MX9704069A - Procedimiento de esterificacion. - Google Patents

Procedimiento de esterificacion.

Info

Publication number
MX9704069A
MX9704069A MX9704069A MX9704069A MX9704069A MX 9704069 A MX9704069 A MX 9704069A MX 9704069 A MX9704069 A MX 9704069A MX 9704069 A MX9704069 A MX 9704069A MX 9704069 A MX9704069 A MX 9704069A
Authority
MX
Mexico
Prior art keywords
esterification process
reaction
esterification
transesterification
ester
Prior art date
Application number
MX9704069A
Other languages
English (en)
Other versions
MXPA97004069A (es
Inventor
John Ridland
Iain Wesley Hepplewhite
Brian Steven Jolly
Original Assignee
Tioxide Specialties Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tioxide Specialties Ltd filed Critical Tioxide Specialties Ltd
Publication of MXPA97004069A publication Critical patent/MXPA97004069A/es
Publication of MX9704069A publication Critical patent/MX9704069A/es

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78Preparation processes
    • C08G63/82Preparation processes characterised by the catalyst used
    • C08G63/85Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/03Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/08Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/76Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring
    • C07C69/80Phthalic acid esters
    • C07C69/82Terephthalic acid esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16Dicarboxylic acids and dihydroxy compounds
    • C08G63/18Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
    • C08G63/181Acids containing aromatic rings
    • C08G63/183Terephthalic acids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Polyesters Or Polycarbonates (AREA)

Abstract

Un procedimiento para la preparacion de un éster comprende llevar a cabo una esterificacion en presencia de un catalizador que comprende el producto de reaccion de un ortoéster o de un ortoéster condensado de titanio o de circonio, un alcohol que contiene por lo menos dos grupos hidroxilo, un ácido 2-hidroxi y una base. El procedimiento puede ser una esterificacion directa o una transesterificacion y puede ser una poliesterficacion. El catalizador puede producir efectivamenteésteres sin conducir a una nebulosidad en el producto final y existe una cantidad reducida de amarilleo de los poliésteres en comparacion con catalizadores conocidos.
MX9704069A 1996-06-11 1997-06-02 Procedimiento de esterificacion. MX9704069A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GBGB9612161.1A GB9612161D0 (en) 1996-06-11 1996-06-11 Esterification process
GB9612161.1 1996-06-11

Publications (2)

Publication Number Publication Date
MXPA97004069A MXPA97004069A (es) 1998-04-01
MX9704069A true MX9704069A (es) 1998-04-30

Family

ID=10795084

Family Applications (1)

Application Number Title Priority Date Filing Date
MX9704069A MX9704069A (es) 1996-06-11 1997-06-02 Procedimiento de esterificacion.

Country Status (25)

Country Link
US (1) US5866710A (es)
EP (2) EP0812818B1 (es)
JP (1) JP4354541B2 (es)
KR (1) KR100567476B1 (es)
CN (1) CN1068864C (es)
AR (1) AR007540A1 (es)
AT (2) ATE254096T1 (es)
AU (1) AU730131B2 (es)
BR (1) BR9703577A (es)
CA (1) CA2207111A1 (es)
CO (1) CO4810331A1 (es)
CZ (1) CZ176297A3 (es)
DE (2) DE69707757T2 (es)
DK (1) DK0812818T3 (es)
ES (2) ES2211678T3 (es)
GB (1) GB9612161D0 (es)
HU (1) HU218143B (es)
MX (1) MX9704069A (es)
MY (1) MY115541A (es)
NO (1) NO307961B1 (es)
PL (1) PL194313B1 (es)
PT (2) PT812818E (es)
RU (1) RU2178783C2 (es)
TR (1) TR199700487A3 (es)
TW (1) TW349937B (es)

Families Citing this family (51)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6255441B1 (en) 1998-04-17 2001-07-03 E. I. Du Pont De Nemours And Company Titanium-containing catalyst composition and processes therefor and therewith
DE19825350A1 (de) * 1998-06-05 1999-12-09 Basf Ag Thermoplastische Polyesterformmasse mit verbesserter Stabilität
US6130191A (en) * 1998-09-29 2000-10-10 Henkel Corporation Process for the preparation of trimethylolpropane caprylate/caprate
US6664413B1 (en) 1998-11-19 2003-12-16 A. E. Staley Manufacturing Co. Process for production of esters
KR20000059815A (ko) * 1999-03-09 2000-10-05 한형수 지방족 폴리에스테르 제조방법
US6075115A (en) * 1999-10-19 2000-06-13 E. I. Du Pont De Nemours And Company Process for the production of 5-sulfo isophthalate bis-glycolate ester metal salts and oxysulfonated polyesters made therefrom
US6166170A (en) * 1999-12-02 2000-12-26 E. I. Du Pont De Nemours And Company Esterification catalysts and processes therefor and therewith
KR20020063208A (ko) 1999-12-10 2002-08-01 다우 글로벌 테크놀로지스 인크. 중축합 반응용 촉매 시스템
US6372879B1 (en) 2000-01-07 2002-04-16 Atofina Chemicals, Inc. Polyester polycondensation with catalyst and a catalyst enhancer
US6355817B1 (en) * 2000-07-15 2002-03-12 Exxonmobil Chemical Patents Inc. Optimized catalyst addition to enhance esterification catalyst performance
US6303738B1 (en) 2000-08-04 2001-10-16 E. I. Du Pont De Nemours And Company Esterification process
US7767612B2 (en) * 2000-11-21 2010-08-03 Johnson Matthey Plc Esterification catalyst, polyester process and polyester article
DE10059612A1 (de) 2000-12-01 2002-06-20 Bayer Ag Titan-/Zirkonium-Katalysatoren sowie deren Verwendung zur Herstellung von Estern oder Polyestern
US6914107B2 (en) 2001-01-24 2005-07-05 E. I. Du Pont De Nemours And Company Catalyst composition and process therewith
US6489433B2 (en) 2001-02-23 2002-12-03 E. I. Du Pont De Nemours And Company Metal-containing composition and process therewith
US20030203811A1 (en) 2002-04-25 2003-10-30 Putzig Donald Edward Stable aqueous solutions comprising titanium and zinc and process therewith
US6855797B2 (en) 2002-04-25 2005-02-15 E. I. Du Pont De Nemours And Company Stable aqueous solutions comprising titanium and zinc and process therewith
KR20030084183A (ko) * 2002-04-25 2003-11-01 켐엔텍 주식회사 폴리에스테르의 제조방법
US6841505B2 (en) * 2002-07-26 2005-01-11 E..I. Du Pont De Nemours And Company Titanium-zirconium catalyst compositions and use thereof
GB0228267D0 (en) * 2002-12-04 2003-01-08 Johnson Matthey Plc Catalyst and process
JP2006509070A (ja) * 2002-12-04 2006-03-16 ジョンソン、マッセイ、パブリック、リミテッド、カンパニー 有機金属触媒組成物及び前記触媒を用いるポリウレタン製造プロセス
JP4529485B2 (ja) * 2003-03-07 2010-08-25 三菱化学株式会社 ポリエステル重合触媒、その製造方法、及びそれを用いたポリエステルの製造方法
EP1640398B1 (en) * 2003-06-17 2014-03-19 Mitsui Chemicals, Inc. Titanium-containing solutions, catalysts for production of polyester, processes for production of polyester resins, and blow moldings of polyester
DE10336883A1 (de) * 2003-08-08 2005-03-10 Basf Ag Kunststoff, insbesondere Polyurethan enthaltend ein sterisch gehindertes, verestertes Amin
GB0323386D0 (en) * 2003-10-07 2003-11-05 Johnson Matthey Plc Catalyst for manufacture of esters
KR100760027B1 (ko) 2006-09-22 2007-09-18 이수화학 주식회사 고정층형 반응기를 이용한 바이오디젤의 연속식 제조방법
KR100849206B1 (ko) * 2006-12-21 2008-07-31 주식회사 자연사랑 무독성 생분해성 수용성 폴리에스테르 수지 제조 방법
JP2010520944A (ja) 2007-03-13 2010-06-17 エクソンモービル・ケミカル・パテンツ・インク バッチエステル化
DE102007031474A1 (de) * 2007-07-05 2009-01-08 Evonik Röhm Gmbh Verfahren zur Herstellung von Butandioldimethacrylaten
KR101044393B1 (ko) * 2007-12-27 2011-06-27 주식회사 엘지화학 지르코늄 화합물을 포함하는 에스테르화 촉매 조성물 및이를 이용한 에스테르 화합물의 제조방법
DE102008040221A1 (de) * 2008-07-07 2010-01-14 Evonik Röhm Gmbh Verfahren zur Herstellung von (Meth)acrylsäureestern
JP5326741B2 (ja) 2008-09-29 2013-10-30 東レ株式会社 ポリエステル重合触媒およびそれを用いるポリエステルの製造方法
EP2287225A1 (en) 2009-08-20 2011-02-23 Saudi Basic Industries Corporation Process for making polyethylene terephthalate
US8933162B2 (en) 2011-07-15 2015-01-13 Saudi Basic Industries Corporation Color-stabilized biodegradable aliphatic-aromatic copolyesters, methods of manufacture, and articles thereof
US9334360B2 (en) 2011-07-15 2016-05-10 Sabic Global Technologies B.V. Color-stabilized biodegradable aliphatic-aromatic copolyesters, methods of manufacture, and articles thereof
US8877862B2 (en) 2011-07-15 2014-11-04 Saudi Basic Industries Corporation Method for color stabilization of poly(butylene-co-adipate terephthalate
US8946345B2 (en) 2011-08-30 2015-02-03 Saudi Basic Industries Corporation Method for the preparation of (polybutylene-co-adipate terephthalate) through the in situ phosphorus containing titanium based catalyst
US8969506B2 (en) 2012-02-15 2015-03-03 Saudi Basic Industries Corporation Amorphous, high glass transition temperature copolyester compositions, methods of manufacture, and articles thereof
US8889820B2 (en) 2012-02-15 2014-11-18 Saudi Basic Industries Corporation Amorphous, high glass transition temperature copolyester compositions, methods of manufacture, and articles thereof
US8901273B2 (en) 2012-02-15 2014-12-02 Saudi Basic Industries Corporation Amorphous, high glass transition temperature copolyester compositions, methods of manufacture, and articles thereof
US8895660B2 (en) 2012-03-01 2014-11-25 Saudi Basic Industries Corporation Poly(butylene-co-adipate terephthalate), method of manufacture, and uses thereof
US9034983B2 (en) 2012-03-01 2015-05-19 Saudi Basic Industries Corporation Poly(butylene-co-adipate terephthalate), method of manufacture and uses thereof
US8901243B2 (en) 2012-03-30 2014-12-02 Saudi Basic Industries Corporation Biodegradable aliphatic-aromatic copolyesters, methods of manufacture, and articles thereof
ES2599165T3 (es) * 2012-10-29 2017-01-31 Uhde Inventa-Fischer Gmbh Procedimiento para la preparación de un poliéster o un copoliéster de alto peso molecular así como mezclas poliméricas que los contienen
LT2765149T (lt) * 2013-02-06 2019-03-12 Uhde Inventa-Fischer Gmbh Katalizatoriaus, kurio sudėtyje yra titano, gamybos būdas, katalizatorius, kurio sudėtyje yra titano, poliesterio gamybos būdas ir poliesteris
TWI466863B (zh) * 2013-03-21 2015-01-01 Chang Chun Plastics Co Ltd 對苯二甲酸二(2-乙基己酯)之製造方法
CN105237393B (zh) * 2015-09-06 2017-06-30 浙江皇马科技股份有限公司 一种癸二酸脂肪醇酯的制备方法
EP3687969B1 (en) * 2017-09-26 2023-08-02 Public Joint Stock Company "Sibur Holding" Method of preparing esters of terephthalic acid
TWI670291B (zh) * 2018-08-02 2019-09-01 遠東新世紀股份有限公司 低黏度聚酯多元醇的製法
CN111087583B (zh) * 2018-10-23 2022-11-04 中国石油化工股份有限公司 低端羧基pbt树脂的制备方法
EP3882295A4 (en) 2018-11-15 2021-12-15 Dalian Institute Of Chemical Physics, Chinese Academy Of Sciences PROCESS FOR PREPARING A POLYESTER POLYOL

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3056818A (en) * 1955-10-13 1962-10-02 Goodrich Co B F Titanium and zirconium esterification catalysts
GB811425A (en) * 1955-10-31 1959-04-08 Nat Lead Co Organic titanium complex and method of making same
US3047515A (en) * 1956-07-09 1962-07-31 Goodyear Tire & Rubber Preparation of polyesters using titanium-containing catalysts
DE1142868B (de) * 1960-08-23 1963-01-31 Wachker Chemie G M B H Verfahren zur diskontinuierlichen oder kontinuierlichen Herstellung von Carbonsaeureestern
CH398538A (de) * 1960-08-23 1966-03-15 Wacker Chemie Gmbh Verfahren zur Herstellung von Estern
GB991020A (en) * 1960-11-29 1965-05-05 Martin Marietta Corp Esterification of iso- and terephthalic acids
GB970431A (es) * 1961-02-04 1900-01-01
JPS5133890B2 (es) * 1971-09-10 1976-09-22
GB1514361A (en) * 1976-03-13 1978-06-14 Tioxide Group Ltd Titanium chelates
JPS5398393A (en) * 1977-02-09 1978-08-28 Teijin Ltd Production of polyester
DD144674A1 (de) * 1979-06-28 1980-10-29 Rema S Barshtein Verfahren zur herstellung der polyestern
JPS59157058A (ja) * 1983-02-28 1984-09-06 Ueno Seiyaku Oyo Kenkyusho:Kk 芳香族ヒドロキシカルボン酸ベンジルエステル類の製造法
US4452969A (en) * 1983-06-09 1984-06-05 General Electric Company Poly(alkylene dicarboxylate) process and catalysts for use therein
US4780527A (en) * 1987-05-06 1988-10-25 Industrial Technology Research Institute Preparation of polyesters from terephthalic acid
GB8717667D0 (en) * 1987-07-25 1987-09-03 Tioxide Group Plc Titanium compounds
EP0397653B1 (en) * 1987-09-29 1994-07-13 BUCKNELL, John Wentworth Force applicators
JP3341430B2 (ja) * 1994-01-07 2002-11-05 三菱化学株式会社 チタン触媒組成液

Also Published As

Publication number Publication date
PL320469A1 (en) 1997-12-22
EP1120392A1 (en) 2001-08-01
CZ176297A3 (cs) 1998-05-13
AU2363597A (en) 1997-12-18
DE69707757T2 (de) 2002-04-25
HUP9701024A3 (en) 2000-03-28
TR199700487A2 (xx) 1997-12-21
EP1120392B1 (en) 2003-11-12
US5866710A (en) 1999-02-02
AR007540A1 (es) 1999-11-10
HUP9701024A2 (hu) 1998-03-02
KR980001982A (ko) 1998-03-30
RU2178783C2 (ru) 2002-01-27
TW349937B (en) 1999-01-11
JP4354541B2 (ja) 2009-10-28
EP0812818A1 (en) 1997-12-17
ATE254096T1 (de) 2003-11-15
NO972645D0 (no) 1997-06-09
CA2207111A1 (en) 1997-12-11
BR9703577A (pt) 1998-11-10
HU218143B (hu) 2000-06-28
ES2166505T3 (es) 2002-04-16
TR199700487A3 (tr) 1997-12-21
HU9701024D0 (en) 1997-08-28
NO307961B1 (no) 2000-06-26
KR100567476B1 (ko) 2006-12-01
DK0812818T3 (da) 2001-11-19
PT1120392E (pt) 2004-04-30
ES2211678T3 (es) 2004-07-16
CN1068864C (zh) 2001-07-25
PL194313B1 (pl) 2007-05-31
JPH1081646A (ja) 1998-03-31
MY115541A (en) 2003-07-31
EP0812818B1 (en) 2001-10-31
GB9612161D0 (en) 1996-08-14
DE69707757D1 (de) 2001-12-06
PT812818E (pt) 2002-02-28
DE69726200T2 (de) 2004-04-15
DE69726200D1 (de) 2003-12-18
ATE207866T1 (de) 2001-11-15
CN1169412A (zh) 1998-01-07
AU730131B2 (en) 2001-02-22
CO4810331A1 (es) 1999-06-30
NO972645L (no) 1997-12-12

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