ES2206718T3 - Procedimiento para preparar copolimeros y composicion de mezclas que los contienen. - Google Patents
Procedimiento para preparar copolimeros y composicion de mezclas que los contienen.Info
- Publication number
- ES2206718T3 ES2206718T3 ES97926596T ES97926596T ES2206718T3 ES 2206718 T3 ES2206718 T3 ES 2206718T3 ES 97926596 T ES97926596 T ES 97926596T ES 97926596 T ES97926596 T ES 97926596T ES 2206718 T3 ES2206718 T3 ES 2206718T3
- Authority
- ES
- Spain
- Prior art keywords
- copolymer
- ethylene
- component
- temperature
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims abstract description 159
- 239000000203 mixture Substances 0.000 title claims description 253
- 229920001577 copolymer Polymers 0.000 title claims description 193
- 229920001038 ethylene copolymer Polymers 0.000 claims abstract description 198
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 152
- 239000005977 Ethylene Substances 0.000 claims abstract description 151
- 150000001875 compounds Chemical class 0.000 claims abstract description 121
- 229910052723 transition metal Inorganic materials 0.000 claims abstract description 54
- 239000012190 activator Substances 0.000 claims abstract description 53
- 150000003624 transition metals Chemical class 0.000 claims abstract description 48
- 239000007787 solid Substances 0.000 claims abstract description 46
- 230000008569 process Effects 0.000 claims abstract description 39
- 238000002360 preparation method Methods 0.000 claims abstract description 17
- 150000002736 metal compounds Chemical class 0.000 claims abstract description 14
- -1 carbonium cations Chemical class 0.000 claims description 147
- 238000009826 distribution Methods 0.000 claims description 125
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 119
- 239000000463 material Substances 0.000 claims description 118
- 239000003054 catalyst Substances 0.000 claims description 102
- 229920000642 polymer Polymers 0.000 claims description 78
- 229910052739 hydrogen Inorganic materials 0.000 claims description 75
- 239000001257 hydrogen Substances 0.000 claims description 74
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 66
- 238000006116 polymerization reaction Methods 0.000 claims description 63
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- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 54
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- 125000004432 carbon atom Chemical group C* 0.000 claims description 49
- 150000003623 transition metal compounds Chemical class 0.000 claims description 48
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- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 46
- 238000000605 extraction Methods 0.000 claims description 46
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 42
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 41
- 125000004122 cyclic group Chemical group 0.000 claims description 39
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 38
- 125000001424 substituent group Chemical group 0.000 claims description 36
- 239000000725 suspension Substances 0.000 claims description 36
- 239000002904 solvent Substances 0.000 claims description 34
- 229910052782 aluminium Inorganic materials 0.000 claims description 33
- 238000006243 chemical reaction Methods 0.000 claims description 33
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 31
- 125000003118 aryl group Chemical group 0.000 claims description 31
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- 125000000217 alkyl group Chemical group 0.000 claims description 30
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- 239000010936 titanium Substances 0.000 claims description 27
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- 239000003085 diluting agent Substances 0.000 claims description 25
- 229920001519 homopolymer Polymers 0.000 claims description 25
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 claims description 25
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 claims description 24
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 claims description 24
- 238000010438 heat treatment Methods 0.000 claims description 24
- 150000004820 halides Chemical class 0.000 claims description 22
- 230000007704 transition Effects 0.000 claims description 21
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 claims description 20
- 229910052799 carbon Inorganic materials 0.000 claims description 20
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 claims description 20
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- 229910052719 titanium Inorganic materials 0.000 claims description 19
- 239000011949 solid catalyst Substances 0.000 claims description 18
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 17
- 150000001993 dienes Chemical class 0.000 claims description 17
- 125000005843 halogen group Chemical group 0.000 claims description 17
- 239000000155 melt Substances 0.000 claims description 17
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 claims description 16
- 229910052796 boron Inorganic materials 0.000 claims description 16
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims description 16
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 claims description 16
- 230000000737 periodic effect Effects 0.000 claims description 16
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 15
- 229910052736 halogen Inorganic materials 0.000 claims description 15
- 150000002430 hydrocarbons Chemical class 0.000 claims description 15
- 229910052760 oxygen Inorganic materials 0.000 claims description 15
- 238000005406 washing Methods 0.000 claims description 15
- 239000004215 Carbon black (E152) Substances 0.000 claims description 14
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 13
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 13
- 238000004587 chromatography analysis Methods 0.000 claims description 13
- 230000007935 neutral effect Effects 0.000 claims description 13
- 229910052698 phosphorus Inorganic materials 0.000 claims description 13
- 239000011574 phosphorus Substances 0.000 claims description 13
- 238000010926 purge Methods 0.000 claims description 13
- 125000000129 anionic group Chemical group 0.000 claims description 12
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 12
- 150000002738 metalloids Chemical class 0.000 claims description 12
- 229910052717 sulfur Inorganic materials 0.000 claims description 12
- 230000003213 activating effect Effects 0.000 claims description 11
- 125000003800 germyl group Chemical group [H][Ge]([H])([H])[*] 0.000 claims description 11
- 150000002367 halogens Chemical class 0.000 claims description 11
- 230000003647 oxidation Effects 0.000 claims description 11
- 238000007254 oxidation reaction Methods 0.000 claims description 11
- 239000001301 oxygen Substances 0.000 claims description 11
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 10
- 230000015572 biosynthetic process Effects 0.000 claims description 10
- 150000004678 hydrides Chemical class 0.000 claims description 10
- 125000006736 (C6-C20) aryl group Chemical group 0.000 claims description 9
- 238000005194 fractionation Methods 0.000 claims description 9
- 238000010557 suspension polymerization reaction Methods 0.000 claims description 9
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 8
- 239000012298 atmosphere Substances 0.000 claims description 8
- 125000002091 cationic group Chemical group 0.000 claims description 8
- 239000011777 magnesium Substances 0.000 claims description 8
- 229910052749 magnesium Inorganic materials 0.000 claims description 8
- 239000011593 sulfur Substances 0.000 claims description 8
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 7
- 239000007800 oxidant agent Substances 0.000 claims description 7
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 7
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 7
- 101000623895 Bos taurus Mucin-15 Proteins 0.000 claims description 6
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 6
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 6
- 229910052726 zirconium Inorganic materials 0.000 claims description 6
- 238000004364 calculation method Methods 0.000 claims description 5
- 229910052732 germanium Inorganic materials 0.000 claims description 5
- 125000004469 siloxy group Chemical group [SiH3]O* 0.000 claims description 5
- 230000009466 transformation Effects 0.000 claims description 5
- 239000007848 Bronsted acid Substances 0.000 claims description 4
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 4
- 150000001408 amides Chemical class 0.000 claims description 4
- 150000001412 amines Chemical class 0.000 claims description 4
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims description 4
- 125000000743 hydrocarbylene group Chemical group 0.000 claims description 4
- 238000000465 moulding Methods 0.000 claims description 4
- 239000002685 polymerization catalyst Substances 0.000 claims description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052804 chromium Inorganic materials 0.000 claims description 3
- 239000011651 chromium Substances 0.000 claims description 3
- 239000000395 magnesium oxide Substances 0.000 claims description 3
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- 229920003023 plastic Polymers 0.000 claims description 3
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- 238000003856 thermoforming Methods 0.000 claims description 3
- 125000003837 (C1-C20) alkyl group Chemical group 0.000 claims description 2
- 238000007664 blowing Methods 0.000 claims description 2
- 230000007613 environmental effect Effects 0.000 claims description 2
- 239000000835 fiber Substances 0.000 claims description 2
- 238000012685 gas phase polymerization Methods 0.000 claims description 2
- 238000001746 injection moulding Methods 0.000 claims description 2
- 238000005245 sintering Methods 0.000 claims description 2
- 238000004611 spectroscopical analysis Methods 0.000 claims description 2
- 229920000089 Cyclic olefin copolymer Polymers 0.000 claims 2
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 claims 2
- 101710168651 Thioredoxin 1 Proteins 0.000 claims 1
- WHYHZFHCWGGCOP-UHFFFAOYSA-N germyl Chemical compound [GeH3] WHYHZFHCWGGCOP-UHFFFAOYSA-N 0.000 claims 1
- 150000002431 hydrogen Chemical class 0.000 claims 1
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- 238000007334 copolymerization reaction Methods 0.000 abstract description 10
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- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 43
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 35
- LWNGJAHMBMVCJR-UHFFFAOYSA-N (2,3,4,5,6-pentafluorophenoxy)boronic acid Chemical compound OB(O)OC1=C(F)C(F)=C(F)C(F)=C1F LWNGJAHMBMVCJR-UHFFFAOYSA-N 0.000 description 27
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- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 8
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- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 7
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 7
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- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 4
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Classifications
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- C08L23/04—Homopolymers or copolymers of ethene
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- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
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- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
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- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
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Applications Claiming Priority (2)
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| JP8148392A JPH09309926A (ja) | 1996-05-17 | 1996-05-17 | エチレン共重合体の製造方法 |
| JP14839296 | 1996-05-17 |
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| ES2206718T3 true ES2206718T3 (es) | 2004-05-16 |
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| ES97926596T Expired - Lifetime ES2206718T3 (es) | 1996-05-17 | 1997-05-16 | Procedimiento para preparar copolimeros y composicion de mezclas que los contienen. |
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-
1996
- 1996-05-17 JP JP8148392A patent/JPH09309926A/ja active Pending
-
1997
- 1997-05-16 PL PL97329949A patent/PL329949A1/xx unknown
- 1997-05-16 DE DE69724607T patent/DE69724607T2/de not_active Expired - Lifetime
- 1997-05-16 AU AU31319/97A patent/AU3131997A/en not_active Abandoned
- 1997-05-16 CN CN97196207A patent/CN1096476C/zh not_active Expired - Fee Related
- 1997-05-16 ES ES97926596T patent/ES2206718T3/es not_active Expired - Lifetime
- 1997-05-16 ID IDP971630A patent/ID17390A/id unknown
- 1997-05-16 CZ CZ983728A patent/CZ372898A3/cs unknown
- 1997-05-16 TW TW086106545A patent/TW440568B/zh active
- 1997-05-16 KR KR1019980709269A patent/KR20000011110A/ko not_active Ceased
- 1997-05-16 EP EP97926596A patent/EP0898586B1/en not_active Expired - Lifetime
- 1997-05-16 WO PCT/US1997/008466 patent/WO1997043323A1/en not_active Ceased
- 1997-05-16 BR BR9710969-0A patent/BR9710969A/pt not_active Application Discontinuation
- 1997-05-16 NZ NZ332846A patent/NZ332846A/xx unknown
- 1997-05-16 AT AT97926596T patent/ATE248866T1/de not_active IP Right Cessation
- 1997-05-16 TR TR1998/02352T patent/TR199802352T2/xx unknown
- 1997-05-16 ZA ZA9704269A patent/ZA974268B/xx unknown
- 1997-05-16 JP JP54117597A patent/JP2001512497A/ja not_active Withdrawn
- 1997-05-16 RU RU98122704/04A patent/RU2179558C2/ru active
- 1997-05-16 AR ARP970102088A patent/AR007177A1/es not_active Application Discontinuation
- 1997-05-16 HU HU9902561A patent/HUP9902561A3/hu unknown
- 1997-05-16 IL IL12705097A patent/IL127050A0/xx unknown
- 1997-05-16 CA CA002255754A patent/CA2255754A1/en not_active Abandoned
-
1998
- 1998-11-16 NO NO985329A patent/NO985329L/no not_active Application Discontinuation
-
2002
- 2002-06-07 US US10/165,815 patent/US7166676B2/en not_active Expired - Fee Related
-
2006
- 2006-06-28 US US11/477,198 patent/US7714073B2/en not_active Expired - Fee Related
-
2010
- 2010-03-16 US US12/724,487 patent/US20100292407A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| PL329949A1 (en) | 1999-04-26 |
| US7714073B2 (en) | 2010-05-11 |
| HUP9902561A2 (hu) | 1999-11-29 |
| RU2179558C2 (ru) | 2002-02-20 |
| KR20000011110A (ko) | 2000-02-25 |
| US7166676B2 (en) | 2007-01-23 |
| EP0898586A1 (en) | 1999-03-03 |
| NO985329L (no) | 1999-01-15 |
| US20070088129A1 (en) | 2007-04-19 |
| HUP9902561A3 (en) | 2000-08-28 |
| BR9710969A (pt) | 2002-01-29 |
| DE69724607T2 (de) | 2004-06-17 |
| AU3131997A (en) | 1997-12-05 |
| JPH09309926A (ja) | 1997-12-02 |
| US20030055176A1 (en) | 2003-03-20 |
| IL127050A0 (en) | 1999-09-22 |
| CN1096476C (zh) | 2002-12-18 |
| CN1225101A (zh) | 1999-08-04 |
| ID17390A (id) | 1997-12-24 |
| US20100292407A1 (en) | 2010-11-18 |
| DE69724607D1 (de) | 2003-10-09 |
| ZA974268B (en) | 1998-11-16 |
| AR007177A1 (es) | 1999-10-13 |
| NZ332846A (en) | 2000-05-26 |
| EP0898586B1 (en) | 2003-09-03 |
| NO985329D0 (no) | 1998-11-16 |
| CZ372898A3 (cs) | 1999-03-17 |
| ATE248866T1 (de) | 2003-09-15 |
| CA2255754A1 (en) | 1997-11-20 |
| WO1997043323A1 (en) | 1997-11-20 |
| TR199802352T2 (xx) | 1999-02-22 |
| TW440568B (en) | 2001-06-16 |
| JP2001512497A (ja) | 2001-08-21 |
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