RU2014126870A - Бифункциональный катализатор частичного окисления для превращения пропана в акриловую кислоту и способ его получения - Google Patents
Бифункциональный катализатор частичного окисления для превращения пропана в акриловую кислоту и способ его получения Download PDFInfo
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- 239000003054 catalyst Substances 0.000 title claims 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 title claims 4
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 title claims 4
- 230000001588 bifunctional effect Effects 0.000 title claims 2
- 230000003647 oxidation Effects 0.000 title claims 2
- 238000007254 oxidation reaction Methods 0.000 title claims 2
- 239000001294 propane Substances 0.000 title claims 2
- 238000004519 manufacturing process Methods 0.000 title 1
- 230000001131 transforming effect Effects 0.000 title 1
- 239000000203 mixture Substances 0.000 claims abstract 21
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract 21
- 229910052697 platinum Inorganic materials 0.000 claims abstract 10
- 150000001875 compounds Chemical class 0.000 claims abstract 9
- 229910052684 Cerium Inorganic materials 0.000 claims abstract 3
- 229910052779 Neodymium Inorganic materials 0.000 claims abstract 3
- 229910052777 Praseodymium Inorganic materials 0.000 claims abstract 3
- 229910052772 Samarium Inorganic materials 0.000 claims abstract 3
- 229910052771 Terbium Inorganic materials 0.000 claims abstract 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract 3
- 229910052796 boron Inorganic materials 0.000 claims abstract 3
- 229910052804 chromium Inorganic materials 0.000 claims abstract 3
- 229910052802 copper Inorganic materials 0.000 claims abstract 3
- 229910052737 gold Inorganic materials 0.000 claims abstract 3
- 229910052738 indium Inorganic materials 0.000 claims abstract 3
- 229910052741 iridium Inorganic materials 0.000 claims abstract 3
- 229910052742 iron Inorganic materials 0.000 claims abstract 3
- 229910052745 lead Inorganic materials 0.000 claims abstract 3
- 229910052759 nickel Inorganic materials 0.000 claims abstract 3
- 239000001301 oxygen Substances 0.000 claims abstract 3
- 229910052760 oxygen Inorganic materials 0.000 claims abstract 3
- 229910052763 palladium Inorganic materials 0.000 claims abstract 3
- 229910052702 rhenium Inorganic materials 0.000 claims abstract 3
- 229910052703 rhodium Inorganic materials 0.000 claims abstract 3
- 229910052706 scandium Inorganic materials 0.000 claims abstract 3
- 229910052715 tantalum Inorganic materials 0.000 claims abstract 3
- 229910052719 titanium Inorganic materials 0.000 claims abstract 3
- 229910052721 tungsten Inorganic materials 0.000 claims abstract 3
- 229910052725 zinc Inorganic materials 0.000 claims abstract 3
- 229910052726 zirconium Inorganic materials 0.000 claims abstract 3
- 239000007864 aqueous solution Substances 0.000 claims 11
- 238000000034 method Methods 0.000 claims 10
- 239000012018 catalyst precursor Substances 0.000 claims 4
- 229930195733 hydrocarbon Natural products 0.000 claims 4
- 150000002430 hydrocarbons Chemical class 0.000 claims 4
- 239000004215 Carbon black (E152) Substances 0.000 claims 3
- 150000001735 carboxylic acids Chemical class 0.000 claims 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 2
- 238000001816 cooling Methods 0.000 claims 2
- 238000000354 decomposition reaction Methods 0.000 claims 2
- 238000001035 drying Methods 0.000 claims 2
- 238000010438 heat treatment Methods 0.000 claims 2
- 229910052751 metal Inorganic materials 0.000 claims 2
- 239000002184 metal Substances 0.000 claims 2
- 150000002739 metals Chemical class 0.000 claims 2
- 239000010955 niobium Substances 0.000 claims 2
- 239000007858 starting material Substances 0.000 claims 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims 1
- 239000012300 argon atmosphere Substances 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 238000001354 calcination Methods 0.000 claims 1
- 229910002092 carbon dioxide Inorganic materials 0.000 claims 1
- 239000001569 carbon dioxide Substances 0.000 claims 1
- 229910002091 carbon monoxide Inorganic materials 0.000 claims 1
- 229910001873 dinitrogen Inorganic materials 0.000 claims 1
- 229910052750 molybdenum Inorganic materials 0.000 claims 1
- 239000011733 molybdenum Substances 0.000 claims 1
- 229910052758 niobium Inorganic materials 0.000 claims 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims 1
- 150000007524 organic acids Chemical class 0.000 claims 1
- 230000001590 oxidative effect Effects 0.000 claims 1
- 238000011084 recovery Methods 0.000 claims 1
- 238000004064 recycling Methods 0.000 claims 1
- 239000000725 suspension Substances 0.000 claims 1
- 229910052720 vanadium Inorganic materials 0.000 claims 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
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- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/28—Molybdenum
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- B01J23/66—Silver or gold
- B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/683—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten
- B01J23/686—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten with molybdenum
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Abstract
1. Композиция, содержащая соединение следующей общей формулы:MoVNbPtMZOa обозначает число, имеющее значение в диапазоне от 0,15 до 0,50,b обозначает число, имеющее значение в диапазоне от 0,05 до 0,30,c обозначает число, имеющее значение в диапазоне от 0,0001 до 0,10,d обозначает число, имеющее значение в диапазоне от 0,0 до 0,35,e обозначает число, имеющее значение в диапазоне от 0 до 0,10,х обозначает число, зависящее от относительного количества и валентности элементов, отличных от кислорода, в формуле (I),М присутствует и представляет собой один или несколько следующих элементов, выбранных из группы, которая включает Ag, Te, Sb, а если присутствует больше одного элемента М, то каждый элемент М изменяется независимо в диапазоне значений d, иZ представляет собой один или несколько элементов, выбранных из группы, состоящей из Ru, Mn, Sc, Ti, Cr, Fe, Co, Ni, Cu, Zn, Ga, Y, Zr, Rh, Pd, In, Ce, Pr, Nd, Sm, Tb, Та, W, Re, Ir, Au, Pb и В, а если присутствует больше одного элемента Z, то каждый элемент Z изменяется независимо в диапазоне значений e.2. Композиция по п. 1, где c обозначает число, имеющеезначение в диапазоне от 0,0001 до 0,05.3. Композиция по п. 1, где c обозначает число, имеющее значение в диапазоне от 0,0001 до 0,03.4. Композиция по п. 1, где c обозначает число, имеющее значение в диапазоне от 0,0001 до 0,01.5. Композиция по п. 1, где c обозначает число, имеющее значение в диапазоне от 0,001 до 0,03.6. Композиция по любому из пп. 1-5, где соединение содержит платину с концентрацией от 0,1% масс. до 4,5% масс.7. Композиция по любому из пп. 1-5, где соединение содержит платину с концентрацией от 0,1% масс. до 1,2% масс.8. Композиция по любому из пп. 1-5, где соединение содержит платину с концентрацией от 0,1% масс. до 0,6% масс.9. Композиция по любому
Claims (19)
1. Композиция, содержащая соединение следующей общей формулы:
MoVaNbbPtcMdZeOx
a обозначает число, имеющее значение в диапазоне от 0,15 до 0,50,
b обозначает число, имеющее значение в диапазоне от 0,05 до 0,30,
c обозначает число, имеющее значение в диапазоне от 0,0001 до 0,10,
d обозначает число, имеющее значение в диапазоне от 0,0 до 0,35,
e обозначает число, имеющее значение в диапазоне от 0 до 0,10,
х обозначает число, зависящее от относительного количества и валентности элементов, отличных от кислорода, в формуле (I),
М присутствует и представляет собой один или несколько следующих элементов, выбранных из группы, которая включает Ag, Te, Sb, а если присутствует больше одного элемента М, то каждый элемент М изменяется независимо в диапазоне значений d, и
Z представляет собой один или несколько элементов, выбранных из группы, состоящей из Ru, Mn, Sc, Ti, Cr, Fe, Co, Ni, Cu, Zn, Ga, Y, Zr, Rh, Pd, In, Ce, Pr, Nd, Sm, Tb, Та, W, Re, Ir, Au, Pb и В, а если присутствует больше одного элемента Z, то каждый элемент Z изменяется независимо в диапазоне значений e.
2. Композиция по п. 1, где c обозначает число, имеющее
значение в диапазоне от 0,0001 до 0,05.
3. Композиция по п. 1, где c обозначает число, имеющее значение в диапазоне от 0,0001 до 0,03.
4. Композиция по п. 1, где c обозначает число, имеющее значение в диапазоне от 0,0001 до 0,01.
5. Композиция по п. 1, где c обозначает число, имеющее значение в диапазоне от 0,001 до 0,03.
6. Композиция по любому из пп. 1-5, где соединение содержит платину с концентрацией от 0,1% масс. до 4,5% масс.
7. Композиция по любому из пп. 1-5, где соединение содержит платину с концентрацией от 0,1% масс. до 1,2% масс.
8. Композиция по любому из пп. 1-5, где соединение содержит платину с концентрацией от 0,1% масс. до 0,6% масс.
9. Композиция по любому из пп. 1-5, где соединение содержит платину с концентрацией от 0,1% масс. до 0,3% масс.
10. Способ превращения углеводорода в ненасыщенную карбоновую кислоту, который включает:
контактирование потока, содержащего углеводород, который имеет от трех до пяти атомов углерода, кислород и инертный компонент, выбранный из группы, которая включает газообразный азот, водяной пар и их смеси, в присутствии композиции по любому из пп. 1-9;
образование отходящего потока со стадии контактирования; и
извлечение ненасыщенной карбоновой кислоты из отходящего потока.
11. Способ по п. 10, дополнительно включающий рециклирование, по крайней мере, части отходящего потока на
указанную стадию контактирования.
12. Способ по любому из пп. 10-11, где указанный углеводород представляет собой один или несколько углеводородов, имеющих три атома углерода, а ненасыщенной карбоновой кислотой является акриловая кислота.
13. Способ получения бифункционального катализатора окисления, способного одновременно окислять пропан в акриловую кислоту, а монооксид углерода - в диоксид углерода, включающий:
приготовление первого водного раствора, включающего источник молибдена, источник ванадия и источник платины;
приготовление второго водного раствора, включающего органическую кислоту и источник ниобия;
добавление второго водного раствора к первому водному раствору с образованием суспензии предшественника катализатора;
сушку предшественника катализатора; и
разложение предшественника катализатора с образованием композиции катализатора;
где платина присутствует в количестве, достаточном, для формирования катализатора, массовый процент платины в котором составляет от 0,1 до 4,5 в пересчете на общую массу катализатора.
14. Способ по п. 13, где первый водный раствор дополнительно включает источник одного или нескольких металлов, выбранных из группы, состоящей из Ag, Te, и Sb.
15. Способ по любому из пп. 13-14, где первый водный раствор дополнительно включает источник одного или нескольких металлов, выбранных из группы, которая состоит из Ru, Mn, Sc,
Ti, Cr, Fe, Co, Ni, Cu, Zn, Ga, Y, Zr, Rh, Pd, In, Се, Pr, Nd, Sm, Tb, Та, W, Re, Ir, Au, Pb и В.
16. Способ любому из пп. 13, 14, где сушку осуществляют на воздухе при температуре 120ºС в течение 1 часа, а разложение осуществляют при температуре 300ºС в течение 5 часов.
17. Способ по любому из пп. 13, 14, который дополнительно включает прокаливание предшественника катализатора в атмосфере аргона при температуре 600ºС в течение 2 часов.
18. Способ по любому из пп. 13, 14, дополнительно включающий:
перед стадией добавления, нагревание первого водного раствора при первой температуре и в течение первого времени, чтобы растворить исходные вещества, и охлаждение нагретого первого водного раствора; и
перед стадией добавления, нагревание второго водного раствора при второй температуре и в течение второго времени, чтобы растворить исходные вещества, и охлаждение нагретого первого водного раствора.
19. Способ по п. 18, где первая температура составляет 90ºC, и первое время равно 1 часу, и первый водный раствор охлаждают до температуры 35ºС, а вторая температура составляет от 95ºC до 100ºС, и второе время равно 1 часу.
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-
2011
- 2011-12-02 US US13/310,693 patent/US8921257B2/en not_active Expired - Fee Related
-
2012
- 2012-11-30 WO PCT/US2012/067422 patent/WO2013082514A1/en unknown
- 2012-11-30 EP EP12799458.0A patent/EP2785451A1/en not_active Withdrawn
- 2012-11-30 JP JP2014544952A patent/JP6038169B2/ja not_active Expired - Fee Related
- 2012-11-30 RU RU2014126870A patent/RU2621033C2/ru active
- 2012-11-30 CN CN201280058762.6A patent/CN103958054A/zh active Pending
- 2012-12-03 TW TW101145286A patent/TWI568494B/zh not_active IP Right Cessation
Also Published As
Publication number | Publication date |
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JP2015505805A (ja) | 2015-02-26 |
CN103958054A (zh) | 2014-07-30 |
EP2785451A1 (en) | 2014-10-08 |
RU2621033C2 (ru) | 2017-05-31 |
TW201334867A (zh) | 2013-09-01 |
US20130144085A1 (en) | 2013-06-06 |
US8921257B2 (en) | 2014-12-30 |
TWI568494B (zh) | 2017-02-01 |
WO2013082514A1 (en) | 2013-06-06 |
JP6038169B2 (ja) | 2016-12-07 |
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