TW457269B - Polyphosphate salt of a 1,3,5-triazine compound, a process for preparing the same, and flame retardant polymer composition containing the same as flame retardant - Google Patents
Polyphosphate salt of a 1,3,5-triazine compound, a process for preparing the same, and flame retardant polymer composition containing the same as flame retardant Download PDFInfo
- Publication number
- TW457269B TW457269B TW088111593A TW88111593A TW457269B TW 457269 B TW457269 B TW 457269B TW 088111593 A TW088111593 A TW 088111593A TW 88111593 A TW88111593 A TW 88111593A TW 457269 B TW457269 B TW 457269B
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- Taiwan
- Prior art keywords
- compound
- polyphosphate
- triazine
- triazine compound
- salt
- Prior art date
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- -1 1,3,5-triazine compound Chemical class 0.000 title claims abstract description 53
- 229920000388 Polyphosphate Polymers 0.000 title claims abstract description 52
- 239000001205 polyphosphate Substances 0.000 title claims abstract description 52
- 235000011176 polyphosphates Nutrition 0.000 title claims abstract description 52
- 239000000203 mixture Substances 0.000 title claims abstract description 44
- 229920000642 polymer Polymers 0.000 title claims abstract description 42
- 150000003839 salts Chemical class 0.000 title claims abstract description 31
- 239000003063 flame retardant Substances 0.000 title claims abstract description 30
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 26
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- 238000009833 condensation Methods 0.000 claims abstract description 21
- 230000005494 condensation Effects 0.000 claims abstract description 21
- 238000000034 method Methods 0.000 claims abstract description 21
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims abstract description 20
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 19
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 235000011007 phosphoric acid Nutrition 0.000 claims abstract description 10
- 239000010452 phosphate Substances 0.000 claims abstract description 9
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 8
- 229920000137 polyphosphoric acid Polymers 0.000 claims abstract description 6
- 238000002360 preparation method Methods 0.000 claims abstract description 5
- 125000004437 phosphorous atom Chemical group 0.000 claims abstract 6
- 239000002002 slurry Substances 0.000 claims abstract 2
- 229920000877 Melamine resin Polymers 0.000 claims description 34
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 33
- 150000001875 compounds Chemical class 0.000 claims description 26
- 239000003054 catalyst Substances 0.000 claims description 12
- 235000021317 phosphate Nutrition 0.000 claims description 12
- 238000011049 filling Methods 0.000 claims description 10
- 230000015572 biosynthetic process Effects 0.000 claims description 9
- 230000002079 cooperative effect Effects 0.000 claims description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 5
- 150000003918 triazines Chemical class 0.000 claims description 5
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 4
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical class C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- 239000011574 phosphorus Substances 0.000 claims description 4
- FIDRAVVQGKNYQK-UHFFFAOYSA-N 1,2,3,4-tetrahydrotriazine Chemical class C1NNNC=C1 FIDRAVVQGKNYQK-UHFFFAOYSA-N 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 claims description 2
- JIHQDMXYYFUGFV-UHFFFAOYSA-N 1,3,5-triazine Chemical compound C1=NC=NC=N1 JIHQDMXYYFUGFV-UHFFFAOYSA-N 0.000 claims description 2
- YZEZMSPGIPTEBA-UHFFFAOYSA-N 2-n-(4,6-diamino-1,3,5-triazin-2-yl)-1,3,5-triazine-2,4,6-triamine Chemical compound NC1=NC(N)=NC(NC=2N=C(N)N=C(N)N=2)=N1 YZEZMSPGIPTEBA-UHFFFAOYSA-N 0.000 claims description 2
- 239000003112 inhibitor Substances 0.000 claims description 2
- 239000008186 active pharmaceutical agent Substances 0.000 claims 1
- 125000004429 atom Chemical group 0.000 claims 1
- OAKJQQAXSVQMHS-UHFFFAOYSA-N hydrazine Substances NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims 1
- 238000006068 polycondensation reaction Methods 0.000 claims 1
- 239000012783 reinforcing fiber Substances 0.000 claims 1
- 150000000182 1,3,5-triazines Chemical class 0.000 description 10
- 239000003365 glass fiber Substances 0.000 description 7
- 239000000047 product Substances 0.000 description 7
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- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
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- 230000000052 comparative effect Effects 0.000 description 2
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- 235000011180 diphosphates Nutrition 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
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- 229910000449 hafnium oxide Inorganic materials 0.000 description 2
- WIHZLLGSGQNAGK-UHFFFAOYSA-N hafnium(4+);oxygen(2-) Chemical compound [O-2].[O-2].[Hf+4] WIHZLLGSGQNAGK-UHFFFAOYSA-N 0.000 description 2
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- 235000012907 honey Nutrition 0.000 description 2
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 2
- 229920000092 linear low density polyethylene Polymers 0.000 description 2
- 239000004707 linear low-density polyethylene Substances 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N perisophthalic acid Natural products OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- XFZRQAZGUOTJCS-UHFFFAOYSA-N phosphoric acid;1,3,5-triazine-2,4,6-triamine Chemical compound OP(O)(O)=O.NC1=NC(N)=NC(N)=N1 XFZRQAZGUOTJCS-UHFFFAOYSA-N 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- CMPGARWFYBADJI-UHFFFAOYSA-L tungstic acid Chemical class O[W](O)(=O)=O CMPGARWFYBADJI-UHFFFAOYSA-L 0.000 description 2
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 1
- PTJWCLYPVFJWMP-UHFFFAOYSA-N 2-[[3-hydroxy-2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)COCC(CO)(CO)CO PTJWCLYPVFJWMP-UHFFFAOYSA-N 0.000 description 1
- JQXYBDVZAUEPDL-UHFFFAOYSA-N 2-methylidene-5-phenylpent-4-enoic acid Chemical compound OC(=O)C(=C)CC=CC1=CC=CC=C1 JQXYBDVZAUEPDL-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- YCGKJPVUGMBDDS-UHFFFAOYSA-N 3-(6-azabicyclo[3.1.1]hepta-1(7),2,4-triene-6-carbonyl)benzamide Chemical compound NC(=O)C1=CC=CC(C(=O)N2C=3C=C2C=CC=3)=C1 YCGKJPVUGMBDDS-UHFFFAOYSA-N 0.000 description 1
- YKZUNWLMLRCVCW-UHFFFAOYSA-N 4-[2-(4-bicyclo[2.2.1]hept-2-enyl)ethyl]bicyclo[2.2.1]hept-2-ene Chemical compound C1CC(C2)C=CC21CCC1(C=C2)CC2CC1 YKZUNWLMLRCVCW-UHFFFAOYSA-N 0.000 description 1
- YUXBNNVWBUTOQZ-UHFFFAOYSA-N 4-phenyltriazine Chemical compound C1=CC=CC=C1C1=CC=NN=N1 YUXBNNVWBUTOQZ-UHFFFAOYSA-N 0.000 description 1
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- 229920001228 polyisocyanate Polymers 0.000 description 1
- 239000005056 polyisocyanate Substances 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001955 polyphenylene ether Polymers 0.000 description 1
- 229920000069 polyphenylene sulfide Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229930000044 secondary metabolite Natural products 0.000 description 1
- 239000011265 semifinished product Substances 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- XMVONEAAOPAGAO-UHFFFAOYSA-N sodium tungstate Chemical compound [Na+].[Na+].[O-][W]([O-])(=O)=O XMVONEAAOPAGAO-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- VKFFEYLSKIYTSJ-UHFFFAOYSA-N tetraazanium;phosphonato phosphate Chemical compound [NH4+].[NH4+].[NH4+].[NH4+].[O-]P([O-])(=O)OP([O-])([O-])=O VKFFEYLSKIYTSJ-UHFFFAOYSA-N 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 229910001930 tungsten oxide Inorganic materials 0.000 description 1
- 229920006305 unsaturated polyester Polymers 0.000 description 1
- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 1
- 229910000165 zinc phosphate Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
- C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
- C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
- C07D251/26—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with only hetero atoms directly attached to ring carbon atoms
- C07D251/40—Nitrogen atoms
- C07D251/54—Three nitrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
- C08K5/34928—Salts
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K21/00—Fireproofing materials
- C09K21/06—Organic materials
- C09K21/12—Organic materials containing phosphorus
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Fireproofing Substances (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL1009588A NL1009588C2 (nl) | 1998-07-08 | 1998-07-08 | Polyfosfaatzout van een 1,3,5-triazineverbinding met hoge condensatiegraad, een werkwijze voor de bereiding ervan en de toepassing als vlamdover in polymeersamenstellingen. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW457269B true TW457269B (en) | 2001-10-01 |
Family
ID=19767447
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW088111593A TW457269B (en) | 1998-07-08 | 1999-07-08 | Polyphosphate salt of a 1,3,5-triazine compound, a process for preparing the same, and flame retardant polymer composition containing the same as flame retardant |
Country Status (18)
| Country | Link |
|---|---|
| US (2) | US6369137B2 (enExample) |
| EP (1) | EP1095030B1 (enExample) |
| JP (2) | JP2002520322A (enExample) |
| KR (1) | KR100570863B1 (enExample) |
| CN (1) | CN1162407C (enExample) |
| AT (1) | ATE370937T1 (enExample) |
| AU (1) | AU758311B2 (enExample) |
| BR (1) | BR9911939B1 (enExample) |
| CA (1) | CA2336705C (enExample) |
| DE (1) | DE69936921T2 (enExample) |
| EA (1) | EA200100119A1 (enExample) |
| ES (1) | ES2292247T3 (enExample) |
| IL (1) | IL140755A (enExample) |
| NL (1) | NL1009588C2 (enExample) |
| NO (1) | NO20010077L (enExample) |
| PL (1) | PL345386A1 (enExample) |
| TW (1) | TW457269B (enExample) |
| WO (1) | WO2000002869A1 (enExample) |
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|---|---|---|---|---|
| DE19919707A1 (de) * | 1999-04-30 | 2000-11-02 | Clariant Gmbh | Brandschutzbeschichtung für Fasermaterialien |
| FR2794467B1 (fr) * | 1999-06-04 | 2004-08-20 | Rhodia Eng Plastics Srl | Composition de polyamide ignifugee |
| NL1014232C2 (nl) * | 2000-01-31 | 2001-08-01 | Dsm Nv | Zout van een melaminecondensatieproduct en een fosfor bevattend zuur. |
| JP4770006B2 (ja) * | 2000-06-30 | 2011-09-07 | 日立化成工業株式会社 | 樹脂組成物、積層板及び配線板 |
| JP4770005B2 (ja) * | 2000-06-30 | 2011-09-07 | 日立化成工業株式会社 | 樹脂組成物、積層板及び配線板 |
| NL1016340C2 (nl) † | 2000-10-05 | 2002-04-08 | Dsm Nv | Halogeenvrije vlamvertragende samenstelling en vlamdovende polyamidesamenstelling. |
| US6921783B2 (en) | 2001-06-29 | 2005-07-26 | Daicel Chemical Industries, Ltd. | Flame retardant polyolefin resin composition |
| EP1386942A1 (en) * | 2002-07-25 | 2004-02-04 | Clariant GmbH | Flame retardant combination |
| EP1563004A1 (en) * | 2002-11-21 | 2005-08-17 | Ciba SC Holding AG | Flame retardant composition comprising a phosphonic acid metal salt and a nitrogen-containing compound |
| US7482397B2 (en) * | 2003-01-13 | 2009-01-27 | Eastman Chemical Company | Polycarbonate compositions |
| US20040143041A1 (en) * | 2003-01-13 | 2004-07-22 | Pearson Jason Clay | Polyester compositions |
| US20040180994A1 (en) * | 2003-03-05 | 2004-09-16 | Pearson Jason Clay | Polyolefin compositions |
| JP2006519916A (ja) * | 2003-03-05 | 2006-08-31 | イーストマン ケミカル カンパニー | 紫外線吸収性化合物を含むポリマー組成物 |
| US7338992B2 (en) * | 2003-03-05 | 2008-03-04 | Eastman Chemical Company | Polyolefin compositions |
| US20060175587A1 (en) * | 2003-03-05 | 2006-08-10 | Kasowski Maya M | Reaction product of a phosphorous acid with ethyleneamines for flame resistance |
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| DE102004042833B4 (de) * | 2004-09-04 | 2022-01-05 | Chemische Fabrik Budenheim Kg | Polyphosphatderivat einer 1,3,5-Triazonverbindung, Verfahren zu dessen Herstellung und dessen Verwendung |
| DE102004050480A1 (de) | 2004-10-15 | 2006-04-27 | Chemische Fabrik Budenheim Kg | Pigment für laserbeschriftbare Kunststoffe und dessen Verwendung |
| DE102004050478A1 (de) | 2004-10-15 | 2006-04-27 | Chemische Fabrik Budenheim Kg | Formmasse für die Herstellung schwer entflammbarer Gegenstände, Pigment hierfür und dessen Verwendung |
| DE102004050479A1 (de) * | 2004-10-15 | 2006-04-27 | Chemische Fabrik Budenheim Kg | Formmasse für die Herstellung schwer entflammbarer Gegenstände, Pigment hierfür und dessen Verwendung |
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| DE102007036465A1 (de) * | 2007-08-01 | 2009-02-05 | Catena Additives Gmbh & Co. Kg | Phosphorhaltige Triazin-Verbindungen als Flammschutzmittel |
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| CN112409786B (zh) | 2020-10-12 | 2022-05-20 | 金发科技股份有限公司 | 一种低模垢无卤阻燃热塑性聚酰胺组合物及其制备方法和应用 |
| WO2022180221A1 (en) | 2021-02-25 | 2022-09-01 | Basf Se | Polymers having improved thermal conductivity |
| RU2758253C1 (ru) * | 2021-03-15 | 2021-10-27 | Федеральное государственное автономное образовательное учреждение высшего образования «Национальный исследовательский Томский государственный университет» | Способ получения полифосфата меламина |
| DE102021119326A1 (de) | 2021-07-26 | 2023-01-26 | Chemische Fabrik Budenheim Kg | Neuartiges Flammschutzmittel |
| CN114015060B (zh) * | 2021-12-07 | 2022-11-22 | 什邡市长丰化工有限公司 | 一种聚磷酸铵阻燃剂、其制备方法及应用 |
| WO2023156294A1 (en) * | 2022-02-18 | 2023-08-24 | Basf Se | Synthesis of melamine polyphosphate with low residual melamine |
| CN117106263A (zh) * | 2023-08-30 | 2023-11-24 | 中裕软管科技股份有限公司 | 一种消防水带用阻燃型epdm/pp热塑性弹性体材料及其制备方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1032941A (en) * | 1974-12-10 | 1978-06-13 | Encoat Chemicals Limited | Substituted ammonium polyphosphate composition |
| US4272414A (en) * | 1978-05-26 | 1981-06-09 | Monsanto Company | Chemical retardants for forest fires |
| DE2907453A1 (de) * | 1979-02-26 | 1980-09-04 | Benckiser Knapsack Gmbh | Verfahren zur kondensation von feststoffen sowie vorrichtung zur durchfuehrung des verfahrens |
| PL143704B1 (en) * | 1984-09-21 | 1988-03-31 | Inst Chemii Nieorganicznej | Method of obtaining melamine polyphosphate |
| JPS61106643A (ja) * | 1984-10-30 | 1986-05-24 | Marubishi Yuka Kogyo Kk | ポリオレフイン用難燃剤 |
| JPH068308B2 (ja) * | 1984-11-26 | 1994-02-02 | 株式会社三和ケミカル | 縮合リン酸アミノトリアジン化合物の製法 |
| JP3606970B2 (ja) * | 1995-10-27 | 2005-01-05 | ダイセル化学工業株式会社 | リン酸メラミンおよび難燃剤 |
| JP4051723B2 (ja) * | 1996-05-22 | 2008-02-27 | 日産化学工業株式会社 | ポリメタリン酸メラミン及びその製造法 |
| TW450972B (en) * | 1996-05-22 | 2001-08-21 | Nissan Chemical Ind Ltd | Melamine polymetaphosphate and process for its production |
| US6015510A (en) * | 1996-08-29 | 2000-01-18 | E. I. Du Pont De Nemours And Company | Polymer flame retardant |
| JP3867234B2 (ja) * | 1997-10-31 | 2007-01-10 | 燐化学工業株式会社 | 難溶性縮合リン酸メラミン及びその製造方法 |
-
1998
- 1998-07-08 NL NL1009588A patent/NL1009588C2/nl not_active IP Right Cessation
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1999
- 1999-07-07 CA CA002336705A patent/CA2336705C/en not_active Expired - Lifetime
- 1999-07-07 EP EP99931596A patent/EP1095030B1/en not_active Expired - Lifetime
- 1999-07-07 IL IL14075599A patent/IL140755A/en not_active IP Right Cessation
- 1999-07-07 BR BRPI9911939-0A patent/BR9911939B1/pt not_active IP Right Cessation
- 1999-07-07 EA EA200100119A patent/EA200100119A1/ru unknown
- 1999-07-07 PL PL99345386A patent/PL345386A1/xx not_active Application Discontinuation
- 1999-07-07 KR KR1020017000189A patent/KR100570863B1/ko not_active Expired - Lifetime
- 1999-07-07 WO PCT/NL1999/000426 patent/WO2000002869A1/en not_active Ceased
- 1999-07-07 CN CNB998101664A patent/CN1162407C/zh not_active Expired - Lifetime
- 1999-07-07 AT AT99931596T patent/ATE370937T1/de active
- 1999-07-07 ES ES99931596T patent/ES2292247T3/es not_active Expired - Lifetime
- 1999-07-07 DE DE69936921T patent/DE69936921T2/de not_active Expired - Lifetime
- 1999-07-07 AU AU48043/99A patent/AU758311B2/en not_active Expired
- 1999-07-07 JP JP2000559100A patent/JP2002520322A/ja active Pending
- 1999-07-08 TW TW088111593A patent/TW457269B/zh not_active IP Right Cessation
-
2001
- 2001-01-05 NO NO20010077A patent/NO20010077L/no not_active Application Discontinuation
- 2001-01-08 US US09/755,116 patent/US6369137B2/en not_active Expired - Lifetime
-
2002
- 2002-01-25 US US10/054,943 patent/US6653474B1/en not_active Expired - Lifetime
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2011
- 2011-06-16 JP JP2011133985A patent/JP2011174095A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| IL140755A (en) | 2004-07-25 |
| NL1009588C2 (nl) | 2000-01-11 |
| AU758311B2 (en) | 2003-03-20 |
| NO20010077D0 (no) | 2001-01-05 |
| JP2002520322A (ja) | 2002-07-09 |
| BR9911939B1 (pt) | 2010-06-01 |
| WO2000002869A1 (en) | 2000-01-20 |
| US20010005745A1 (en) | 2001-06-28 |
| KR20010053412A (ko) | 2001-06-25 |
| ES2292247T3 (es) | 2008-03-01 |
| CA2336705C (en) | 2009-03-17 |
| BR9911939A (pt) | 2001-03-27 |
| ATE370937T1 (de) | 2007-09-15 |
| IL140755A0 (en) | 2002-02-10 |
| PL345386A1 (en) | 2001-12-17 |
| CN1314898A (zh) | 2001-09-26 |
| EP1095030A1 (en) | 2001-05-02 |
| EP1095030B1 (en) | 2007-08-22 |
| DE69936921D1 (de) | 2007-10-04 |
| CA2336705A1 (en) | 2000-01-20 |
| US6369137B2 (en) | 2002-04-09 |
| EA200100119A1 (ru) | 2001-06-25 |
| CN1162407C (zh) | 2004-08-18 |
| NO20010077L (no) | 2001-03-02 |
| DE69936921T2 (de) | 2008-05-15 |
| AU4804399A (en) | 2000-02-01 |
| US6653474B1 (en) | 2003-11-25 |
| KR100570863B1 (ko) | 2006-04-12 |
| JP2011174095A (ja) | 2011-09-08 |
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