WO2017104508A1 - 熱可塑性樹脂組成物 - Google Patents

熱可塑性樹脂組成物 Download PDF

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Publication number
WO2017104508A1
WO2017104508A1 PCT/JP2016/086398 JP2016086398W WO2017104508A1 WO 2017104508 A1 WO2017104508 A1 WO 2017104508A1 JP 2016086398 W JP2016086398 W JP 2016086398W WO 2017104508 A1 WO2017104508 A1 WO 2017104508A1
Authority
WO
WIPO (PCT)
Prior art keywords
copolymer
monomer
mass
aromatic vinyl
maleimide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2016/086398
Other languages
English (en)
French (fr)
Japanese (ja)
Inventor
鷹 池田
隆祥 藤原
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon A&L Inc
Original Assignee
Nippon A&L Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon A&L Inc filed Critical Nippon A&L Inc
Priority to US15/778,172 priority Critical patent/US10865266B2/en
Priority to CN201680057971.7A priority patent/CN108137899B/zh
Publication of WO2017104508A1 publication Critical patent/WO2017104508A1/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F257/00—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00
    • C08F257/02—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00 on to polymers of styrene or alkyl-substituted styrenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02—Homopolymers or copolymers of hydrocarbons
    • C08L25/04—Homopolymers or copolymers of styrene
    • C08L25/08—Copolymers of styrene
    • C08L25/12—Copolymers of styrene with unsaturated nitriles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/36—Amides or imides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • C08F279/04—Vinyl aromatic monomers and nitriles as the only monomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L35/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least one other carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L35/06—Copolymers with vinyl aromatic monomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/17—Viscosity
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
    • C08F2800/20—Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages

Definitions

  • the present invention relates to a thermoplastic resin composition.
  • thermoplastic resin composition having excellent heat resistance, weather resistance, molding processability and excellent surface appearance of a molded product
  • a graft copolymer using a rubber component with a specified gel content is used as a thermoplastic resin composition having excellent heat resistance, weather resistance, molding processability and excellent surface appearance of a molded product.
  • a thermoplastic resin composition is disclosed.
  • thermoplastic resin composition grafts an aromatic vinyl monomer and other monomers other than a maleimide monomer copolymerizable with the aromatic vinyl monomer.
  • the weight average particle diameter of the rubbery polymer is not particularly limited, but is preferably 0.01 to 2.0 ⁇ m from the viewpoint of improving the balance of physical properties such as impact resistance, fluidity and color developability, and preferably 0.1 to 1. 0 ⁇ m is more preferable. Further, the weight average particle diameter can be adjusted by agglomerating and enlarging a rubbery polymer having a weight average particle diameter of 0.05 to 0.3 ⁇ m.
  • graft copolymer (A) that are copolymerizable with the aromatic vinyl monomer (excluding the maleimide monomer)
  • vinyl cyanide monomers include vinyl cyanide monomers, (Meth) acrylic acid ester monomers, amide monomers, unsaturated carboxylic monomers, and the like. These can be used alone or in combination of two or more.
  • vinyl cyanide monomers include acrylonitrile, methacrylonitrile, ethacrylonitrile, fumaronitrile, and examples of (meth) acrylic acid ester monomers include methyl (meth) acrylate and (meth) acrylic acid.
  • thermoplastic resin composition there is no particular limitation on the polymerization method of the graft copolymer (A), copolymer (B), copolymer (C) and copolymer (D) constituting the thermoplastic resin composition. It can be produced by a combination method, a suspension polymerization method, a solution polymerization method, a bulk polymerization method, or a method combining these.
  • the content of the copolymer (C) is 10 to 88% by mass (the total of (A) to (D) is 100% by mass), preferably 19 to 80% by mass, and 28 to 72%. More preferably, it is mass%.
  • the obtained styrene copolymer latex was salted out, dehydrated and dried to obtain a powder of styrene copolymer (D-1).
  • the reduced viscosity of the obtained styrene copolymer (D-1) was 1.2 dl / g.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
PCT/JP2016/086398 2015-12-15 2016-12-07 熱可塑性樹脂組成物 Ceased WO2017104508A1 (ja)

Priority Applications (2)

Application Number Priority Date Filing Date Title
US15/778,172 US10865266B2 (en) 2015-12-15 2016-12-07 Thermoplastic resin composition
CN201680057971.7A CN108137899B (zh) 2015-12-15 2016-12-07 热塑性树脂组合物

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2015244051 2015-12-15
JP2015-244051 2015-12-15

Publications (1)

Publication Number Publication Date
WO2017104508A1 true WO2017104508A1 (ja) 2017-06-22

Family

ID=59056375

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2016/086398 Ceased WO2017104508A1 (ja) 2015-12-15 2016-12-07 熱可塑性樹脂組成物

Country Status (4)

Country Link
US (1) US10865266B2 (https=)
JP (1) JP6246304B2 (https=)
CN (1) CN108137899B (https=)
WO (1) WO2017104508A1 (https=)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020194683A1 (ja) * 2019-03-28 2020-10-01 日本エイアンドエル株式会社 熱可塑性樹脂組成物

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02135255A (ja) * 1988-11-16 1990-05-24 Toray Ind Inc 低光沢熱可塑性樹脂組成物
JPH09316263A (ja) * 1996-05-28 1997-12-09 Toray Ind Inc ブロー成形性にすぐれた熱可塑性樹脂組成物
JPH10330565A (ja) * 1997-03-31 1998-12-15 Toray Ind Inc 熱可塑性樹脂組成物
JP2007537326A (ja) * 2004-05-13 2007-12-20 チェイル インダストリーズ インコーポレイテッド 低線膨張熱可塑性樹脂組成物
WO2008026554A1 (en) * 2006-08-28 2008-03-06 Denki Kagaku Kogyo Kabushiki Kaisha Resin composition and molded body thereof

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2711026B2 (ja) * 1991-03-22 1998-02-10 鐘淵化学工業株式会社 難燃樹脂組成物
JPH06166795A (ja) * 1992-12-01 1994-06-14 Mitsubishi Rayon Co Ltd ブロー用途熱可塑性樹脂組成物
JP2999944B2 (ja) 1994-06-30 2000-01-17 三菱レイヨン株式会社 熱可塑性樹脂組成物
WO1996015188A1 (en) * 1994-11-15 1996-05-23 Kanegafuchi Kagaku Kogyo Kabushiki Kaisha Resin composition excellent in impact resistance
JPH09216980A (ja) * 1996-02-09 1997-08-19 Kanegafuchi Chem Ind Co Ltd 樹脂組成物
JPH101581A (ja) * 1996-06-14 1998-01-06 Toray Ind Inc ブロー成形用熱可塑性樹脂組成物およびそれからなるブロー成形品
JP3342808B2 (ja) 1996-09-03 2002-11-11 三菱レイヨン株式会社 耐熱性、耐衝撃性に優れた熱可塑性樹脂組成物
DE19728629A1 (de) * 1997-07-04 1999-01-07 Basf Ag Thermoplastische Formmassen mit geringer Eigenfarbe
JP3187751B2 (ja) 1997-08-28 2001-07-11 テクノポリマー株式会社 熱可塑性樹脂
DE19831735A1 (de) * 1998-07-15 2000-01-20 Bayer Ag Thermoplastische Formmassen auf Basis hochwirksamer Propfkautschukkomponenten
JP2000044747A (ja) * 1998-08-03 2000-02-15 Kanegafuchi Chem Ind Co Ltd 熱可塑性樹脂組成物
JP4060994B2 (ja) * 1999-07-27 2008-03-12 テクノポリマー株式会社 熱可塑性樹脂組成物
JP2001207011A (ja) * 2000-01-24 2001-07-31 Kanegafuchi Chem Ind Co Ltd 熱可塑性樹脂組成物及びそれを用いた自動車部品
DE10008420A1 (de) * 2000-02-23 2001-08-30 Bayer Ag Polymerzusammensetzungen mit verbesserter Eigenschaftskonstanz
JP4676603B2 (ja) * 2000-11-16 2011-04-27 株式会社カネカ シート成形用樹脂組成物およびそのシート成形品
KR100933103B1 (ko) * 2002-11-21 2009-12-21 테크노 폴리머 가부시키가이샤 열가소성 수지 조성물, 차량 외장용 성형품용 열가소성수지 조성물, 차량 외장용 성형품 및 차량 외장용 성형품의제조 방법
US20110224355A1 (en) * 2008-09-10 2011-09-15 Nippon A&L Inc. Thermoplastic resin composition for vehicular lamp housing
US9328186B2 (en) * 2010-03-05 2016-05-03 Nippon A&L Inc. Thermoplastic resin composition for vehicle lamp housings
CN102918103B (zh) * 2010-06-24 2014-08-06 大科能树脂有限公司 灯罩用热塑性树脂组合物及成型品
KR101469263B1 (ko) * 2011-12-22 2014-12-05 제일모직주식회사 열가소성 수지 조성물 및 그 성형품
WO2014065129A1 (ja) * 2012-10-22 2014-05-01 電気化学工業株式会社 芳香族ビニル－シアン化ビニル系樹脂耐熱性向上用の共重合体

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02135255A (ja) * 1988-11-16 1990-05-24 Toray Ind Inc 低光沢熱可塑性樹脂組成物
JPH09316263A (ja) * 1996-05-28 1997-12-09 Toray Ind Inc ブロー成形性にすぐれた熱可塑性樹脂組成物
JPH10330565A (ja) * 1997-03-31 1998-12-15 Toray Ind Inc 熱可塑性樹脂組成物
JP2007537326A (ja) * 2004-05-13 2007-12-20 チェイル インダストリーズ インコーポレイテッド 低線膨張熱可塑性樹脂組成物
WO2008026554A1 (en) * 2006-08-28 2008-03-06 Denki Kagaku Kogyo Kabushiki Kaisha Resin composition and molded body thereof

Also Published As

Publication number Publication date
CN108137899B (zh) 2019-06-28
US10865266B2 (en) 2020-12-15
JP2017110201A (ja) 2017-06-22
US20180282461A1 (en) 2018-10-04
JP6246304B2 (ja) 2017-12-13
CN108137899A (zh) 2018-06-08

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