RU2360931C2 - Металлоценовые катализаторы, их синтез и их применение для полимеризации олефинов - Google Patents

Металлоценовые катализаторы, их синтез и их применение для полимеризации олефинов Download PDF

Info

Publication number
RU2360931C2
RU2360931C2 RU2007124637/04A RU2007124637A RU2360931C2 RU 2360931 C2 RU2360931 C2 RU 2360931C2 RU 2007124637/04 A RU2007124637/04 A RU 2007124637/04A RU 2007124637 A RU2007124637 A RU 2007124637A RU 2360931 C2 RU2360931 C2 RU 2360931C2
Authority
RU
Russia
Prior art keywords
methyl
indenyl
zirconium dichloride
carbon atoms
bis
Prior art date
Application number
RU2007124637/04A
Other languages
English (en)
Russian (ru)
Other versions
RU2007124637A (ru
Inventor
Никола ПАЧКОВСКИ (US)
Никола ПАЧКОВСКИ
Андреас ВИНТЕР (DE)
Андреас Винтер
Франц ЛАНГХАУЗЕР (DE)
Франц Лангхаузер
Original Assignee
Новолен Текнолоджи Холдингз С.В.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Новолен Текнолоджи Холдингз С.В. filed Critical Новолен Текнолоджи Холдингз С.В.
Publication of RU2007124637A publication Critical patent/RU2007124637A/ru
Application granted granted Critical
Publication of RU2360931C2 publication Critical patent/RU2360931C2/ru

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/655—Pretreating with metals or metal-containing compounds with aluminium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/38—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of titanium, zirconium or hafnium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/02—Carriers therefor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
RU2007124637/04A 2004-12-01 2005-12-01 Металлоценовые катализаторы, их синтез и их применение для полимеризации олефинов RU2360931C2 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/001,272 2004-12-01
US11/001,272 US7169864B2 (en) 2004-12-01 2004-12-01 Metallocene catalysts, their synthesis and their use for the polymerization of olefins

Publications (2)

Publication Number Publication Date
RU2007124637A RU2007124637A (ru) 2009-01-10
RU2360931C2 true RU2360931C2 (ru) 2009-07-10

Family

ID=36129857

Family Applications (1)

Application Number Title Priority Date Filing Date
RU2007124637/04A RU2360931C2 (ru) 2004-12-01 2005-12-01 Металлоценовые катализаторы, их синтез и их применение для полимеризации олефинов

Country Status (13)

Country Link
US (3) US7169864B2 (US07169864-20070130-C00012.png)
EP (1) EP1828266B1 (US07169864-20070130-C00012.png)
JP (2) JP5311827B2 (US07169864-20070130-C00012.png)
KR (1) KR101354477B1 (US07169864-20070130-C00012.png)
CN (2) CN101124252B (US07169864-20070130-C00012.png)
AR (2) AR052985A1 (US07169864-20070130-C00012.png)
BR (1) BRPI0518701B8 (US07169864-20070130-C00012.png)
ES (1) ES2548726T3 (US07169864-20070130-C00012.png)
MX (1) MX2007006313A (US07169864-20070130-C00012.png)
RU (1) RU2360931C2 (US07169864-20070130-C00012.png)
SG (1) SG158099A1 (US07169864-20070130-C00012.png)
WO (1) WO2006060544A1 (US07169864-20070130-C00012.png)
ZA (1) ZA200704403B (US07169864-20070130-C00012.png)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2805112C2 (ru) * 2018-11-06 2023-10-11 Дау Глоубл Текнолоджиз Ллк Способ полимеризации олефинов с применением неметаллоценового предкатализатора, растворимого в алканах

Families Citing this family (107)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7169864B2 (en) * 2004-12-01 2007-01-30 Novolen Technology Holdings, C.V. Metallocene catalysts, their synthesis and their use for the polymerization of olefins
US7598329B2 (en) * 2005-11-04 2009-10-06 Ticona Gmbh Process for manufacturing ultra high molecular weight polymers using novel bridged metallocene catalysts
US8034886B2 (en) 2005-11-04 2011-10-11 Ticona Gmbh Process for manufacturing high to ultra high molecular weight polymers using novel bridged metallocene catalysts
DE102005052654A1 (de) * 2005-11-04 2007-05-16 Ticona Gmbh Verfahren zur Herstellung von ultrahochmolekularen Polymeren unter Verwendung von speziellen verbrückten Metallocen-Katalysatoren
US20070299222A1 (en) 2006-04-04 2007-12-27 Fina Technology, Inc. Transition metal catalysts and formation thereof
US7683002B2 (en) * 2006-04-04 2010-03-23 Fina Technology, Inc. Transition metal catalyst and formation thereof
EP1930348A1 (en) * 2006-12-05 2008-06-11 Ineos Manufacturing France SAS Supported catalyst system
RU2476449C2 (ru) 2007-10-25 2013-02-27 Люммус Новолен Текнолоджи Гмбх Рацемоселективный синтез анса-металлоценовых соединений, анса-металлоценовые соединения, катализаторы, содержащие их, способ получения олефинового полимера с использованием катализаторов и олефиновые гомо- и сополимеры
EP2235071A2 (en) 2007-10-25 2010-10-06 Novolen Technology Holdings, C.V. Metallocene compounds, catalysts comprising them, process for producing an olefin polymer by use of the catalysts, and olefin homo and copolymers
EP2203483B1 (en) * 2007-10-25 2014-04-09 Lummus Novolen Technology Gmbh Metallocene compounds, catalysts comprising them, process for producing an olefin polymer by use of the catalysts, and olefin homo-and copolymers
TW200936619A (en) 2007-11-15 2009-09-01 Univation Tech Llc Polymerization catalysts, methods of making, methods of using, and polyolefin products made therefrom
KR101271055B1 (ko) * 2008-03-28 2013-06-04 에스케이종합화학 주식회사 메탈로센 담지촉매 조성물 및 이를 이용한 폴리올레핀의제조방법
US8076429B2 (en) * 2009-03-11 2011-12-13 Lummus Novolen Technology Gmbh Supertransparent high impact strength random block copolymer
KR101050791B1 (ko) * 2009-10-19 2011-07-20 주식회사 엘지화학 혼성 담지 메탈로센 촉매의 제조방법 및 이를 이용하여 제조된 혼성 담지 메탈로센 촉매
BR112012013675A2 (pt) 2009-12-07 2016-04-19 Univation Tech Llc métodos para a produção de carga estática de um catalisador e métodos para o uso do catalisador para produzir poliolefinas
CN102666603B (zh) * 2009-12-22 2014-10-15 北欧化工公司 在单活性中心催化剂存在的情况下的聚丙烯制备
ES2543635T3 (es) 2010-02-18 2015-08-20 Univation Technologies, Llc Métodos para operación de un reactor de polimerización
MY162328A (en) 2010-02-22 2017-05-31 Univation Tech Llc Catalyst systems and methods for using same to produce polyolefin products
CN102781972B (zh) 2010-03-08 2014-09-17 Lg化学株式会社 负载型茂金属催化剂、制备该催化剂的方法以及使用该催化剂制备聚烯烃的方法
BR112012025925B1 (pt) 2010-04-13 2020-03-17 Univation Technologies, Llc Mistura polimérica e filme
EP2738183A1 (en) 2010-05-07 2014-06-04 Borealis AG Preparation of a solid catalyst system
ES2565438T3 (es) 2010-07-01 2016-04-04 Borealis Ag Proceso para la polimerización de olefinas usando metalocenos del grupo 4 como catalizadores
EP2402353B1 (en) 2010-07-01 2018-04-25 Borealis AG Group 4 metallocenes useful as catalysts for the polymerization of olefins
CN103097015B (zh) 2010-07-16 2015-11-25 尤尼威蒂恩技术有限责任公司 测量反应器表面上颗粒积聚的系统与方法
WO2012009215A1 (en) 2010-07-16 2012-01-19 Univation Technologies, Llc Systems and methods for measuring static charge on particulates
WO2012015898A1 (en) 2010-07-28 2012-02-02 Univation Technologies, Llc Systems and methods for measuring velocity of a particle/fluid mixture
EP2633104A1 (en) 2010-10-28 2013-09-04 Lummus Novolen Technology Gmbh Nonwoven and yarn polypropylene with additivation
US20120116034A1 (en) 2010-11-08 2012-05-10 Dow Global Technologies, Inc. Solution polymerization process and procatalyst carrier systems useful therein
CN103228682B (zh) 2010-11-30 2015-07-22 尤尼威蒂恩技术有限责任公司 用经萃取的金属羧酸盐聚合烯烃的方法
CN103298843B (zh) 2010-11-30 2015-08-19 尤尼威蒂恩技术有限责任公司 具有改进的流动特征的催化剂组合物及其制造和使用方法
EP2651982B1 (en) 2010-12-17 2018-04-11 Univation Technologies, LLC Systems and methods for recovering hydrocarbons from a polyolefin purge gas product
BR112013016116B1 (pt) 2010-12-22 2020-04-28 Univation Tech Llc processo de polimerização e sistema catalisador
WO2012084961A1 (en) 2010-12-22 2012-06-28 Borealis Ag Bridged metallocene catalysts
EP2707398B1 (en) 2011-05-13 2017-08-09 Univation Technologies, LLC Spray-dried catalyst compositions and polymerization processes employing the same
WO2013028283A1 (en) 2011-08-19 2013-02-28 Univation Technologies, Llc Catalyst systems and methods for using same to produce polyolefin products
KR101485567B1 (ko) * 2011-09-07 2015-01-23 주식회사 엘지화학 담지 메탈로센 촉매의 제조방법 및 이를 이용하여 제조된 담지 메탈로센 촉매
EP2573091A1 (en) 2011-09-23 2013-03-27 Lummus Novolen Technology Gmbh Process for recycling of free ligand from their corresponding metallocene complexes
EP2776476B1 (en) 2011-11-08 2019-03-13 Univation Technologies, LLC Methods for producing polyolefins with catalyst systems
BR112014010900B1 (pt) 2011-11-08 2020-02-18 Univation Technologies, Llc Método de preparar um sistema de catalisador, sistema catalisador e processo de polimerização
EP2722344B1 (en) 2012-10-18 2017-03-22 Borealis AG Polymerisation process
ES2711081T3 (es) 2012-10-18 2019-04-30 Borealis Ag Catalizador para la polimerización de olefinas
EP2722346A1 (en) 2012-10-18 2014-04-23 Borealis AG Polymerisation process and catalyst
EP4039366A1 (en) 2012-12-28 2022-08-10 Univation Technologies, LLC Supported catalyst with improved flowability
WO2014120494A1 (en) 2013-01-30 2014-08-07 Univation Technologies, Llc Processes for making catalyst compositions having improved flow
EP4223802A3 (en) 2013-02-07 2023-10-25 Univation Technologies, LLC Polymerization catalyst
EP2970526B1 (en) 2013-03-15 2017-08-09 Univation Technologies, LLC Ligands for catalysts
CN105143281B (zh) 2013-03-15 2018-06-01 尤尼威蒂恩技术有限责任公司 用于烯烃聚合催化剂的三齿氮类配体
CN105308007B (zh) 2013-06-05 2017-07-21 尤尼威蒂恩技术有限责任公司 保护酚基
WO2015009471A1 (en) 2013-07-17 2015-01-22 Exxonmobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
US9938364B2 (en) 2013-07-17 2018-04-10 Exxonmobil Chemical Patents Inc. Substituted metallocene catalysts
CN105358589B (zh) 2013-07-17 2018-07-03 埃克森美孚化学专利公司 金属茂和由其衍生的催化剂组合物
SG10201802959WA (en) 2013-07-17 2018-05-30 Exxonmobil Chemical Patents Inc Cyclopropyl substituted metallocene catalysts
EP3848401A1 (en) 2013-07-17 2021-07-14 ExxonMobil Chemical Patents Inc. Isotactic propylene polymers
KR101721194B1 (ko) * 2013-11-28 2017-03-29 주식회사 엘지화학 담지 메탈로센 촉매의 제조방법
CA2943378C (en) 2014-04-02 2023-09-12 Univation Technologies, Llc Continuity compositions and methods of making and using the same
WO2016028277A1 (en) 2014-08-19 2016-02-25 Univation Technologies, Llc Fluorinated catalyst supports and catalyst systems
US10208139B2 (en) 2014-08-19 2019-02-19 Univation Technologies, Llc Fluorinated catalyst supports and catalyst systems
CN106714967B (zh) 2014-08-19 2020-07-17 尤尼威蒂恩技术有限责任公司 氟化催化剂载体和催化剂系统
KR101653356B1 (ko) * 2014-10-17 2016-09-01 주식회사 엘지화학 고분자량 폴리올레핀 제조용 메탈로센 촉매 및 이의 제조방법
CN105622795B (zh) * 2014-10-28 2019-02-19 中国石油化工股份有限公司 茂金属催化剂组合物及其制备方法
KR101653357B1 (ko) * 2014-11-06 2016-09-01 주식회사 엘지화학 고분자량 폴리올레핀 제조용 메탈로센 촉매 및 이의 제조방법
CA2974122C (en) 2015-01-21 2023-09-19 Univation Technologies, Llc Methods for gel reduction in polyolefins
SG11201705607QA (en) 2015-01-21 2017-08-30 Univation Tech Llc Methods for controlling polymer chain scission
EP3268399B1 (en) 2015-03-10 2021-01-20 Univation Technologies, LLC Spray dried catalyst compositions, methods for preparation and use in olefin polymerization processes
EP3280742B1 (en) 2015-04-08 2019-02-20 Univation Technologies, LLC Closed reactor transitions between metallocene catalysts
US10533063B2 (en) 2015-04-20 2020-01-14 Exxonmobil Chemical Patents Inc. Supported catalyst systems and processes for use thereof
BR112017023052B1 (pt) 2015-04-27 2022-05-10 Univation Technologies, Llc Composição de catalisador de polimerização de poliolefina suportada e método para a produção de composição de catalisador de polimerização de olefina suportada
KR102080640B1 (ko) * 2015-12-23 2020-05-27 주식회사 엘지화학 혼성 담지 촉매 및 이를 이용하는 올레핀계 중합체의 제조방법
KR101969123B1 (ko) 2016-02-17 2019-08-20 주식회사 엘지화학 고강성 및 에너지 절감 발포용 폴리프로필렌
KR102064412B1 (ko) 2016-07-07 2020-01-09 주식회사 엘지화학 폴리올레핀 제조용 메탈로센 촉매의 제조방법
WO2018009016A2 (ko) * 2016-07-07 2018-01-11 주식회사 엘지화학 폴리올레핀 제조용 메탈로센 촉매의 제조방법
KR102206479B1 (ko) * 2016-12-26 2021-01-21 주식회사 엘지화학 담지 메탈로센 촉매의 제조방법
WO2018151903A1 (en) 2017-02-20 2018-08-23 Exxonmobil Chemical Patents Inc. Supported catalyst systems and processes for use thereof
EP3661981A1 (en) 2017-08-04 2020-06-10 ExxonMobil Chemical Patents Inc. Polyethylene compositions and films prepared therefrom
US11021552B2 (en) * 2017-10-31 2021-06-01 Exxonmobil Chemical Patents Inc. Toluene free silica supported single-site metallocene catalysts from in-situ supported alumoxane formation in aliphatic solvents
WO2019103306A1 (ko) * 2017-11-27 2019-05-31 주식회사 엘지화학 폴리프로필렌 및 그 제조방법
KR102326791B1 (ko) * 2017-11-27 2021-11-16 주식회사 엘지화학 폴리프로필렌 및 그 제조방법
KR102405286B1 (ko) * 2017-12-06 2022-06-02 주식회사 엘지화학 메탈로센 담지 촉매의 제조방법, 상기 제조방법으로 제조된 메탈로센 담지 촉매, 및 이를 제조하여 제조한 폴리프로필렌
KR102464410B1 (ko) * 2017-12-14 2022-11-04 주식회사 엘지화학 필라멘트용 폴리프로필렌 및 그 제조방법
KR102343937B1 (ko) 2017-12-26 2021-12-27 주식회사 엘지화학 메탈로센 담지 촉매 및 이를 이용한 폴리프로필렌의 제조 방법
KR102342780B1 (ko) * 2018-02-08 2021-12-23 주식회사 엘지화학 혼성 담지 메탈로센 촉매의 제조방법
WO2019156482A1 (ko) * 2018-02-08 2019-08-15 주식회사 엘지화학 혼성 담지 메탈로센 촉매의 제조방법
WO2019210026A1 (en) 2018-04-26 2019-10-31 Exxonmobil Chemical Patents Inc. Non-coordinating anion type activators containing cation having large alkyl groups
WO2019215122A1 (en) * 2018-05-09 2019-11-14 Borealis Ag Process for preparing propylene copolymers comprising c4-c12-alpha olefin comonomer units
WO2019246069A1 (en) 2018-06-19 2019-12-26 Exxonmobil Chemical Patents Inc. Polyethylene compositions and films prepared therefrom
KR102431269B1 (ko) 2018-11-02 2022-08-10 주식회사 엘지화학 신규 전이금속 화합물 및 이를 이용한 폴리프로필렌의 제조방법
KR102388031B1 (ko) 2018-11-06 2022-04-19 주식회사 엘지화학 펠렛형 폴리프로필렌 수지 및 그 제조방법
KR102372221B1 (ko) * 2018-11-06 2022-03-10 주식회사 엘지화학 프로필렌 공중합체 수지 조성물 및 그 제조방법
KR102576669B1 (ko) * 2018-12-26 2023-09-11 주식회사 엘지화학 메탈로센 담지 촉매 및 이를 이용한 올레핀계 중합체의 제조방법
JP2022534114A (ja) 2019-05-29 2022-07-27 ボレアリス エージー 触媒系
WO2021001176A1 (en) 2019-07-04 2021-01-07 Borealis Ag Long chain branched propylene polymer composition
KR102482938B1 (ko) * 2019-09-30 2022-12-29 주식회사 엘지화학 펠렛형 폴리프로필렌 수지 조성물 및 그 제조방법
WO2021119089A1 (en) 2019-12-11 2021-06-17 Exxonmobil Chemical Patents Inc. Processes for introduction of liquid activators in olefin polymerization reactions
WO2021126523A1 (en) 2019-12-19 2021-06-24 Exxonmobil Chemical Patents Inc. Production of impact copolymer polypropylene using metallocene and ziegler-natta catalysts in parallel reactors
US11613593B2 (en) 2020-02-24 2023-03-28 Exxonmobil Chemical Patents Inc. Ansa-bis(inden-2-yl) catalysts for producing vinylidene-terminated polyalphaolefins
WO2021194831A1 (en) 2020-03-25 2021-09-30 Exxonmobil Chemical Patents Inc. Alkylation of transition metal coordination catalyst complexes
WO2021262842A1 (en) 2020-06-26 2021-12-30 Exxonmobil Chemical Patents Inc. COPOLYMERS OF ETHYLENE, α-OLEFIN, NON-CONJUGATED DIENE, AND ARYL-SUBSTITUTED CYCLOALKENE, METHODS TO PRODUCE, BLENDS, AND ARTICLES THEREFROM
WO2021262838A1 (en) 2020-06-26 2021-12-30 Exxonmobil Chemical Patents Inc. Copolymers composed of ethylene, a-olefin, non-conjugated diene, and substituted styrene and articles therefrom
EP4185622A1 (en) 2020-07-23 2023-05-31 Borealis AG Metallocene complexes and catalysts made therefrom
EP4192888A1 (en) 2020-08-10 2023-06-14 ExxonMobil Chemical Patents Inc. Methods for delivery of non-aromatic solutions to polymerization reactors
CN117561285A (zh) 2021-06-24 2024-02-13 博里利斯股份公司 溶胀剂在多阶段聚烯烃生产中的用途
WO2022268953A1 (en) 2021-06-24 2022-12-29 Borealis Ag Process for producing polyethylene polymers
WO2022268959A1 (en) 2021-06-24 2022-12-29 Borealis Ag Improving catalyst performance in multi-stage polyolefin production
BR112023026990A2 (pt) 2021-06-24 2024-03-12 Borealis Ag Processo para polimerização de olefinas com distribuição estreita de tamanho de partícula
CA3223017A1 (en) 2021-06-24 2022-12-29 Pascal Castro Method for determining compressive character of olefin polymerisation catalysts
CN117561287A (zh) 2021-06-24 2024-02-13 博里利斯股份公司 1-己烯在多阶段聚烯烃生产中的利用
CN117467055A (zh) * 2023-02-03 2024-01-30 中化学科学技术研究有限公司 一种茂金属催化剂及其制备方法和应用

Family Cites Families (103)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US614032A (en) * 1898-11-08 bpicer
US628795A (en) * 1899-05-13 1899-07-11 Charles Bradley Harkness Door-check.
DE3127133A1 (de) 1981-07-09 1983-01-27 Hoechst Ag, 6000 Frankfurt Verfahren zur herstellung von polyolefinen und deren copolymerisaten
US5324800A (en) 1983-06-06 1994-06-28 Exxon Chemical Patents Inc. Process and catalyst for polyolefin density and molecular weight control
US4530914A (en) 1983-06-06 1985-07-23 Exxon Research & Engineering Co. Process and catalyst for producing polyethylene having a broad molecular weight distribution
US4937299A (en) 1983-06-06 1990-06-26 Exxon Research & Engineering Company Process and catalyst for producing reactor blend polyolefins
DE3508887A1 (de) 1985-03-13 1986-09-25 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von optisch aktiven polyolefinen
US4808561A (en) 1985-06-21 1989-02-28 Exxon Chemical Patents Inc. Supported polymerization catalyst
US4701432A (en) * 1985-11-15 1987-10-20 Exxon Chemical Patents Inc. Supported polymerization catalyst
US4752597A (en) 1985-12-12 1988-06-21 Exxon Chemical Patents Inc. New polymerization catalyst
US5384299A (en) 1987-01-30 1995-01-24 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5198401A (en) 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
PL276385A1 (en) 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
DE3726067A1 (de) 1987-08-06 1989-02-16 Hoechst Ag Verfahren zur herstellung von 1-olefinpolymeren
US4931417A (en) 1987-11-09 1990-06-05 Chisso Corporation Transition-metal compound having a bis-substituted-cyclopentadienyl ligand of bridged structure
DE3808268A1 (de) 1988-03-12 1989-09-21 Hoechst Ag Verfahren zur herstellung eines 1-olefinpolymers
US5120867A (en) 1988-03-21 1992-06-09 Welborn Jr Howard C Silicon-bridged transition metal compounds
US5017714A (en) 1988-03-21 1991-05-21 Exxon Chemical Patents Inc. Silicon-bridged transition metal compounds
US4871705A (en) 1988-06-16 1989-10-03 Exxon Chemical Patents Inc. Process for production of a high molecular weight ethylene a-olefin elastomer with a metallocene alumoxane catalyst
DE3907964A1 (de) 1989-03-11 1990-09-13 Hoechst Ag Verfahren zur herstellung eines syndiotaktischen polyolefins
US5057475A (en) 1989-09-13 1991-10-15 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization
US5026798A (en) 1989-09-13 1991-06-25 Exxon Chemical Patents Inc. Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system
US5239022A (en) 1990-11-12 1993-08-24 Hoechst Aktiengesellschaft Process for the preparation of a syndiotactic polyolefin
ES2090209T3 (es) 1990-11-12 1996-10-16 Hoechst Ag Metalocenos con ligandos basados en derivados de indenilo sustituidos en posicion 2, procedimiento para su preparacion y su empleo como catalizadores.
US5243001A (en) 1990-11-12 1993-09-07 Hoechst Aktiengesellschaft Process for the preparation of a high molecular weight olefin polymer
DE59104869D1 (de) 1990-11-12 1995-04-13 Hoechst Ag 2-Substituierte Bisindenylmetallocene, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren bei der Olefinpolymerisation.
US5436305A (en) 1991-05-09 1995-07-25 Phillips Petroleum Company Organometallic fluorenyl compounds, preparation, and use
DE4120009A1 (de) 1991-06-18 1992-12-24 Basf Ag Loesliche katalysatorsysteme zur herstellung von polyalk-1-enen mit hohen molmassen
TW300901B (US07169864-20070130-C00012.png) 1991-08-26 1997-03-21 Hoechst Ag
DE59210001D1 (de) 1991-10-15 2005-02-17 Basell Polyolefine Gmbh Verfahren zur Herstellung eines Olefinpolymers unter Verwendung von Metallocenen mit speziell substituierten Indenylliganden
US5359015A (en) 1991-11-07 1994-10-25 Exxon Chemical Patents Inc. Metallocene catalysts and their production and use
US5932669A (en) 1991-11-30 1999-08-03 Targor Gmbh Metallocenes having benzo-fused indenyl derivatives as ligands, processes for their preparation and their use as catalysts
TW309523B (US07169864-20070130-C00012.png) 1991-11-30 1997-07-01 Hoechst Ag
TW318184B (US07169864-20070130-C00012.png) 1991-11-30 1997-10-21 Hoechst Ag
ES2093166T3 (es) 1991-11-30 1996-12-16 Hoechst Ag Metalocenos con derivados de indenilo condensados con benzo como ligandos, procedimiento para su preparacion y su utilizacion como catalizadores.
US5830821A (en) 1991-11-30 1998-11-03 Targor Gmbh Process for olefin preparation using metallocenes having benzo-fused indenyl derivatives as ligands
US5350723A (en) 1992-05-15 1994-09-27 The Dow Chemical Company Process for preparation of monocyclopentadienyl metal complex compounds and method of use
US5240894A (en) 1992-05-18 1993-08-31 Exxon Chemical Patents Inc. Method for making and using a supported metallocene catalyst system
DK0574597T3 (da) 1992-06-13 1998-09-14 Targor Gmbh Fremgangsmåde til fremstilling af brosluttede chirale metallocenkatalysatorer af bisindenyltypen
TW294669B (US07169864-20070130-C00012.png) 1992-06-27 1997-01-01 Hoechst Ag
EP0882731A3 (de) 1992-08-15 2000-05-31 TARGOR GmbH Verbrückte Metallocenverbindungen und ihre Verwendung als Olefinpolymerisationskatalysatore
JP3307704B2 (ja) 1993-02-19 2002-07-24 三菱化学株式会社 α‐オレフィン重合体の製造法
CA2125247C (en) 1993-06-07 2001-02-20 Daisuke Fukuoka Transition metal compound, olefin polymerization catalyst component comprising said compound, olefin polymerization catalyst containing said catalyst component, process for olefinpolymerization using said catalyst , propylene homopolymer, propylene copolymer and propylene elastomer
DE69431222T2 (de) 1993-06-07 2003-04-17 Mitsui Chemicals Inc Übergangsmetallverbindung, und diese enthaltender Polymerisationkatalysator
JPH06345816A (ja) * 1993-06-14 1994-12-20 Mitsui Toatsu Chem Inc 固体触媒成分およびこれを用いたオレフィンの重合方法
CN1078213C (zh) * 1993-11-08 2002-01-23 尤利维森技术司 乙烯的聚合或共聚方法
JP3423378B2 (ja) 1993-11-12 2003-07-07 三井化学株式会社 新規な遷移金属化合物および該遷移金属化合物からなるオレフィン重合用触媒成分、該オレフィン重合用触媒成分を含むオレフィン重合用触媒ならびにオレフィンの重合方法
DE4344689A1 (de) 1993-12-27 1995-06-29 Hoechst Ag Metallocenverbindung
DE4344688A1 (de) 1993-12-27 1995-06-29 Hoechst Ag Metallocenverbindung
JP3794700B2 (ja) 1994-06-24 2006-07-05 エクソンモービル・ケミカル・パテンツ・インク 重合触媒系、それらの製造及び使用
US6140432A (en) 1995-07-13 2000-10-31 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
US6124230A (en) 1995-07-13 2000-09-26 Exxon Chemical Patents, Inc. Polymerization catalyst systems, their production and use
US6166153A (en) * 1995-07-18 2000-12-26 Fina Technology, Inc. Process for the syndiotactic propagation of olefins
US5635437A (en) 1995-07-28 1997-06-03 Exxon Chemicals Patents, Inc. Method for preparing metallocene catalyst systems
ES2104455T3 (es) 1995-09-13 1997-10-01 Witco Gmbh Procedimiento para la preparacion de sistemas cataliticos de metaloceno sobre materiales inertes de soporte, con utilizacion de reactores de fase de gas.
CA2241812A1 (en) * 1995-09-28 1997-04-03 Cornelia Fritze Supported catalyst system, process for its production and its use in polymerising olefines
DE19544828A1 (de) 1995-12-01 1997-06-05 Hoechst Ag Hochmolekulare Copolymere
KR100473546B1 (ko) * 1996-06-11 2005-05-16 바스프 악티엔게젤샤프트 담체로서무기산화물을이용한메탈로센촉매시스템
AU718884B2 (en) 1996-06-17 2000-04-20 Exxon Chemical Patents Inc. Mixed transition metal catalyst systems for olefin polymerization
KR20000022440A (ko) * 1996-07-04 2000-04-25 스타르크, 카르크 담지된 전이 금속 촉매의 제조 방법
DE69722902T2 (de) 1996-12-09 2004-05-19 Mitsubishi Chemical Corp. Katalysator für Alpha-Olefinpolymerisation
KR19980051220A (ko) * 1996-12-23 1998-09-15 김종진 유동성 실리카를 이용한 담지형 알루미녹산의 제조방법
WO1998031690A1 (en) 1997-01-21 1998-07-23 Mitsubishi Chemical Corporation ORGANIC COMPOUNDS CONTAINING SILICON OR GERMANIUM, TRANSITION METAL COMPLEXES, CATALYST FOR α-OLEFIN POLYMERIZATION, AND PROCESSES FOR PRODUCING α-OLEFIN POLYMERS
DE19757563A1 (de) 1997-03-07 1999-07-08 Targor Gmbh Geträgertes Katalysatorsystem, Verfahren zur Herstellung und seine Verwendung zur Polymerisation von Olefinen
AU743551B2 (en) 1997-06-05 2002-01-31 Exxonmobil Chemical Patents Inc Polymeric supported catalysts for olefin polymerization
US6228795B1 (en) 1997-06-05 2001-05-08 Exxon Chemical Patents, Inc. Polymeric supported catalysts
JP4116148B2 (ja) 1998-06-08 2008-07-09 三菱化学株式会社 新規な遷移金属化合物、オレフィン重合用触媒成分およびα−オレフィン重合体の製造方法
JP4498608B2 (ja) * 1998-08-03 2010-07-07 チッソ株式会社 メタロセン錯体の製造方法
DE19903306A1 (de) 1999-01-28 2000-08-03 Targor Gmbh Organometallverbindung, Katalysatorsystem enthaltend diese Organometallverbindung und seine Verwendung
KR100430438B1 (ko) * 1998-10-22 2004-07-19 대림산업 주식회사 담지메탈로센촉매,그제조방법및이를이용한폴리올레핀의중합방법
JP4195138B2 (ja) * 1998-12-10 2008-12-10 出光興産株式会社 アルミニウムオキシ化合物、オレフィン重合用触媒成分及びポリオレフィンの製造方法
JP2001064322A (ja) * 1999-06-24 2001-03-13 Idemitsu Petrochem Co Ltd プロピレン系重合体及びその成形体並びにプロピレン系重合体の製造方法
DE19962129A1 (de) * 1999-12-21 2001-06-28 Targor Gmbh Verfahren zur Herstellung eines Katalysatorfeststoffs zur Olefinpolymerisation
EP1548022A3 (de) 1999-12-23 2007-06-13 Basell Polyolefine GmbH Übergangsmetallverbindung, Ligandensystem, Katalysatorsystem und seine Verwendung zur Polymerisation und Copolymerisation von Olefinen
DE10028432A1 (de) 2000-06-13 2001-12-20 Basell Polyolefine Gmbh Auf calciniertes Hydrotalcit geträgerter Katalysatorfeststoff zur Olefinpolymerisation
US6380334B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380123B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380120B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376627B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376411B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380331B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380330B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376410B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376413B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376412B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376408B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380122B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380124B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6399723B1 (en) 2000-06-30 2002-06-04 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6380121B1 (en) 2000-06-30 2002-04-30 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376409B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6376407B1 (en) 2000-06-30 2002-04-23 Exxonmobil Chemical Patents Inc. Metallocene compositions
US6608149B2 (en) 2000-12-04 2003-08-19 Univation Technologies, Llc Polymerization process
US6555495B2 (en) 2000-12-06 2003-04-29 Univation Technologies, Llc Catalyst support method and polymerization with supported catalysts
US6777366B2 (en) * 2001-02-13 2004-08-17 Fina Technology, Inc. Method for the preparation of metallocene catalysts
US6583242B2 (en) * 2001-08-02 2003-06-24 Equistar Chemicals, Lp Supported olefin polymerization catalysts
JP2005526008A (ja) * 2001-12-04 2005-09-02 オニックス ファーマシューティカルズ，インコーポレイティド 癌を処置するためのｒａｆ−ｍｅｋ−ｅｒｋ経路インヒビター
US6908972B2 (en) * 2002-04-16 2005-06-21 Equistar Chemicals, Lp Method for making polyolefins
US20030236365A1 (en) * 2002-06-24 2003-12-25 Fina Technology, Inc. Polyolefin production with a high performance support for a metallocene catalyst system
US6765074B2 (en) * 2002-09-27 2004-07-20 Equistar Chemicals, Lp Olefin polymerization process
US6710005B1 (en) 2003-04-10 2004-03-23 Equistar Chemicals, Lp Aluminoxane modification
DE10326273B4 (de) * 2003-06-11 2008-06-12 Advanced Micro Devices, Inc., Sunnyvale Verfahren zur Reduzierung der Scheibenkontaminierung durch Entfernen von Metallisierungsunterlagenschichten am Scheibenrand
US7169864B2 (en) * 2004-12-01 2007-01-30 Novolen Technology Holdings, C.V. Metallocene catalysts, their synthesis and their use for the polymerization of olefins

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2805112C2 (ru) * 2018-11-06 2023-10-11 Дау Глоубл Текнолоджиз Ллк Способ полимеризации олефинов с применением неметаллоценового предкатализатора, растворимого в алканах

Also Published As

Publication number Publication date
AR052985A1 (es) 2007-04-18
EP1828266B1 (en) 2015-07-22
BRPI0518701B1 (pt) 2018-09-25
ZA200704403B (en) 2008-09-25
JP5311827B2 (ja) 2013-10-09
CN103012623A (zh) 2013-04-03
CN101124252B (zh) 2011-10-05
CN103012623B (zh) 2015-09-16
SG158099A1 (en) 2010-01-29
MX2007006313A (es) 2007-11-23
WO2006060544A1 (en) 2006-06-08
KR20070092217A (ko) 2007-09-12
US7169864B2 (en) 2007-01-30
BRPI0518701B8 (pt) 2023-01-24
BRPI0518701A2 (pt) 2008-12-02
US20070082806A1 (en) 2007-04-12
JP2008522013A (ja) 2008-06-26
US20080287286A1 (en) 2008-11-20
ES2548726T3 (es) 2015-10-20
KR101354477B1 (ko) 2014-01-24
US20060116490A1 (en) 2006-06-01
CN101124252A (zh) 2008-02-13
EP1828266A1 (en) 2007-09-05
JP2011231328A (ja) 2011-11-17
AR084818A2 (es) 2013-06-26
RU2007124637A (ru) 2009-01-10

Similar Documents

Publication Publication Date Title
RU2360931C2 (ru) Металлоценовые катализаторы, их синтез и их применение для полимеризации олефинов
KR101197098B1 (ko) 메탈로센 리간드, 메탈로센 화합물 및 메탈로센 촉매,그들의 합성 방법 및 올레핀 중합을 위한 용도
JP5598856B2 (ja) メタロセン化合物、それを含む触媒、その触媒を使用するオレフィンポリマーの製造プロセス、ならびにオレフィンホモポリマーおよびコポリマー
US6444606B1 (en) Supported catalyst system, method for the production and use thereof in olefin polymerization
EP1882000B1 (en) Catalyst composition for olefin polymerization
EP1234837B1 (en) Method for the preparation of metallocene catalysts
JP2002504569A (ja) 触媒組成物、その製造法、及び同触媒組成物のオレフィンの重合における使用法
WO2009054833A2 (en) Metallocene compounds, catalysts comprising them, process for producing an olefin polymer by use of the catalysts, and olefin homo and copolymers
JP2002535416A (ja) 有機金属化合物、この有機金属化合物を含む触媒組成物およびその使用
JPH1057815A (ja) 担持触媒系、その合成方法及びオレフィン重合のためのその使用
JP6196581B2 (ja) メタロセン化合物、それを含む触媒、その触媒を使用するオレフィンポリマーの製造プロセス、ならびにオレフィンホモポリマーおよびコポリマー