NO321515B1 - Polymerblanding med hoy transparens - Google Patents
Polymerblanding med hoy transparens Download PDFInfo
- Publication number
- NO321515B1 NO321515B1 NO19996212A NO996212A NO321515B1 NO 321515 B1 NO321515 B1 NO 321515B1 NO 19996212 A NO19996212 A NO 19996212A NO 996212 A NO996212 A NO 996212A NO 321515 B1 NO321515 B1 NO 321515B1
- Authority
- NO
- Norway
- Prior art keywords
- weight
- mixture
- copolymers
- polystyrene
- block
- Prior art date
Links
- 229920002959 polymer blend Polymers 0.000 title claims description 5
- 239000000203 mixture Substances 0.000 claims description 52
- 229920001577 copolymer Polymers 0.000 claims description 34
- 239000004793 Polystyrene Substances 0.000 claims description 33
- 229920002223 polystyrene Polymers 0.000 claims description 33
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 29
- KAKZBPTYRLMSJV-UHFFFAOYSA-N butadiene group Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 22
- 150000001993 dienes Chemical class 0.000 claims description 14
- 229920001400 block copolymer Polymers 0.000 claims description 11
- 239000000178 monomer Substances 0.000 claims description 11
- 229920006301 statistical copolymer Polymers 0.000 claims description 4
- 229920001519 homopolymer Polymers 0.000 claims description 2
- 125000002897 diene group Chemical group 0.000 claims 2
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 27
- 239000000243 solution Substances 0.000 description 22
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 18
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 15
- 238000000034 method Methods 0.000 description 13
- MGMXGCZJYUCMGY-UHFFFAOYSA-N tris(4-nonylphenyl) phosphite Chemical compound C1=CC(CCCCCCCCC)=CC=C1OP(OC=1C=CC(CCCCCCCCC)=CC=1)OC1=CC=C(CCCCCCCCC)C=C1 MGMXGCZJYUCMGY-UHFFFAOYSA-N 0.000 description 11
- 239000013078 crystal Substances 0.000 description 10
- 229920000642 polymer Polymers 0.000 description 10
- 238000006243 chemical reaction Methods 0.000 description 9
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 9
- 230000003287 optical effect Effects 0.000 description 8
- 239000003963 antioxidant agent Substances 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 7
- 239000003153 chemical reaction reagent Substances 0.000 description 7
- 229920003048 styrene butadiene rubber Polymers 0.000 description 7
- QRLSTWVLSWCGBT-UHFFFAOYSA-N 4-((4,6-bis(octylthio)-1,3,5-triazin-2-yl)amino)-2,6-di-tert-butylphenol Chemical compound CCCCCCCCSC1=NC(SCCCCCCCC)=NC(NC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=N1 QRLSTWVLSWCGBT-UHFFFAOYSA-N 0.000 description 6
- 229920005684 linear copolymer Polymers 0.000 description 6
- 229910001220 stainless steel Inorganic materials 0.000 description 6
- 239000010935 stainless steel Substances 0.000 description 6
- 238000003786 synthesis reaction Methods 0.000 description 6
- 238000005266 casting Methods 0.000 description 5
- 229920001971 elastomer Polymers 0.000 description 5
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 4
- RDHPKYGYEGBMSE-UHFFFAOYSA-N bromoethane Chemical compound CCBr RDHPKYGYEGBMSE-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 229920005605 branched copolymer Polymers 0.000 description 3
- 238000001746 injection moulding Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- 239000005060 rubber Substances 0.000 description 3
- SDJHPPZKZZWAKF-UHFFFAOYSA-N 2,3-dimethylbuta-1,3-diene Chemical compound CC(=C)C(C)=C SDJHPPZKZZWAKF-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000000806 elastomer Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical group C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 1
- AZUYLZMQTIKGSC-UHFFFAOYSA-N 1-[6-[4-(5-chloro-6-methyl-1H-indazol-4-yl)-5-methyl-3-(1-methylindazol-5-yl)pyrazol-1-yl]-2-azaspiro[3.3]heptan-2-yl]prop-2-en-1-one Chemical compound ClC=1C(=C2C=NNC2=CC=1C)C=1C(=NN(C=1C)C1CC2(CN(C2)C(C=C)=O)C1)C=1C=C2C=NN(C2=CC=1)C AZUYLZMQTIKGSC-UHFFFAOYSA-N 0.000 description 1
- VDNSZPNSUQRUMS-UHFFFAOYSA-N 1-cyclohexyl-4-ethenylbenzene Chemical compound C1=CC(C=C)=CC=C1C1CCCCC1 VDNSZPNSUQRUMS-UHFFFAOYSA-N 0.000 description 1
- DMADTXMQLFQQII-UHFFFAOYSA-N 1-decyl-4-ethenylbenzene Chemical compound CCCCCCCCCCC1=CC=C(C=C)C=C1 DMADTXMQLFQQII-UHFFFAOYSA-N 0.000 description 1
- JZHGRUMIRATHIU-UHFFFAOYSA-N 1-ethenyl-3-methylbenzene Chemical compound CC1=CC=CC(C=C)=C1 JZHGRUMIRATHIU-UHFFFAOYSA-N 0.000 description 1
- RRRXUCMQOPNVAT-UHFFFAOYSA-N 1-ethenyl-4-(4-methylphenyl)benzene Chemical compound C1=CC(C)=CC=C1C1=CC=C(C=C)C=C1 RRRXUCMQOPNVAT-UHFFFAOYSA-N 0.000 description 1
- JHTICDZLXFNVKL-UHFFFAOYSA-N 1-ethenyl-4-(4-phenylbutyl)benzene Chemical compound C1=CC(C=C)=CC=C1CCCCC1=CC=CC=C1 JHTICDZLXFNVKL-UHFFFAOYSA-N 0.000 description 1
- VVTGQMLRTKFKAM-UHFFFAOYSA-N 1-ethenyl-4-propylbenzene Chemical compound CCCC1=CC=C(C=C)C=C1 VVTGQMLRTKFKAM-UHFFFAOYSA-N 0.000 description 1
- IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical compound C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 description 1
- KXYAVSFOJVUIHT-UHFFFAOYSA-N 2-vinylnaphthalene Chemical compound C1=CC=CC2=CC(C=C)=CC=C21 KXYAVSFOJVUIHT-UHFFFAOYSA-N 0.000 description 1
- DXFURPHVJQITAC-UHFFFAOYSA-N 4-benzyl-1-ethenyl-2-ethylbenzene Chemical compound C1=C(C=C)C(CC)=CC(CC=2C=CC=CC=2)=C1 DXFURPHVJQITAC-UHFFFAOYSA-N 0.000 description 1
- UGWOAPBVIGCNOV-UHFFFAOYSA-N 5-ethenyldec-5-ene Chemical compound CCCCC=C(C=C)CCCC UGWOAPBVIGCNOV-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical class [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- 229920013645 Europrene Polymers 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 239000006085 branching agent Substances 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000012442 inert solvent Substances 0.000 description 1
- 150000002641 lithium Chemical class 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/06—Polystyrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Graft Or Block Polymers (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT1998MI002769A IT1304497B1 (it) | 1998-12-22 | 1998-12-22 | Composizione polimerica ad elevata trasparenza. |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| NO996212D0 NO996212D0 (no) | 1999-12-15 |
| NO996212L NO996212L (no) | 2000-06-23 |
| NO321515B1 true NO321515B1 (no) | 2006-05-15 |
Family
ID=11381300
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO19996212A NO321515B1 (no) | 1998-12-22 | 1999-12-15 | Polymerblanding med hoy transparens |
Country Status (18)
| Country | Link |
|---|---|
| US (1) | US6867258B2 (cs) |
| EP (1) | EP1013712B1 (cs) |
| JP (1) | JP4672100B2 (cs) |
| AT (1) | ATE259859T1 (cs) |
| BG (1) | BG64287B1 (cs) |
| CA (1) | CA2292137C (cs) |
| CZ (1) | CZ300839B6 (cs) |
| DE (1) | DE69914869T2 (cs) |
| ES (1) | ES2215361T3 (cs) |
| HR (1) | HRP990390B1 (cs) |
| HU (1) | HU224707B1 (cs) |
| IT (1) | IT1304497B1 (cs) |
| NO (1) | NO321515B1 (cs) |
| PL (1) | PL196195B1 (cs) |
| RU (1) | RU2237687C2 (cs) |
| SK (1) | SK285482B6 (cs) |
| TR (1) | TR199903203A3 (cs) |
| UA (1) | UA69384C2 (cs) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2739903C (en) | 2008-10-07 | 2016-12-06 | Ross Technology Corporation | Highly durable superhydrophobic, oleophobic and anti-icing coatings and methods and compositions for their preparation |
| WO2011116005A1 (en) | 2010-03-15 | 2011-09-22 | Ross Technology Corporation | Plunger and methods of producing hydrophobic surfaces |
| PE20140834A1 (es) | 2011-02-21 | 2014-07-10 | Ross Technology Corp | Revestimiento superhidrofos y oleofobos con sistema aglutinantes con bajo contenido de cov |
| WO2013090939A1 (en) | 2011-12-15 | 2013-06-20 | Ross Technology Corporation | Composition and coating for superhydrophobic performance |
| MX2015000119A (es) * | 2012-06-25 | 2015-04-14 | Ross Technology Corp | Recubrimientos elastoméricos con propiedades hidrofóbicas y/u oleofóbicas. |
| JP6006430B2 (ja) * | 2013-09-20 | 2016-10-12 | Ｐｓジャパン株式会社 | ビニル芳香族炭化水素重合体組成物及びビニル芳香族炭化水素重合体組成物の製造方法 |
| WO2015041328A1 (ja) * | 2013-09-20 | 2015-03-26 | Ｐｓジャパン株式会社 | 押出発泡体及び容器 |
| JP6258088B2 (ja) * | 2014-03-17 | 2018-01-10 | Ｐｓジャパン株式会社 | 二軸延伸シート |
| JP6262577B2 (ja) * | 2014-03-17 | 2018-01-17 | Ｐｓジャパン株式会社 | 二軸延伸シート |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5943059B2 (ja) * | 1977-10-27 | 1984-10-19 | 新日鐵化学株式会社 | 透明性を改良したスチレン系樹脂組成物 |
| DE3049186A1 (de) * | 1980-12-24 | 1982-07-29 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung einer biaxial gereckten folie aus styrol-butadien-blockcopolymerisaten |
| DE3816294A1 (de) | 1988-05-13 | 1989-11-23 | Basf Ag | Transparente, thermoplastische formmasse, verfahren zu ihrer herstellung und ihre verwendung |
| GB2232677B (en) | 1989-06-08 | 1993-06-30 | Labofina Sa | Polymeric material composition |
| JP2986178B2 (ja) * | 1990-06-04 | 1999-12-06 | 電気化学工業株式会社 | ブロツク共重合体樹脂組成物 |
| JP3103384B2 (ja) * | 1991-02-15 | 2000-10-30 | 旭化成工業株式会社 | ブロック共重合体樹脂組成物 |
| JPH0717809B2 (ja) * | 1991-10-17 | 1995-03-01 | 旭化成工業株式会社 | ブロック共重合体樹脂組成物 |
| JP3332281B2 (ja) * | 1994-01-31 | 2002-10-07 | 電気化学工業株式会社 | 透明高強度樹脂組成物 |
| US5596041A (en) | 1994-04-04 | 1997-01-21 | Japan Synthetic Rubber Co., Ltd. | Hydrogenated block copolymer and hydrogenated block copolymer compositon |
| IT1269803B (it) * | 1994-05-20 | 1997-04-15 | Enichem Elastomers | Composizione adesiva hot melt per etichette |
| JPH0966554A (ja) * | 1995-08-31 | 1997-03-11 | Daicel Chem Ind Ltd | スチレン系透明シートおよびフィルムの製造方法 |
| JPH09324084A (ja) * | 1996-06-05 | 1997-12-16 | Denki Kagaku Kogyo Kk | ブロック共重合体樹脂組成物、成形体及びその製造方法 |
| DE19810141A1 (de) * | 1998-03-10 | 1999-09-16 | Basf Ag | Polymermischungen aus Styrolpolymeren |
| IT1302040B1 (it) * | 1998-09-04 | 2000-07-20 | Enichem Spa | Copolimeri a blocchi idrogenati aventi struttura parzialmenteramificata. |
-
1998
- 1998-12-22 IT IT1998MI002769A patent/IT1304497B1/it active
-
1999
- 1999-12-15 BG BG104014A patent/BG64287B1/bg unknown
- 1999-12-15 CA CA002292137A patent/CA2292137C/en not_active Expired - Lifetime
- 1999-12-15 NO NO19996212A patent/NO321515B1/no not_active IP Right Cessation
- 1999-12-16 ES ES99204355T patent/ES2215361T3/es not_active Expired - Lifetime
- 1999-12-16 DE DE69914869T patent/DE69914869T2/de not_active Expired - Lifetime
- 1999-12-16 AT AT99204355T patent/ATE259859T1/de active
- 1999-12-16 EP EP99204355A patent/EP1013712B1/en not_active Expired - Lifetime
- 1999-12-17 CZ CZ0461999A patent/CZ300839B6/cs not_active IP Right Cessation
- 1999-12-17 HR HR990390A patent/HRP990390B1/xx not_active IP Right Cessation
- 1999-12-20 UA UA99126957A patent/UA69384C2/uk unknown
- 1999-12-21 SK SK1831-99A patent/SK285482B6/sk not_active IP Right Cessation
- 1999-12-21 HU HU9904690A patent/HU224707B1/hu active IP Right Grant
- 1999-12-21 PL PL337356A patent/PL196195B1/pl unknown
- 1999-12-22 JP JP36530999A patent/JP4672100B2/ja not_active Expired - Lifetime
- 1999-12-22 TR TR1999/03203A patent/TR199903203A3/tr unknown
- 1999-12-22 RU RU99128077A patent/RU2237687C2/ru active
-
2002
- 2002-09-23 US US10/251,854 patent/US6867258B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DE69914869T2 (de) | 2005-01-05 |
| CZ300839B6 (cs) | 2009-08-26 |
| TR199903203A2 (xx) | 2000-07-21 |
| DE69914869D1 (de) | 2004-03-25 |
| NO996212D0 (no) | 1999-12-15 |
| HRP990390B1 (en) | 2004-08-31 |
| US20030065093A1 (en) | 2003-04-03 |
| IT1304497B1 (it) | 2001-03-19 |
| NO996212L (no) | 2000-06-23 |
| HU224707B1 (en) | 2006-01-30 |
| HUP9904690A3 (en) | 2002-02-28 |
| HUP9904690A2 (hu) | 2000-11-28 |
| CA2292137A1 (en) | 2000-06-22 |
| RU2237687C2 (ru) | 2004-10-10 |
| BG104014A (en) | 2001-08-31 |
| HU9904690D0 (en) | 2000-02-28 |
| SK183199A3 (en) | 2000-11-07 |
| UA69384C2 (uk) | 2004-09-15 |
| EP1013712A1 (en) | 2000-06-28 |
| HRP990390A2 (en) | 2000-10-31 |
| CA2292137C (en) | 2007-10-02 |
| ES2215361T3 (es) | 2004-10-01 |
| ITMI982769A1 (it) | 2000-06-22 |
| CZ9904619A3 (cs) | 2000-12-13 |
| JP4672100B2 (ja) | 2011-04-20 |
| PL337356A1 (en) | 2000-07-03 |
| SK285482B6 (sk) | 2007-02-01 |
| BG64287B1 (bg) | 2004-08-31 |
| ATE259859T1 (de) | 2004-03-15 |
| JP2000191869A (ja) | 2000-07-11 |
| US6867258B2 (en) | 2005-03-15 |
| PL196195B1 (pl) | 2007-12-31 |
| TR199903203A3 (tr) | 2000-07-21 |
| EP1013712B1 (en) | 2004-02-18 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MK1K | Patent expired |