JPH09309926A - エチレン共重合体の製造方法 - Google Patents
エチレン共重合体の製造方法Info
- Publication number
- JPH09309926A JPH09309926A JP8148392A JP14839296A JPH09309926A JP H09309926 A JPH09309926 A JP H09309926A JP 8148392 A JP8148392 A JP 8148392A JP 14839296 A JP14839296 A JP 14839296A JP H09309926 A JPH09309926 A JP H09309926A
- Authority
- JP
- Japan
- Prior art keywords
- group
- molecular weight
- copolymer
- temperature
- transition metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920001038 ethylene copolymer Polymers 0.000 title claims abstract description 161
- 238000004519 manufacturing process Methods 0.000 title claims description 17
- 229920001577 copolymer Polymers 0.000 claims abstract description 127
- 238000000034 method Methods 0.000 claims abstract description 84
- 150000001875 compounds Chemical class 0.000 claims abstract description 79
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 67
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 36
- 239000005977 Ethylene Substances 0.000 claims abstract description 36
- 238000000605 extraction Methods 0.000 claims abstract description 27
- 238000005227 gel permeation chromatography Methods 0.000 claims abstract description 26
- 239000002002 slurry Substances 0.000 claims abstract description 23
- 150000001993 dienes Chemical class 0.000 claims abstract description 11
- 238000005194 fractionation Methods 0.000 claims abstract description 7
- 238000004587 chromatography analysis Methods 0.000 claims abstract description 5
- 239000000463 material Substances 0.000 claims description 98
- 239000003054 catalyst Substances 0.000 claims description 87
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 86
- 238000009826 distribution Methods 0.000 claims description 83
- -1 carbonium cations Chemical class 0.000 claims description 80
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 69
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 63
- 239000012190 activator Substances 0.000 claims description 57
- 150000003623 transition metal compounds Chemical class 0.000 claims description 56
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 51
- 239000000203 mixture Substances 0.000 claims description 48
- 229910052739 hydrogen Inorganic materials 0.000 claims description 45
- 239000001257 hydrogen Substances 0.000 claims description 43
- 229910052751 metal Inorganic materials 0.000 claims description 39
- 239000002184 metal Substances 0.000 claims description 39
- 229910052723 transition metal Inorganic materials 0.000 claims description 39
- 150000002902 organometallic compounds Chemical class 0.000 claims description 37
- 150000001450 anions Chemical class 0.000 claims description 36
- 229910052782 aluminium Inorganic materials 0.000 claims description 35
- 125000004122 cyclic group Chemical group 0.000 claims description 34
- 125000001424 substituent group Chemical group 0.000 claims description 33
- 150000003624 transition metals Chemical class 0.000 claims description 33
- 125000004432 carbon atom Chemical group C* 0.000 claims description 30
- 239000002904 solvent Substances 0.000 claims description 30
- 239000011949 solid catalyst Substances 0.000 claims description 29
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 27
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 26
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 24
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 claims description 24
- 239000003085 diluting agent Substances 0.000 claims description 24
- 229920000642 polymer Polymers 0.000 claims description 24
- 239000000377 silicon dioxide Substances 0.000 claims description 24
- 150000001768 cations Chemical class 0.000 claims description 23
- 125000005843 halogen group Chemical group 0.000 claims description 19
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 claims description 15
- 150000004678 hydrides Chemical class 0.000 claims description 15
- 239000003446 ligand Substances 0.000 claims description 15
- 229910052760 oxygen Inorganic materials 0.000 claims description 15
- 229910052757 nitrogen Inorganic materials 0.000 claims description 14
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 claims description 13
- 125000003800 germyl group Chemical group [H][Ge]([H])([H])[*] 0.000 claims description 13
- 150000002430 hydrocarbons Chemical group 0.000 claims description 13
- 230000000737 periodic effect Effects 0.000 claims description 13
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 12
- 238000007334 copolymerization reaction Methods 0.000 claims description 12
- 229910052698 phosphorus Inorganic materials 0.000 claims description 12
- 239000011574 phosphorus Substances 0.000 claims description 12
- 229910052717 sulfur Inorganic materials 0.000 claims description 12
- 239000010936 titanium Substances 0.000 claims description 12
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 11
- 239000001301 oxygen Substances 0.000 claims description 11
- 229910052719 titanium Inorganic materials 0.000 claims description 11
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 10
- 229910052796 boron Inorganic materials 0.000 claims description 10
- 230000007935 neutral effect Effects 0.000 claims description 10
- 125000000129 anionic group Chemical group 0.000 claims description 9
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 8
- 230000003647 oxidation Effects 0.000 claims description 8
- 238000007254 oxidation reaction Methods 0.000 claims description 8
- 239000011593 sulfur Substances 0.000 claims description 8
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 7
- 239000007848 Bronsted acid Substances 0.000 claims description 6
- 125000006702 (C1-C18) alkyl group Chemical group 0.000 claims description 5
- 125000002091 cationic group Chemical group 0.000 claims description 5
- 150000002738 metalloids Chemical class 0.000 claims description 5
- 239000007800 oxidant agent Substances 0.000 claims description 5
- 125000004469 siloxy group Chemical group [SiH3]O* 0.000 claims description 5
- 125000006736 (C6-C20) aryl group Chemical group 0.000 claims description 4
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 4
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical group [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 4
- 150000001408 amides Chemical class 0.000 claims description 4
- 150000001412 amines Chemical class 0.000 claims description 4
- 229910052732 germanium Inorganic materials 0.000 claims description 4
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims description 4
- 150000004820 halides Chemical class 0.000 claims description 4
- 150000004706 metal oxides Chemical class 0.000 claims description 4
- 238000010926 purge Methods 0.000 claims description 4
- 229910052718 tin Inorganic materials 0.000 claims description 4
- 229910052726 zirconium Chemical group 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 3
- 229910021482 group 13 metal Inorganic materials 0.000 claims description 3
- 239000000395 magnesium oxide Substances 0.000 claims description 3
- 229910052752 metalloid Inorganic materials 0.000 claims description 3
- 125000003808 silyl group Chemical group [H][Si]([H])([H])[*] 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 abstract description 19
- 125000003118 aryl group Chemical group 0.000 abstract description 16
- 239000012535 impurity Substances 0.000 abstract description 10
- 238000004566 IR spectroscopy Methods 0.000 abstract description 2
- 230000009466 transformation Effects 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 description 31
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 23
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 21
- 238000006243 chemical reaction Methods 0.000 description 19
- 239000007787 solid Substances 0.000 description 17
- 239000000243 solution Substances 0.000 description 17
- 238000005406 washing Methods 0.000 description 17
- 239000012968 metallocene catalyst Substances 0.000 description 16
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 15
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 description 15
- 239000000843 powder Substances 0.000 description 14
- 229930195733 hydrocarbon Natural products 0.000 description 13
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 12
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 12
- 239000004215 Carbon black (E152) Substances 0.000 description 12
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 11
- 239000000499 gel Substances 0.000 description 11
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 10
- 238000009792 diffusion process Methods 0.000 description 9
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 9
- 230000008569 process Effects 0.000 description 9
- 230000002829 reductive effect Effects 0.000 description 9
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 8
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 8
- 229910003480 inorganic solid Inorganic materials 0.000 description 8
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 8
- 238000003756 stirring Methods 0.000 description 8
- 239000000725 suspension Substances 0.000 description 8
- 239000001993 wax Substances 0.000 description 8
- 125000004429 atom Chemical group 0.000 description 7
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 7
- 230000001747 exhibiting effect Effects 0.000 description 7
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 7
- 238000002156 mixing Methods 0.000 description 7
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 7
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 7
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 6
- 125000004093 cyano group Chemical group *C#N 0.000 description 6
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 6
- 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 239000000523 sample Substances 0.000 description 6
- 230000000087 stabilizing effect Effects 0.000 description 6
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 5
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 5
- 125000002877 alkyl aryl group Chemical group 0.000 description 5
- 239000012298 atmosphere Substances 0.000 description 5
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 5
- 150000004696 coordination complex Chemical class 0.000 description 5
- 238000005336 cracking Methods 0.000 description 5
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- 230000006353 environmental stress Effects 0.000 description 5
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- 125000002868 norbornyl group Chemical group C12(CCC(CC1)C2)* 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 5
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 4
- GQEZCXVZFLOKMC-UHFFFAOYSA-N 1-hexadecene Chemical compound CCCCCCCCCCCCCCC=C GQEZCXVZFLOKMC-UHFFFAOYSA-N 0.000 description 4
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 4
- HFDVRLIODXPAHB-UHFFFAOYSA-N 1-tetradecene Chemical compound CCCCCCCCCCCCC=C HFDVRLIODXPAHB-UHFFFAOYSA-N 0.000 description 4
- AQZWEFBJYQSQEH-UHFFFAOYSA-N 2-methyloxaluminane Chemical compound C[Al]1CCCCO1 AQZWEFBJYQSQEH-UHFFFAOYSA-N 0.000 description 4
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- VAMFXQBUQXONLZ-UHFFFAOYSA-N n-alpha-eicosene Natural products CCCCCCCCCCCCCCCCCCC=C VAMFXQBUQXONLZ-UHFFFAOYSA-N 0.000 description 4
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- CCCMONHAUSKTEQ-UHFFFAOYSA-N octadec-1-ene Chemical compound CCCCCCCCCCCCCCCCC=C CCCMONHAUSKTEQ-UHFFFAOYSA-N 0.000 description 4
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- 238000002360 preparation method Methods 0.000 description 4
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- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 4
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- 239000002879 Lewis base Substances 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 150000001335 aliphatic alkanes Chemical class 0.000 description 3
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 3
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 3
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- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 3
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- CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical compound C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 description 3
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- 239000010703 silicon Substances 0.000 description 3
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- 125000006659 (C1-C20) hydrocarbyl group Chemical group 0.000 description 2
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- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 2
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- MGNZXYYWBUKAII-UHFFFAOYSA-N cyclohexa-1,3-diene Chemical compound C1CC=CC=C1 MGNZXYYWBUKAII-UHFFFAOYSA-N 0.000 description 2
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 2
- BOXSCYUXSBYGRD-UHFFFAOYSA-N cyclopenta-1,3-diene;iron(3+) Chemical group [Fe+3].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 BOXSCYUXSBYGRD-UHFFFAOYSA-N 0.000 description 2
- 125000002897 diene group Chemical group 0.000 description 2
- UBHZUDXTHNMNLD-UHFFFAOYSA-N dimethylsilane Chemical group C[SiH2]C UBHZUDXTHNMNLD-UHFFFAOYSA-N 0.000 description 2
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- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
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- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 2
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- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
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- 125000000538 pentafluorophenyl group Chemical group FC1=C(F)C(F)=C(*)C(F)=C1F 0.000 description 2
- XYFCBTPGUUZFHI-UHFFFAOYSA-N phosphine group Chemical group P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
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- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
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- 230000000630 rising effect Effects 0.000 description 2
- SCABQASLNUQUKD-UHFFFAOYSA-N silylium Chemical compound [SiH3+] SCABQASLNUQUKD-UHFFFAOYSA-N 0.000 description 2
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
- C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
- D01F6/46—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
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- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
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- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
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- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
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- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
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- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
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- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
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Priority Applications (28)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8148392A JPH09309926A (ja) | 1996-05-17 | 1996-05-17 | エチレン共重合体の製造方法 |
| HU9902561A HUP9902561A3 (en) | 1996-05-17 | 1997-05-16 | Process for preparing copolymers and blend compositions containing the same |
| IL12705097A IL127050A0 (en) | 1996-05-17 | 1997-05-16 | Process for preparing copolymers and blend compositions containing same |
| ES97926596T ES2206718T3 (es) | 1996-05-17 | 1997-05-16 | Procedimiento para preparar copolimeros y composicion de mezclas que los contienen. |
| RU98122704/04A RU2179558C2 (ru) | 1996-05-17 | 1997-05-16 | Способ получения сополимеров и содержащих их смесевых композиций |
| TR1998/02352T TR199802352T2 (xx) | 1996-05-17 | 1997-05-16 | Kopolimerlerin haz�rlanmas� i�in i�lem ve kopolimerleri ihtiva eden harman bile�imleri. |
| PCT/US1997/008466 WO1997043323A1 (en) | 1996-05-17 | 1997-05-16 | Process for preparing copolymers and blend compositions containing the same |
| KR1019980709269A KR20000011110A (ko) | 1996-05-17 | 1997-05-16 | 공중합체 및 이를 함유한 블렌드 조성물의 제조방법 |
| NZ332846A NZ332846A (en) | 1996-05-17 | 1997-05-16 | Process for preparing copolymers and blend compositions containing the same |
| ARP970102088A AR007177A1 (es) | 1996-05-17 | 1997-05-16 | Copolimeros de etileno, procedimientos para obtenerlos, composiciones de mezcla que incluyen dichos copolimeros, procedimiento para preparar dichascomposiciones y peliculas y articulos fabricados con dicha composicion |
| EP97926596A EP0898586B1 (en) | 1996-05-17 | 1997-05-16 | Process for preparing copolymers and blend compositions containing the same |
| PL97329949A PL329949A1 (en) | 1996-05-17 | 1997-05-16 | Method of obtaining copolymers and mixtures containing them |
| CA002255754A CA2255754A1 (en) | 1996-05-17 | 1997-05-16 | Process for preparing copolymers and blend compositions containing the same |
| CN97196207A CN1096476C (zh) | 1996-05-17 | 1997-05-16 | 制备共聚物和含该共聚物的共混组合物的方法 |
| AT97926596T ATE248866T1 (de) | 1996-05-17 | 1997-05-16 | Verfahren zur herstellung von ethylen copolymeren und diese enthaltende zusammensetzungen |
| CZ983728A CZ372898A3 (cs) | 1996-05-17 | 1997-05-16 | Ethylenové kopolymery, způsob jejich přípravy, polymerní směsné kompozice obsahující tyto kopolymery a způsob jejich přípravy, a výrobky získané z těchto směsných kompozic |
| ZA9704269A ZA974268B (en) | 1996-05-17 | 1997-05-16 | Ethylene copolymers and blend compositions |
| JP54117597A JP2001512497A (ja) | 1996-05-17 | 1997-05-16 | 共重合体の製造方法およびそれを含有するブレンド組成物 |
| DE69724607T DE69724607T2 (de) | 1996-05-17 | 1997-05-16 | Verfahren zur herstellung von ethylen copolymeren und diese enthaltende zusammensetzungen |
| BR9710969-0A BR9710969A (pt) | 1996-05-17 | 1997-05-16 | Processo para preparar um copolìmero de etileno, copolìmero de etileno, composição de mistura polimérica, processo para formar uma composição de mistura polìmerica, pó de sintetização e artigo fabricado |
| TW086106545A TW440568B (en) | 1996-05-17 | 1997-05-16 | Ethylene copolymer and polymer blend compositions and processes thereof, and articles and products produced therefrom |
| AU31319/97A AU3131997A (en) | 1996-05-17 | 1997-05-16 | Process for preparing copolymers and blend compositions containing the same |
| IDP971630A ID17390A (id) | 1996-05-17 | 1997-05-16 | Kopolimer etilen dan komposisi campurannya |
| NO985329A NO985329L (no) | 1996-05-17 | 1998-11-16 | FremgangsmÕte for Õ fremstille kopolymerer og blandinger inneholdende de sa |
| US10/165,815 US7166676B2 (en) | 1996-05-17 | 2002-06-07 | Process for preparing copolymers and blend compositions containing the same |
| US11/477,198 US7714073B2 (en) | 1996-05-17 | 2006-06-28 | Ethylene copolymers and blend compositions |
| JP2007193093A JP4553924B2 (ja) | 1996-05-17 | 2007-07-25 | 共重合体の製造方法およびそれを含有するブレンド組成物 |
| US12/724,487 US20100292407A1 (en) | 1996-05-17 | 2010-03-16 | Process for preparing copolymers and blend compositions containing the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8148392A JPH09309926A (ja) | 1996-05-17 | 1996-05-17 | エチレン共重合体の製造方法 |
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| JP54117597A Withdrawn JP2001512497A (ja) | 1996-05-17 | 1997-05-16 | 共重合体の製造方法およびそれを含有するブレンド組成物 |
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| JP54117597A Withdrawn JP2001512497A (ja) | 1996-05-17 | 1997-05-16 | 共重合体の製造方法およびそれを含有するブレンド組成物 |
Country Status (24)
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| US (3) | US7166676B2 (enExample) |
| EP (1) | EP0898586B1 (enExample) |
| JP (2) | JPH09309926A (enExample) |
| KR (1) | KR20000011110A (enExample) |
| CN (1) | CN1096476C (enExample) |
| AR (1) | AR007177A1 (enExample) |
| AT (1) | ATE248866T1 (enExample) |
| AU (1) | AU3131997A (enExample) |
| BR (1) | BR9710969A (enExample) |
| CA (1) | CA2255754A1 (enExample) |
| CZ (1) | CZ372898A3 (enExample) |
| DE (1) | DE69724607T2 (enExample) |
| ES (1) | ES2206718T3 (enExample) |
| HU (1) | HUP9902561A3 (enExample) |
| ID (1) | ID17390A (enExample) |
| IL (1) | IL127050A0 (enExample) |
| NO (1) | NO985329L (enExample) |
| NZ (1) | NZ332846A (enExample) |
| PL (1) | PL329949A1 (enExample) |
| RU (1) | RU2179558C2 (enExample) |
| TR (1) | TR199802352T2 (enExample) |
| TW (1) | TW440568B (enExample) |
| WO (1) | WO1997043323A1 (enExample) |
| ZA (1) | ZA974268B (enExample) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP2003531921A (ja) * | 2000-01-11 | 2003-10-28 | ビーピー ケミカルズ リミテッド | 化学改質支持体およびそれから作成される支持触媒系 |
| WO2004081064A1 (ja) * | 2003-03-10 | 2004-09-23 | Asahi Kasei Chemicals Corporation | 超高分子量エチレン系重合体 |
| JPWO2004011548A1 (ja) * | 2002-07-25 | 2005-11-24 | 三井化学株式会社 | 熱可塑性樹脂組成物およびその組成物からなる成形体 |
| JPWO2004081064A1 (ja) * | 2003-03-10 | 2006-06-08 | 旭化成ケミカルズ株式会社 | 超高分子量エチレン系重合体 |
| JP2009530433A (ja) * | 2006-03-14 | 2009-08-27 | イネオス ユーロープ リミテッド | ポリマーフィルム |
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| JPH09309926A (ja) * | 1996-05-17 | 1997-12-02 | Dow Chem Co:The | エチレン共重合体の製造方法 |
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- 1997-05-16 CA CA002255754A patent/CA2255754A1/en not_active Abandoned
- 1997-05-16 AT AT97926596T patent/ATE248866T1/de not_active IP Right Cessation
- 1997-05-16 WO PCT/US1997/008466 patent/WO1997043323A1/en not_active Ceased
- 1997-05-16 IL IL12705097A patent/IL127050A0/xx unknown
-
1998
- 1998-11-16 NO NO985329A patent/NO985329L/no not_active Application Discontinuation
-
2002
- 2002-06-07 US US10/165,815 patent/US7166676B2/en not_active Expired - Fee Related
-
2006
- 2006-06-28 US US11/477,198 patent/US7714073B2/en not_active Expired - Fee Related
-
2010
- 2010-03-16 US US12/724,487 patent/US20100292407A1/en not_active Abandoned
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003531921A (ja) * | 2000-01-11 | 2003-10-28 | ビーピー ケミカルズ リミテッド | 化学改質支持体およびそれから作成される支持触媒系 |
| JPWO2004011548A1 (ja) * | 2002-07-25 | 2005-11-24 | 三井化学株式会社 | 熱可塑性樹脂組成物およびその組成物からなる成形体 |
| WO2004081064A1 (ja) * | 2003-03-10 | 2004-09-23 | Asahi Kasei Chemicals Corporation | 超高分子量エチレン系重合体 |
| JPWO2004081064A1 (ja) * | 2003-03-10 | 2006-06-08 | 旭化成ケミカルズ株式会社 | 超高分子量エチレン系重合体 |
| JP4868853B2 (ja) * | 2003-03-10 | 2012-02-01 | 旭化成ケミカルズ株式会社 | 超高分子量エチレン系重合体 |
| JP2009530433A (ja) * | 2006-03-14 | 2009-08-27 | イネオス ユーロープ リミテッド | ポリマーフィルム |
Also Published As
| Publication number | Publication date |
|---|---|
| US7714073B2 (en) | 2010-05-11 |
| CN1225101A (zh) | 1999-08-04 |
| ZA974268B (en) | 1998-11-16 |
| ES2206718T3 (es) | 2004-05-16 |
| NO985329D0 (no) | 1998-11-16 |
| CN1096476C (zh) | 2002-12-18 |
| US20030055176A1 (en) | 2003-03-20 |
| ATE248866T1 (de) | 2003-09-15 |
| NZ332846A (en) | 2000-05-26 |
| RU2179558C2 (ru) | 2002-02-20 |
| US20100292407A1 (en) | 2010-11-18 |
| DE69724607T2 (de) | 2004-06-17 |
| EP0898586A1 (en) | 1999-03-03 |
| CA2255754A1 (en) | 1997-11-20 |
| EP0898586B1 (en) | 2003-09-03 |
| PL329949A1 (en) | 1999-04-26 |
| TR199802352T2 (xx) | 1999-02-22 |
| HUP9902561A3 (en) | 2000-08-28 |
| DE69724607D1 (de) | 2003-10-09 |
| TW440568B (en) | 2001-06-16 |
| AU3131997A (en) | 1997-12-05 |
| BR9710969A (pt) | 2002-01-29 |
| HUP9902561A2 (hu) | 1999-11-29 |
| JP2001512497A (ja) | 2001-08-21 |
| NO985329L (no) | 1999-01-15 |
| US20070088129A1 (en) | 2007-04-19 |
| US7166676B2 (en) | 2007-01-23 |
| IL127050A0 (en) | 1999-09-22 |
| KR20000011110A (ko) | 2000-02-25 |
| ID17390A (id) | 1997-12-24 |
| AR007177A1 (es) | 1999-10-13 |
| WO1997043323A1 (en) | 1997-11-20 |
| CZ372898A3 (cs) | 1999-03-17 |
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