SU1612985A3 - Инсектоакарицидна композици - Google Patents

Инсектоакарицидна композици Download PDF

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Publication number
SU1612985A3
SU1612985A3 SU864028674A SU4028674A SU1612985A3 SU 1612985 A3 SU1612985 A3 SU 1612985A3 SU 864028674 A SU864028674 A SU 864028674A SU 4028674 A SU4028674 A SU 4028674A SU 1612985 A3 SU1612985 A3 SU 1612985A3
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USSR - Soviet Union
Prior art keywords
compound
proposed
osng
concentration
act
Prior art date
Application number
SU864028674A
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English (en)
Inventor
Не Харриберт
Бюманн Ульрих
Вегнер Петер
Йоппиен Хартмут
Джайлес Дэвид
Понт Роусон Грэхэм
Original Assignee
Шеринг Аг (Фирма)
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE19863628647 external-priority patent/DE3628647A1/de
Application filed by Шеринг Аг (Фирма) filed Critical Шеринг Аг (Фирма)
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Publication of SU1612985A3 publication Critical patent/SU1612985A3/ru

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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D231/00Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/06Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/38Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/65Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by splitting-off hydrogen atoms or functional groups; by hydrogenolysis of functional groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/70Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction with functional groups containing oxygen only in singly bound form
    • C07C45/71Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction with functional groups containing oxygen only in singly bound form being hydroxy groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/76Ketones containing a keto group bound to a six-membered aromatic ring
    • C07C49/84Ketones containing a keto group bound to a six-membered aromatic ring containing ether groups, groups, groups, or groups
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D401/00Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/12Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dentistry (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Plant Pathology (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Financial Or Insurance-Related Operations Such As Payment And Settlement (AREA)
  • Fats And Perfumes (AREA)
  • Transformer Cooling (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Measurement And Recording Of Electrical Phenomena And Electrical Characteristics Of The Living Body (AREA)
  • Radar Systems Or Details Thereof (AREA)
  • Farming Of Fish And Shellfish (AREA)

Abstract

Изобретение относитс  к химическому средству защиты растений от вредного воздействи  насекомых и клещей. Изобретение позвол ет повысить эффективность действи  предлагаемой композиции за счет того, что она содержит, мас.%: производные пиразолина формулы @ где X-OCH2CF3 или OCH2 @ , Y-CL или OCHF2 20
изофорон 75 и смесь нонилфенилполиоксиэтилена с кальцийдодецилбензолсульфонатом 5. 7 табл.

Description

Таблица 3
0«С-МН- Вг
гаемое (3) (1) (2)
ное
CFjCH O
«Ч. 0-C-NHHQ-OCHF2
СГзС1-Ц
6 С-МНнОк-С1
0,0004 0,00016
0,0004 0,00016
0,0004 0,00016
С -О гуСьа I 0,000473
Y0,0001657
0 C-NHHQ)-F
СГзСН.О-ОтТТ С ое (3)
V
0«C- 4H-Q-OCHr,
a-f - -r-Oci
ы(у
0
Y
0 C-NH ,Соединение
Предлагаемое
CTjCHjO-O-rT -F
Y oj
0 C-NHHQ -Ct
ci-O-йУТ Известное W
o c-NH-O-ci
To же
0 C-NH- F
Таблица 4
100 100
95 83
93 70
Таблица 5
2,5
2,5 2,5
50
Таблица 6
Концентраци  биологически активного вещества, %
80
0,1 0,1
20
20
г г Предлагаемое (1) Х„)
CHjO
же (2) .
СГзСН О
То же (3)
0-C-NH-O CI
CTjCH o-Q -O-f
O-C-NH- -OCHFj
Известное
Таблица 7
0,1
98
O -0 С-КНООСНГ7
м:
0,1
100
0,1
100
0,1
30

Claims (1)

  1. Формула изобретения
    Инсехтоакарицидная композиция, включающая производное пиразолина в качестве действующего начала, жидкий носитель и поверхностно-активное вещество, отличающаяся тем, что, с целью повышения эффективности •действия, в качестве производного пиразолина она содержит соединение формулы
    в качестве жидкого носителя - изофорон, а в качестве поверхностно-активного вещества - смесь нонилфенилполиоксиэтйлена с кальцийдодецилбензолсульфонатом при следующем соотношении компонентов, мас.%:
    Производное пиразолина ' 20
    Изофорок 75
    Смесь нонилфенилполчоксиэтилена с кальцийдодецил бензол сульфонатом 5
    5
    1612985
    6
    Т аг б л и ц а 1
    Соединение X Υ Т,пл., °С Г Г 1 осн2-^ оснг. 154-155 2 ОСН^СГз С1 180 3 оснгсг3 оснг2 153-154
    Таблица 2
    Соединение
    Концентрация Гибель, биолоически % активного вещества, %
    Предлагаемое
    е сг3ен20-О^^уО-г
    0,1 зо
    Известное
    о«с-~ш-£Уоснгг
    ’-Ч^а
    Ο=ΟΝΗ40-Γ
    ο,ι о
    Таблица 3
    Соединение Концентрация Действие, биологически % активного ве- щества, %
    Предлагаемое
    ос-ш-О-оснб
    0«С-ЫН-ф-Вг
    Известное
    : о-^-ин-ф-оснг,
    0,040 30 0,016 25 0,040 30 0,016 0 0,040 20 0,016 10 0,040 0 0,016 0
    7
    1612985 ' 8
    Таблица 4
    Соединение Концентрация Действие биологически спустя 7 активного вещества, % 48 ч, 7,
    Предлагаемое
    То же (1)
    Тц же (2)
    (3)
    О-С-ЫН-0-Г
    Г г
    О«С-КК-0-ОСНР2
    0,0004
    0,00016
    0,0004
    0,00016
    100
    100
    95
    83
    Известное
    Соединение
    <*3снго<2>^С>-г
    0=С-Ш~О-С1
    I
    Ο»€-ΝΗ-0-Γ
    0,0004
    0,00016
    0,0004
    0,00016
    73
    57
    93
    70
    Таблица 5
    Концентрация биологически активного вещества, млн ~1 Действие, 7а
    1 Предлагаемое СГзСНг0-О^уО-Г . Ο’-Ο-ΝΗ-θ-ΟΟΗΓ, 2,5 50 Известное ΟΟ-ΝΗ-θ-Βη 2,5 0 ο=ς-ΝΗ-θ-Γ 2,5 0
    Таблица 6
    .Соединение
    Концентрация биологически активного вещества, %
    Овицидное
    действие,
    7, с
    Предлагаемое
    Известное
    • То же
    ч/ о 1
    ι „ υ» 1
    0=С-МН-{УС1
    «О^гу-Ос, 0>|
    о=с-инч£Ус1
    О,,
    ОС-ΝΗ-θ-τ"
    80
    20
    20
    9
    1612985
    10
    Соединение
    .3.
    Таблица 7
    Концентрация биологически активного вещества, %
    •η
    Овицидное действие,%
    Предлагаемое О«С-ЫН-0-ОСНГ7 0,1 98 То же (2) . 0“С-МН-О-С1 0,1 100 То же (3) ОзСНгО-О^г-уО-г О-С-ЫН-0-ОСНГг ν4γ Ο’ό-ΝΗ-^-εΐ 0,1 100 Известное 0,1 30
SU864028674A 1985-12-21 1986-12-19 Инсектоакарицидна композици SU1612985A3 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19853545786 DE3545786A1 (de) 1985-12-21 1985-12-21 Pyrazolinderivate, ihre herstellung und ihre verwendung als mittel mit insektizider wirkung
DE19863628647 DE3628647A1 (de) 1986-08-22 1986-08-22 Pyrazolin-derivate, ihre herstellung und ihre verwendung als mittel mit insektizider und akarizider wirkung

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SU1612985A3 true SU1612985A3 (ru) 1990-12-07

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SU864028674A SU1612985A3 (ru) 1985-12-21 1986-12-19 Инсектоакарицидна композици

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US (1) US4888340A (ru)
EP (1) EP0227055B1 (ru)
JP (1) JPS62228064A (ru)
KR (1) KR940008289B1 (ru)
CN (1) CN1013671B (ru)
AT (1) ATE65994T1 (ru)
AU (1) AU600688B2 (ru)
BR (1) BR8606336A (ru)
CA (1) CA1283111C (ru)
CS (1) CS258495B2 (ru)
DD (1) DD259996A5 (ru)
DE (2) DE3545786A1 (ru)
DK (1) DK166208C (ru)
EG (1) EG18334A (ru)
ES (1) ES2040208T3 (ru)
FI (1) FI87773C (ru)
GR (1) GR3003067T3 (ru)
HU (2) HU204790B (ru)
IE (1) IE59522B1 (ru)
IL (1) IL81002A (ru)
MW (1) MW8086A1 (ru)
MX (1) MX168494B (ru)
MY (1) MY102540A (ru)
NZ (1) NZ218642A (ru)
OA (1) OA08455A (ru)
PH (1) PH24969A (ru)
PT (1) PT83961B (ru)
SU (1) SU1612985A3 (ru)
ZA (1) ZA869269B (ru)
ZW (1) ZW24786A1 (ru)

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DE4218745A1 (de) * 1992-06-04 1993-12-09 Schering Ag 1-(4-Cyanophenyl-carbamoyl)-pyrazoline

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US5756340A (en) * 1995-05-08 1998-05-26 The Regents Of The University Of California Insect control with multiple toxins
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TWI356822B (en) 2001-08-13 2012-01-21 Du Pont Novel substituted dihydro 3-halo-1h-pyrazole-5-car
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US8378281B2 (en) 2008-10-24 2013-02-19 Suncore Photovoltaics, Inc. Terrestrial solar tracking photovoltaic array with offset solar cell modules
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4218745A1 (de) * 1992-06-04 1993-12-09 Schering Ag 1-(4-Cyanophenyl-carbamoyl)-pyrazoline

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FI865233A (fi) 1987-06-22
CN1013671B (zh) 1991-08-28
FI865233A0 (fi) 1986-12-19
DK166208B (da) 1993-03-22
GR3003067T3 (en) 1993-02-17
HUT45021A (en) 1988-05-30
NZ218642A (en) 1990-02-26
DE3680772D1 (de) 1991-09-12
DD259996A5 (de) 1988-09-14
FI87773C (fi) 1993-02-25
MX168494B (es) 1993-05-27
IL81002A (en) 1991-07-18
CA1283111C (en) 1991-04-16
PT83961A (de) 1987-01-01
IE863330L (en) 1987-06-21
JPS62228064A (ja) 1987-10-06
ZA869269B (en) 1987-07-29
AU6680586A (en) 1987-06-25
EP0227055A1 (en) 1987-07-01
CN86108628A (zh) 1987-07-01
US4888340A (en) 1989-12-19
DK166208C (da) 1993-08-16
AU600688B2 (en) 1990-08-23
MW8086A1 (en) 1987-12-09
OA08455A (fr) 1988-06-30
ATE65994T1 (de) 1991-08-15
EG18334A (en) 1992-11-30
PH24969A (en) 1990-12-26
DK611686A (da) 1987-06-22
KR940008289B1 (ko) 1994-09-10
DK611686D0 (da) 1986-12-18
ZW24786A1 (en) 1987-06-17
ES2040208T3 (es) 1993-10-16
KR870006001A (ko) 1987-07-08
BR8606336A (pt) 1987-10-06
PT83961B (pt) 1989-05-12
CS960586A2 (en) 1988-01-15
EP0227055B1 (en) 1991-08-07
CS258495B2 (en) 1988-08-16
MY102540A (en) 1992-07-31
IE59522B1 (en) 1994-03-09
IL81002A0 (en) 1987-03-31
HU204790B (en) 1992-02-28
DE3545786A1 (de) 1987-06-25
FI87773B (fi) 1992-11-13

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