RU2179558C2 - Способ получения сополимеров и содержащих их смесевых композиций - Google Patents
Способ получения сополимеров и содержащих их смесевых композиций Download PDFInfo
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- RU2179558C2 RU2179558C2 RU98122704/04A RU98122704A RU2179558C2 RU 2179558 C2 RU2179558 C2 RU 2179558C2 RU 98122704/04 A RU98122704/04 A RU 98122704/04A RU 98122704 A RU98122704 A RU 98122704A RU 2179558 C2 RU2179558 C2 RU 2179558C2
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- Prior art keywords
- ethylene
- copolymer
- component
- group
- molecular weight
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- 125000001424 substituent group Chemical group 0.000 claims description 33
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- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 claims description 23
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- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 claims description 16
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- 238000004519 manufacturing process Methods 0.000 claims description 13
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- 125000003710 aryl alkyl group Chemical group 0.000 claims description 12
- 125000003800 germyl group Chemical group [H][Ge]([H])([H])[*] 0.000 claims description 12
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- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 10
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- 125000002091 cationic group Chemical group 0.000 claims description 8
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- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 7
- 101000623895 Bos taurus Mucin-15 Proteins 0.000 claims description 6
- 229920000089 Cyclic olefin copolymer Polymers 0.000 claims description 6
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical group [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 6
- 150000001408 amides Chemical class 0.000 claims description 6
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- 238000010926 purge Methods 0.000 claims description 6
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical group [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 claims description 6
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- 238000004587 chromatography analysis Methods 0.000 claims description 5
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 5
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- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 4
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- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims description 4
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Images
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- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
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- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
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- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
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- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
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- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
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- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
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- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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Applications Claiming Priority (2)
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| JP8148392A JPH09309926A (ja) | 1996-05-17 | 1996-05-17 | エチレン共重合体の製造方法 |
| JP8-148392 | 1996-05-17 |
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| RU98122704A RU98122704A (ru) | 2000-12-27 |
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- 1997-05-16 EP EP97926596A patent/EP0898586B1/en not_active Expired - Lifetime
- 1997-05-16 WO PCT/US1997/008466 patent/WO1997043323A1/en not_active Ceased
- 1997-05-16 CZ CZ983728A patent/CZ372898A3/cs unknown
- 1997-05-16 JP JP54117597A patent/JP2001512497A/ja not_active Withdrawn
- 1997-05-16 CN CN97196207A patent/CN1096476C/zh not_active Expired - Fee Related
- 1997-05-16 BR BR9710969-0A patent/BR9710969A/pt not_active Application Discontinuation
- 1997-05-16 AR ARP970102088A patent/AR007177A1/es not_active Application Discontinuation
- 1997-05-16 ES ES97926596T patent/ES2206718T3/es not_active Expired - Lifetime
- 1997-05-16 DE DE69724607T patent/DE69724607T2/de not_active Expired - Lifetime
- 1997-05-16 NZ NZ332846A patent/NZ332846A/xx unknown
- 1997-05-16 AT AT97926596T patent/ATE248866T1/de not_active IP Right Cessation
- 1997-05-16 ZA ZA9704269A patent/ZA974268B/xx unknown
- 1997-05-16 AU AU31319/97A patent/AU3131997A/en not_active Abandoned
- 1997-05-16 CA CA002255754A patent/CA2255754A1/en not_active Abandoned
- 1997-05-16 IL IL12705097A patent/IL127050A0/xx unknown
- 1997-05-16 TR TR1998/02352T patent/TR199802352T2/xx unknown
- 1997-05-16 RU RU98122704/04A patent/RU2179558C2/ru active
- 1997-05-16 TW TW086106545A patent/TW440568B/zh active
- 1997-05-16 KR KR1019980709269A patent/KR20000011110A/ko not_active Ceased
- 1997-05-16 HU HU9902561A patent/HUP9902561A3/hu unknown
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1998
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8097678B2 (en) | 2005-06-30 | 2012-01-17 | Borealis Technology Oy | Outer sheath layer for power or communication cable |
| RU2487015C2 (ru) * | 2008-01-29 | 2013-07-10 | ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи | Полиэтиленовые композиции, способ их получения, изготовленные из них изделия и способ изготовления указанных изделий |
| RU2553474C1 (ru) * | 2011-06-02 | 2015-06-20 | Бриджстоун Корпорейшн | Сополимер, резиновая смесь, сшитая резиновая смесь и шина |
| RU2645216C2 (ru) * | 2012-07-13 | 2018-02-19 | Юнивейшн Текнолоджиз, Ллк | Увеличенное отношение индексов расплава для полимера путем загрузки катализатора на подложке, насыщенного выбранным жидким агентом |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0898586A1 (en) | 1999-03-03 |
| US7166676B2 (en) | 2007-01-23 |
| CA2255754A1 (en) | 1997-11-20 |
| HUP9902561A2 (hu) | 1999-11-29 |
| AR007177A1 (es) | 1999-10-13 |
| NZ332846A (en) | 2000-05-26 |
| JPH09309926A (ja) | 1997-12-02 |
| TR199802352T2 (xx) | 1999-02-22 |
| AU3131997A (en) | 1997-12-05 |
| EP0898586B1 (en) | 2003-09-03 |
| US20030055176A1 (en) | 2003-03-20 |
| ZA974268B (en) | 1998-11-16 |
| PL329949A1 (en) | 1999-04-26 |
| DE69724607D1 (de) | 2003-10-09 |
| NO985329D0 (no) | 1998-11-16 |
| IL127050A0 (en) | 1999-09-22 |
| US7714073B2 (en) | 2010-05-11 |
| KR20000011110A (ko) | 2000-02-25 |
| WO1997043323A1 (en) | 1997-11-20 |
| CN1096476C (zh) | 2002-12-18 |
| ES2206718T3 (es) | 2004-05-16 |
| NO985329L (no) | 1999-01-15 |
| US20070088129A1 (en) | 2007-04-19 |
| TW440568B (en) | 2001-06-16 |
| CN1225101A (zh) | 1999-08-04 |
| HUP9902561A3 (en) | 2000-08-28 |
| BR9710969A (pt) | 2002-01-29 |
| DE69724607T2 (de) | 2004-06-17 |
| US20100292407A1 (en) | 2010-11-18 |
| JP2001512497A (ja) | 2001-08-21 |
| ATE248866T1 (de) | 2003-09-15 |
| CZ372898A3 (cs) | 1999-03-17 |
| ID17390A (id) | 1997-12-24 |
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