1 (de) 1981-06-11 1983-01-05 Varta Batterie Ag, 3000 Hannover Ionenleitender mischkristall
US4512905A (en) 1982-05-18 1985-04-23 The Texas A&M University System Method of making sodium zirconium silico-phosphates
US4465744A (en) 1982-11-30 1984-08-14 The United States Of America As Represented By The United States Department Of Energy Super ionic conductive glass
US4477541A (en) 1982-12-22 1984-10-16 The United States Of America As Represented By The United States Department Of Energy Solid electrolyte structure
EP0205856B1 (en) 1985-05-10 1991-07-17 Asahi Kasei Kogyo Kabushiki Kaisha Secondary battery
US4792504A (en) 1987-09-18 1988-12-20 Mhb Joint Venture Liquid containing polymer networks as solid electrolytes
US4830939B1 (en) 1987-10-30 1996-10-08 Mhb Joint Venture Radiation cured solid electrolytes and electrochemical devices employing the same
US5037712A (en) 1987-10-30 1991-08-06 Ultracell, Inc. Preparation of radiation cured solid electrolytes and electrochemical devices employing the same
US4990413A (en) 1989-01-18 1991-02-05 Mhb Joint Venture Composite solid electrolytes and electrochemical devices employing the same
US4925752A (en) 1989-03-03 1990-05-15 Fauteux Denis G Solid state electrochemical cell having porous cathode current collector
US5011501A (en) 1989-04-26 1991-04-30 Shackle Dale R Process for making a solid state cell
US5028500A (en) 1989-05-11 1991-07-02 Moli Energy Limited Carbonaceous electrodes for lithium cells
US4935317A (en) 1989-06-21 1990-06-19 Mhb Joint Venture Method for producing solid state electrochemical laminar cell utilizing cathode rolling step
DE4024409A1 (de) 1990-08-01 1992-02-06 Geismar Guenter Phosphathaltige gruen-, tuerkis- und blaupigmente
US5130211A (en) 1990-10-24 1992-07-14 Her Majesty The Queen In Right Of The Provence Of British Columbia Electrolyte solution sequestering agents for electrochemical cells having carbonaceous electrodes
CA2096386A1 (en) 1992-05-18 1993-11-19 Masahiro Kamauchi Lithium secondary battery
US5262253A (en) 1992-07-22 1993-11-16 Valence Technology, Inc. Solid electrolytes derived by polymerization of vinyl sulfonate polyalkylene oxides
US5620810A (en) 1992-07-22 1997-04-15 Valence Technology, Inc. Solid, solvent-containing electrolytes and electrolytic cells produced therefrom
US5508130A (en) 1992-07-22 1996-04-16 Golovin; Milton N. Solid electrolytes containing LiN(SO2 CF3)2 and a triglyme-carbonate solvent, and electrochemical cells produced therefrom
US5300373A (en) 1992-09-11 1994-04-05 Valence Technology, Inc. Electrochemical cell stack and method of making an electrochemical cell stack
US5326653A (en) 1992-10-29 1994-07-05 Valence Technology, Inc. Battery unit with reinforced current collector tabs and method of making a battery unit having strengthened current collector tabs
US5418090A (en) 1993-02-17 1995-05-23 Valence Technology, Inc. Electrodes for rechargeable lithium batteries
US5460904A (en) 1993-08-23 1995-10-24 Bell Communications Research, Inc. Electrolyte activatable lithium-ion rechargeable battery cell
US5418091A (en) 1993-03-05 1995-05-23 Bell Communications Research, Inc. Polymeric electrolytic cell separator membrane
US5540741A (en) 1993-03-05 1996-07-30 Bell Communications Research, Inc. Lithium secondary battery extraction method
US5411820A (en) 1993-06-08 1995-05-02 Valence Technology, Inc. Solid, glyme-containing electrolytes including ion salt derivatives and electrolytic cells produced therefrom
US5541020A (en) 1993-07-22 1996-07-30 Golovin; Milton N. Compositions and methods for improving the cumulative capacity of solid, secondary electrolytic cells
US5435054A (en) 1993-11-15 1995-07-25 Valence Technology, Inc. Method for producing electrochemical cell
US5399447A (en) 1993-12-06 1995-03-21 Valence Technology, Inc. Acidity reduction of adhesion promoter layer and electrolytic cells produced therefrom
US5463179A (en) 1993-12-06 1995-10-31 Chaloner-Gill; Benjamin Solid electrolyte obtained by the polymerization of diacrylate monomer having a rigid alkane segment
US5482795A (en) 1994-05-25 1996-01-09 Chaloner-Gill; Benjamin Solid electrolyte utilizing a polymeric matrix obtained by the polymerization of a substituted allylic chloroformate
US5514490A (en) 1994-08-30 1996-05-07 Industrial Technology Research Institute Secondary lithium battery using a new layered anode material
JPH08138744A (ja) * 1994-11-16 1996-05-31 Fuji Photo Film Co Ltd 非水二次電池
JPH08153541A (ja) 1994-11-28 1996-06-11 Mitsubishi Cable Ind Ltd リチウム二次電池
JPH08171938A (ja) 1994-12-15 1996-07-02 Mitsubishi Cable Ind Ltd Ｌｉ二次電池及びその正極
CA2175856C (en) 1995-05-18 2000-01-18 Hajime Arai A method for producing positive electrode material and lithium batteries incorporating this material
US5643695A (en) 1995-09-26 1997-07-01 Valence Technology, Inc. Carbonaceous electrode and compatible electrolyte
US5660948A (en) 1995-09-26 1997-08-26 Valence Technology, Inc. Lithium ion electrochemical cell
US5712059A (en) 1995-09-26 1998-01-27 Valence Technology, Inc. Carbonaceous electrode and compatible electrolyte solvent
JP3484003B2 (ja) 1995-11-07 2004-01-06 日本電信電話株式会社 非水電解質二次電池
JP3523397B2 (ja) 1995-11-07 2004-04-26 日本電信電話株式会社 非水電解質二次電池
US5702995A (en) 1995-11-15 1997-12-30 Kabushiki Kaisha Ohara Lithium ion conductive glass-ceramics
JP3319258B2 (ja) 1995-12-21 2002-08-26 ソニー株式会社 リチウム二次電池用正極活物質の製造方法及びリチウム二次電池の製造方法
US5700298A (en) 1996-03-15 1997-12-23 Valence Technology, Inc. Carbon anode for lithium ion electrochemical cell
US5910382A (en) 1996-04-23 1999-06-08 Board Of Regents, University Of Texas Systems Cathode materials for secondary (rechargeable) lithium batteries
US6514640B1 (en) * 1996-04-23 2003-02-04 Board Of Regents, The University Of Texas System Cathode materials for secondary (rechargeable) lithium batteries
US6103419A (en) 1996-09-06 2000-08-15 Valence Technology, Inc. Solid secondary lithium cell based on lithiated zirconium, titanium or hafnium oxide cathode material
US5871866A (en) 1996-09-23 1999-02-16 Valence Technology, Inc. Lithium-containing phosphates, method of preparation, and use thereof
US6447951B1 (en) 1996-09-23 2002-09-10 Valence Technology, Inc. Lithium based phosphates, method of preparation, and uses thereof
US5851504A (en) 1996-09-23 1998-12-22 Valence Technology, Inc. Carbon based electrodes
US6183718B1 (en) 1996-12-09 2001-02-06 Valence Technology, Inc. Method of making stabilized electrochemical cell active material of lithium manganese oxide
US5869207A (en) 1996-12-09 1999-02-09 Valence Technology, Inc. Stabilized electrochemical cell
US5830602A (en) 1997-02-20 1998-11-03 Valence Technology, Inc. Carbonaceous active material and method of making same
CA2200998A1 (en) 1997-03-25 1998-09-25 Hydro-Quebec New lithium insertion electrode materials based on tetraoxyanions derivatives with olivine structure
US6085015A (en) 1997-03-25 2000-07-04 Hydro-Quebec Lithium insertion electrode materials based on orthosilicate derivatives
JPH1125983A (ja) 1997-07-04 1999-01-29 Japan Storage Battery Co Ltd リチウム電池用活物質
US20020192137A1 (en) * 2001-04-30 2002-12-19 Benjamin Chaloner-Gill Phosphate powder compositions and methods for forming particles with complex anions
US6020087A (en) 1998-01-30 2000-02-01 Valence Technology, Inc. Polymer electrolytes containing lithiated fillers
US6306215B1 (en) 1998-03-10 2001-10-23 Valence Technology, Inc. Apparatus for coating current collectors
US6136472A (en) 1998-06-26 2000-10-24 Valence Technology, Inc. Lithium-containing silicon/phosphates, method of preparation, and uses thereof including as electrodes for a battery
JP2000173654A (ja) 1998-12-04 2000-06-23 Toshiba Battery Co Ltd ポリマーリチウム二次電池
US6153333A (en) 1999-03-23 2000-11-28 Valence Technology, Inc. Lithium-containing phosphate active materials
CN1323447C (zh) * 1999-04-06 2007-06-27 索尼株式会社 正极活性物质及无水电解质二次电池
EP1094532A1 (en) 1999-04-06 2001-04-25 Sony Corporation Method for manufacturing active material of positive plate and method for manufacturing nonaqueous electrolyte secondary cell
CA2270771A1 (fr) 1999-04-30 2000-10-30 Hydro-Quebec Nouveaux materiaux d'electrode presentant une conductivite de surface elevee
JP3246480B2 (ja) 1999-06-17 2002-01-15 独立行政法人 農業技術研究機構 造粒方法及び装置
US6468695B1 (en) 1999-08-18 2002-10-22 Valence Technology Inc. Active material having extended cycle life
JP3504195B2 (ja) 1999-09-16 2004-03-08 日本電信電話株式会社 リチウム二次電池正極活物質およびリチウム二次電池
JP2001110414A (ja) 1999-10-04 2001-04-20 Nippon Telegr & Teleph Corp <Ntt> リチウム二次電池正極活物質およびリチウム二次電池
JP2001110455A (ja) 1999-10-12 2001-04-20 Sony Corp 非水電解質電池
US7001690B2 (en) 2000-01-18 2006-02-21 Valence Technology, Inc. Lithium-based active materials and preparation thereof
US6528033B1 (en) 2000-01-18 2003-03-04 Valence Technology, Inc. Method of making lithium-containing materials
JP3952491B2 (ja) 2000-04-24 2007-08-01 株式会社ジーエス・ユアサコーポレーション 電極材料及びそれを用いた電池
JP4461566B2 (ja) * 2000-04-25 2010-05-12 ソニー株式会社 正極活物質及び非水電解質電池
JP4432203B2 (ja) * 2000-04-25 2010-03-17 ソニー株式会社 正極活物質及び非水電解質電池
CA2344903C (en) 2000-04-25 2013-03-05 Sony Corporation Positive electrode active material and non-aqueous electrolyte cell
US6387568B1 (en) 2000-04-27 2002-05-14 Valence Technology, Inc. Lithium metal fluorophosphate materials and preparation thereof
JP2001338694A (ja) * 2000-05-26 2001-12-07 Japan Storage Battery Co Ltd リチウム電池
JP2002117908A (ja) 2000-10-06 2002-04-19 Sony Corp 非水電解液電池
US6814764B2 (en) 2000-10-06 2004-11-09 Sony Corporation Method for producing cathode active material and method for producing non-aqueous electrolyte cell

Also Published As

Publication number Publication date
CN1663063A (zh) 2005-08-31
US6815122B2 (en) 2004-11-09
EP1490919A4 (en) 2009-05-06
WO2003077335A1 (en) 2003-09-18
KR20040094762A (ko) 2004-11-10
US20060246351A1 (en) 2006-11-02
US7767332B2 (en) 2010-08-03
JP2005519451A (ja) 2005-06-30
US20050058905A1 (en) 2005-03-17
CA2721206A1 (en) 2003-09-18
US20030170542A1 (en) 2003-09-11
EP2436647A3 (en) 2012-07-04
US7087346B2 (en) 2006-08-08
AU2003217990A1 (en) 2003-09-22
CA2478507A1 (en) 2003-09-18
EP1490919A1 (en) 2004-12-29
CN100413124C (zh) 2008-08-20
EP2436647A2 (en) 2012-04-04

Similar Documents

Publication Publication Date Title
CA2721206C (en) Alkali/transition metal phosphates and related electrode active materials
CA2463872C (en) Halo-and hydroxy-modified metal phosphates
CA2479790C (en) Batteries comprising alkali-transition metal phosphates and preferred electrolytes
US7270915B2 (en) Alkali/transition metal HALO-and hydroxy-phosphates and related electrode active materials
US7422823B2 (en) Alkali-iron-cobalt phosphates and related electrode active materials
CA2483918C (en) Synthesis of metal compounds useful as cathode active materials
US7482097B2 (en) Alkali-transition metal phosphates having a +3 valence non-transition element and related electrode active materials
CA2520876A1 (en) Electrodes comprising mixed active particles
US8367036B2 (en) Alkali/transition metal halo-and hydroxy-phosphates and related electrode active materials
CA2772255A1 (en) Manganese phosphates and related electrode active materials

Legal Events

Date Code Title Description
EEER Examination request
MKLA Lapsed

Effective date: 20160307

MKLA Lapsed

Effective date: 20160307